CN109728178A - Organic electroluminescent device, array substrate and preparation method thereof and display panel - Google Patents

Organic electroluminescent device, array substrate and preparation method thereof and display panel Download PDF

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CN109728178A
CN109728178A CN201910002418.9A CN201910002418A CN109728178A CN 109728178 A CN109728178 A CN 109728178A CN 201910002418 A CN201910002418 A CN 201910002418A CN 109728178 A CN109728178 A CN 109728178A
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organic electroluminescent
electroluminescent device
electrode
light emitting
functional layer
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CN109728178B (en
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张娟
王路
焦志强
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BOE Technology Group Co Ltd
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BOE Technology Group Co Ltd
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Abstract

The present invention provides a kind of organic electroluminescent device, array substrate and preparation method thereof and display panel.The organic electroluminescent device includes first electrode, light emitting functional layer and second electrode, and light emitting functional layer is located between first electrode and second electrode, and light emitting functional layer is Curved plate structure.The organic electroluminescent device of the organic electroluminescent device relative to the planar panel structure light emitting functional layer with same big lighting area, the light-emitting area of organic electroluminescent device can be expanded, so that it is guaranteed that in the case where organic electroluminescent device light emission luminance is constant, the voltage of organic electroluminescent device load with Curved plate structure light emitting functional layer is significantly lower than the voltage that the organic electroluminescent device with planar panel structure light emitting functional layer loads, thereby reduce the heat radiation of organic electroluminescent device, improve temperature it is higher caused by exciton Quenching, the rate of ageing of exciton is slowed down, ultimately improve the service life of organic electroluminescent device.

Description

Organic electroluminescent device, array substrate and preparation method thereof and display panel
Technical field
The present invention relates to field of display technology, and in particular, to a kind of organic electroluminescent device, array substrate and its system Preparation Method and display panel.
Background technique
OLED (Organic Light-Emitting Diode, OLED) display panel is because contrast is high, colour gamut is wide, response The advantages that speed is fast, flexible, is applied to intelligent display terminal more and more, becomes next-generation display technology.
OLED display panel generally includes RGB (red, green, blue) three-colour light-emitting element, in the case where providing equivalent voltage, The heat radiation of blue light emitting device is higher, and exciton Quenching of the blue light emitting device when lighting is more serious, leads to blue The service life of light-emitting component is shorter, shorter so as to cause the service life of OLED display panel.
Summary of the invention
The present invention is directed to the above-mentioned technical problems in the prior art, provides a kind of organic electroluminescent device, array Substrate and preparation method thereof and display panel.The organic electroluminescent device is relative to the surface plate with same big lighting area The organic electroluminescent device of structure light emitting functional layer, can expand the light-emitting area of organic electroluminescent device, thus really It protects in the case where organic electroluminescent device light emission luminance is constant, the organic electroluminescence with Curved plate structure light emitting functional layer is sent out The voltage of optical element load is significantly lower than the electricity that the organic electroluminescent device with planar panel structure light emitting functional layer loads Pressure, thereby reduce the heat radiation of organic electroluminescent device, improve temperature it is higher caused by exciton Quenching, The rate of ageing for having slowed down exciton ultimately improves the service life of organic electroluminescent device.
The present invention provides a kind of organic electroluminescent device, including first electrode, light emitting functional layer and second electrode, described Light emitting functional layer is located between the first electrode and the second electrode, and the light emitting functional layer is Curved plate structure.
Preferably, the light emitting functional layer is cambered plate, and side is recessed where the cambered plate to the first electrode, described First electrode and the second electrode are the cambered plate to match with the light emitting functional layer.
Preferably, the light emitting functional layer is cambered plate, and side is recessed where the cambered plate to the second electrode, described First electrode and the second electrode are the cambered plate to match with the light emitting functional layer.
Preferably, the light emitting functional layer is wave-shape board, and the wave crest of the wave-shape board is identical with trough shape size, described First electrode and the second electrode are the wave-shape board to match with the light emitting functional layer.
