CN109730081A - A kind of agriculture bactericide composition - Google Patents
A kind of agriculture bactericide composition Download PDFInfo
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- CN109730081A CN109730081A CN201910141480.6A CN201910141480A CN109730081A CN 109730081 A CN109730081 A CN 109730081A CN 201910141480 A CN201910141480 A CN 201910141480A CN 109730081 A CN109730081 A CN 109730081A
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- China
- Prior art keywords
- prochloraz
- polylysine
- epsilon
- bactericide
- bactericide composition
- Prior art date
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- 230000000844 anti-bacterial effect Effects 0.000 title claims abstract description 54
- 239000003899 bactericide agent Substances 0.000 title claims abstract description 48
- 239000000203 mixture Substances 0.000 title claims abstract description 21
- 108010039918 Polylysine Proteins 0.000 claims abstract description 45
- TVLSRXXIMLFWEO-UHFFFAOYSA-N prochloraz Chemical compound C1=CN=CN1C(=O)N(CCC)CCOC1=C(Cl)C=C(Cl)C=C1Cl TVLSRXXIMLFWEO-UHFFFAOYSA-N 0.000 claims abstract description 37
- 239000005820 Prochloraz Substances 0.000 claims abstract description 34
- 239000005784 Fluoxastrobin Substances 0.000 claims abstract description 26
- UFEODZBUAFNAEU-NLRVBDNBSA-N fluoxastrobin Chemical compound C=1C=CC=C(OC=2C(=C(OC=3C(=CC=CC=3)Cl)N=CN=2)F)C=1C(=N/OC)\C1=NOCCO1 UFEODZBUAFNAEU-NLRVBDNBSA-N 0.000 claims abstract description 26
- 150000003217 pyrazoles Chemical class 0.000 claims abstract description 24
- 239000004615 ingredient Substances 0.000 claims abstract description 20
- 239000000463 material Substances 0.000 claims description 8
- 239000000839 emulsion Substances 0.000 claims description 7
- 150000003839 salts Chemical class 0.000 claims description 6
- 239000003795 chemical substances by application Substances 0.000 claims description 4
- 239000000470 constituent Substances 0.000 claims description 4
- 239000002904 solvent Substances 0.000 claims description 4
- 239000004563 wettable powder Substances 0.000 claims description 4
- 239000003995 emulsifying agent Substances 0.000 claims description 3
- 239000000945 filler Substances 0.000 claims description 3
- 239000004530 micro-emulsion Substances 0.000 claims description 3
- 239000000375 suspending agent Substances 0.000 claims description 3
- 239000004562 water dispersible granule Substances 0.000 claims description 3
- 239000000080 wetting agent Substances 0.000 claims description 3
- 229910021380 Manganese Chloride Inorganic materials 0.000 claims description 2
- 229910052791 calcium Inorganic materials 0.000 claims description 2
- 229910052802 copper Inorganic materials 0.000 claims description 2
- OXBLHERUFWYNTN-UHFFFAOYSA-M copper(I) chloride Chemical compound [Cu]Cl OXBLHERUFWYNTN-UHFFFAOYSA-M 0.000 claims description 2
- 229910052742 iron Inorganic materials 0.000 claims description 2
- 229910052748 manganese Inorganic materials 0.000 claims description 2
- 239000011572 manganese Substances 0.000 claims description 2
- 229940099607 manganese chloride Drugs 0.000 claims description 2
- 239000011565 manganese chloride Substances 0.000 claims description 2
- OXOKTPUZOHPXSA-UHFFFAOYSA-L manganese(2+);n-propyl-n-[2-(2,4,6-trichlorophenoxy)ethyl]imidazole-1-carboxamide;dichloride Chemical group Cl[Mn]Cl.C1=CN=CN1C(=O)N(CCC)CCOC1=C(Cl)C=C(Cl)C=C1Cl.C1=CN=CN1C(=O)N(CCC)CCOC1=C(Cl)C=C(Cl)C=C1Cl.C1=CN=CN1C(=O)N(CCC)CCOC1=C(Cl)C=C(Cl)C=C1Cl.C1=CN=CN1C(=O)N(CCC)CCOC1=C(Cl)C=C(Cl)C=C1Cl OXOKTPUZOHPXSA-UHFFFAOYSA-L 0.000 claims description 2
- 229910052700 potassium Inorganic materials 0.000 claims description 2
- 229910052708 sodium Inorganic materials 0.000 claims description 2
- 229910052725 zinc Inorganic materials 0.000 claims description 2
- 239000006185 dispersion Substances 0.000 claims 1
- 239000000126 substance Substances 0.000 abstract description 21
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 abstract description 10
- 201000010099 disease Diseases 0.000 abstract description 8
- 244000052769 pathogen Species 0.000 abstract description 8
- 230000001954 sterilising effect Effects 0.000 abstract description 8
- 238000004659 sterilization and disinfection Methods 0.000 abstract description 8
- 230000001717 pathogenic effect Effects 0.000 abstract description 7
- 230000000694 effects Effects 0.000 abstract description 5
- 235000013305 food Nutrition 0.000 abstract description 3
