CN109721941A - Base material for high-hardness air conditioner panel and preparation process thereof - Google Patents
Base material for high-hardness air conditioner panel and preparation process thereof Download PDFInfo
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- CN109721941A CN109721941A CN201811624547.3A CN201811624547A CN109721941A CN 109721941 A CN109721941 A CN 109721941A CN 201811624547 A CN201811624547 A CN 201811624547A CN 109721941 A CN109721941 A CN 109721941A
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- conditioning panel
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- 238000002360 preparation method Methods 0.000 title claims abstract description 12
- 239000000463 material Substances 0.000 title abstract description 13
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 claims abstract description 60
- 229920005989 resin Polymers 0.000 claims abstract description 55
- 239000011347 resin Substances 0.000 claims abstract description 55
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 46
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 46
- 239000012745 toughening agent Substances 0.000 claims abstract description 33
- 230000002195 synergetic effect Effects 0.000 claims abstract description 30
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 13
- 239000000314 lubricant Substances 0.000 claims abstract description 10
- 239000002270 dispersing agent Substances 0.000 claims abstract description 6
- 238000004378 air conditioning Methods 0.000 claims description 51
- 239000004417 polycarbonate Substances 0.000 claims description 47
- 229920000515 polycarbonate Polymers 0.000 claims description 42
- 239000000758 substrate Substances 0.000 claims description 41
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims description 26
- 239000002994 raw material Substances 0.000 claims description 19
- 239000000203 mixture Substances 0.000 claims description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 12
- XECAHXYUAAWDEL-UHFFFAOYSA-N acrylonitrile butadiene styrene Chemical compound C=CC=C.C=CC#N.C=CC1=CC=CC=C1 XECAHXYUAAWDEL-UHFFFAOYSA-N 0.000 claims description 11
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 claims description 11
- -1 polypropylene Polymers 0.000 claims description 11
- 239000006087 Silane Coupling Agent Substances 0.000 claims description 10
- DCXXMTOCNZCJGO-UHFFFAOYSA-N tristearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCCCCCCCC)COC(=O)CCCCCCCCCCCCCCCCC DCXXMTOCNZCJGO-UHFFFAOYSA-N 0.000 claims description 10
- 239000000945 filler Substances 0.000 claims description 9
- VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 claims description 8
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 8
- 229920002554 vinyl polymer Polymers 0.000 claims description 8
- 229920001897 terpolymer Polymers 0.000 claims description 7
- KGRVJHAUYBGFFP-UHFFFAOYSA-N 2,2'-Methylenebis(4-methyl-6-tert-butylphenol) Chemical compound CC(C)(C)C1=CC(C)=CC(CC=2C(=C(C=C(C)C=2)C(C)(C)C)O)=C1O KGRVJHAUYBGFFP-UHFFFAOYSA-N 0.000 claims description 6
- 239000004609 Impact Modifier Substances 0.000 claims description 6
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical group COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 6
- 150000001408 amides Chemical class 0.000 claims description 6
- 229920001577 copolymer Polymers 0.000 claims description 6
- 239000011258 core-shell material Substances 0.000 claims description 6
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 claims description 6
- 238000005516 engineering process Methods 0.000 claims description 6
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 6
- 238000005453 pelletization Methods 0.000 claims description 6
- ZQBAKBUEJOMQEX-UHFFFAOYSA-N phenyl salicylate Chemical compound OC1=CC=CC=C1C(=O)OC1=CC=CC=C1 ZQBAKBUEJOMQEX-UHFFFAOYSA-N 0.000 claims description 6
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 4
- 229920000049 Carbon (fiber) Polymers 0.000 claims description 4
- 239000004743 Polypropylene Substances 0.000 claims description 4
- 239000006096 absorbing agent Substances 0.000 claims description 4
- 229920006231 aramid fiber Polymers 0.000 claims description 4
- AGXUVMPSUKZYDT-UHFFFAOYSA-L barium(2+);octadecanoate Chemical compound [Ba+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O AGXUVMPSUKZYDT-UHFFFAOYSA-L 0.000 claims description 4
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 claims description 4
- 239000012964 benzotriazole Substances 0.000 claims description 4
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 claims description 4
- 239000008116 calcium stearate Substances 0.000 claims description 4
- 235000013539 calcium stearate Nutrition 0.000 claims description 4
- 239000004917 carbon fiber Substances 0.000 claims description 4
- 150000002148 esters Chemical class 0.000 claims description 4
- 239000000835 fiber Substances 0.000 claims description 4
- 239000003365 glass fiber Substances 0.000 claims description 4
- 239000003292 glue Substances 0.000 claims description 4
- HQKMJHAJHXVSDF-UHFFFAOYSA-L magnesium stearate Chemical compound [Mg+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O HQKMJHAJHXVSDF-UHFFFAOYSA-L 0.000 claims description 4
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 4
- 239000002480 mineral oil Substances 0.000 claims description 4
- 235000010446 mineral oil Nutrition 0.000 claims description 4
- LYRFLYHAGKPMFH-UHFFFAOYSA-N octadecanamide Chemical class CCCCCCCCCCCCCCCCCC(N)=O LYRFLYHAGKPMFH-UHFFFAOYSA-N 0.000 claims description 4
- 229920001155 polypropylene Polymers 0.000 claims description 4
- 239000000843 powder Substances 0.000 claims description 4
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 claims description 4
- 229910010271 silicon carbide Inorganic materials 0.000 claims description 4
- ISIJQEHRDSCQIU-UHFFFAOYSA-N tert-butyl 2,7-diazaspiro[4.5]decane-7-carboxylate Chemical compound C1N(C(=O)OC(C)(C)C)CCCC11CNCC1 ISIJQEHRDSCQIU-UHFFFAOYSA-N 0.000 claims description 4
- 239000002253 acid Substances 0.000 claims description 3
- 239000011521 glass Substances 0.000 claims description 3
- 229920000092 linear low density polyethylene Polymers 0.000 claims description 3