The present invention also provides a kind of array substrate, the Organic Electricities of the different colours including substrate and setting on the substrate Electroluminescent element, the organic electroluminescent device are arranged in array, the organic electroluminescent device of at least the first color For above-mentioned organic electroluminescent device;
The organic electroluminescent device of first color is the constant condition of emitting brightness on same light-emitting surface Under, the on-load voltage of the organic electroluminescent device of first color is relatively the same as the planar panel structure light-emitting function of color The on-load voltage range of decrease of the organic electroluminescent device of layer is greater than the organic electroluminescent device of predetermined value.
Preferably, the organic electroluminescent device of different colours includes organic electroluminescence described in red, green and blue Light-emitting component;
The organic electroluminescent device of first color is the blue organic electroluminescent device, red and green The light emitting functional layer of organic electroluminescent device described in color is planar panel structure.
Preferably, resin layer is additionally provided on the substrate, the organic electroluminescent device is arranged in the resin layer On, the surface of the resin layer being in contact with the organic electroluminescent device and the shape of the organic electroluminescent device Match.
Preferably, the array substrate is top emission type or bottom emitting type array substrate.
The present invention also provides a kind of display panels, including above-mentioned array substrate.
The present invention also provides a kind of preparation methods of above-mentioned array substrate, form different colours including preparing on substrate Organic electroluminescent device.
Preferably, the preparation method includes preparing shape on the substrate using nano-imprint method or intermediate tone mask method At resin layer;
Then it prepares to form the organic electroluminescent device using vapour deposition method or solwution method.
Beneficial effects of the present invention: organic electroluminescent device provided by the present invention, by the way that organic electroluminescent is first The light emitting functional layer of part is set as Curved plate structure, relative to the planar panel structure light emitting functional layer with same big lighting area The organic electroluminescent device, the light-emitting area of organic electroluminescent device can be expanded, so that it is guaranteed that organic electroluminescence send out In the case that optical element light emission luminance is constant, the electricity of the organic electroluminescent device load with Curved plate structure light emitting functional layer Pressure has been thereby reduced significantly lower than the voltage that the organic electroluminescent device with planar panel structure light emitting functional layer loads The heat radiation of electro-luminescence element, improve temperature it is higher caused by exciton Quenching, slowed down the old of exciton Change rate, ultimately improves the service life of organic electroluminescent device.
Array substrate provided by the present invention, by the organic electroluminescent device at least making service life shorter the first color Using above-mentioned organic electroluminescent device, the on-load voltage of the organic electroluminescent device of the first color can be at least reduced, from And at least reduce the heat radiation of the organic electroluminescent device of the first color, improve the first color organic electroluminescent device by In the higher caused exciton Quenching of temperature, slow down the exciton rate of ageing of the organic electroluminescent device of the first color, And then improve the service life of the organic electroluminescent device of the first color, finally ensuring the constant situation of array substrate light emission luminance Under, improve the service life of array substrate.
Display panel provided by the present invention can ensure display panel display brightness by using above-mentioned array substrate In the case where constant, improve the service life of display panel.
Detailed description of the invention
Fig. 1 is the schematic structural cross-sectional view of existing OLED display panel;
Fig. 2 is the schematic structural cross-sectional view of organic electroluminescent device in the embodiment of the present invention 1;
Fig. 3 is that the light-emitting area of the light emitting functional layer of Curved plate structure is greater than shining for the light emitting functional layer of planar panel structure The schematic cross-sectional view of area;
Fig. 4 is the schematic structural cross-sectional view of organic electroluminescent device in the embodiment of the present invention 2;
Fig. 5 is the schematic structural cross-sectional view of organic electroluminescent device in the embodiment of the present invention 3;
Fig. 6 is the schematic structural cross-sectional view of top emission type array substrate in the embodiment of the present invention 4;
Fig. 7 is the schematic structural cross-sectional view of bottom emitting type array substrate in the embodiment of the present invention 4.