- 239000000447 pesticide residue Substances 0.000 abstract description 3
- 230000002829 reductive effect Effects 0.000 abstract description 3
- 239000002689 soil Substances 0.000 abstract description 3
- 230000000855 fungicidal effect Effects 0.000 description 27
- 239000000417 fungicide Substances 0.000 description 27
- 238000002360 preparation method Methods 0.000 description 14
- 230000003449 preventive effect Effects 0.000 description 13
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 7
- 241000234295 Musa Species 0.000 description 7
- 235000018290 Musa x paradisiaca Nutrition 0.000 description 7
- 210000004027 cell Anatomy 0.000 description 7
- 241000209094 Oryza Species 0.000 description 6
- 235000007164 Oryza sativa Nutrition 0.000 description 6
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 6
- 235000009566 rice Nutrition 0.000 description 6
- 238000012360 testing method Methods 0.000 description 6
- 208000003351 Melanosis Diseases 0.000 description 5
- 239000005869 Pyraclostrobin Substances 0.000 description 5
- HZRSNVGNWUDEFX-UHFFFAOYSA-N pyraclostrobin Chemical compound COC(=O)N(OC)C1=CC=CC=C1COC1=NN(C=2C=CC(Cl)=CC=2)C=C1 HZRSNVGNWUDEFX-UHFFFAOYSA-N 0.000 description 5
- -1 Prochloraz copper Salt Chemical class 0.000 description 4
- KAESVJOAVNADME-UHFFFAOYSA-N Pyrrole Chemical compound C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 description 4
- 229940051841 polyoxyethylene ether Drugs 0.000 description 4
- 229920000056 polyoxyethylene ether Polymers 0.000 description 4
- 238000012545 processing Methods 0.000 description 4
- DMAXMXPDVWTIRV-UHFFFAOYSA-N 2-(2-phenylethyl)phenol Chemical compound OC1=CC=CC=C1CCC1=CC=CC=C1 DMAXMXPDVWTIRV-UHFFFAOYSA-N 0.000 description 3
- 241000196324 Embryophyta Species 0.000 description 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 3
- 229910019142 PO4 Inorganic materials 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 230000000845 anti-microbial effect Effects 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 238000013329 compounding Methods 0.000 description 3
- 239000002270 dispersing agent Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 3
- 239000010452 phosphate Substances 0.000 description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 239000005995 Aluminium silicate Substances 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 2
- 206010059866 Drug resistance Diseases 0.000 description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- 235000012211 aluminium silicate Nutrition 0.000 description 2
- 125000003368 amide group Chemical group 0.000 description 2
- 150000003851 azoles Chemical group 0.000 description 2
- 230000015556 catabolic process Effects 0.000 description 2
- 238000006731 degradation reaction Methods 0.000 description 2
- 239000008367 deionised water Substances 0.000 description 2
- 229910021641 deionized water Inorganic materials 0.000 description 2
- 239000000645 desinfectant Substances 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 239000012895 dilution Substances 0.000 description 2
- 238000010790 dilution Methods 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 229920000656 polylysine Polymers 0.000 description 2
- 210000001082 somatic cell Anatomy 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 230000002195 synergetic effect Effects 0.000 description 2
- 230000001225 therapeutic effect Effects 0.000 description 2
- 208000035240 Disease Resistance Diseases 0.000 description 1
- 241000192125 Firmicutes Species 0.000 description 1
- 229920001732 Lignosulfonate Polymers 0.000 description 1
- KDXKERNSBIXSRK-UHFFFAOYSA-N Lysine Natural products NCCCCC(N)C(O)=O KDXKERNSBIXSRK-UHFFFAOYSA-N 0.000 description 1
- 239000004472 Lysine Substances 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 231100000674 Phytotoxicity Toxicity 0.000 description 1
- 241000235342 Saccharomycetes Species 0.000 description 1
- 206010039509 Scab Diseases 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 230000002159 abnormal effect Effects 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 238000012271 agricultural production Methods 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 150000008051 alkyl sulfates Chemical class 0.000 description 1
- 150000008052 alkyl sulfonates Chemical class 0.000 description 1