- 239000004707 linear low-density polyethylene Substances 0.000 claims description 3
- 229960000969 phenyl salicylate Drugs 0.000 claims description 3
- 235000019260 propionic acid Nutrition 0.000 claims description 3
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 claims description 3
- 239000007787 solid Substances 0.000 claims description 3
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 claims description 3
- FGHOOJSIEHYJFQ-UHFFFAOYSA-N (2,4-ditert-butylphenyl) dihydrogen phosphite Chemical class CC(C)(C)C1=CC=C(OP(O)O)C(C(C)(C)C)=C1 FGHOOJSIEHYJFQ-UHFFFAOYSA-N 0.000 claims description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 2
- 229920009204 Methacrylate-butadiene-styrene Polymers 0.000 claims description 2
- 229910019142 PO4 Inorganic materials 0.000 claims description 2
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 claims description 2
- TXQVDVNAKHFQPP-UHFFFAOYSA-N [3-hydroxy-2,2-bis(hydroxymethyl)propyl] octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(CO)(CO)CO TXQVDVNAKHFQPP-UHFFFAOYSA-N 0.000 claims description 2
- 125000003118 aryl group Chemical group 0.000 claims description 2
- WWNGFHNQODFIEX-UHFFFAOYSA-N buta-1,3-diene;methyl 2-methylprop-2-enoate;styrene Chemical compound C=CC=C.COC(=O)C(C)=C.C=CC1=CC=CC=C1 WWNGFHNQODFIEX-UHFFFAOYSA-N 0.000 claims description 2
- 239000002274 desiccant Substances 0.000 claims description 2
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 2
- 239000006185 dispersion Substances 0.000 claims description 2
- 239000000194 fatty acid Substances 0.000 claims description 2
- 229930195729 fatty acid Natural products 0.000 claims description 2
- 150000004665 fatty acids Chemical class 0.000 claims description 2
- 229920000578 graft copolymer Polymers 0.000 claims description 2
- 235000019359 magnesium stearate Nutrition 0.000 claims description 2
- 239000010445 mica Substances 0.000 claims description 2
- 229910052618 mica group Inorganic materials 0.000 claims description 2
- 239000012188 paraffin wax Substances 0.000 claims description 2
- 239000010452 phosphate Substances 0.000 claims description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 2
- 239000001993 wax Substances 0.000 claims description 2
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 claims 2
- UHOVQNZJYSORNB-UHFFFAOYSA-N monobenzene Natural products C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims 2
- WBYWAXJHAXSJNI-VOTSOKGWSA-M .beta-Phenylacrylic acid Natural products [O-]C(=O)\C=C\C1=CC=CC=C1 WBYWAXJHAXSJNI-VOTSOKGWSA-M 0.000 claims 1
- ZYUVGYBAPZYKSA-UHFFFAOYSA-N 5-(3-hydroxybutan-2-yl)-4-methylbenzene-1,3-diol Chemical compound CC(O)C(C)C1=CC(O)=CC(O)=C1C ZYUVGYBAPZYKSA-UHFFFAOYSA-N 0.000 claims 1
- WBYWAXJHAXSJNI-SREVYHEPSA-N Cinnamic acid Chemical compound OC(=O)\C=C/C1=CC=CC=C1 WBYWAXJHAXSJNI-SREVYHEPSA-N 0.000 claims 1
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims 1
- 239000004698 Polyethylene Substances 0.000 claims 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims 1
- ACOGMWBDRJJKNB-UHFFFAOYSA-N acetic acid;ethene Chemical group C=C.CC(O)=O ACOGMWBDRJJKNB-UHFFFAOYSA-N 0.000 claims 1
- 150000008065 acid anhydrides Chemical class 0.000 claims 1
- 150000001298 alcohols Chemical class 0.000 claims 1
- 229930016911 cinnamic acid Natural products 0.000 claims 1
- 235000013985 cinnamic acid Nutrition 0.000 claims 1
- NHADDZMCASKINP-HTRCEHHLSA-N decarboxydihydrocitrinin Natural products C1=C(O)C(C)=C2[C@H](C)[C@@H](C)OCC2=C1O NHADDZMCASKINP-HTRCEHHLSA-N 0.000 claims 1
- 150000001993 dienes Chemical class 0.000 claims 1
- 229920001971 elastomer Polymers 0.000 claims 1
- 239000000806 elastomer Substances 0.000 claims 1
- 229920006242 ethylene acrylic acid copolymer Polymers 0.000 claims 1
- 229920001038 ethylene copolymer Polymers 0.000 claims 1
- 229940075507 glyceryl monostearate Drugs 0.000 claims 1
- 239000012784 inorganic fiber Substances 0.000 claims 1
- WBYWAXJHAXSJNI-UHFFFAOYSA-N methyl p-hydroxycinnamate Natural products OC(=O)C=CC1=CC=CC=C1 WBYWAXJHAXSJNI-UHFFFAOYSA-N 0.000 claims 1
- 239000001788 mono and diglycerides of fatty acids Substances 0.000 claims 1
- SSDSCDGVMJFTEQ-UHFFFAOYSA-N octadecyl 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 SSDSCDGVMJFTEQ-UHFFFAOYSA-N 0.000 claims 1
- 239000003921 oil Substances 0.000 claims 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims 1
- 229920000573 polyethylene Polymers 0.000 claims 1
- 229910052710 silicon Inorganic materials 0.000 claims 1
- 239000010703 silicon Substances 0.000 claims 1
- 229920001909 styrene-acrylic polymer Polymers 0.000 claims 1
- 239000000853 adhesive Substances 0.000 abstract description 5
- 230000001070 adhesive effect Effects 0.000 abstract description 5
- 238000002156 mixing Methods 0.000 abstract description 5
- 230000032683 aging Effects 0.000 abstract description 4
- 239000002904 solvent Substances 0.000 abstract 2
- 238000000034 method Methods 0.000 description 13
- 229920000642 polymer Polymers 0.000 description 11
- 230000008569 process Effects 0.000 description 11
- 239000000047 product Substances 0.000 description 7
- 239000000126 substance Substances 0.000 description 7
- 229920000402 bisphenol A polycarbonate polymer Polymers 0.000 description 6
- 230000000694 effects Effects 0.000 description 5
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 4
- 150000001336 alkenes Chemical class 0.000 description 4
- 238000001035 drying Methods 0.000 description 4
- 230000008901 benefit Effects 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- 229920006124 polyolefin elastomer Polymers 0.000 description 3
- 229920002545 silicone oil Polymers 0.000 description 3
- CWNSVVHTTQBGQB-UHFFFAOYSA-N N,N-Diethyldodecanamide Chemical group CCCCCCCCCCCC(=O)N(CC)CC CWNSVVHTTQBGQB-UHFFFAOYSA-N 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000005461 lubrication Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- LDVVTQMJQSCDMK-UHFFFAOYSA-N 1,3-dihydroxypropan-2-yl formate Chemical compound OCC(CO)OC=O LDVVTQMJQSCDMK-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 235000017858 Laurus nobilis Nutrition 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- JKIJEFPNVSHHEI-UHFFFAOYSA-N Phenol, 2,4-bis(1,1-dimethylethyl)-, phosphite (3:1) Chemical group CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OP(OC=1C(=CC(=CC=1)C(C)(C)C)C(C)(C)C)OC1=CC=C(C(C)(C)C)C=C1C(C)(C)C JKIJEFPNVSHHEI-UHFFFAOYSA-N 0.000 description 1
