CN104845471A - Mold-proof coating based on nano copper - Google Patents
Mold-proof coating based on nano copper Download PDFInfo
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- CN104845471A CN104845471A CN201510293086.6A CN201510293086A CN104845471A CN 104845471 A CN104845471 A CN 104845471A CN 201510293086 A CN201510293086 A CN 201510293086A CN 104845471 A CN104845471 A CN 104845471A
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- proof coating
- nano copper
- titanium dioxide
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- 238000000576 coating method Methods 0.000 title claims abstract description 43
- 239000011248 coating agent Substances 0.000 title claims abstract description 41
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 title claims abstract description 37
- 229910052802 copper Inorganic materials 0.000 title claims abstract description 33
- 239000010949 copper Substances 0.000 title claims abstract description 33
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 32
- 239000004408 titanium dioxide Substances 0.000 claims abstract description 16
- 239000002131 composite material Substances 0.000 claims abstract description 15
- 239000000049 pigment Substances 0.000 claims abstract description 15
- 229920001479 Hydroxyethyl methyl cellulose Polymers 0.000 claims abstract description 12
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 claims abstract description 12
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims abstract description 12
- 239000004816 latex Substances 0.000 claims abstract description 12
- 229920000126 latex Polymers 0.000 claims abstract description 12
- 239000002245 particle Substances 0.000 claims abstract description 11
- 239000002253 acid Substances 0.000 claims description 12
- 239000002174 Styrene-butadiene Substances 0.000 claims description 11
- 229920000180 alkyd Polymers 0.000 claims description 11
- 229920005989 resin Polymers 0.000 claims description 11
- 239000011347 resin Substances 0.000 claims description 11
- 239000011115 styrene butadiene Substances 0.000 claims description 11
- 229920003048 styrene butadiene rubber Polymers 0.000 claims description 11
- 239000013530 defoamer Substances 0.000 claims description 10
- 239000000463 material Substances 0.000 claims description 7
- 230000000694 effects Effects 0.000 abstract description 10
- 238000004519 manufacturing process Methods 0.000 abstract description 9
- 238000005516 engineering process Methods 0.000 abstract description 5
- 241000894006 Bacteria Species 0.000 abstract description 4
- 238000010276 construction Methods 0.000 abstract description 4
- 230000002045 lasting effect Effects 0.000 abstract description 4
- 238000009395 breeding Methods 0.000 abstract description 3
- 230000001488 breeding effect Effects 0.000 abstract description 3
- 239000000126 substance Substances 0.000 abstract description 3
- 239000002994 raw material Substances 0.000 abstract description 2
- 239000004925 Acrylic resin Substances 0.000 abstract 1
- 229920000178 Acrylic resin Polymers 0.000 abstract 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 abstract 1
- 239000000853 adhesive Substances 0.000 abstract 1
- 230000001070 adhesive effect Effects 0.000 abstract 1
- 239000002518 antifoaming agent Substances 0.000 abstract 1
- 239000003973 paint Substances 0.000 abstract 1
- 229920001225 polyester resin Polymers 0.000 abstract 1
- 239000004645 polyester resin Substances 0.000 abstract 1
- 239000000843 powder Substances 0.000 description 5
- 238000002360 preparation method Methods 0.000 description 5
- 238000013329 compounding Methods 0.000 description 4
- 238000001125 extrusion Methods 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 230000003260 anti-sepsis Effects 0.000 description 2
- 239000000919 ceramic Substances 0.000 description 2
- 238000001514 detection method Methods 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 229930182555 Penicillin Natural products 0.000 description 1
- JGSARLDLIJGVTE-MBNYWOFBSA-N Penicillin G Chemical compound N([C@H]1[C@H]2SC([C@@H](N2C1=O)C(O)=O)(C)C)C(=O)CC1=CC=CC=C1 JGSARLDLIJGVTE-MBNYWOFBSA-N 0.000 description 1
- 235000010627 Phaseolus vulgaris Nutrition 0.000 description 1
- 244000046052 Phaseolus vulgaris Species 0.000 description 1
- 241000191940 Staphylococcus Species 0.000 description 1
- 241000191967 Staphylococcus aureus Species 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 230000001046 anti-mould Effects 0.000 description 1
- 239000002546 antimould Substances 0.000 description 1
- 235000013405 beer Nutrition 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 150000001555 benzenes Chemical class 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 210000000795 conjunctiva Anatomy 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 210000003298 dental enamel Anatomy 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 239000011152 fibreglass Substances 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 230000000855 fungicidal effect Effects 0.000 description 1
- 238000001879 gelation Methods 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 230000000968 intestinal effect Effects 0.000 description 1
- 239000010985 leather Substances 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 230000005923 long-lasting effect Effects 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 235000008935 nutritious Nutrition 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 229940049954 penicillin Drugs 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 239000003223 protective agent Substances 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D113/00—Coating compositions based on rubbers containing carboxyl groups
- C09D113/02—Latex
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Plant Pathology (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a mold-proof coating based on nano copper, and belongs to the technical field of coatings. The mold-proof coating is prepared from the following substances in parts by weight: 10-30 parts of organic silicon-modified acrylic resin, 20-40 parts of carboxylic butadiene-styrene latex, 10-25 parts of terminal carboxyl polyester resin, 6-15 parts of hydroxyethylmethylcellulose, 3-4 parts of a defoaming agent, 1-3 parts of nano copper with the particle sizes of 30-40nm and 6-10 parts of a GR composite titanium dioxide pigment. According to the mold-proof coating based on the nano copper, the proportions of various components are reasonable; and the nano copper, the GR composite titanium dioxide pigment and various components in the paint are organically combined, so that the mold-proof coating is available in raw material, environment-friendly, free of harm to a human body, good and lasting in anti-mold effect, high in adhesive force, good in film-forming property, and low in production cost; the construction technology is the same as that of an original construction technology; and breeding and reproduction of various bacteria can be effectively prevented in various occasions to which the mold-proof coating is applied.
