CN109694562A - A kind of high speed rotor plastic packaging BMC material and preparation method thereof - Google Patents
A kind of high speed rotor plastic packaging BMC material and preparation method thereof Download PDFInfo
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- CN109694562A CN109694562A CN201811629181.9A CN201811629181A CN109694562A CN 109694562 A CN109694562 A CN 109694562A CN 201811629181 A CN201811629181 A CN 201811629181A CN 109694562 A CN109694562 A CN 109694562A
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- plastic packaging
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- speed rotor
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- 239000000463 material Substances 0.000 title claims abstract description 42
- 239000004033 plastic Substances 0.000 title claims abstract description 38
- 229920003023 plastic Polymers 0.000 title claims abstract description 38
- 238000004806 packaging method and process Methods 0.000 title claims abstract description 25
- 238000002360 preparation method Methods 0.000 title claims description 9
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 38
- 229920005989 resin Polymers 0.000 claims abstract description 32
- 239000011347 resin Substances 0.000 claims abstract description 32
- 239000000945 filler Substances 0.000 claims abstract description 23
- 239000003112 inhibitor Substances 0.000 claims abstract description 23
- 239000002562 thickening agent Substances 0.000 claims abstract description 20
- 239000003365 glass fiber Substances 0.000 claims abstract description 17
- 239000002994 raw material Substances 0.000 claims abstract description 15
- 229920006337 unsaturated polyester resin Polymers 0.000 claims abstract description 15
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims abstract description 10
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N 1,4-Benzenediol Natural products OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000000395 magnesium oxide Substances 0.000 claims abstract description 5
- 150000003242 quaternary ammonium salts Chemical class 0.000 claims abstract description 4
- 125000000687 hydroquinonyl group Chemical group C1(O)=C(C=C(O)C=C1)* 0.000 claims abstract description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 12
- 239000000843 powder Substances 0.000 claims description 11
- 238000003756 stirring Methods 0.000 claims description 9
- 239000006185 dispersion Substances 0.000 claims description 8
- 239000007788 liquid Substances 0.000 claims description 8
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 6
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical group [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims description 5
- 229910021502 aluminium hydroxide Inorganic materials 0.000 claims description 5
- 150000004054 benzoquinones Chemical class 0.000 claims description 5
- -1 tert-butyl o Benzenediol Chemical compound 0.000 claims description 5
- 102220043159 rs587780996 Human genes 0.000 claims description 4
- 230000008719 thickening Effects 0.000 claims description 3
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 claims description 2
- 238000000034 method Methods 0.000 abstract description 8
- 230000008569 process Effects 0.000 abstract description 6
- XESZUVZBAMCAEJ-UHFFFAOYSA-N 4-tert-butylcatechol Chemical compound CC(C)(C)C1=CC=C(O)C(O)=C1 XESZUVZBAMCAEJ-UHFFFAOYSA-N 0.000 abstract description 3
- 230000000694 effects Effects 0.000 abstract description 3
- 238000005457 optimization Methods 0.000 abstract description 2
- AZQWKYJCGOJGHM-UHFFFAOYSA-N 1,4-benzoquinone Chemical compound O=C1C=CC(=O)C=C1 AZQWKYJCGOJGHM-UHFFFAOYSA-N 0.000 abstract 4
- 229940005561 1,4-benzoquinone Drugs 0.000 abstract 2
- 229960004337 hydroquinone Drugs 0.000 abstract 1
- UHOVQNZJYSORNB-UHFFFAOYSA-N monobenzene Natural products C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 9
- 229920006305 unsaturated polyester Polymers 0.000 description 8
- 239000005022 packaging material Substances 0.000 description 7
- AGXUVMPSUKZYDT-UHFFFAOYSA-L barium(2+);octadecanoate Chemical compound [Ba+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O AGXUVMPSUKZYDT-UHFFFAOYSA-L 0.000 description 4
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 4
- 229920002521 macromolecule Polymers 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 3
- NFPBWZOKGZKYRE-UHFFFAOYSA-N 2-propan-2-ylperoxypropane Chemical compound CC(C)OOC(C)C NFPBWZOKGZKYRE-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical group [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 2