- 240000000203 Salix gracilistyla Species 0.000 description 1
- 244000125380 Terminalia tomentosa Species 0.000 description 1
- 235000005212 Terminalia tomentosa Nutrition 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 239000002313 adhesive film Substances 0.000 description 1
- 150000001447 alkali salts Chemical class 0.000 description 1
- 235000006708 antioxidants Nutrition 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- NTXGQCSETZTARF-UHFFFAOYSA-N buta-1,3-diene;prop-2-enenitrile Chemical compound C=CC=C.C=CC#N NTXGQCSETZTARF-UHFFFAOYSA-N 0.000 description 1
- 125000005587 carbonate group Chemical group 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 230000001143 conditioned effect Effects 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 229920006351 engineering plastic Polymers 0.000 description 1
- 239000005038 ethylene vinyl acetate Substances 0.000 description 1
- 229920006226 ethylene-acrylic acid Polymers 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 238000005189 flocculation Methods 0.000 description 1
- 230000016615 flocculation Effects 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 239000004611 light stabiliser Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000011325 microbead Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 230000009965 odorless effect Effects 0.000 description 1
- 238000011017 operating method Methods 0.000 description 1
- 239000012860 organic pigment Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 150000008301 phosphite esters Chemical group 0.000 description 1
- 208000007578 phototoxic dermatitis Diseases 0.000 description 1
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 238000006748 scratching Methods 0.000 description 1
- 230000002393 scratching effect Effects 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
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- 239000000725 suspension Substances 0.000 description 1
- 230000009967 tasteless effect Effects 0.000 description 1
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- 230000010148 water-pollination Effects 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Laminated Bodies (AREA)
Abstract
The invention discloses a preparation process of a high-hardness air conditioner panel adopting a PC ABS blending material, which is characterized by comprising the following steps of: the base material is prepared from the following components in parts by weight: PC resin: 50-90 parts; ABS resin: 50-90 parts; filling: 20-40 parts of a solvent; a main toughening agent: 7-13 parts; a synergistic toughening agent: 5-9 parts of a solvent; a compatilizer: 4-8 parts; lubricant: 3-5 parts; dispersing agent: 3-5 parts; antioxidant: 2-4 parts; anti-ultraviolet agent: 2-4 parts. The toughening agent in the invention can reduce the brittleness of the finished product and increase the toughness without influencing other main performances of the adhesive. The compatilizer is added to increase the compatibility of the two resins, so that the adhesive force between the two resins is increased, a stable structure is formed, and the dispersed phase and the continuous phase are uniform. The antioxidant and the ultraviolet resistant agent are added to prevent the aging of the air conditioner panel and prolong the service life of the air conditioner panel.
Description
Technical field
The invention belongs to technical field of polymer materials, in particular to substrate and its system used in a kind of high rigidity air-conditioning panel
Standby technique.
Background technique
Critical function appearance part of the air-conditioning panel as wall-hanging air conditioner indoor unit, quality to substrate used in it and
Appearance requirement with higher.
Polycarbonate (PC) is because its physical mechanical property is excellent, excellent in cushion effect, good electrical property, dimensional stability
The features such as good and be widely used in each field of the social life such as electronic apparatus, building materials, packaging, auto industry, be current production rate
Maximum, one of most widely used polymer, so, polycarbonate (PC) is one of most common substrate of common air-conditioning panel.
ABS resin refers to that acrylonitrile-butadiene-styrene copolymer, ABS are Acrylonitrile Butadiene
The acronym of Styrene, since it is with many excellent properties, ABS resin is also used as substrate extensively should be in common air-conditioning
Processing preparation in.
Present, the main problems are as follows:
1, since air-conditioning panel is particularly significant in the use process of air-conditioning, and it makes common PC tree to the high request of hardness
Rouge and ABS resin cannot reach its standard, and there are poor in processability, impact resistance is low, surface hardness is inadequate, easy stress cracking
The problem of, so it is badly in need of a kind of preparation process of high-intensitive air-conditioning panel currently on the market；
2, substrate used in the more typical air-conditioning panel occurred on the market is usually single PC resin or single ABS tree
The shortcomings that rouge, the air-conditioning panel produced in this way has chosen material, there is more apparent short slab, and usually two
The air-conditioning panel advantage and disadvantage that kind of material is mixed to prepare are more balanced, and without obvious short slab, but only, surplus a few is mixed to prepare
Air-conditioning panel, the preparation method problem inadequate there are still the compatibility of PC and two component of ABS；
3, in air due to air-conditioning panel exposure, so it needs certain antioxidant and uviolresistance, and on the market compared with
More air-conditioning panels does not have such property, so that in the long period in use, air-conditioning panel corrodes, peeling
Phenomenon.
