CN105086352B - A kind of bakelite and preparation method thereof - Google Patents
A kind of bakelite and preparation method thereof Download PDFInfo
- Publication number
- CN105086352B CN105086352B CN201510579969.3A CN201510579969A CN105086352B CN 105086352 B CN105086352 B CN 105086352B CN 201510579969 A CN201510579969 A CN 201510579969A CN 105086352 B CN105086352 B CN 105086352B
- Authority
- CN
- China
- Prior art keywords
- parts
- bakelite
- inserts
- phenolic resin
- asbestos
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 229920001342 Bakelite® Polymers 0.000 title claims abstract description 36
- 239000004637 bakelite Substances 0.000 title claims abstract description 36
- 238000002360 preparation method Methods 0.000 title claims abstract description 11
- 239000000463 material Substances 0.000 claims abstract description 22
- 229920001568 phenolic resin Polymers 0.000 claims abstract description 14
- 239000000843 powder Substances 0.000 claims abstract description 13
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000005011 phenolic resin Substances 0.000 claims abstract description 12
- 239000002023 wood Substances 0.000 claims abstract description 12
- 239000005995 Aluminium silicate Substances 0.000 claims abstract description 11
- 229920000459 Nitrile rubber Polymers 0.000 claims abstract description 11
- 235000012211 aluminium silicate Nutrition 0.000 claims abstract description 11
- 239000010425 asbestos Substances 0.000 claims abstract description 11
- 239000000839 emulsion Substances 0.000 claims abstract description 11
- 239000003365 glass fiber Substances 0.000 claims abstract description 11
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims abstract description 11
- 229910052895 riebeckite Inorganic materials 0.000 claims abstract description 11
- 229920001909 styrene-acrylic polymer Polymers 0.000 claims abstract description 11
- 239000002202 Polyethylene glycol Substances 0.000 claims abstract description 10
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims abstract description 10
- 229910021502 aluminium hydroxide Inorganic materials 0.000 claims abstract description 10
- 235000013312 flour Nutrition 0.000 claims abstract description 10
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims abstract description 10
- 229920001223 polyethylene glycol Polymers 0.000 claims abstract description 10
- 239000004575 stone Substances 0.000 claims abstract description 10
- CSKNSYBAZOQPLR-UHFFFAOYSA-N benzenesulfonyl chloride Chemical compound ClS(=O)(=O)C1=CC=CC=C1 CSKNSYBAZOQPLR-UHFFFAOYSA-N 0.000 claims abstract description 9
- 238000001125 extrusion Methods 0.000 claims abstract description 6
- 238000004898 kneading Methods 0.000 claims abstract description 6
- 239000002994 raw material Substances 0.000 claims abstract description 5
- 238000003756 stirring Methods 0.000 claims description 6
- 238000005815 base catalysis Methods 0.000 claims description 2
- 150000002989 phenols Chemical class 0.000 claims description 2
- AHIBWURJLGCHAY-UHFFFAOYSA-N [S].C1=CC=CC=C1 Chemical compound [S].C1=CC=CC=C1 AHIBWURJLGCHAY-UHFFFAOYSA-N 0.000 claims 1
- 150000001263 acyl chlorides Chemical class 0.000 claims 1
- 150000001299 aldehydes Chemical class 0.000 claims 1
- 239000011810 insulating material Substances 0.000 abstract description 4
- 230000004913 activation Effects 0.000 abstract description 3
- 239000004033 plastic Substances 0.000 description 5
- 229920003023 plastic Polymers 0.000 description 5
- 238000010521 absorption reaction Methods 0.000 description 3
- 239000000945 filler Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 238000005452 bending Methods 0.000 description 2
- INJRKJPEYSAMPD-UHFFFAOYSA-N aluminum;silicic acid;hydrate Chemical compound O.[Al].[Al].O[Si](O)(O)O INJRKJPEYSAMPD-UHFFFAOYSA-N 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000010292 electrical insulation Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 125000002485 formyl group Chemical class [H]C(*)=O 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 239000010443 kyanite Substances 0.000 description 1
- 229910052850 kyanite Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- -1 phenolic aldehyde Chemical class 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
- Separation, Recovery Or Treatment Of Waste Materials Containing Plastics (AREA)
Abstract
The invention discloses a kind of bakelite and preparation method thereof, belong to Material Field.Solve existing bakelite size unstable, the big problem of creep properties.It is made up of the raw material of following weight portion:80 100 parts of phenolic resin, 10 20 parts of bakelite reclaimed materials, 5 10 parts of nitrile rubber, 37 parts of styrene-acrylic emulsion, 10 15 parts of aluminium hydroxide, 8 12 parts of polyethylene glycol, 15 parts of benzene sulfonyl chloride, 7 12 parts of odium stearate, 10 20 parts of wood powder of activation, 15 30 parts of kaolin, 38 parts of aquamaine stone flour, 30 35 parts of glass fibre, 8 13 parts of asbestos.Preparation method includes preparing inserts;High-speed kneading is plasticated;Extrusion finished product.Bakelite of the invention can be extensively using the insulating materials for making various machine components, electric parts.