- 235000013539 calcium stearate Nutrition 0.000 description 2
- 239000008116 calcium stearate Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 239000003822 epoxy resin Substances 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- BPMFZUMJYQTVII-UHFFFAOYSA-N guanidinoacetic acid Chemical compound NC(=N)NCC(O)=O BPMFZUMJYQTVII-UHFFFAOYSA-N 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 2
- 229920000647 polyepoxide Polymers 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 239000004926 polymethyl methacrylate Substances 0.000 description 2
- 229920002689 polyvinyl acetate Polymers 0.000 description 2
- 239000004576 sand Substances 0.000 description 2
- 238000007711 solidification Methods 0.000 description 2
- 230000008023 solidification Effects 0.000 description 2
- ISXSCDLOGDJUNJ-UHFFFAOYSA-N tert-butyl prop-2-enoate Chemical compound CC(C)(C)OC(=O)C=C ISXSCDLOGDJUNJ-UHFFFAOYSA-N 0.000 description 2
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 2
- 239000004342 Benzoyl peroxide Substances 0.000 description 1
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 1
- FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Chemical compound CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 description 1
- 229920006387 Vinylite Polymers 0.000 description 1
- 239000010426 asphalt Substances 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 235000019400 benzoyl peroxide Nutrition 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000010304 firing Methods 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 230000001629 suppression Effects 0.000 description 1
- GJBRNHKUVLOCEB-UHFFFAOYSA-N tert-butyl benzenecarboperoxoate Chemical compound CC(C)(C)OOC(=O)C1=CC=CC=C1 GJBRNHKUVLOCEB-UHFFFAOYSA-N 0.000 description 1
- RUPAXCPQAAOIPB-UHFFFAOYSA-N tert-butyl formate Chemical compound CC(C)(C)OC=O RUPAXCPQAAOIPB-UHFFFAOYSA-N 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/06—Unsaturated polyesters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/20—Applications use in electrical or conductive gadgets
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Macromonomer-Based Addition Polymer (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a kind of high speed rotor plastic packaging BMC material, including unsaturated polyester resin, low shrink resin, release agent, filler, curing agent, glass fibre, inhibitor；The inhibitor is hydroquinone, 1,4-benzoquinone, 1,4-benzoquinone, p-tert-Butylcatechol or quaternary ammonium salt；It further include thickener, the thickener is the magnesia of Chun Du≤99%.The present invention by adding inhibitor in the material, curing time (slow down cured effect) of the material inside the runner and mold in flow process can be effectively increased, so that completion of cure, optimization selection and rational proportion in conjunction with each component raw material, make BMC plastic packaging product that there is excellent surface smoothness, compactness and mechanical strength, is able to satisfy the requirement of the high revolving speed rotor of 20000 r/min.
Description
Technical field
The invention belongs to BMC material technical field, in particular to a kind of high speed rotor plastic packaging BMC material and its preparation side
Method.
Background technique
Rotor is the rotary body by bearing support.Rotor is mostly the main rotation member in dynamic power machine and work mechanism.
Typical rotor has Turbomachine Rotor, rotor, the rotor of various pumps and rotor of turbocompressor etc..Rotor is certain
Very big deformation can occur and cause to resonate when being rotated under specific revolving speed, since rotor makees high speed rotary motion, so needing
Balance.
Existing ordinary motor rotor speed only has 5000r/min or so, and the material used is conventional motor plastic package material,
There are two types of types substantially for the high molecular structure of plastics: the first is linear structure, and the high-molecular compound with this structure claims
For chain macromolecule compound；Second is three-dimensional-structure, and the producing high-molecular with this structure is collectively referred to as three-dimensional polymeric molecule
Close object.Some macromolecules have branch, referred to as branched high molecular, belong to linear structure.Some macromolecules are although intermolecular friendship
Join, but crosslinking is less, referred to as reticular structure, belongs to three-dimensional-structure.Two different structures show two kinds of opposite performances.