Description
Technical field
The invention belongs to technical field of coatings, be specially a kind of mould-repellant coating based on Nanometer Copper.
Background technology
Mould-repellant coating is topmost except having the same function of coating common with other is exactly to lose by fungus-proof antisepsis, so general action is in the product surface protection such as reinforcing bar, cement, glass reinforced plastic, pottery, enamel, water pipe, timber and decoration, play the effect of fungus-proof antisepsis erosion.But the most frequently used thing is coated in building surface, makes buildings top layer not be subject to mold corrosion and cause film cracking and peel off.Some special manufacturing enterprises, as pharmacy, beer, bean product, milk-product, brewage, leather, makeup etc., because product is nutritious, production environment is damp and hot, and the temperature and humidity of production environment is applicable to growth, the breeding of mould very much.Therefore mouldy situation is quite serious, especially the interior wall of production plant and top ceiling, and some packing shops and warehouse even production unit, also has mouldy situation in various degree.The product produced in this environment and store, can be subject to pollution in various degree undoubtedly, and bring potential hazard to people are healthy, therefore factory is also often forced to stop production.Therefore, the GMP standard of medicine and food all proposes requirement to the metope of factory building and the mildew-resistant problem of ceiling.Adopting mould-repellant coating to carry out suitable application to the metope of production plant, ceiling and equipment, is a kind of not only economy but also practical mold-proof method.Existing coating adopts and adds copper powder and carry out mildew-resistant, but due to the granularity of copper powder too large, anti-mold effect is remarkable not.
Summary of the invention
For the above-mentioned problems in the prior art, content of the present invention is to design provides a kind of technical scheme with the mould-repellant coating based on Nanometer Copper of excellent anti-mold effect, the reasonable ratio of each component, and anti-mold effect is lasting, and strong adhesion, moulding property is good.
Described a kind of mould-repellant coating based on Nanometer Copper, is characterized in that being made up of the following material of parts by weight: organosilicon modified crylic acid resin 10-30 part, carboxylic styrene butadiene latex 20-40 part, end carboxyl alkyd resin 10-25 part, hydroxyethylmethyl-cellulose 6-15 part, defoamer 3-4 part, particle diameter are Nanometer Copper 1-3 part, GR composite titanium dioxide pigment 6-10 part of 30-40nm.
Described a kind of mould-repellant coating based on Nanometer Copper, is characterized in that organosilicon modified crylic acid resin 12-25 part, carboxylic styrene butadiene latex 22-35 part, end carboxyl alkyd resin 12-20 part, hydroxyethylmethyl-cellulose 8-12 part, defoamer 3.5 parts, Nanometer Copper 2 parts, GR composite titanium dioxide pigment 7-8 part.
Described a kind of mould-repellant coating based on Nanometer Copper, is characterized in that organosilicon modified crylic acid resin 15-20 part, carboxylic styrene butadiene latex 25-30 part, end carboxyl alkyd resin 15-18 part, hydroxyethylmethyl-cellulose 9-10 part, defoamer 3.5 parts, Nanometer Copper 2 parts, GR composite titanium dioxide pigment 7.5 parts.
Described organosilicon modified crylic acid resin has excellent sticking power, shock-resistance and snappiness, remarkable weathering resistance and Bao Se gloss retention, and feel is smooth, stain resistant, and scratch resistance is good, and outstanding thermotolerance, can stand the working temperature of 200 DEG C for a long time.