Description of symbols therein:
1. first electrode;2. light emitting functional layer;3. second electrode;4. substrate;5. the organic electroluminescent member of the first color Part;6. resin layer;7. pixel defining layer;8. anode;9. cathode;10. blue light emitting device;11. organic electroluminescent device Light-emitting surface;12. pixel circuit layer.
Specific embodiment
To make those skilled in the art more fully understand technical solution of the present invention, with reference to the accompanying drawing and it is embodied Mode makees into one a kind of organic electroluminescent device provided by the present invention, array substrate and preparation method thereof and display panel Step detailed description.
In existing OLED display panel, as shown in Figure 1, pixel circuit layer 12 is provided on substrate 4, pixel circuit layer 12 On be provided with pixel defining layer 7, pixel defining layer 7 is intersected in length and breadth defines multiple pixel regions, sets respectively in each pixel region It is equipped with RGB (red, green, blue) three-colour light-emitting element.Wherein, the anode 8 of RGB three-colour light-emitting element, light emitting functional layer 2 and cathode 9 It is planar panel structure.In the case where providing equivalent voltage to RGB three-colour light-emitting element, the heat radiation of blue light emitting device 10 It is higher, and exciton Quenching of the blue light emitting device 10 when lighting is more serious, cause the service life of blue light emitting device 10 compared with It is short, it is shorter so as to cause the service life of OLED display panel.
Embodiment 1:
The present embodiment provides a kind of organic electroluminescent devices, as shown in Fig. 2, including first electrode 1, light emitting functional layer 2 With second electrode 3, light emitting functional layer 2 is located between first electrode 1 and second electrode 3, and light emitting functional layer 2 is that curved surface is hardened Structure.
Wherein, light emitting functional layer 2 includes hole transmission layer, hole injection layer, luminescent layer, electron transfer layer, electron injection Layer.Each film layer for constituting light emitting functional layer 2 is Curved plate structure, and the Curved plate structure of each film layer matches, to constitute The light emitting functional layer 2 of Curved plate structure.Alternatively, light emitting functional layer 2 can also only include luminescent layer.First electrode 1 is organic The anode of electroluminescent cell, second electrode 3 are the cathode of organic electroluminescent device.
In the present embodiment, it is preferred that light emitting functional layer 2 is cambered plate, and cambered plate is recessed to 1 place side of first electrode, the One electrode 1 and second electrode 3 are the cambered plate to match with light emitting functional layer 2.
It should be noted that first electrode 1 and second electrode 3 can also be the face that is in contact with light emitting functional layer 2 with The shape of light emitting functional layer 2 matches.
As shown in figure 3, the light-emitting surface 11 for being equipped with electro-luminescence element is a plane, the orthographic projection on light-emitting surface 11 In the case where area equation (i.e. in the case where lighting area is equal), the light-emitting area of the light emitting functional layer 2 of Curved plate structure It is apparently higher than the light-emitting area of the light emitting functional layer 2 of planar panel structure.
It is same big relative to having by setting Curved plate structure for the light emitting functional layer 2 of organic electroluminescent device The organic electroluminescent device of the planar panel structure light emitting functional layer of lighting area, can expand organic electroluminescent device Light-emitting area, so that it is guaranteed that there is the luminous function of Curved plate structure in the case where organic electroluminescent device light emission luminance is constant The voltage of the organic electroluminescent device load of ergosphere 2 is significantly lower than the organic electroluminescence with planar panel structure light emitting functional layer The voltage of light-emitting component load, thereby reduces the heat radiation of organic electroluminescent device, improves and led since temperature is higher The exciton Quenching of cause, has slowed down the rate of ageing of exciton, ultimately improves the service life of organic electroluminescent device.
Embodiment 2:
The present embodiment provides a kind of organic electroluminescent devices, unlike embodiment 1, as shown in figure 4, the function that shines Ergosphere 2 is cambered plate, and cambered plate is recessed to 3 place side of second electrode, and first electrode 1 and second electrode 3 are and light-emitting function The cambered plate that layer 2 matches.