Summary of the invention
Goal of the invention: in order to overcome the above deficiency, the object of the present invention is to provide bases used in a kind of high rigidity air-conditioning panel
Material solves after solidifying in PC resin and ABS resin process that elongation is low by the way that toughener is added, and brittleness is larger, when viscous
Socket part position bears to be easy to crack when external force, and extends rapidly, causes glue-line to crack, not endurance, cannot function as structure
The problem of bonding is used.The use of toughener can lower the brittleness of finished product, increase toughness, and not influence other masters of adhesive
Want the substance of performance.Use the two kinds of resin mixing of PC resin and ABS resin as the main material for preparing substrate, air-conditioning obtained
Panel effect is preferable.The compatibility that compatilizer increases by two kinds of resins is added, bonding force increases between being allowed to two kinds of resins, is formed and is stablized
Structure, keep dispersed phase and continuous phase uniform.Antioxidant and UV resistant agent is added simultaneously, to absorb in sunlight and fluorescent light source
Ultraviolet light portion and delay or inhibit the progress of air-conditioning panel oxidation process, to prevent the aging of air-conditioning panel and extend it to make
Use the service life.
Technical solution: to achieve the goals above, the present invention provides substrates used in a kind of high rigidity air-conditioning panel, special
Sign is: the substrate is made of the component of following several weights:
PC resin: 50 ~ 90 parts；
ABS resin: 50 ~ 90 parts；
Filler: 20 ~ 40 parts；
Main toughener: 7 ~ 13 parts；
Synergistic toughener: 5 ~ 9 parts；
Compatilizer: 4 ~ 8 parts；
Lubricant: 3 ~ 5 parts；
Dispersing agent: 3 ~ 5 parts；
Antioxidant: 2 ~ 4 parts；
UV resistant agent: 2 ~ 4 parts.
PC resin, that is, polycarbonate in the present invention, it is the high molecular polymer in strand containing carbonate group, tool
There are wide high-intensitive and coefficient of elasticity, high impact, use temperature range, heigh clarity and free dyeability, forming to shrink
Rate is low, dimensional stability is good, fatigue durability is good, weatherability is good, electrical characteristic is excellent, tasteless odorless harmless meets health
The advantage of safety.ABS resin refers to acrylonitrile-butadiene-styrene copolymer, be a kind of intensity height, good toughness, be easy to plus
The molding thermoplastics type's high molecular material of work, acrylonitrile provide the chemical attacks such as hardness, heat resistance, acidproof alkali salt for ABS resin
Property；Butadiene provides low temperature ductility and impact resistance for ABS resin；Styrene provides the stream of hardness, processing for ABS resin
The finish of dynamic property and product surface.So by both resins as the main material for preparing substrate, resulting air-conditioning panel
Various aspects of performance is more excellent.
Heretofore described PC resin is bisphenol A polycarbonate, and refractive index is 1.56 ~ 1.62, transmissivity 86%
~ 92%, melt index is 1 ~ 2g/min；The ABS resin is acrylonitrile-butadiene-styrene copolymer, and butadiene content is
30% ~ 40%, melt index is 1 ~ 4g/min.
Bisphenol-a polycarbonate in the present invention is a kind of polymer, has preferable mechanical strength, excellent heat resistance
The advantages that energy, impact resistant strength height, creep resistant, the high grade of transparency, good dimensional stability and electrical insulating property, be purposes extremely
One of extensive engineering plastics.And the fine requirement of refractive index, transmissivity, melt index is so that selected PC resin is property
The most excellent resin material of energy, the various aspects of performance of thus obtained air-conditioning panel are also ensured.To fourth two in ABS resin
The requirement of alkene content is because of although butadiene provides low temperature ductility and impact resistance, excessive fourth two for ABS resin
Alkene can reduce hardness, gloss and the mobility of resin, and the ABS resin of 30% ~ 40% content is the most excellent resin of performance
The various aspects of performance of material, thus obtained air-conditioning panel is also ensured.
Filler of the present invention is inorfil, is surface through the processed glass fibre of silane coupling agent, silicon carbide
One of fiber, MF, carbon fiber, aramid fiber, solid glass micro-bead, mica or multiple combinations.
Filler in the present invention is also known as filler, it is one kind to improve processing performance, Mechanical Properties of Products and drop
The solid material of low cost.Filler can reduce the shrinking percentage of molded article, improve dimensional stability, any surface finish of product
Degree, flatness and zero diopter or without photosensitiveness etc., and the still effective regulator of resin viscosity.
Heretofore described main toughener is silicon-acrylic type impact modifier, MBS, high glue powder, acrylate, second
Alkene-methyl acrylate-glycidyl methacrylate random terpolymer, the poly- second of maleic anhydride grafted linear low-density
One of alkene, methyl methacrylate-butadiene-styrene terpolymer or multiple combinations；The synergistic toughener is
Core-shell structure, core are methyl methacrylate, and shell is butadiene.
Heretofore described toughener refers to and can increase the flexible substance of adhesive film layer.PC resin and ABS resin
Elongation is low after solidifying in process, and brittleness is larger, is easy to crack when external force is born in bonding site, and expand rapidly
Exhibition, causes glue-line to crack, not endurance, cannot function as structural bond and be used.Therefore, it is necessary to try to reduce brittleness, increase toughness,
Improve bearing strength.The use of toughener can lower the brittleness of finished product, increase toughness, and do not influence adhesive other are main
The substance of performance.
