CN109721924A - A kind of efficient antifungi AES resin combination - Google Patents
A kind of efficient antifungi AES resin combination Download PDFInfo
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- CN109721924A CN109721924A CN201711023622.6A CN201711023622A CN109721924A CN 109721924 A CN109721924 A CN 109721924A CN 201711023622 A CN201711023622 A CN 201711023622A CN 109721924 A CN109721924 A CN 109721924A
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- antifungi
- efficient
- resin combination
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- aes resin
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Abstract
A kind of efficient antifungi AES resin combination of the present invention, raw material and raw material weight percentage composition are as follows: acrylonitritrile-styrene resin 40-50%, vinyltriethoxysilane 0.1-1%, hematite 0.1-3%, vinyl acetate 0.1-3%, modified nano zinc oxide 0.1-3%, ammonium polyphosphate 40-60%.The present invention has the characteristics that anti-mildew, non-discolouring, mechanical performance is high, can be suitable for different occasions.
Description
Technical field
The invention belongs to material science and technology field more particularly to a kind of efficient antifungi AES resin combinations.
Background technique
Acrylonitrile-ethylene propylene diene rubber-phenylethene grafted copolymer (AES) is a kind of weatherability engineering plastics, with third
Alkene nitrile-butadiene-styrene graft copolymer (ABS) structure is similar, and remains splendid machine of the ABS as engineering plastics
Tool physical property.AES resin majority is applied to the more demanding outdoor occasion of weatherability, and product using the time generally compared with
Long, under long-term illumination, temperature and humidity, chemical reagent and microbial action, resin surface is easy to breed mould out, and then invades
Lose inside strand, destroy chemical structure, not only have an adverse effect to the appearance of product, and it is serious when can also show
The disastrous effects such as surface dusting, product rupture, seriously affect the safety used and service life；Therefore, antifungi is carried out to AES resin
Processing is particularly important.Currently, the effective ways for improving resin resistance to fungi are addition antibacterial and mouldproof substances, can mainly divide
Other for the organic and natural organic three categories of inorganic, synthesis, inorganic antiseptic is research than a kind of antibacterial agent earlier, it is a kind of
Manufactured a kind of antibacterial agent is used interchangeably by inorganic carrier in the antibacterial metal ions such as silver, copper, zinc；The advantages of this material
It is not only there is antibiotic property, and its high temperature resistance is also fine, and metal ion is not easy decomposition etc..But inorganic antiseptic
The problem of always existing be easy discoloration, it is expensive, be easy the disadvantages of being lost, the requirement to light of photocatalytic is again very high,
So its industrialization produces limitation.
Organic antibacterial agent in terms of its antibacterial group for, can by point of natural antibacterial agent and organic synthesis antibacterial agent,
The disadvantages of for natural antibacterial agent there are heat resistance deficiency, antibacterial drug effect persistence is poor, not easy to be processed；Synthesis class organic antibacterial agent has
Wide spectrum, efficiently, persistently, the characteristics such as machinability is strong, but the disadvantages of there is also poor heat resistances, mechanical performance decline.
Also it studies have reported that, is imitated by the method that inorganic and organic antibacterial agent compound to improve the antifungi of resin
Fruit still can equally have the problems such as bad mechanical property, easy to change；It is multiple that patent CN103740024A discloses a kind of antibacterial AES
Condensation material and preparation method thereof realizes that material is anti-by using the mode that montmorillonite and myristyl tributyl quaternary alkylphosphonium salt compound
Bacterium property, but the patent only has studied the behavior pattern after addition complex antimicrobials, analysis is not added and is not added with antibacterial agent
Composite property difference, in fact, toughness, the appearance of material all can be by a fixings added with after inorganic matter
It rings；Patent CN103059494B discloses a kind of Antibacterial ASA plastic, by addition cedar wood oil, chitosan, nano-titanium dioxide,
Nano phase ag_2 o, Ju hexa-methylene Gua Phosphonium hydrochlorate and N- (trichloro-methylthio) phthalimide compounding are to improve fungus and mildew resistance
Effect, but the method higher cost, it is unfavorable for industrialized production.
However, there is no a kind of AES resins at present, in the case where non-discolouring after keeping mechanical performance not decline, blend,
Effective antifungi can be reached.
Summary of the invention
In order to solve the above-mentioned prior art problems, the present invention uses following scheme:
A kind of efficient antifungi AES resin combination, raw material and raw material weight percentage composition are as follows:
Acrylonitritrile-styrene resin 40-50%；
Vinyltriethoxysilane 0.1-1%；
Hematite 0.1-3%；
Vinyl acetate 0.1-3%；
Modified nano zinc oxide 0.1-3%；
Ammonium polyphosphate 40-60%.
The present invention has the characteristics that anti-mildew, non-discolouring, mechanical performance is high, can be suitable for different occasions.
Specific embodiment
Below in conjunction with specific embodiment, the present invention will be described in detail, herein illustrative examples and explanation of the invention
For explaining the present invention, but it is not as a limitation of the invention.
Embodiment
A kind of efficient antifungi AES resin combination of the present invention, raw material and raw material weight percentage composition are as follows: third
Alkene nitrile-styrol copolymer 45%, hematite 0.5%, vinyl acetate 1%, is modified vinyltriethoxysilane 0.5%
Nano zine oxide 2%, ammonium polyphosphate 51%.
The above-described embodiments merely illustrate the principles and effects of the present invention, and is not intended to limit the present invention.It is any ripe
The personage for knowing this technology all without departing from the spirit and scope of the present invention, carries out modifications and changes to above-described embodiment.Cause
This, institute is complete without departing from the spirit and technical ideas disclosed in the present invention by those of ordinary skill in the art such as
At all equivalent modifications or change, should be covered by the claims of the present invention.
Claims (1)
1. a kind of efficient antifungi AES resin combination, which is characterized in that its raw material and raw material weight percentage composition are as follows:
Acrylonitritrile-styrene resin 40-50%；
Vinyltriethoxysilane 0.1-1%；
Hematite 0.1-3%；
Vinyl acetate 0.1-3%；
Modified nano zinc oxide 0.1-3%；
Ammonium polyphosphate 40-60%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711023622.6A CN109721924A (en) | 2017-10-27 | 2017-10-27 | A kind of efficient antifungi AES resin combination |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711023622.6A CN109721924A (en) | 2017-10-27 | 2017-10-27 | A kind of efficient antifungi AES resin combination |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109721924A true CN109721924A (en) | 2019-05-07 |
Family
ID=66290837
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711023622.6A Withdrawn CN109721924A (en) | 2017-10-27 | 2017-10-27 | A kind of efficient antifungi AES resin combination |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109721924A (en) |
-
2017
- 2017-10-27 CN CN201711023622.6A patent/CN109721924A/en not_active Withdrawn
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| WW01 | Invention patent application withdrawn after publication |
Application publication date: 20190507 |
|
| WW01 | Invention patent application withdrawn after publication |