- WMGSQTMJHBYJMQ-UHFFFAOYSA-N aluminum;magnesium;silicate Chemical compound [Mg+2].[Al+3].[O-][Si]([O-])([O-])[O-] WMGSQTMJHBYJMQ-UHFFFAOYSA-N 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- SRSXLGNVWSONIS-UHFFFAOYSA-M benzenesulfonate Chemical compound [O-]S(=O)(=O)C1=CC=CC=C1 SRSXLGNVWSONIS-UHFFFAOYSA-M 0.000 description 1
- 229940077388 benzenesulfonate Drugs 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 210000000481 breast Anatomy 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 230000030833 cell death Effects 0.000 description 1
- 210000000170 cell membrane Anatomy 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 230000000295 complement effect Effects 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 230000004345 fruit ripening Effects 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 230000003834 intracellular effect Effects 0.000 description 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 1
- 230000002147 killing effect Effects 0.000 description 1
- 125000003588 lysine group Chemical group [H]N([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])(N([H])[H])C(*)=O 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 230000004060 metabolic process Effects 0.000 description 1
- 230000003641 microbiacidal effect Effects 0.000 description 1
- 239000002068 microbial inoculum Substances 0.000 description 1
- 229940124561 microbicide Drugs 0.000 description 1
- 239000002855 microbicide agent Substances 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- PSZYNBSKGUBXEH-UHFFFAOYSA-M naphthalene-1-sulfonate Chemical compound C1=CC=C2C(S(=O)(=O)[O-])=CC=CC2=C1 PSZYNBSKGUBXEH-UHFFFAOYSA-M 0.000 description 1
- 235000016709 nutrition Nutrition 0.000 description 1
- 230000035764 nutrition Effects 0.000 description 1
- 239000000575 pesticide Substances 0.000 description 1
- 230000008635 plant growth Effects 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920001184 polypeptide Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 108090000765 processed proteins & peptides Proteins 0.000 description 1
- 102000004196 processed proteins & peptides Human genes 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- MZSDGDXXBZSFTG-UHFFFAOYSA-M sodium;benzenesulfonate Chemical compound [Na+].[O-]S(=O)(=O)C1=CC=CC=C1 MZSDGDXXBZSFTG-UHFFFAOYSA-M 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a kind of agriculture bactericide compositions, by the way that biological bactericide and chemical bactericide are combined, based on biological bactericide epsilon-polylysine, supplemented by chemical bactericide pyrazoles Fluoxastrobin and Prochloraz, three kinds of ingredient synergy have broad-spectrum sterilization effect, the pathogen for leading to soil-borne disease in soil can be killed or cause the pathogen of crop Common Diseases, chemical bactericide dosage can be substantially reduced, pesticide residue, the demand of more agricultural food safety are reduced.
Description
Technical field
The present invention relates to disinfectant use in agriculture, especially a kind of sterilization containing epsilon-polylysine, pyrazoles Fluoxastrobin and Prochloraz
Composition.
Background technique
Plant disease is always one of the important restriction factor of crops good quality and high output.It is estimated that global staple crops
Because average loss accounts for about the 10%~15% of total output caused by by invading pathogens, annual direct economic loss is up to hundreds billion of
Dollar.
Agricultural is that fungicide usage amount is maximum, and kind used is most, a most wide field of use scope.Disinfectant use in agriculture
Referring to play pathogen inhibits the substance of perhaps killing effect to have kill germ spore, mycelium or inhibit it to develop, is raw
Long effect.However, the fungicide applied in current agricultural production is mainly chemical classes medicament, easily biological-degradable, is not remained easily,
Long-time service easily causes environmental pollution, and food-safe constitutes a threat to.Ideal fungicide should have high efficiency, Gao Xuan
Selecting property, it is environmentally friendly, to plant without phytotoxicity and the disease resistance of plant can be improved, do not put aside in people, animal body.In recent years,
It is more and more to the research of biological source bactericide.Biological bactericide have additive amount is few, use cost is low, bactericidal effect is obvious,
The advantages that harmless to the human body, no pollution to the environment.