Heretofore described compatilizer be styrene-acrylonitrile-glycidyl methacrylate copolymer (SAG),
Polypropylene grafted glycidyl methacrylate (PP-g-GMA), ethylene-methyl acrylate-glyceryl methacrylate
Random terpolymer (EMA-g-GMA), polyolefin elastomer graft glycidyl methacrylate (POE-g-GMA), third
One of alkene nitrile-copolymer in cinnamic acrylic ester-maleic anhydride graft copolymer (GMA-g-GMA) or multiple combinations.
Heretofore described compatilizer is also known as expanding material, refers to by means of intermolecular bonding force, promotes incompatible
Two kinds of polymer is incorporated in one, and then obtains the auxiliary agent of stable blend.Since both PC resin and ABS resin are mixing
It is in the process and incompatible, it is necessary to which that the two is combined together by compatilizer.It is grafted appeared in the present invention with maleic anhydride
Compatilizer be relatively good compatilizer at present, it is strong that maleic anhydride monomer and other monomers compare Polarity comparision, com-patibilising effect ratio
Preferably.It can increase the compatibility of two kinds of polymer, and bonding force increases between being allowed to two kinds of polymer, form stable structure,
Keep dispersed phase and continuous phase uniform, i.e. compatibilized.The polymer compatibilized why compatilizer can make two kinds of properties different, be because
To have the reason for the group that can be physically or chemically combined with two kinds of polymer respectively in the molecule thereof.
Lubricant of the present invention is silicone oil, White Mineral Oil, fatty acid amide, barium stearate, magnesium stearate, paraffin, gathers
The double stearic amides of ethylene waxes, vinyl, ethylene-vinyl acetate copolymer, pentaerythritol stearate, ethylene-acrylic acid are total
One of polymers and aromatic phosphate acid ester or multiple combinations.
Heretofore described lubricant is the lubricant medium to drop the frictional resistance of low friction pair, slow down its abrasion.
The effects of lubricant can also play cooling, clean and prevent pollution to friction pair.It can increase the service life of air-conditioning panel, drop
The expense of low PC resin and ABS resin saves the energy, efficiently production, increase added value.And selected many profits in the present invention
Lubrication prescription may also help in defoaming and demoulding in mixed process while lubrication.
Heretofore described dispersing agent is lauric acid diethyl amide, calcium stearate, vinyl double hard amides, tristearin
One of sour monoglyceride, glyceryl tristearate or multiple combinations.
Heretofore described dispersing agent refers to one kind in the molecule while having lipophilic and two kinds of phase reflexives of hydrophily
The interfacial agent of matter.It uniform can disperse those and be poorly soluble in the inorganic of liquid, the solid and liquid of organic pigment
Grain, while the sedimentation and cohesion of particle can be also prevented, amphipathic reagent needed for forming stable suspension.It can not only be promoted
Finished product gloss can also prevent loose colour from scratching, reduce flocculation and increase color developing.
Heretofore described antioxidant is mixed by primary antioxidant and synergistic antioxidant 1:1 in mass ratio；Wherein
The primary antioxidant is the double -3-(3- tertiary butyl-4-hydroxy -5- aminomethyl phenyls of triethylene glycol) acrylonitrile, three (2,4- di-t-butyls
Phenol) it is phosphite ester, four [3-(3,5- di-tert-butyl-hydroxy phenyl) propionic acid] seasons, four alcohol ester, MD-697, antioxidant 1010, anti-
One of oxygen agent 1076；The synergistic antioxidant is phosphorous acid three (2,4- 6- di-tert-butyl phenyl ester), antioxidant 412S, antioxidant
One of 168.
Antioxidant in the present invention, in the presence of it is only a small amount of in polymeric system, so that it may delay or inhibit polymer
The progress of oxidation process, to prevent the aging of polymer and prolong its service life.
Heretofore described UV resistant agent be benzotriazole light absorber, phenyl salicylate, UV-329, UV-329,
One of UV-234, UV-531 or multiple combinations.
Heretofore described UV resistant agent is a kind of light stabilizer, can absorb the ultraviolet light in sunlight and fluorescent light source
Part, and itself does not change.
The preparation process of substrate used in heretofore described high rigidity air-conditioning panel, it is characterised in that: including following several
A step:
1. stock: each raw material component is weighed by composition of raw materials ratio, it is spare；
2. 5 ~ 7h is dried in PC resin at a temperature of 120 to 140 ° c, until the water content of PC resin is lower than
0.02%；
3. 3 ~ 4h is dried under conditions of temperature is 170 ~ 180 DEG C in ABS resin, until the water content of ABS resin is lower than
0.02%；
4. by PC resin and the same filler of ABS resin, main toughener, synergistic toughener, compatilizer, lubricant, dispersion after drying
Agent, antioxidant, UV resistant agent put into the high-speed mixer high speed that blade revolving speed is 120 revs/min together and are pre-mixed 5 points
Clock；
5. mixed raw mixture pre- in high-speed mixer is added in double screw extruder hopper melted, be kneaded,
It squeezes out, the extruder temperature of double screw extruder controls between 250 ~ 280 DEG C, and screw speed is 180 revs/min.
6. the raw material after double screw extruder is squeezed out is drawn, cooled down, dried, pelletizing and technology of the package, obtain described
Substrate used in high rigidity air-conditioning panel.
Step scientific order used in the present invention, now pre-processes PC resin and ABS resin, makes it close to preferably
Mixed under state, high-speed mixer can make all substances be stirred mixing under very high speed so that its
It is distributed under physical state more uniformly.And using for double screw extruder hopper makes under the chemical state of raw material after melting again
It is kneaded.Such operating procedure makes mixed process scientific order, easily operated, and final product quality is higher.
