CN100465232C - Nylon 66 nano composite material and preparation method thereof - Google Patents
Nylon 66 nano composite material and preparation method thereof Download PDFInfo
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- CN100465232C CN100465232C CNB2006100257637A CN200610025763A CN100465232C CN 100465232 C CN100465232 C CN 100465232C CN B2006100257637 A CNB2006100257637 A CN B2006100257637A CN 200610025763 A CN200610025763 A CN 200610025763A CN 100465232 C CN100465232 C CN 100465232C
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- nano
- inorganic particle
- composite material
- preparation
- elastomerics
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- 229920002302 Nylon 6,6 Polymers 0.000 title claims abstract description 49
- 239000000463 material Substances 0.000 title claims abstract description 31
- 239000002114 nanocomposite Substances 0.000 title claims description 17
- 238000002360 preparation method Methods 0.000 title claims description 12
- 238000000034 method Methods 0.000 claims abstract description 13
- 239000010954 inorganic particle Substances 0.000 claims description 20
- -1 polyethylene Polymers 0.000 claims description 15
- 239000003112 inhibitor Substances 0.000 claims description 14
- 230000003647 oxidation Effects 0.000 claims description 14
- 238000007254 oxidation reaction Methods 0.000 claims description 14
- 239000003795 chemical substances by application Substances 0.000 claims description 11
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 11
- 239000000203 mixture Substances 0.000 claims description 11
- 150000001875 compounds Chemical class 0.000 claims description 9
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 claims description 8
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical group CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 6
- 229920001577 copolymer Polymers 0.000 claims description 6
- VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 claims description 6
- 239000004576 sand Substances 0.000 claims description 6
- HEAMQYHBJQWOSS-UHFFFAOYSA-N ethene;oct-1-ene Chemical compound C=C.CCCCCCC=C HEAMQYHBJQWOSS-UHFFFAOYSA-N 0.000 claims description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 5
- 239000005977 Ethylene Substances 0.000 claims description 4
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 claims description 4
- 239000004698 Polyethylene Substances 0.000 claims description 4
- 239000006087 Silane Coupling Agent Substances 0.000 claims description 4
- VTYYLEPIZMXCLO-UHFFFAOYSA-L calcium carbonate Substances [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 4
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 4
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 claims description 4
- 235000013539 calcium stearate Nutrition 0.000 claims description 4
- 239000008116 calcium stearate Substances 0.000 claims description 4
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 claims description 4
- 239000006185 dispersion Substances 0.000 claims description 4
- 239000000314 lubricant Substances 0.000 claims description 4
- RKISUIUJZGSLEV-UHFFFAOYSA-N n-[2-(octadecanoylamino)ethyl]octadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(=O)NCCNC(=O)CCCCCCCCCCCCCCCCC RKISUIUJZGSLEV-UHFFFAOYSA-N 0.000 claims description 4
- 229920000573 polyethylene Polymers 0.000 claims description 4
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 4
- RYYKJJJTJZKILX-UHFFFAOYSA-M sodium octadecanoate Chemical group [Na+].CCCCCCCCCCCCCCCCCC([O-])=O RYYKJJJTJZKILX-UHFFFAOYSA-M 0.000 claims description 4
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 claims description 4
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 3
- 238000001125 extrusion Methods 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- 239000005543 nano-size silicon particle Substances 0.000 claims description 3
- 238000012545 processing Methods 0.000 claims description 3
- 239000002002 slurry Substances 0.000 claims description 3
- WYTZZXDRDKSJID-UHFFFAOYSA-N (3-aminopropyl)triethoxysilane Chemical group CCO[Si](OCC)(OCC)CCCN WYTZZXDRDKSJID-UHFFFAOYSA-N 0.000 claims description 2
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 claims description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Natural products C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 2
- 239000002253 acid Substances 0.000 claims description 2