Linear structure (including branched structure) high polymer is due to the presence of independent molecule, therefore flexible, plasticity, in a solvent can be molten
Solution, heating can melt, hardness and the lesser feature of brittleness.Three-dimensional-structure high polymer since no independent macromolecular exists, therefore
Without elasticity and plasticity, it cannot dissolve and melt, can only be swollen, hardness and brittleness are larger.The high score of plastics then two kinds of structures
Son has, and is thermoplastic made of linear macromolecule, is thermosetting plastics made of three-dimensional polymeric molecule.
The most of plastics of motor plastic package material are light, chemical stabilization, will not corrode；But it has the disadvantage that plastics are resistance to
Hot difference, coefficient of thermal expansion is big, easy firing；Poor dimensional stability is easily deformed；Weatherability is poor.In addition, being directed to part rotor
Revolving speed needs to reach the high revolving speed rotor of 20000r/min, using ordinary motor plastic packaging material, can because intensity not enough due to burst apart and fall off,
Seriously affect the service life of rotor and using safe.
Summary of the invention
The invention discloses a kind of mobility and good moldabilities, are able to satisfy the high speed rotor modeling of high revolving speed rotor requirement
Envelope uses BMC material.
In order to achieve the above objectives, concrete scheme of the invention is as follows:
A kind of high speed rotor plastic packaging BMC material, including unsaturated polyester resin, low shrink resin, release agent, filler,
Curing agent, glass fibre, inhibitor；The inhibitor is hydroquinone, benzoquinones, p-tert-Butylcatechol or quaternary ammonium salt.
The unsaturated polyester resin is isophthalic resin, vinylite, epoxy resin or adjacent benzene resin；Described is low
Shrinkage resin is PS solution, PMMA solution, PVAC solution, EVA solution, rubber, PE powder or saturated resin；The release agent is
Calcium stearate, zinc stearate or barium stearate；The curing agent is bis- (t-amyl peroxy) hexamethylenes of 1,1-, peroxidating 2- second
Penta rouge of guanidine-acetic acid uncle, peroxidized t-butyl perbenzoate, three tert-butyl acrylate of isopropyl peroxide, the tertiary fourth of peroxidating 2- ethyl acid
Ester, 1,1- bis- (t-butyl peroxy) -3, any one of 3,5- trimethyl-cyclohexanes or more than one mixture.
The filler is at least one of aluminium hydroxide and calcium carbonate.Preferably, the filler is partial size D50=
At least one of the calcium carbonate of the aluminium hydroxide and partial size D50=5-8um of 8-10um, the aluminium hydroxide and calcium carbonate of above-mentioned partial size
With preferable oil absorbency, the combination of the two can effectively reduce the problems such as material, sand hole are lacked in material forming process, so that
Material has more preferable compactness.
It further include thickener to be conducive to material molding, the thickener is the magnesia of Chun Du≤99%.It adds pure
The magnesia of Du≤99% can be effectively improved the processing forming of high speed rotor plastic packaging BMC material as thickener.
Preferably, the unsaturated polyester resin is isophthalic neopentyl glycol resins, and the resin viscosity is in 2000-
3000mPa.S, solid content is in 60-65%, relative to other unsaturated polyester resins, has more excellent water resistance, weather-proof
Property and glass wellability；The low shrink resin is modified PS solution, with impact, excellent color compatibility and
Heat-resisting weatherability.
More effectively to slow down solidification of the BMC material inside the runner and mold in flow process, it is preferred that the suppression
Preparation is the hydroquinone or benzoquinones of Chun Du≤98%.
A kind of high speed rotor plastic packaging BMC material, the raw material including following weight percent: unsaturated polyester resin 12-
18%；Low shrink resin 4-10%；Release agent 1-3%；Filler 50-65%；Curing agent 0.1-0.5%；Glass fibre 15-
25%；Inhibitor 0.1-0.5%；Thickener 0-0.1%.