Epsilon-polylysine (ε-Polylysine) is that a kind of Microbe synthesis by 25~45 lysine residues passes through α-
Hydroxyl and epsilon-amino form amido bond and the lysine polymers that connect into.The antimicrobial spectrum of epsilon-polylysine is very wide, to gram
Positive bacteria, Gram-negative bacteria, saccharomycete, mould etc. have good inhibiting effect.Its dominant mechanism be epsilon-polylysine with
Somatic cells film combines, and forms hole on film, destroys the membrane structure of microorganism, and a small amount of intracellular molten beyond the region of objective existence is caused to be let out,
But cell quality remains unchanged, and still survives.Then epsilon-polylysine continue with somatic cells act on, by the duct on film into
Enter cell, and then influence the structure and function of cell membrane, destroys the normal physiological metabolism of bacterium, cause substance, the energy of cell
It with the transmitting of information, has an effect with cell interior substance, destroys cell core, eventually lead to cell death.Polylysine is
A kind of abnormal shape polypeptide, can finally be degraded to lysine salt, slowly provide nutrition for plant growth.
Although biological bactericide has environmental-friendly advantage, however, being tended to out when biological bactericide is used alone
The problems such as existing fungicide degradation is fast, and sterilization is not thorough.And traditional chemical bactericide group, although sterilization effectiveness is high, action time
Persistently, but there is not easily biological-degradable, contaminated soil environment, and be easy the disadvantages of making pathogen develop drug resistance.Therefore, raw
It is the effective way to solve the above problems that object fungicide and chemical bactericide, which are applied in combination,.
Summary of the invention
The technical problem to be solved by the present invention is to easily remain for existing chemical bactericide, biological bactericide it is degradable
Problem provides a kind of combined bactericide comprising biological bactericide and chemical bactericide, specially a kind of to contain epsilon-polylysine, pyrrole
The bactericidal composition of azoles Fluoxastrobin and Prochloraz significantly improves sterilization effectiveness, effectively extends the degradation time of biological bactericide, subtracts
The usage amount of few chemical bactericide, and be not easy that pathogen is made to form drug resistance.
In order to solve the above-mentioned technical problem, the invention discloses a kind of agriculture bactericide composition, its active constituent packets
Containing epsilon-polylysine, pyrazoles Fluoxastrobin and Prochloraz, weight ratio is (0.5~10): (0.2~2): (0.2~2).
Wherein, biological bactericide epsilon-polylysine plays a leading role, and chemical bactericide pyrazoles Fluoxastrobin and Prochloraz are auxiliary
Effect is helped, three kinds of ingredient synergy can substantially reduce chemical bactericide dosage, reduce pesticide residue.
Preferably, the average molecular weight of the epsilon-polylysine is 3500-4500Da.
The epsilon-polylysine can with epsilon-polylysine salt replace, the epsilon-polylysine salt be chelated Na, K,
One of Ca, Mn, Cu, Zn, Fe or multiple element form epsilon-polylysine salt.
The Prochloraz can be replaced with Prochloraz salt, and the Prochloraz salt is prochloraz-manganese chloride complex or Prochloraz copper
Salt.
Further, which is made of active constituent and auxiliary material, and different application agent can be made
Type, including but not limited to microemulsion, aqueous emulsion, suspending agent, wettable powder or water dispersible granules.
Wherein, the active component content is 10~95wt%, remaining is that remaining ingredient is auxiliary material.
The auxiliary material includes one or more of filler, dispersing agent, emulsifier, wetting agent, solvent.
The dispersing agent includes one of NNO, lignosulfonates, naphthalene sulfonate and polymeric carboxylic salt or a variety of
Combination；The emulsifier includes phenethyl phenol polyethenoxy ether phosphate, nonylphenol polyoxyethylene ether, Nongru-700 # and agriculture breast
One of 2201 or a variety of combinations；The wetting agent includes alkylphenol polyoxyethylene ether formaldehyde condensate sulfate, alkane
Base phenol polyethenoxy base ether phosphate, alkylsulfonate, alkyl sulfate and to methoxyl group fatty acid amido benzene sulfonate etc. change
Close one of object or a variety of combinations；The filler includes one of bentonite, kaolin, aluminium-magnesium silicate and water or a variety of
Combination；The solvent includes dimethylbenzene, one of solvent naphtha and toluene or a variety of combinations.The main function of auxiliary material is
Bactericidal composition of the present invention can be assisted to be made different application forms, including microemulsion, aqueous emulsion, suspending agent, can
Wet powder or water dispersible granules.Therefore, auxiliary material of the present invention is not limited only to mentioned kind, is not departing from present inventive concept
In the case where, the sterilization of other complementary ingredients and epsilon-polylysine of the present invention, pyrazoles Fluoxastrobin and Prochloraz composition
Composition is also included within the scope of the present invention.