The other structures setting of organic electroluminescent device and the principle for improving the service life and phase in embodiment 1 in the present embodiment Together, details are not described herein again.
Embodiment 3:
The present embodiment provides a kind of organic electroluminescent devices, unlike embodiment 1-2, as shown in figure 5, the function that shines Ergosphere 2 is wave-shape board, and the wave crest of wave-shape board is identical with trough shape size, and first electrode 1 and second electrode 3 are and luminous function The wave-shape board that ergosphere 2 matches.
It should be noted that the wave crest of wave-shape board and trough can also with shape is identical and size is not identical.
The other structures setting of organic electroluminescent device and the principle for improving the service life and phase in embodiment 1 in the present embodiment Together, details are not described herein again.
Embodiment 1-3's the utility model has the advantages that organic electroluminescent device provided by embodiment 1-3, by by organic electroluminescence The light emitting functional layer of light-emitting component is set as Curved plate structure, and relative to having equally, the planar panel structure of lighting area shines greatly The organic electroluminescent device of functional layer, can expand the light-emitting area of organic electroluminescent device, so that it is guaranteed that organic In the case that electroluminescent cell light emission luminance is constant, the organic electroluminescent device with Curved plate structure light emitting functional layer adds The voltage of load is significantly lower than the voltage that the organic electroluminescent device with planar panel structure light emitting functional layer loads, and then drops The low heat radiation of organic electroluminescent device, improve temperature it is higher caused by exciton Quenching, slowed down and swashed The rate of ageing of son, ultimately improves the service life of organic electroluminescent device.
Embodiment 4:
The present embodiment provides a kind of array substrates, as shown in fig. 6, including substrate 4 and the different colours being arranged on substrate 4 Organic electroluminescent device, organic electroluminescent device is arranged in array, the organic electroluminescent device 5 of at least the first color For embodiment 1-3 it is any in organic electroluminescent device;The organic electroluminescent device 5 of first color is in same light-emitting surface Under conditions of upper emitting brightness is constant, the on-load voltage of the organic electroluminescent device 5 of the first color is relatively the same as the plane of color The on-load voltage range of decrease of the organic electroluminescent device of hardened structure light emitting functional layer is greater than the organic electroluminescent device of predetermined value.
In the present embodiment, the organic electroluminescent device 5 of the first color is the organic electroluminescent device in embodiment 1.
Wherein, criss-cross pixel defining layer 7 is provided on substrate 4, pixel defining layer 7 defines multiple pixel regions Domain is respectively arranged with the organic electroluminescent device of different colours in each pixel region.On-load voltage is organic electroluminescent member On-load voltage when part shines.Predetermined range are as follows: 2.5V~10V.The predetermined range indicates the organic electroluminescence of the first color Light-emitting component 5 is the organic electroluminescence hair for being easy to cause certain color compared with high-heating radiation in array substrate under same on-load voltage Optical element, i.e., the service life shortest organic electroluminescent device under same on-load voltage.
By at least make the organic electroluminescent device 5 of service life shorter the first color using embodiment 1-3 it is any in Organic electroluminescent device can at least reduce the on-load voltage of the organic electroluminescent device 5 of the first color, at least drop The heat radiation of the organic electroluminescent device 5 of low first color improves the organic electroluminescent device 5 of the first color due to temperature Exciton Quenching caused by higher, slows down the exciton rate of ageing of the organic electroluminescent device 5 of the first color, Jin Ergai The service life of the organic electroluminescent device 5 of shorter the first color of kind service life, the final service life for improving array substrate.
In the present embodiment, the organic electroluminescent device of different colours includes red, green and blue organic electroluminescent Element;The organic electroluminescent device 5 of first color is blue organic electroluminescent element, red and green organic electroluminescent The light emitting functional layer of element is planar panel structure.Since blue organic electroluminescent element is relative to red and green organic electroluminescence Light-emitting component is easier to lead to higher heat radiation under same on-load voltage, and is easier under higher heat radiation effect There is exciton Quenching, i.e., faster, the service life is shorter for the rate of ageing of blue organic electroluminescent element exciton, therefore, as long as Curved plate structure is set by the light emitting functional layer 2 of blue organic electroluminescent element in array substrate, can be improved well The service life of blue organic electroluminescent element, to be effectively improved the service life of array substrate.