Preferably, the raw material including following weight percent: unsaturated polyester resin 12-16%；Low shrink resin 6-
10%；Release agent 1-2%；Filler 50-60%；Curing agent 0.1-0.3%；Glass fibre 18-25%；Inhibitor 0.1-0.3%；
Thickener 0.01-0.08%.
Preferably, the raw material including following weight percent: unsaturated polyester resin 14-16%；Low shrink resin 8-
10%；Release agent 1-2%；Filler 50-55%；Curing agent 0.1-0.2%；Glass fibre 20-25%；Inhibitor 0.1-0.2%；
Thickener 0.03-0.05%.
The invention also discloses a kind of preparation methods of high speed rotor plastic packaging BMC material, with simple process, operation
Convenient feature.
In order to achieve the above objectives, concrete scheme of the invention is as follows:
A kind of preparation method of high speed rotor plastic packaging BMC material, includes the following steps:
(1) resin, curing agent, release agent, inhibitor are added in dispersion cylinder, dispersion stirs to get liquid；
(2) kneader is added in filler, stirs to get powder；
(3) liquid of step 1 is added in the powder of step 2, paste is stirred to get in kneader；
(4) when needing to add thickener, thickener is added in the paste of step 3, thickening is stirred to get in kneader
Paste；
(5) it is uniformly added into glass fibre, stirs to get this product.
Compared with prior art, the present invention having the advantages that following prominent and good effect:
(1) by the way that in high speed rotor plastic packaging, with inhibitor is added in BMC material, material can be effectively increased in runner and mold
Curing time (slowing down cured effect) in the flow process of the inside solves material forming process so that solidification is more complete
Scarce material, precuring, ripple glaze, sand hole the problems such as.
(2) screening is compared by further investigation to existing rotor plastic packaging material and test, to unsaturated polyester (UP)
Resin, low shrink resin, filler, inhibitor raw material optimize selection, can be comprehensive in conjunction with the rational proportion of each component raw material
Close optimization select each component raw material excellent properties, make BMC plastic packaging product have excellent surface smoothness, compactness and
Mechanical strength is able to satisfy the requirement of the high revolving speed rotor of 20000r/min；Meanwhile also there is good mouldability, it is suitble to
Industrialized mass production.
Detailed description of the invention
Fig. 1 is the curing reaction curve comparison figure (temperature/time) of embodiment 1 and comparative example.
Label declaration: 1 is the curing reaction curve of comparative example, and 2 be the curing reaction curve of embodiment 1.
Specific embodiment
Embodiment 1
A kind of high speed rotor plastic packaging BMC material, the raw material including following weight percent: unsaturated polyester resin (
Benzene resin) 15%；Low shrink resin (PS solution) 8%；Release agent (calcium stearate) 1.5%；Filler (calcium carbonate, similarly hereinafter)
50%；Curing agent (bis- (t-amyl peroxy) hexamethylenes of 1,1-) 0.15%；Glass fibre 25.07%；Inhibitor (hydroquinone)
0.2%；The magnesia of thickener (Chun Du≤99%, similarly hereinafter) 0.08%.
A kind of preparation method of high speed rotor plastic packaging BMC material, includes the following steps:
1. resin, curing agent, pigment, release agent, inhibitor are added in dispersion cylinder, dispersion stirring 20min is stirred
Mix uniform liquid；
2. kneader is added in a filler material, 10min, the powder stirred evenly are stirred；
3. the liquid stirred evenly is added in the powder stirred evenly, 20min is stirred in kneader, is uniformly mixed
Paste；
4. uniformly mixed paste, the thickening paste that stirring 5min is stirred evenly in kneader is added in thickener
Object；
5. being uniformly added into glass fibre, 10min, the material mixed are stirred.