Above-mentioned technical proposal can be seen that the invention has the following beneficial effects:
1, toughener is added, solves after solidifying in PC resin and ABS resin process that elongation is low, brittleness is larger, when viscous
Socket part position bears to be easy to crack when external force, and extends rapidly, causes glue-line to crack, not endurance, cannot function as structure
The problem of bonding is used.The use of toughener can lower the brittleness of finished product, increase toughness, and not influence other masters of adhesive
Want the substance of performance.
2, use the two kinds of resin mixing of PC resin and ABS resin as the main material for preparing substrate, conditioned surface obtained
Plate effect is preferable.The compatibility that compatilizer increases by two kinds of resins is added, bonding force increases between being allowed to two kinds of resins, is formed stable
Structure keeps dispersed phase and continuous phase uniform.
3, antioxidant and UV resistant agent is added, to absorb the ultraviolet light portion in sunlight and fluorescent light source and delay or inhibit
The progress of air-conditioning panel oxidation process, to prevent the aging of air-conditioning panel and prolong its service life.
Specific embodiment
Combined with specific embodiments below, the present invention is furture elucidated.
Embodiment 1
Substrate used in a kind of high rigidity air-conditioning panel described in the present embodiment, it is characterised in that: the substrate is by following several
The component of kind weight is made:
PC resin: 50 parts；
ABS resin: 50 parts；
Surface is through the processed glass fibre of silane coupling agent: 20 parts；
Silicon-acrylic type impact modifier: 7 parts；
Synergistic toughener: 5 parts；
Styrene-acrylonitrile-glycidyl methacrylate copolymer (SAG): 4 parts；
Silicone oil: 3 parts；
Lauric acid diethyl amide: 3 parts；
Antioxidant: 2 parts；
Benzotriazole light absorber: 2 parts.
Furthermore the PC resin is bisphenol A polycarbonate, refractive index 1.56, transmissivity 86%, melt index
For 1g/min；The ABS resin is acrylonitrile-butadiene-styrene copolymer, and butadiene content 30%, melt index is
1g/min。
In addition, the synergistic toughener core-shell structure, core are methyl methacrylate, shell is butadiene.
Separately have, the antioxidant is mixed by primary antioxidant and synergistic antioxidant 1:1 in mass ratio；The wherein master
Antioxidant is the double -3-(3- tertiary butyl-4-hydroxy -5- aminomethyl phenyls of triethylene glycol) acrylonitrile, the synergistic antioxidant is phosphorous acid
Three (2,4- 6- di-tert-butyl phenyl esters).
Further, the preparation process of substrate used in the high rigidity air-conditioning panel, it is characterised in that: including following
Step:
1. stock: each raw material component is weighed by composition of raw materials ratio, it is spare；
2. 5h is dried under conditions of temperature is 120 DEG C in PC resin, until the water content of PC resin is lower than 0.02%；
3. 3h is dried under conditions of temperature is 170 DEG C in ABS resin, until the water content of ABS resin is lower than 0.02%；
4. by after drying PC resin and ABS resin with surface through the processed glass fibre of silane coupling agent, silicon-acrylic type
Impact modifier, synergistic toughener, styrene-acrylonitrile-glycidyl methacrylate copolymer (SAG), silicone oil, laurel
It is mixed that sour diglycollic amide, antioxidant, benzotriazole light absorber put into the high speed that blade revolving speed is 120 revs/min together
Conjunction machine high speed is pre-mixed 5 minutes；
5. mixed raw mixture pre- in high-speed mixer is added in double screw extruder hopper melted, be kneaded,
It squeezes out, at 250 DEG C, screw speed is 180 revs/min for the extruder temperature control of double screw extruder.
6. the raw material after double screw extruder is squeezed out is drawn, cooled down, dried, pelletizing and technology of the package, obtain described
Substrate used in high rigidity air-conditioning panel.
Embodiment 2
Substrate used in a kind of high rigidity air-conditioning panel described in the present embodiment, it is characterised in that: the substrate is by following several
The component of kind weight is made:
PC resin: 90 parts；
ABS resin: 90 parts；
Surface is through the processed silicon carbide fibre of silane coupling agent: 40 parts；
High glue powder: 13 parts；
Synergistic toughener: 9 parts；
Polypropylene grafted glycidyl methacrylate (PP-g-GMA): 8 parts；
White Mineral Oil: 5 parts；
Calcium stearate: 5 parts；
Antioxidant: 4 parts；
Phenyl salicylate: 4 parts.
Furthermore the PC resin is bisphenol A polycarbonate, refractive index 1.62, transmissivity 92%, melt index
For 2g/min；The ABS resin is acrylonitrile-butadiene-styrene copolymer, and butadiene content 40%, melt index is
4g/min。
In addition, the synergistic toughener core-shell structure, core are methyl methacrylate, shell is butadiene.
Separately have, the antioxidant is mixed by primary antioxidant and synergistic antioxidant 1:1 in mass ratio；The wherein master
Antioxidant is three (2,4- di-tert-butylphenol) phosphite esters, and the synergistic antioxidant is antioxidant 412S.
Further, the preparation process of substrate used in the high rigidity air-conditioning panel, it is characterised in that: including following
Step:
1. stock: each raw material component is weighed by composition of raw materials ratio, it is spare；
2. 7h is dried under conditions of temperature is 140 DEG C in PC resin, until the water content of PC resin is lower than 0.02%；
3. 4h is dried under conditions of temperature is 180 DEG C in ABS resin, until the water content of ABS resin is lower than 0.02%；
4. by after drying PC resin and ABS resin with surface through the processed silicon carbide fibre of silane coupling agent, high glue powder, association
Imitate toughener, polypropylene grafted glycidyl methacrylate (PP-g-GMA), White Mineral Oil, calcium stearate, antioxidant, bigcatkin willow
Acid phenenyl ester is put into the high-speed mixer high speed that blade revolving speed is 120 revs/min together and is pre-mixed 5 minutes；
5. mixed raw mixture pre- in high-speed mixer is added in double screw extruder hopper melted, be kneaded,
It squeezes out, the extruder temperature of double screw extruder controls between 280 DEG C, and screw speed is 180 revs/min.