- 150000001412 amines Chemical group 0.000 claims description 2
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 claims description 2
- 239000007822 coupling agent Substances 0.000 claims description 2
- 150000002148 esters Chemical class 0.000 claims description 2
- 238000009413 insulation Methods 0.000 claims description 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 2
- 229910052760 oxygen Inorganic materials 0.000 claims description 2
- 239000001301 oxygen Substances 0.000 claims description 2
- 235000019260 propionic acid Nutrition 0.000 claims description 2
- 125000001501 propionyl group Chemical group O=C([*])C([H])([H])C([H])([H])[H] 0.000 claims description 2
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 claims description 2
- APSBXTVYXVQYAB-UHFFFAOYSA-M sodium docusate Chemical group [Na+].CCCCC(CC)COC(=O)CC(S([O-])(=O)=O)C(=O)OCC(CC)CCCC APSBXTVYXVQYAB-UHFFFAOYSA-M 0.000 claims description 2
- YUYCVXFAYWRXLS-UHFFFAOYSA-N trimethoxysilane Chemical compound CO[SiH](OC)OC YUYCVXFAYWRXLS-UHFFFAOYSA-N 0.000 claims 1
- 239000002245 particle Substances 0.000 abstract description 8
- 239000002131 composite material Substances 0.000 abstract description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 8
- 230000000052 comparative effect Effects 0.000 description 5
- 238000011056 performance test Methods 0.000 description 3
- 229910004298 SiO 2 Inorganic materials 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 238000009833 condensation Methods 0.000 description 2
- 230000005494 condensation Effects 0.000 description 2
- 229920001971 elastomer Polymers 0.000 description 2
- 239000000806 elastomer Substances 0.000 description 2
- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 description 2
- 235000012204 lemonade/lime carbonate Nutrition 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- 238000010992 reflux Methods 0.000 description 2
- 230000035939 shock Effects 0.000 description 2
- 235000012239 silicon dioxide Nutrition 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 229960001866 silicon dioxide Drugs 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000002086 nanomaterial Substances 0.000 description 1
- 239000002105 nanoparticle Substances 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 238000005453 pelletization Methods 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- PZJJKWKADRNWSW-UHFFFAOYSA-N trimethoxysilicon Chemical compound CO[Si](OC)OC PZJJKWKADRNWSW-UHFFFAOYSA-N 0.000 description 1
- 229910052882 wollastonite Inorganic materials 0.000 description 1
- 239000010456 wollastonite Substances 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
Testing standard | Embodiment 1 | Comparative Examples 1 | Embodiment 2 | Comparative Examples 2 | |
Tensile strength (MPa) | ASTM D638 | 48 | 45 | 59 | 58 |
Elongation at break (%) | ASTM D638 | 82 | 80 | 35 | 30 |
Flexural strength (MPa) | ASTM D790 | 71 | 62 | 82 | 70 |
Modulus in flexure (MPa) | ASTM D790 | 1920 | 1700 | 2400 | 2210 |
Socle girder notch shock (J/m, 23 ℃) | ASTM D256 | 740 | 720 | 140 | 98 |
Heat-drawn wire (℃, 18.2MPa) | ASTM D648 | 55 | 50 | 70 | 62 |
Shrinking percentage (%) | ASTM D955 | 0.8~1.0 | 0.9~1.1 | 0.7~1.0 | 1.1~1.4 |
Claims (9)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CNB2006100257637A CN100465232C (en) | 2006-04-17 | 2006-04-17 | Nylon 66 nano composite material and preparation method thereof |
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Application Number | Priority Date | Filing Date | Title |
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CNB2006100257637A CN100465232C (en) | 2006-04-17 | 2006-04-17 | Nylon 66 nano composite material and preparation method thereof |
Publications (2)
Publication Number | Publication Date |
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CN101058671A CN101058671A (en) | 2007-10-24 |
CN100465232C true CN100465232C (en) | 2009-03-04 |
Family
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CNB2006100257637A Expired - Fee Related CN100465232C (en) | 2006-04-17 | 2006-04-17 | Nylon 66 nano composite material and preparation method thereof |
Country Status (1)
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CN (1) | CN100465232C (en) |
Families Citing this family (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101376744B (en) * | 2008-09-04 | 2011-04-27 | 中国蓝星(集团)股份有限公司 | Nylon 6 complex and preparation thereof |