Description
Technical field
The present invention relates to a kind of bakelite and preparation method thereof, belong to Material Field.
Background technology
Bakelite is a kind of hard and crisp thermosetting plastics, is being commonly called as phenoplasts with wood powder as filler.Relative to general
Logical plastics, bakelite has high mechanical strength, and tough and hard wear resistant, dimensionally stable is corrosion-resistant, the features such as electrical insulation capability is excellent.With
Power system scale expands day by day, in the process of deployment of supply line, it is necessary to it is substantial amounts of using all kinds of insulating materials to line
Road is supported or connects, and wherein bakelite material has extremely wide application.
Water oxygen base in phenoplasts is strong to the compatibility of water, and easy moisture absorption, volumetric expansion after plastic moisture absorption produces planted agent
Power, meeting buckling deformation, general moisture absorption 3%, bending strength will reduce by 25% or so.As moisture content increases, impact strength is gradually
Improve, and tensile strength and bending strength are then substantially reduced.It is 100% in relative humidity, under temperature is 50 DEG C of wet heat condition,
The time that plastic part size reaches balance only has half under room temperature state.The material moulding plastics of water content 0.1%, its size is steady
Qualitative very poor, temperature reaches 150 DEG C, and phenolic aldehyde shrinkage of injection molded parts tends to be balanced, and again when rising, plastic may proceed to shrink temperature again,
That is existing bakelite size is unstable, and creep properties is big, is not suitable for use in high-precision mechanical and electric parts
Insulating materials.
Goal of the invention
It is an object of the invention to provide a kind of bakelite, with dimensionally stable, the characteristics of creep is small.
The present invention also aims to provide a kind of preparation method of bakelite.
Described bakelite, is made up of the raw material of following weight portion:Phenolic resin 80-100 parts, bakelite reclaimed materials
10-20 parts, nitrile rubber 5-10 parts, styrene-acrylic emulsion 3-7 parts, aluminium hydroxide 10-15 parts, polyethylene glycol 8-12 parts, benzene sulfonyl chloride
1-5 parts, odium stearate 7-12 parts, activate 10-20 parts of wood powder, kaolin 15-30 parts, 3-8 parts of aquamaine stone flour, glass fibre 30-
35 parts, asbestos 8-13 parts.
Described phenolic resin is aldehydes and phenols according to 1:1.4 mol ratio, the obtained first rank under base catalysis
Section resin.
Preferred bakelite, is made up of the raw material of following weight portion:90 parts of phenolic resin, bakelite reclaimed materials 15
Part, 7 parts of nitrile rubber, 5 parts of styrene-acrylic emulsion, 12 parts of aluminium hydroxide, 10 parts of polyethylene glycol, 3 parts of benzene sulfonyl chloride, 9 parts of odium stearate,
15 parts of wood powder of activation, 20 parts of kaolin, 5 parts of aquamaine stone flour, 32 parts of glass fibre, 10 parts of asbestos.
The preparation method of described bakelite, comprises the following steps:
1) inserts is prepared:
By 10-20 parts of bakelite reclaimed materials mechanical crushing to 100-200 mesh, then with aluminium hydroxide 10-15 parts, activation
Wood powder 10-20 parts, kaolin 15-30 parts, 3-8 parts of aquamaine stone flour, glass fibre 30-35 parts, asbestos 8-13 parts, odium stearate 7-
12 parts are sufficiently mixed uniformly, obtain inserts;
2) high-speed kneading is plasticated:
Phenolic resin and nitrile rubber are heated to molten state, are poured into inserts, under the conditions of 55-65 DEG C, with
After the rotating speed of 1000-1600r/min is stirred 30-50 minutes, by styrene-acrylic emulsion 3-7 parts, polyethylene glycol 8-12 parts, benzene sulfonyl chloride 1-
In 5 parts of addition inserts, continue to stir 3-5 hours;
3) finished product is extruded:
Material is delivered into mould press mold extrusion finished product.