The utility model has the advantages that
Microbicide compositions of the present invention are by the way that biological bactericide and chemical bactericide to be combined, with biological bactericide ε-
Based on polylysine, supplemented by chemical bactericide pyrazoles Fluoxastrobin and Prochloraz, three kinds of ingredient synergy have broad-spectrum sterilization effect
It answers, the pathogen for leading to soil-borne disease in soil can be killed or causes the pathogen of crop Common Diseases, it can substantially reducing
Fungicide dosage is learned, pesticide residue, the demand of more agricultural food safety are reduced.
Specific embodiment
According to following embodiments, the present invention may be better understood.
Embodiment 1:
A kind of bactericidal composition wettable powder containing epsilon-polylysine, pyrazoles Fluoxastrobin and Prochloraz.
By epsilon-polylysine 4.5g, pyraclostrobin 0.5g, Prochloraz 0.2g, to methoxyl group fatty acid amido benzene sulfonic acid sodium salt
0.2g, dispersing agent NNO 0.4g, kaolin add to 10 grams, are sufficiently mixed uniformly and high speed crushes, wettable powder is made.
Embodiment 2:
A kind of bactericidal composition aqueous emulsion containing epsilon-polylysine, pyrazoles Fluoxastrobin and Prochloraz.
By epsilon-polylysine 2.5g, pyraclostrobin 0.2g, Prochloraz 0.8g, phenethyl phenol polyethenoxy ether phosphate
0.2g, nonylphenol polyoxyethylene ether 0.2g, propylene glycol 0.6g, deionized water are mended to 10g, are stirred evenly using high-shear homogenizer,
Aqueous emulsion is made.
Embodiment 3:
A kind of bactericidal composition aqueous emulsion containing epsilon-polylysine, pyrazoles Fluoxastrobin and Prochloraz.
By the sodium salt 5g of epsilon-polylysine, pyraclostrobin 1g, prochloraz nantokite 1g, phenethyl phenol polyethenoxy ether phosphoric acid
Ester 0.2g, nonylphenol polyoxyethylene ether 0.2g, propylene glycol 0.6g, deionized water are mended to 10g, are stirred using high-shear homogenizer equal
It is even, aqueous emulsion is made.
Embodiment 4:
Combined bactericide tests the preventive effect of banana freckle:
Different fungicide is prepared by following scheme:
Fungicide 1: epsilon-polylysine 5.2g, remaining adjunct ingredient and preparation type are the same as embodiment 1；
Fungicide 2: pyraclostrobin 5.2g, remaining adjunct ingredient and preparation type are the same as embodiment 1；
Fungicide 3: Prochloraz 5.2g, remaining adjunct ingredient and preparation type are the same as embodiment 1；
Fungicide 4: epsilon-polylysine 4.7g, pyrazoles Fluoxastrobin 0.5g, remaining adjunct ingredient and the same embodiment of preparation type
1；
Fungicide 5: epsilon-polylysine 5.0g, Prochloraz 0.2g, remaining adjunct ingredient and preparation type are the same as embodiment 1；
Fungicide 6: pyrazoles Fluoxastrobin 5.0g, Prochloraz 0.2g, remaining adjunct ingredient and preparation type are the same as embodiment 1；
Fungicide 7: pyrazoles Fluoxastrobin 0.5g, Prochloraz 4.7g, remaining adjunct ingredient and preparation type are the same as embodiment 1；
Fungicide 8: the combined bactericide prepared by embodiment 1.
This test selection carries out in the more serious banana garden of banana freckle over the years.Test sets 9 processing, each place
Manage 3 repetitions, zone leader 10m, wide 5m, plot area 50m2, cell surrounding setting protection row will according to 80g/ mus of dosage
After 2000 times of dilution agent of sterilization, is imposed on by the way of spraying on test Banana tree, apply, examine before taking out flower bud within 10 days before fruit maturation
Preventive effect is examined, the results are shown in Table 1.