Embodiment 2
Other are as described in Example 1, and difference is: the raw material including following weight percent: unsaturated polyester resin (second
Ene based resins) 12%；Low shrink resin (PMMA solution) 7%；Release agent (zinc stearate) 3%；Filler 60%；Curing agent (mistake
Aoxidize penta rouge of 2- ethyl acetic acid uncle) 0.3%；Glass fibre 17.2%；Inhibitor (benzoquinones) 0.5%.
Embodiment 3
Other are as described in Example 1, and difference is: the raw material including following weight percent: unsaturated polyester (UP) (asphalt mixtures modified by epoxy resin
Rouge) 18%；Low shrink resin (PVAC solution) 4%；Release agent (barium stearate) 1%；Filler 55%；Curing agent (benzoyl peroxide
T-butyl formate) 0.5%；Glass fibre 21.28%；Inhibitor (p-tert-Butylcatechol) 0.2%；Thickener 0.02%.
Embodiment 4
Other are as described in Example 1, and difference is: the raw material including following weight percent: unsaturated polyester (UP) (adjacent benzene tree
Rouge) 11.5%；Low shrink resin (PE powder) 10%；Release agent (barium stearate) 1.5%；Filler 61.17%；Curing agent (peroxide
Change three tert-butyl acrylate of isopropyl) 0.4%；Glass fibre 15%；Inhibitor ((quaternary ammonium salt)) 0.4%；Thickener 0.03%.
Comparative example
A kind of conventional motor plastic packaging material, the raw material including following weight percent: unsaturated polyester (UP) (adjacent benzene resin) 15%；
Low shrink resin (PE powder) 8%；Release agent (barium stearate) 1.5%；Filler 51.1%；Curing agent (three acid of isopropyl peroxide
The tert-butyl ester) 0.15%；Glass fibre 24.25%.
A kind of preparation method of conventional motor plastic packaging material, includes the following steps:
1. resin, curing agent, pigment, release agent are added in dispersion cylinder, dispersion stirring 20min is stirred evenly
Liquid；
2. kneader is added in a filler material, 10min, the powder stirred evenly are stirred；
3. the liquid stirred evenly is added in the powder stirred evenly, 20min is stirred in kneader, is uniformly mixed
Paste；
4. being uniformly added into glass, 10min is stirred, obtains comparison rotor material.
Following table is the specific gravity of conventional motor plastic packaging material and embodiment 1-4, shrinking percentage, curing time, mobility, stretches by force
Degree, bending strength, impact strength data.
As it can be seen that the curing time of high speed rotor plastic packaging BMC material of the present invention is much larger than conventional motor plastic packaging material,
It stretches, be bent, impact strength is above conventional motor plastic packaging material.
Above specific embodiment is only presently preferred embodiments of the present invention, is not intended to limit the invention, all in this hair
Any modification, equivalent substitution, improvement and etc. done within bright spirit and principle, should be included in protection scope of the present invention it
It is interior.
Claims (10)
1. a kind of high speed rotor plastic packaging BMC material, including unsaturated polyester resin, low shrink resin, release agent, filler, Gu
Agent, glass fibre, it is characterized in that: it further include inhibitor；The inhibitor is hydroquinone, benzoquinones, to tert-butyl o
Benzenediol or quaternary ammonium salt.
2. high speed rotor plastic packaging BMC material as described in claim 1, it is characterized in that: the filler is aluminium hydroxide
At least one of with calcium carbonate.
3. high speed rotor plastic packaging BMC material as described in claim 1, it is characterized in that: the filler be partial size D50=
At least one of the calcium carbonate of the aluminium hydroxide and partial size D50=5-8um of 8-10um.
4. high speed rotor plastic packaging BMC material as described in claim 1, it is characterized in that: it further include thickener, the increasing
The thick dose of magnesia for Chun Du≤99%.
5. high speed rotor plastic packaging BMC material as described in claim 1, it is characterized in that: the unsaturated polyester resin
For isophthalic neopentyl glycol resins；The low shrink resin is modified PS solution.