In the present embodiment, resin layer 6 is additionally provided on substrate 4, organic electroluminescent device is arranged on resin layer 6, tree The surface of rouge layer 6 being in contact with organic electroluminescent device and the shape of organic electroluminescent device match.Resin layer 6 Shape setting is conducive to the preparation on resin layer 6 and forms the organic electroluminescent member that light emitting functional layer 2 is Curved plate structure Part.
In the present embodiment, array substrate is top emission type array substrate.Wherein, the first electrode of organic electroluminescent device 1 relative to second electrode 3 closer to substrate 4, first electrode 1 is made of light-proof material, to realize top emission type array Substrate.
It should be noted that array substrate may be bottom emitting type array substrate, as shown in fig. 7, organic electroluminescent The second electrode 3 relative to first electrode 1 far from substrate 4 of element is made of light-proof material, to realize bottom emitting type Array substrate.
It is further to note that the red and green organic electroluminescent device in array substrate also can be using real Apply a 1-3 it is any in organic electroluminescent device structure, so as to further improve red and green organic electroluminescent member The service life of part, and then can further improve the service life of array substrate.
In the present embodiment, the side away from organic electroluminescent device on substrate 4 in resin layer 6 is additionally provided with pixel electricity Road floor 12, pixel circuit layer 12 include TFT circuit and the pixel-driving circuits such as grid line and data line, and pixel circuit layer is existing There is setting, specifically repeats no more.
Above structure based on array substrate, the present embodiment also provide a kind of preparation method of array substrate, are included in Preparation forms the organic electroluminescent device of different colours on substrate.
The preparation method of the array substrate is specifically included to be prepared on substrate using nano-imprint method or intermediate tone mask method Form resin layer;Then it prepares to form organic electroluminescent device using vapour deposition method or solwution method.
Wherein, resin layer uses resin material, and nano-imprint method being capable of direct pressing formation surface and organic electroluminescent The resin layer that the shape of element matches, nano-imprint method are the preparation process of comparative maturity, and which is not described herein again.Halftoning is covered Embrane method be by using intermediate tone mask plate to coating formed resin layer basement membrane carry out halftone exposure, by exposure and it is subsequent Developing process prepares to form the resin layer that the shape on surface and organic electroluminescent device matches, and intermediate tone mask method is to compare Mature preparation process, which is not described herein again.
It includes successive using vapour deposition method or solwution method for being prepared using vapour deposition method or solwution method and forming organic electroluminescent device The step of preparation forms first electrode, light emitting functional layer and second electrode, vapour deposition method and solwution method are the preparation of comparative maturity Technique, which is not described herein again.
In addition, further including preparing to form pixel defining layer on the resin layer before preparation forms organic electroluminescent device The step of, pixel defining layer prepares to be formed using the patterning processes of comparative maturity, and details are not described herein again.
Embodiment 4 the utility model has the advantages that array substrate provided in embodiment 4, by least make the service life it is shorter first The organic electroluminescent device of color using embodiment 1-3 it is any in organic electroluminescent device, can at least reduce by first The on-load voltage of the organic electroluminescent device of color, at least reduce the hot spoke of the organic electroluminescent device of the first color Penetrate, improve the first color organic electroluminescent device temperature it is higher caused by exciton Quenching, slow down the first face The exciton rate of ageing of the organic electroluminescent device of color, and then improve the service life of the organic electroluminescent device of the first color, Finally in the case where ensuring that array substrate light emission luminance is constant, improve the service life of array substrate.
Embodiment 5:
The present embodiment provides a kind of display panels, including the array substrate in embodiment 4.
By using the array substrate in embodiment 4, can improve in the case where ensuring that display panel display brightness is constant The service life of display panel.