Described carboxylic styrene butadiene latex, has higher cohesive force and conjunctiva intensity, machinery and chemical stability good, the advantages such as mobility, package stability are all good, and loading level is large.Residual benzene class monomer is very micro-, belongs to environmentally friendly machine.
Described end carboxyl alkyd resin has the features such as lower viscosity, higher reactive behavior, low heat release, excellent mechanical property and ambient cure.
Described hydroxyethylmethyl-cellulose, water-soluble and part organic solvent, viscosity is lower, and solubleness is larger; More stable in aqueous, but excessive interpolation ionogen, gel and precipitation can be caused; Because the aqueous solution has surface active function, can be used as colloid protective agent, emulsifying agent and dispersion agent; There is reasonable Antimould power, have good viscosity stability when standing storage; The impact of the viscosity of product water solution almost acid and alkali or alkali, pH value is more stable in the scope of 3.0-11.0; Because the highly enriched aqueous solution of product has special viscoelastic property compared with the aqueous solution of other polymkeric substance, its ability etc. adding the shape invariance being improved extruding ceramic ceramic products.
Described copper powder can breed with Mycophyta needed for amino react, thus play anti-mold effect.Copper can not stripping in aqueous environment, and therefore effect is more lasting compared with other mould inhibitor.Size, the use properties of shape on coating of copper powder particle used have impact.Particle diameter is less, and result of use is better; Particle diameter is excessive, and its effect is inferior.Applicant finds through research, and the particle diameter of Nanometer Copper is less, then fungicidal properties is better.Nanometer Copper can adopt the preparation method of conventional nano metal to obtain, and also can directly buy from the market.
The performance index that GR composite titanium dioxide pigment can be identical or close with titanium dioxide are used in coating system; GR composite titanium dioxide pigment can be widely used in coating system, improves the performance of coating, reduces the use cost of material greatly.
The difference of each component, content in above-mentioned coating, has significant impact to the performance of coating.
Above-mentioned a kind of mould-repellant coating based on Nanometer Copper, the reasonable ratio of each component, in Nanometer Copper and GR composite titanium dioxide pigment and coating, various composition realizes organically combining, and raw material is easy to get, environmental protection, harmless, anti-mold effect is good, lasting, strong adhesion, moulding property is good, and production cost is low.Its construction technology is identical with original construction technology, in the various occasions that mould-repellant coating uses, effectively can prevent growing and breeding of various bacterium.
Embodiment
Below in conjunction with specific embodiment, the invention will be further described.
Embodiment 1
Described a kind of mould-repellant coating based on Nanometer Copper, is made up of the following material of parts by weight: organosilicon modified crylic acid resin 10 parts, carboxylic styrene butadiene latex 20 parts, end carboxyl alkyd resin 10 parts, hydroxyethylmethyl-cellulose 6 parts, defoamer 3 parts, particle diameter are Nanometer Copper 1 part, the GR composite titanium dioxide pigment 6 parts of 30nm.
Its preparation method is as follows: above-mentioned each component is dropped into high speed compounding jar high-speed mixing 3 minutes by proportioning, then extrudes at screw extrusion press, namely obtain mildew resistance powder coating.
Embodiment 2
Described a kind of mould-repellant coating based on Nanometer Copper, is made up of the following material of parts by weight: organosilicon modified crylic acid resin 12 parts, carboxylic styrene butadiene latex 25 parts, end carboxyl alkyd resin 12 parts, hydroxyethylmethyl-cellulose 8 parts, defoamer 3 parts, particle diameter are Nanometer Copper 2 parts, the GR composite titanium dioxide pigment 8 parts of 32nm.
Its preparation method is as follows: above-mentioned each component is dropped into high speed compounding jar high-speed mixing 4 minutes by proportioning, then extrudes at screw extrusion press, namely obtain mildew resistance powder coating.
Embodiment 3
Described a kind of mould-repellant coating based on Nanometer Copper, is made up of the following material of parts by weight: organosilicon modified crylic acid resin 25 parts, carboxylic styrene butadiene latex 35 parts, end carboxyl alkyd resin 20 parts, hydroxyethylmethyl-cellulose 12 parts, defoamer 4 parts, particle diameter are Nanometer Copper 2 parts, the GR composite titanium dioxide pigment 9 parts of 35nm.
Its preparation method is as follows: above-mentioned each component is dropped into high speed compounding jar high-speed mixing 5 minutes by proportioning, then extrudes at screw extrusion press, namely obtain mildew resistance powder coating.
Embodiment 4
Described a kind of mould-repellant coating based on Nanometer Copper, is made up of the following material of parts by weight: organosilicon modified crylic acid resin 30 parts, carboxylic styrene butadiene latex 40 parts, end carboxyl alkyd resin 25 parts, hydroxyethylmethyl-cellulose 15 parts, defoamer 4 parts, particle diameter are Nanometer Copper 3 parts, the GR composite titanium dioxide pigment 10 parts of 40nm.