CN101367991B (en) * | 2008-09-25 | 2011-01-05 | 上海交通大学 | Method of manufacturing polycarbonate/vinyl cyanide-butadiene-styrol copolymer alloy |
CN101367992B (en) * | 2008-09-25 | 2011-01-05 | 上海交通大学 | Method of manufacturing polycarbonate/polyester alloy |
CN101531835B (en) * | 2009-04-24 | 2012-05-23 | 吉林大学 | Wollastonite powder surface wet modification method assisted by microwave |
CN102850784A (en) * | 2012-09-06 | 2013-01-02 | 江苏兆鋆新材料科技有限公司 | Nylon 6 modified material and preparation method thereof |
CN104109377B (en) * | 2013-04-17 | 2018-01-12 | 上海杰事杰新材料(集团)股份有限公司 | A kind of nano silicon/NYLON610 T composites and preparation method thereof |
CN103450666B (en) * | 2013-09-03 | 2016-08-17 | 金发科技股份有限公司 | A kind of polyamide compoiste material and its preparation method and application |
CN103965622A (en) * | 2014-05-09 | 2014-08-06 | 安徽嘉木橡塑工业有限公司 | Release type high temperature resistant thin film |
CN103992474B (en) * | 2014-06-11 | 2016-03-30 | 南方医科大学 | A kind of preparation method of ultrabranching polyamide modified organic silicone resin and the standby coating of this resin-made |
CN104387760A (en) * | 2014-11-07 | 2015-03-04 | 佛山佛塑科技集团股份有限公司 | Anti-blocking nylon masterbatch and preparation method thereof |
CN104592450B (en) * | 2015-01-04 | 2018-04-27 | 佳易容相容剂江苏有限公司 | The polyolefin elastomer of the compound grafting of nano-particle, maleic anhydride and its preparation |
CN105778495B (en) * | 2016-04-06 | 2017-08-25 | 广东泰昊新材料科技有限公司 | For water pump vane can high-frequency welding enhancing nylon plastic(s) and preparation method thereof |
CN108211799B (en) * | 2017-12-27 | 2021-03-05 | 浙江海洋大学 | Preparation method of high-strength PA66 ultrafiltration membrane |
CN112920593A (en) * | 2019-12-05 | 2021-06-08 | 苏州荣昌复合材料有限公司 | High-strength low-shrinkage reinforced nylon and preparation method thereof |
CN115651396B (en) * | 2022-10-13 | 2023-09-26 | 金发科技股份有限公司 | Polyamide resin composite material and preparation method and application thereof |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1445278A (en) * | 2003-04-10 | 2003-10-01 | 上海交通大学 | Super malleable nylon and its preparing method |
EP1359196A1 (en) * | 2002-05-03 | 2003-11-05 | REHAU AG + Co | Polyamide composition reinforced with layered silicate |
CN1530399A (en) * | 2003-03-17 | 2004-09-22 | ���з��ɹ�˾ | Polyamide and polyolefine blend containing nanometer filler and with polyamide as matrix |
CN1571818A (en) * | 2001-10-19 | 2005-01-26 | 陶氏康宁公司 | Thermoplastic silicone elastomers from compatibilized polyamide resins |
-
2006
- 2006-04-17 CN CNB2006100257637A patent/CN100465232C/en not_active Expired - Fee Related
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1571818A (en) * | 2001-10-19 | 2005-01-26 | 陶氏康宁公司 | Thermoplastic silicone elastomers from compatibilized polyamide resins |
EP1359196A1 (en) * | 2002-05-03 | 2003-11-05 | REHAU AG + Co | Polyamide composition reinforced with layered silicate |
CN1530399A (en) * | 2003-03-17 | 2004-09-22 | ���з��ɹ�˾ | Polyamide and polyolefine blend containing nanometer filler and with polyamide as matrix |
CN1445278A (en) * | 2003-04-10 | 2003-10-01 | 上海交通大学 | Super malleable nylon and its preparing method |
Also Published As
Publication number | Publication date |
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CN101058671A (en) | 2007-10-24 |
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Address after: 200237 No. 130, Meilong Road, Shanghai, Xuhui District Patentee after: EAST CHINA University OF SCIENCE AND TECHNOLOGY Patentee after: Shanghai Juwei New Material Co.,Ltd. Address before: 200237 No. 130, Meilong Road, Shanghai, Xuhui District Patentee before: EAST CHINA University OF SCIENCE AND TECHNOLOGY Patentee before: POLYSTAR ENGINEERING PLASTICS (SHANGHAI) Co.,Ltd. |
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Effective date of registration: 20210823 Address after: 200237 No. 130, Meilong Road, Shanghai, Xuhui District Patentee after: EAST CHINA University OF SCIENCE AND TECHNOLOGY Address before: 200237 No. 130, Meilong Road, Shanghai, Xuhui District Patentee before: EAST CHINA University OF SCIENCE AND TECHNOLOGY Patentee before: Shanghai Juwei New Material Co.,Ltd. |
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CF01 | Termination of patent right due to non-payment of annual fee | ||
CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20090304 Termination date: 20210417 |