6. high speed rotor plastic packaging BMC material as described in claim 1, it is characterized in that: the inhibitor be Chun Du≤
98% hydroquinone or benzoquinones.
7. the high speed rotor plastic packaging BMC material as described in claim 1-6 is any, it is characterized in that: including following weight hundred
Divide the raw material of ratio: unsaturated polyester resin 12-18%；Low shrink resin 4-10%；Release agent 1-3%；Filler 50-65%；Curing agent
0.1-0.5%；Glass fibre 15-25%；Inhibitor 0.1-0.5%；Thickener 0-0.1%.
8. the high speed rotor plastic packaging BMC material as described in claim 1-6 is any, it is characterised in that: including following weight hundred
Divide the raw material of ratio: unsaturated polyester resin 12-16%；Low shrink resin 6-10%；Release agent 1-2%；Filler 50-60%；Curing agent
0.1-0.3%；Glass fibre 18-25%；Inhibitor 0.1-0.3%；Thickener 0.01-0.08%.
9. the high speed rotor plastic packaging BMC material as described in claim 1-6 is any, it is characterised in that: including following weight hundred
Divide the raw material of ratio: unsaturated polyester resin 14-16%；Low shrink resin 8-10%；Release agent 1-2%；Filler 50-55%；Curing agent
0.1-0.2%；Glass fibre 20-25%；Inhibitor 0.1-0.2%；Thickener 0.03-0.05%.
10. the preparation method of high speed rotor plastic packaging BMC material as described in claim 1-6 is any, which is characterized in that including such as
Lower step:
(1) resin, curing agent, release agent, inhibitor are added in dispersion cylinder, dispersion stirs to get liquid；
(2) kneader is added in filler, stirs to get powder；
(3) liquid of step 1 is added in the powder of step 2, paste is stirred to get in kneader；
(4) when needing to add thickener, thickener is added in the paste of step 3, thickening paste is stirred to get in kneader
Object；
(5) it is uniformly added into glass fibre, stirs to get this product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811629181.9A CN109694562A (en) | 2018-12-29 | 2018-12-29 | A kind of high speed rotor plastic packaging BMC material and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811629181.9A CN109694562A (en) | 2018-12-29 | 2018-12-29 | A kind of high speed rotor plastic packaging BMC material and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109694562A true CN109694562A (en) | 2019-04-30 |
Family
ID=66232402
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811629181.9A Pending CN109694562A (en) | 2018-12-29 | 2018-12-29 | A kind of high speed rotor plastic packaging BMC material and preparation method thereof |
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| Country | Link |
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| CN (1) | CN109694562A (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002212408A (en) * | 2001-01-17 | 2002-07-31 | Hitachi Chem Co Ltd | Unsaturated polyester resin composition |
| CN102757630A (en) * | 2012-07-30 | 2012-10-31 | 无锡新宏泰电器科技股份有限公司 | Low temperature and low pressure BMC (Bulk Molding Compound) material, preparation method thereof and purpose thereof |
| CN108017891A (en) * | 2016-11-04 | 2018-05-11 | 无锡创达新材料股份有限公司 | A kind of anlistatig unsaturated polyester glass fibre enhancing tubular molding compound |
-
2018
- 2018-12-29 CN CN201811629181.9A patent/CN109694562A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002212408A (en) * | 2001-01-17 | 2002-07-31 | Hitachi Chem Co Ltd | Unsaturated polyester resin composition |
| CN102757630A (en) * | 2012-07-30 | 2012-10-31 | 无锡新宏泰电器科技股份有限公司 | Low temperature and low pressure BMC (Bulk Molding Compound) material, preparation method thereof and purpose thereof |
| CN108017891A (en) * | 2016-11-04 | 2018-05-11 | 无锡创达新材料股份有限公司 | A kind of anlistatig unsaturated polyester glass fibre enhancing tubular molding compound |
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Application publication date: 20190430 |
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