Compared with prior art the beneficial effects of the invention are as follows:
The present invention uses SI semi-insulation bakelite reclaimed materials, not only solves bakelite and reclaims problem, and is conducive to drop
Low production cost;Addition nitrile rubber be conducive to improve product mechanical performance, with activate wood powder, kaolin, glass fibre with
And asbestos do filler, can make bakelite that there are dielectric properties higher, and avoid bakelite moisture expantion, styrene-acrylic emulsion and kyanite
Powder can at high temperature play a part of to offset and shrink as expansion component, the species and consumption by adjusting filler of the invention,
The stabilization of product size has been effectively ensured, creep is atomic small, thus bakelite of the present invention can extensively using make it is high-precision machinery and
The insulating materials of electric parts.
Specific embodiment
With reference to specific embodiment, the present invention will be further described.
Embodiment 1
The preparation method of described bakelite, comprises the following steps:
1) inserts is prepared:
By 15 parts of bakelite reclaimed materials mechanical crushings to 150 mesh, then with 12 parts of aluminium hydroxide, 15 parts of wood powder is activated,
20 parts of kaolin, 5 parts of aquamaine stone flour, 32 parts of glass fibre, 10 parts of asbestos, 9 parts of odium stearate is sufficiently mixed uniformly, is filled
Material;
2) high-speed kneading is plasticated:
Phenolic resin and nitrile rubber are heated to molten state, are poured into inserts, under the conditions of 60 DEG C, with 1400
Rev/min rotating speed stir 40 minutes after, by 5 parts of styrene-acrylic emulsion, 10 parts of polyethylene glycol, 3 parts of benzene sulfonyl chloride is added in inserts, after
Continuous stirring 4 hours;
3) finished product is extruded:
Material is delivered into mould press mold extrusion finished product.
Embodiment 2
The preparation method of described bakelite, comprises the following steps:
1) inserts is prepared:
By 10 parts of bakelite reclaimed materials mechanical crushings to 100 mesh, then with 10 parts of aluminium hydroxide, 10 parts of wood powder is activated,
15 parts of kaolin, 3 parts of aquamaine stone flour, 30 parts of glass fibre, 8 parts of asbestos, 7 parts of odium stearate is sufficiently mixed uniformly, is filled
Material;
2) high-speed kneading is plasticated:
Phenolic resin and nitrile rubber are heated to molten state, are poured into inserts, under the conditions of 55 DEG C, with 1000r/
After the rotating speed of min is stirred 30 minutes, by 3 parts of styrene-acrylic emulsion, 8 parts of polyethylene glycol, 1 part of benzene sulfonyl chloride is added in inserts, is continued
Stirring 3 hours;
3) finished product is extruded:
Material is delivered into mould press mold extrusion finished product.
Embodiment 3
The preparation method of described bakelite, comprises the following steps:
1) inserts is prepared:
By 20 parts of bakelite reclaimed materials mechanical crushings to 200 mesh, then with 15 parts of aluminium hydroxide, 20 parts of wood powder is activated,
30 parts of kaolin, 8 parts of aquamaine stone flour, 35 parts of glass fibre, 13 parts of asbestos, 12 parts of odium stearate is sufficiently mixed uniformly, is filled out
Charge;
2) high-speed kneading is plasticated:
Phenolic resin and nitrile rubber are heated to molten state, are poured into inserts, under the conditions of 65 DEG C, with 1600r/
After the rotating speed of min is stirred 50 minutes, by 7 parts of styrene-acrylic emulsion, 12 parts of polyethylene glycol, 5 parts of benzene sulfonyl chloride is added in inserts, is continued
Stirring 5 hours;
3) finished product is extruded:
Material is delivered into mould press mold extrusion finished product.