6. the raw material after double screw extruder is squeezed out is drawn, cooled down, dried, pelletizing and technology of the package, obtain described
Substrate used in high rigidity air-conditioning panel.
Embodiment 3
Substrate used in a kind of high rigidity air-conditioning panel described in the present embodiment, it is characterised in that: the substrate is by following several
The component of kind weight is made:
PC resin: 60 parts；
ABS resin: 80 parts；
Surface is through the processed carbon fiber of silane coupling agent: 30 parts；
Silicon-acrylic type impact modifier: 8 parts；
Synergistic toughener: 6 parts；
Ethylene-methyl acrylate-glyceryl methacrylate random terpolymer (EMA-g-GMA): 5 parts；
Barium stearate: 4 parts；
The double hard amides of vinyl: 4 parts；
Antioxidant: 3 parts；
UV-329:3 parts.
Furthermore the PC resin is bisphenol A polycarbonate, refractive index 1.57, transmissivity 87%, melt index
For 1.5g/min；The ABS resin is acrylonitrile-butadiene-styrene copolymer, and butadiene content 35%, melt index is
2g/min。
In addition, the synergistic toughener core-shell structure, core are methyl methacrylate, shell is butadiene.
Separately have, the antioxidant is mixed by primary antioxidant and synergistic antioxidant 1:1 in mass ratio；The wherein master
Antioxidant is four [3-(3,5- di-tert-butyl-hydroxy phenyl) propionic acid] seasons, four alcohol ester, and the synergistic antioxidant is antioxidant
168。
Further, the preparation process of substrate used in the high rigidity air-conditioning panel, it is characterised in that: including following
Step:
1. stock: each raw material component is weighed by composition of raw materials ratio, it is spare；
2. 6h is dried under conditions of temperature is 130 DEG C in PC resin, until the water content of PC resin is lower than 0.02%；
3. 3.5h is dried under conditions of temperature is 175 DEG C in ABS resin, until the water content of ABS resin is lower than
0.02%；
4. by after drying PC resin and ABS resin resist through the processed carbon fiber of silane coupling agent, silicon-acrylic type with surface
Impact modifier, synergistic toughener, ethylene-methyl acrylate-glyceryl methacrylate random terpolymer (EMA-g-
GMA), it is 120 revs/min that barium stearate, vinyl double hard amide, antioxidant, UV-329 put into blade revolving speed together
High-speed mixer high speed is pre-mixed 5 minutes；
5. mixed raw mixture pre- in high-speed mixer is added in double screw extruder hopper melted, be kneaded,
It squeezes out, the extruder temperature of double screw extruder controls between 260 DEG C, and screw speed is 180 revs/min.
6. the raw material after double screw extruder is squeezed out is drawn, cooled down, dried, pelletizing and technology of the package, obtain described
Substrate used in high rigidity air-conditioning panel.
Embodiment 4
Substrate used in a kind of high rigidity air-conditioning panel described in the present embodiment, it is characterised in that: the substrate is by following several
The component of kind weight is made:
PC resin: 70 parts；
ABS resin: 70 parts；
Surface is through the processed aramid fiber of silane coupling agent: 20 parts；
Maleic anhydride grafted linear low density polyethylene: 13 parts；
Synergistic toughener: 5 parts；
Polyolefin elastomer graft glycidyl methacrylate (POE-g-GMA): 8 parts；
The double stearic amides of vinyl: 3 ~ 5 parts；
Glyceryl tristearate: 3 ~ 5 parts；
Antioxidant: 2 ~ 4 parts；
UV-531:2 ~ 4 part.
Furthermore the PC resin is bisphenol A polycarbonate, refractive index 1.61, transmissivity 90%, melt index
For 1g/min；The ABS resin is acrylonitrile-butadiene-styrene copolymer, and butadiene content 40%, melt index is
3g/min。
In addition, the synergistic toughener core-shell structure, core are methyl methacrylate, shell is butadiene.
Separately have, the antioxidant is mixed by primary antioxidant and synergistic antioxidant 1:1 in mass ratio；The wherein master
Antioxidant is MD-697, and the synergistic antioxidant is phosphorous acid three (2,4- 6- di-tert-butyl phenyl ester).
Further, the preparation process of substrate used in the high rigidity air-conditioning panel, it is characterised in that: including following
Step:
1. stock: each raw material component is weighed by composition of raw materials ratio, it is spare；
2. 7h is dried under conditions of temperature is 120 DEG C in PC resin, until the water content of PC resin is lower than 0.02%；
3. 4h is dried under conditions of temperature is 170 DEG C in ABS resin, until the water content of ABS resin is lower than 0.02%；
4. by after drying PC resin and ABS resin connect through the processed aramid fiber of silane coupling agent, maleic anhydride with surface
Branch linear low density polyethylene, synergistic toughener, polyolefin elastomer graft glycidyl methacrylate (POE-g-
GMA), it is 120 that vinyl double stearic amide, glyceryl tristearate, antioxidant, UV-531 put into blade revolving speed together
Rev/min high-speed mixer high speed be pre-mixed 5 minutes；
5. mixed raw mixture pre- in high-speed mixer is added in double screw extruder hopper melted, be kneaded,
It squeezes out, the extruder temperature of double screw extruder controls between 270 DEG C, and screw speed is 180 revs/min.
6. the raw material after double screw extruder is squeezed out is drawn, cooled down, dried, pelletizing and technology of the package, obtain described
Substrate used in high rigidity air-conditioning panel.
The above is only a preferred embodiment of the present invention, it is noted that for the ordinary skill people of the art
For member, without departing from the principle of the present invention, several improvement can also be made, these improvement also should be regarded as of the invention
Protection scope.