The different fungicide of table 1 handle the influence to banana freckle disease incidence
As shown in Table 1, the epsilon-polylysine of single component, pyrazoles Fluoxastrobin, Prochloraz can generate banana freckle
Preventive and therapeutic effect, but compared with chemical bactericide, biological bactericide epsilon-polylysine preventive effect is relatively poor, and pyrazoles Fluoxastrobin is being prevented and treated
Preventive effect is optimal on scab；And after epsilon-polylysine is compounded with pyrazoles Fluoxastrobin, Prochloraz any one, preventive effect significantly increases,
And it is better than the compounding of two kinds of chemical bactericides, this shows that pyrazoles Fluoxastrobin or Prochloraz have synergistic work to epsilon-polylysine
With.When three kinds of epsilon-polylysine, pyrazoles Fluoxastrobin, Prochloraz antimicrobial combinations are in use, preventive effect reaches highest, with control group phase
Than banana freckle disease incidence reduces 24.2%, and disease incidence is only 1.3%.The combination of three kinds of fungicide, greatly reducing
Learn the usage amount of fungicide.
Embodiment 5:
Preventive effect of the combined bactericide to rice blast:
Different fungicide is prepared by following scheme:
Fungicide 1: epsilon-polylysine 3.5g, remaining adjunct ingredient and preparation type are the same as embodiment 2；
Fungicide 2: pyraclostrobin 3.5g, remaining adjunct ingredient and preparation type are the same as embodiment 2；
Fungicide 3: Prochloraz 3.5g, remaining adjunct ingredient and preparation type are the same as embodiment 2；
Fungicide 4: epsilon-polylysine 3.3g, pyrazoles Fluoxastrobin 0.2g, remaining adjunct ingredient and the same embodiment of preparation type
2；
Fungicide 5: epsilon-polylysine 2.7g, Prochloraz 0.8g, remaining adjunct ingredient and preparation type are the same as embodiment 2；
Fungicide 6: pyrazoles Fluoxastrobin 0.2g, Prochloraz 3.3g, remaining adjunct ingredient and preparation type are the same as embodiment 2；
Fungicide 7: pyrazoles Fluoxastrobin 2.7g, Prochloraz 0.8g, remaining adjunct ingredient and preparation type are the same as embodiment 2；
Fungicide 8: the combined bactericide prepared by embodiment 2.
This test selection carries out in the more serious plantation plot of rice blast.Test sets 9 processing, each processing
3 repetitions, zone leader 8m, wide 3m, plot area 24m2, the setting of cell surrounding, which is protected, goes, and according to 80g/ mus of dosage, will sterilize
After 2000 times of dilution agent, rice field, tillering stage application are imposed on by the way of spraying, the pustulation period investigates preventive effect, the results are shown in Table 2.
Respectively influence of the processing to rice blast disease incidence of table 2
As shown in Table 2, the epsilon-polylysine of single component, pyrazoles Fluoxastrobin, Prochloraz can generate rice blast
Preventive and therapeutic effect, but compared with chemical bactericide, biological bactericide epsilon-polylysine preventive effect is relatively poor, and epsilon-polylysine and pyrrole
After azoles Fluoxastrobin, Prochloraz any one compounding, preventive effect is significantly increased, and is better than the compounding of two kinds of chemical bactericides, this shows
Pyrazoles Fluoxastrobin or Prochloraz have synergistic function to epsilon-polylysine.When epsilon-polylysine, pyrazoles Fluoxastrobin, Prochloraz three
Kind antimicrobial combination is in use, preventive effect reaches highest, and compared with the control group, rice blast disease incidence reduces 62.4%.Three kinds are killed
The combination of microbial inoculum, greatly reduces the usage amount of chemical bactericide, and then reduces residual of the pesticide in crop, is more advantageous to
Safeguard food safety.
The present invention provides a kind of thinking of agriculture bactericide composition and method, the method for implementing the technical solution
It is many with approach, the above is only a preferred embodiment of the present invention, it is noted that for the ordinary skill of the art
For personnel, various improvements and modifications may be made without departing from the principle of the present invention, these improvements and modifications
It should be regarded as protection scope of the present invention.All undefined components in this embodiment can be implemented in the prior art.