Display panel provided by the present invention can appoint for oled panel, OLED TV, display, mobile phone, navigator etc. What products or components having a display function, or the semi-finished articles of above-mentioned products or components having a display function.
It is understood that the principle that embodiment of above is intended to be merely illustrative of the present and the exemplary implementation that uses Mode, however the present invention is not limited thereto.For those skilled in the art, essence of the invention is not being departed from In the case where mind and essence, various changes and modifications can be made therein, these variations and modifications are also considered as protection scope of the present invention.

Claims (11)

1. a kind of organic electroluminescent device, including first electrode, light emitting functional layer and second electrode, the light emitting functional layer folder Between the first electrode and the second electrode, which is characterized in that the light emitting functional layer is Curved plate structure.
2. organic electroluminescent device according to claim 1, which is characterized in that the light emitting functional layer is cambered plate, Side is recessed where the cambered plate to the first electrode, and the first electrode and the second electrode are and the luminous function The cambered plate that ergosphere matches.
3. organic electroluminescent device according to claim 1, which is characterized in that the light emitting functional layer is cambered plate, Side is recessed where the cambered plate to the second electrode, and the first electrode and the second electrode are and the luminous function The cambered plate that ergosphere matches.
4. organic electroluminescent device according to claim 1, which is characterized in that the light emitting functional layer is wave-shape board, The wave crest of the wave-shape board is identical with trough shape size, and the first electrode and the second electrode are and the luminous function The wave-shape board that ergosphere matches.
5. a kind of array substrate, the organic electroluminescent device of the different colours including substrate and setting on the substrate, institute It states organic electroluminescent device to be arranged in array, which is characterized in that the organic electroluminescent device of at least the first color is Organic electroluminescent device described in claim 1-4 any one;
The organic electroluminescent device of first color is institute under conditions of emitting brightness is constant on same light-emitting surface The on-load voltage of the organic electroluminescent device of the first color is stated relatively with the planar panel structure light emitting functional layer of color The on-load voltage range of decrease of the organic electroluminescent device is greater than the organic electroluminescent device of predetermined value.
6. array substrate according to claim 5, which is characterized in that the organic electroluminescent device packet of different colours Include organic electroluminescent device described in red, green and blue;
The organic electroluminescent device of first color is the blue organic electroluminescent device, red and green institute The light emitting functional layer for stating organic electroluminescent device is planar panel structure.
7. array substrate according to claim 5 or 6, which is characterized in that resin layer is additionally provided on the substrate, it is described Organic electroluminescent device is arranged on the resin layer, and the resin layer is in contact with the organic electroluminescent device The shape of surface and the organic electroluminescent device matches.
8. array substrate according to claim 5, which is characterized in that the array substrate is top emission type or bottom emitting type Array substrate.
9. a kind of display panel, which is characterized in that including array substrate described in claim 5-8 any one.
10. a kind of preparation method of the array substrate as described in claim 5-8 any one, which is characterized in that be included in base Preparation forms the organic electroluminescent device of different colours on plate.
11. preparation method according to claim 10, which is characterized in that the array substrate is as claimed in claim 7 Array substrate, the preparation method include preparing to form resin on the substrate using nano-imprint method or intermediate tone mask method Layer;
Then it prepares to form the organic electroluminescent device using vapour deposition method or solwution method.
CN201910002418.9A 2019-01-02 2019-01-02 Organic electroluminescent element, array substrate, preparation method of array substrate and display panel Active CN109728178B (en)

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CN107799662A (en) * 2017-12-05 2018-03-13 京东方科技集团股份有限公司 Organic light emitting diode device and preparation method thereof, display panel, display device
CN108364989A (en) * 2018-02-26 2018-08-03 上海天马有机发光显示技术有限公司 Organic light emitting display panel and preparation method thereof, organic light-emitting display device
CN108538896A (en) * 2018-04-26 2018-09-14 武汉华星光电半导体显示技术有限公司 Oled pixel structure and oled display panel

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