Claims (10)
1. substrate used in a kind of high rigidity air-conditioning panel, it is characterised in that: the substrate is by following several weights
Component is made:
PC resin: 50 ~ 90 parts；
ABS resin: 50 ~ 90 parts；
Filler: 20 ~ 40 parts；
Main toughener: 7 ~ 13 parts；
Synergistic toughener: 5 ~ 9 parts；
Compatilizer: 4 ~ 8 parts；
Lubricant: 3 ~ 5 parts；
Dispersing agent: 3 ~ 5 parts；
Antioxidant: 2 ~ 4 parts；
UV resistant agent: 2 ~ 4 parts.
2. substrate used in a kind of high rigidity air-conditioning panel according to claim 1, it is characterised in that: the PC resin is double
Phenol A type polycarbonate, refractive index are 1.56 ~ 1.62, and transmissivity is 86% ~ 92%, and melt index is 1 ~ 2g/min；The ABS
Resin is acrylonitrile-butadiene-styrene copolymer, and butadiene content is 30% ~ 40%, and melt index is 1 ~ 4g/min.
3. substrate used in a kind of high rigidity air-conditioning panel according to claim 1, it is characterised in that: the filler is inorganic
Fiber is surface through the processed glass fibre of silane coupling agent, silicon carbide fibre, MF, carbon fiber, aramid fiber, solid glass
One of glass microballon, mica or multiple combinations.
4. substrate used in a kind of high rigidity air-conditioning panel according to claim 1, it is characterised in that: the main toughener is
Silicon-acrylic type impact modifier, MBS, high glue powder, acrylate, ethylene-methyl acrylate-methyl propenoic acid glycidyl
Ester random terpolymer, maleic anhydride grafted linear low density polyethylene, methyl methacrylate-butadiene-styrene three
One of membered copolymer or multiple combinations；The synergistic toughener is core-shell structure, and core is methyl methacrylate, and shell is fourth
Diene.
5. substrate used in a kind of high rigidity air-conditioning panel according to claim 1, it is characterised in that: the compatilizer is benzene
Ethylene-propylene nitrile-glycidyl methacrylate copolymer (SAG), polypropylene grafted glycidyl methacrylate
(PP-g-GMA), ethylene-methyl acrylate-glyceryl methacrylate random terpolymer (EMA-g-GMA), polyene
Olefin elastomer graft glycidyl methacrylate (POE-g-GMA), acrylonitrile-styrene-acrylic ester copolymer-Malaysia
One of graft copolymer (GMA-g-GMA) of acid anhydrides or multiple combinations.
6. substrate used in a kind of high rigidity air-conditioning panel according to claim 1, it is characterised in that: the lubricant is silicon
Oil, White Mineral Oil, fatty acid amide, barium stearate, magnesium stearate, paraffin, polyethylene wax, vinyl double stearic amides, ethylene-
One of acetate ethylene copolymer, pentaerythritol stearate, ethylene-acrylic acid copolymer and aromatic phosphate acid ester or a variety of groups
It closes.
7. substrate used in a kind of high rigidity air-conditioning panel according to claim 1, it is characterised in that: the dispersing agent is the moon
The double hard amide of cinnamic acid diglycollic amide, calcium stearate, vinyl, glyceryl monostearate, one in glyceryl tristearate
Kind or multiple combinations.
8. substrate used in a kind of high rigidity air-conditioning panel according to claim 1, it is characterised in that: the antioxidant be by
Primary antioxidant and synergistic antioxidant 1:1 in mass ratio are mixed；Wherein the primary antioxidant is the tertiary fourth of the double -3-(3- of triethylene glycol
Base -4- hydroxy-5-methyl base phenyl) acrylonitrile, three (2,4- di-tert-butylphenol) phosphite esters, four [3-(3,5- di-t-butyl -4-
Hydroxy phenyl) propionic acid] season four alcohol esters, MD-697, antioxidant 1010, one of antioxidant 1076；The synergistic antioxidant is
One of phosphorous acid three (2,4- 6- di-tert-butyl phenyl ester), antioxidant 412S, irgasfos 168.
9. substrate used in a kind of high rigidity air-conditioning panel according to claim 1, it is characterised in that: the UV resistant agent
For one of benzotriazole light absorber, phenyl salicylate, UV-329, UV-329, UV-234, UV-531 or a variety of groups
It closes.
10. the preparation process of substrate used in described in any item high rigidity air-conditioning panels, feature exist according to claim 1 ~ 9
In: including the following steps:
1. stock: each raw material component is weighed by composition of raw materials ratio, it is spare；
2. 5 ~ 7h is dried in PC resin at a temperature of 120 to 140 ° c, until the water content of PC resin is lower than
0.02%；
3. 3 ~ 4h is dried under conditions of temperature is 170 ~ 180 DEG C in ABS resin, until the water content of ABS resin is lower than
0.02%；
4. by PC resin and the same filler of ABS resin, main toughener, synergistic toughener, compatilizer, lubricant, dispersion after drying
Agent, antioxidant, UV resistant agent put into the high-speed mixer high speed that blade revolving speed is 120 revs/min together and are pre-mixed 5 points
Clock；
5. mixed raw mixture pre- in high-speed mixer is added in double screw extruder hopper melted, be kneaded,
It squeezes out, the extruder temperature of double screw extruder controls between 250 ~ 280 DEG C, and screw speed is 180 revs/min；
6. the raw material after double screw extruder is squeezed out is drawn, cooled down, dried, pelletizing and technology of the package, obtain described high hard
Spend substrate used in air-conditioning panel.
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| CN111171543A (en) * | 2019-12-23 | 2020-05-19 | 上海普利特伴泰材料科技有限公司 | Reinforced PC/ABS composite material for sound absorption and damping and preparation method thereof |
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| CN117402455A (en) * | 2023-11-28 | 2024-01-16 | 句容协鑫光伏科技有限公司 | Resin composition, preparation method thereof, plastic plate and application |
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Application publication date: 20190507 |