Claims (7)
1. a kind of agriculture bactericide composition, which is characterized in that its active constituent include epsilon-polylysine, pyrazoles Fluoxastrobin and
Prochloraz, weight ratio are (0.5~10): (0.2~2): (0.2~2).
2. agriculture bactericide composition according to claim 1, which is characterized in that the mean molecule of the epsilon-polylysine
Amount is 3500-4500Da.
3. agriculture bactericide composition according to claim 1 or 2, which is characterized in that the epsilon-polylysine is poly- with ε-
Lysine salt replacement, the epsilon-polylysine salt are to have chelated one of Na, K, Ca, Mn, Cu, Zn, Fe or multiple element
Form epsilon-polylysine salt.
4. agriculture bactericide composition according to claim 1, which is characterized in that the Prochloraz is replaced with Prochloraz salt
It changes, the Prochloraz salt is prochloraz-manganese chloride complex or prochloraz nantokite.
5. agriculture bactericide composition according to claim 1, which is characterized in that it is made of active constituent and auxiliary material,
Different application forms, including microemulsion, aqueous emulsion, suspending agent, wettable powder or water dispersible granules can be made.
6. agriculture bactericide composition according to claim 5, which is characterized in that the active component content be 10~
95wt%, remaining is that remaining ingredient is auxiliary material.
7. agriculture bactericide composition according to claim 5 or 6, which is characterized in that the auxiliary material includes filler, dispersion
One or more of agent, emulsifier, wetting agent, solvent.
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Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101151023A (en) * | 2005-01-27 | 2008-03-26 | 弗拉梅技术公司 | Copolyhydroxyalkylglutamines which are functionalised with hydrophobic groups and applications thereof, such as in therapeutics |
| CN101524082A (en) * | 2009-04-28 | 2009-09-09 | 北京燕化永乐农药有限公司 | Pyraclostrobin and prochloraz pesticide mixture |
| CN102273454A (en) * | 2011-08-25 | 2011-12-14 | 浙江东奇生物科技有限公司 | Application of epsilon-poly-l-lysine to control of mould disease of crops |
| CN102783496A (en) * | 2012-09-07 | 2012-11-21 | 浙江农林大学 | Composite bactericide comprising prochloraz and use thereof |
| CN104798801A (en) * | 2015-04-22 | 2015-07-29 | 陕西省蒲城美尔果农化有限责任公司 | Aqueous emulsion-fungicide composition containing pyraclostrobin and prochloraz and preparation method of aqueous emulsion-fungicide composition |
| CN105532663A (en) * | 2016-02-22 | 2016-05-04 | 西北农林科技大学 | Biological agent for controlling gray molds by being sprayed on flowers |
-
2019
- 2019-02-26 CN CN201910141480.6A patent/CN109730081A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101151023A (en) * | 2005-01-27 | 2008-03-26 | 弗拉梅技术公司 | Copolyhydroxyalkylglutamines which are functionalised with hydrophobic groups and applications thereof, such as in therapeutics |
| CN101524082A (en) * | 2009-04-28 | 2009-09-09 | 北京燕化永乐农药有限公司 | Pyraclostrobin and prochloraz pesticide mixture |
| CN102273454A (en) * | 2011-08-25 | 2011-12-14 | 浙江东奇生物科技有限公司 | Application of epsilon-poly-l-lysine to control of mould disease of crops |
| CN102783496A (en) * | 2012-09-07 | 2012-11-21 | 浙江农林大学 | Composite bactericide comprising prochloraz and use thereof |
| CN104798801A (en) * | 2015-04-22 | 2015-07-29 | 陕西省蒲城美尔果农化有限责任公司 | Aqueous emulsion-fungicide composition containing pyraclostrobin and prochloraz and preparation method of aqueous emulsion-fungicide composition |
| CN105532663A (en) * | 2016-02-22 | 2016-05-04 | 西北农林科技大学 | Biological agent for controlling gray molds by being sprayed on flowers |
Non-Patent Citations (3)
| Title |
|---|
| 翟宏伟: "9%吡唑醚菌酯悬浮剂（稻清）防治水稻稻瘟病田间药效试验报告", 《北方水稻》 * |
| 陈金雄: "250 g/L吡唑醚菌酯悬浮剂不同剂量防治香蕉黑星病的田间药效试验", 《中国热带农业》 * |
| 龚伟 等: "7种杀菌剂对稻瘟病的田间防效研究", 《现代农业科技》 * |
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