Its preparation method is as follows: above-mentioned each component is dropped into high speed compounding jar high-speed mixing 5 minutes by proportioning, then extrudes at screw extrusion press, namely obtain mildew resistance powder coating.
The powder coating of each embodiment 2 above-mentioned is through Performance Detection, and detected result is in table 1.
Test result shows: the degradation efficiency of this coating to compounds such as the formaldehyde in enclosed space, ammonia and benzene classes all can reach 96.3%, effectively can kill the microorganisms such as the intestinal bacteria of surrounding, streptococcus aureus, penicillin staphylococcus, mould, play the effect of mildew-resistant mildew-resistant, to multiple unwanted bacteria, all there is sterilization thoroughness and long-lasting; Coating time of drying, set time are short, and coating adhesion is good, and coating resistance to impact shock is strong, good film flexibility, and heat-resisting, ageing-resistant; VOC content is 35 grams often liter, well below national standard.Carry out Performance Detection with embodiment 1, embodiment 3, embodiment 4, also can reach beneficial effect of the present invention.
Claims (3)
1. based on a mould-repellant coating for Nanometer Copper, it is characterized in that being made up of the following material of parts by weight: organosilicon modified crylic acid resin 10-30 part, carboxylic styrene butadiene latex 20-40 part, end carboxyl alkyd resin 10-25 part, hydroxyethylmethyl-cellulose 6-15 part, defoamer 3-4 part, particle diameter are Nanometer Copper 1-3 part, GR composite titanium dioxide pigment 6-10 part of 30-40nm.
2. a kind of mould-repellant coating based on Nanometer Copper as claimed in claim 1, is characterized in that organosilicon modified crylic acid resin 12-25 part, carboxylic styrene butadiene latex 22-35 part, end carboxyl alkyd resin 12-20 part, hydroxyethylmethyl-cellulose 8-12 part, defoamer 3.5 parts, Nanometer Copper 2 parts, GR composite titanium dioxide pigment 7-8 part.
3. a kind of mould-repellant coating based on Nanometer Copper as claimed in claim 1, is characterized in that organosilicon modified crylic acid resin 15-20 part, carboxylic styrene butadiene latex 25-30 part, end carboxyl alkyd resin 15-18 part, hydroxyethylmethyl-cellulose 9-10 part, defoamer 3.5 parts, Nanometer Copper 2 parts, GR composite titanium dioxide pigment 7.5 parts.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510293086.6A CN104845471B (en) | 2015-05-29 | 2015-05-29 | A kind of mildew resistant paint based on Nanometer Copper |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510293086.6A CN104845471B (en) | 2015-05-29 | 2015-05-29 | A kind of mildew resistant paint based on Nanometer Copper |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104845471A true CN104845471A (en) | 2015-08-19 |
| CN104845471B CN104845471B (en) | 2017-07-21 |
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| CN201510293086.6A Expired - Fee Related CN104845471B (en) | 2015-05-29 | 2015-05-29 | A kind of mildew resistant paint based on Nanometer Copper |
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| Country | Link |
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| CN (1) | CN104845471B (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108395780A (en) * | 2018-02-05 | 2018-08-14 | 安徽加隆工艺品有限公司 | A kind of lamps and lanterns metal pendant craftwork |
| CN108441009A (en) * | 2018-04-23 | 2018-08-24 | 苏州聚康新材料科技有限公司 | A kind of preparation method of mildewproof waterproof coating |
| CN110643211A (en) * | 2019-11-13 | 2020-01-03 | 南京中旌科技发展有限公司 | Mildew-proof coating and production process thereof |
| CN112876952A (en) * | 2021-01-18 | 2021-06-01 | 广东歌丽斯化学有限公司 | Imitation leather handfeel powder coating and preparation method and application thereof |
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- 2015-05-29 CN CN201510293086.6A patent/CN104845471B/en not_active Expired - Fee Related
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN108395780A (en) * | 2018-02-05 | 2018-08-14 | 安徽加隆工艺品有限公司 | A kind of lamps and lanterns metal pendant craftwork |
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| CN112876952A (en) * | 2021-01-18 | 2021-06-01 | 广东歌丽斯化学有限公司 | Imitation leather handfeel powder coating and preparation method and application thereof |
| CN112876952B (en) * | 2021-01-18 | 2022-04-12 | 广东歌丽斯化学有限公司 | Imitation leather handfeel powder coating and preparation method and application thereof |
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| Publication number | Publication date |
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| CN104845471B (en) | 2017-07-21 |
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