Claims (3)
1. a kind of bakelite, it is characterised in that be made up of the raw material of following weight portion:Phenolic resin 80-100 parts, bakelite
Reclaimed materials 10-20 parts, nitrile rubber 5-10 parts, styrene-acrylic emulsion 3-7 parts, aluminium hydroxide 10-15 parts, polyethylene glycol 8-12 parts, benzene
Sulfonic acid chloride 1-5 parts, odium stearate 7-12 parts, activate 10-20 parts of wood powder, kaolin 15-30 parts, 3-8 parts of aquamaine stone flour, glass fibers
30-35 parts, asbestos 8-13 parts of dimension;
Described phenolic resin is aldehydes and phenols according to 1:1.4 mol ratio, the obtained first stage tree under base catalysis
Fat.
2. bakelite according to claim 1, it is characterised in that be made up of the raw material of following weight portion:Phenolic resin 90
Part, 15 parts of bakelite reclaimed materials, 7 parts of nitrile rubber, 5 parts of styrene-acrylic emulsion, 12 parts of aluminium hydroxide, 10 parts of polyethylene glycol, benzene sulphur
3 parts of acyl chlorides, 9 parts of odium stearate activates 15 parts of wood powder, 20 parts of kaolin, 5 parts of aquamaine stone flour, 32 parts of glass fibre, asbestos 10
Part.
3. the preparation method of the bakelite described in a kind of claim 1, it is characterised in that comprise the following steps:
1) inserts is prepared:
By 10-20 parts of bakelite reclaimed materials mechanical crushing to 100-200 mesh, then with aluminium hydroxide 10-15 parts, wood powder is activated
10-20 parts, kaolin 15-30 parts, 3-8 parts, glass fibre 30-35 parts, asbestos 8-13 parts, odium stearate 7-12 parts of aquamaine stone flour
It is sufficiently mixed uniformly, obtains inserts;
2) high-speed kneading is plasticated:
Phenolic resin and nitrile rubber are heated to molten state, are poured into inserts, under the conditions of 55-65 DEG C, with 1000-
After the rotating speed of 1600r/min is stirred 30-50 minutes, by styrene-acrylic emulsion 3-7 parts, polyethylene glycol 8-12 parts, benzene sulfonyl chloride 1-5 parts adds
Enter in inserts, continue to stir 3-5 hours;
3) finished product is extruded:
Material is delivered into mould pressing mold extrusion finished product.
Priority Applications (1)
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CN201510579969.3A CN105086352B (en) | 2015-09-14 | 2015-09-14 | A kind of bakelite and preparation method thereof |
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CN201510579969.3A CN105086352B (en) | 2015-09-14 | 2015-09-14 | A kind of bakelite and preparation method thereof |
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CN105086352A CN105086352A (en) | 2015-11-25 |
CN105086352B true CN105086352B (en) | 2017-06-20 |
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CN201510579969.3A Expired - Fee Related CN105086352B (en) | 2015-09-14 | 2015-09-14 | A kind of bakelite and preparation method thereof |
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Publication number | Priority date | Publication date | Assignee | Title |
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CN107603130A (en) * | 2017-09-15 | 2018-01-19 | 郑素云 | Bakelite |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101974198A (en) * | 2010-10-14 | 2011-02-16 | 常熟东南塑料有限公司 | Heat-resisting phenolic moulding compound |
CN101974199A (en) * | 2010-10-14 | 2011-02-16 | 常熟东南塑料有限公司 | Low-shrinkage phenolic moulding compound |
CN102408670A (en) * | 2011-09-16 | 2012-04-11 | 无锡创达电子有限公司 | Ammonia-free phenolic molding compound and its preparation method |
-
2015
- 2015-09-14 CN CN201510579969.3A patent/CN105086352B/en not_active Expired - Fee Related
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101974198A (en) * | 2010-10-14 | 2011-02-16 | 常熟东南塑料有限公司 | Heat-resisting phenolic moulding compound |
CN101974199A (en) * | 2010-10-14 | 2011-02-16 | 常熟东南塑料有限公司 | Low-shrinkage phenolic moulding compound |
CN102408670A (en) * | 2011-09-16 | 2012-04-11 | 无锡创达电子有限公司 | Ammonia-free phenolic molding compound and its preparation method |
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CN105086352A (en) | 2015-11-25 |
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Granted publication date: 20170620 Termination date: 20180914 |