CN103804851A - Injection moulded phenolic moulding plastic for communtator - Google Patents

Injection moulded phenolic moulding plastic for communtator Download PDF

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Publication number
CN103804851A
CN103804851A CN201410052922.7A CN201410052922A CN103804851A CN 103804851 A CN103804851 A CN 103804851A CN 201410052922 A CN201410052922 A CN 201410052922A CN 103804851 A CN103804851 A CN 103804851A
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China
Prior art keywords
injection molding
moulding compound
phenolaldehyde moulding
parts
commutator
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CN201410052922.7A
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Chinese (zh)
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CN103804851B (en
Inventor
邱维
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GUANGXI XINHEXIN SYNTHETIC MATERIALS CO Ltd
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GUANGXI XINHEXIN SYNTHETIC MATERIALS CO Ltd
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Priority to CN201410052922.7A priority Critical patent/CN103804851B/en
Publication of CN103804851A publication Critical patent/CN103804851A/en
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Publication of CN103804851B publication Critical patent/CN103804851B/en
Expired - Fee Related legal-status Critical Current
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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25Component parts, details or accessories; Auxiliary operations
    • B29C48/92Measuring, controlling or regulating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25Component parts, details or accessories; Auxiliary operations
    • B29C48/78Thermal treatment of the extrusion moulding material or of preformed parts or layers, e.g. by heating or cooling
    • B29C48/875Thermal treatment of the extrusion moulding material or of preformed parts or layers, e.g. by heating or cooling for achieving a non-uniform temperature distribution, e.g. using barrels having both cooling and heating zones
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2948/00Indexing scheme relating to extrusion moulding
    • B29C2948/92Measuring, controlling or regulating
    • B29C2948/92504Controlled parameter
    • B29C2948/92704Temperature
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2948/00Indexing scheme relating to extrusion moulding
    • B29C2948/92Measuring, controlling or regulating
    • B29C2948/92819Location or phase of control
    • B29C2948/92857Extrusion unit
    • B29C2948/92876Feeding, melting, plasticising or pumping zones, e.g. the melt itself
    • B29C2948/92895Barrel or housing

Abstract

The invention discloses an injection moulded phenolic moulding plastic for a commentator. The injection moulded phenolic moulding plastic comprises the following components in parts by weight: 15-24 parts of phenolic resin, 3-8 parts of a curing agent, 1-3 parts of a curing accelerator, 25-33 parts of reinforced fibers, 0.5-2 parts of a releasing agent, 10-45 parts of inorganic filler and 1-5 parts of a flexibilizer. The phenolic moulding plastic can be used for an injection moulding machine, so that the moulding efficiency is greatly improved. The mould is not sticky, the bending strength of the moulded product reaches up to over 180Mpa, the thermal deformation temperature is greater than 240 DEG C, and the insulation resistance is greater than 1011 ohms.

Description

Commutator injection molding phenolaldehyde moulding compound
Technical field
The invention belongs to phenolaldehyde moulding compound field, be specifically related to a kind of commutator injection molding phenolaldehyde moulding compound.
Background technology
Commutator is an important component of electric motor, should have good electric property, resistance toheat, physical strength and dimensional stability for the phenolaldehyde moulding compound of commutator.The phenolaldehyde moulding compound that existing domestic commutator is used is subject to its performance limitations, not being suitable for small-sized reverser (external diameter 10mm is following) uses, and mostly can only be used for compression molding, cannot meet injection molding requirement, for example, before applicant, a kind of high bending strength phenolaldehyde moulding compound (CN102775723A) of application has high bending strength and shock strength, but also having some limitations property, thereby the pushing ram that can block injector when for injection molding cannot be produced, and for ensureing dimensional stability, can only be used for into the commutator that molded external diameter is greater than 10mm, if commutator endoporus less (endoporus 3mm is following), when fraising or last item, easily ftracture.In addition, the efficiency of compression molding is far below injection molding, and as compression molding needs a 2-3 minute mould (dwell time 75-120 second), and injection molding only needs 1 minute mould (dwell time 25-35 second).
Summary of the invention
The deficiency that the object of the invention is to overcome above-mentioned commutator phenolaldehyde moulding compound, makes improvements, and provides one to can be used for injection molding commutator phenolaldehyde moulding compound.
It is as follows that the present invention realizes the technical scheme that above-mentioned purpose adopts:
A kind of commutator injection molding phenolaldehyde moulding compound, by weight, comprises following component:
Resol 15-24 part, solidifying agent 3-8 part, curing catalyst 1-3 part, fortifying fibre 25-33 part, releasing agent 0.5-2 part, mineral filler 10-45 part and toughner 1-5 part.
Further, the softening temperature of described resol is that 90-100 ℃, free phenol content are 0.5-8%.
Further, described solidifying agent is vulkacit H.
Further, described curing catalyst is at least one in calcium oxide, magnesium oxide, calcium hydroxide and magnesium hydroxide.
Further, described fortifying fibre is alkali free glass fibre.
Further, described releasing agent is at least one in stearic acid, Zinic stearas, calcium stearate, Magnesium Stearate, aluminum stearate, silicone release and paraffin.
Further, described mineral filler is at least one in wollastonite, mica powder and talcum powder.
Further, described toughner is urethane.
The preparation method of injection molding phenolaldehyde moulding compound for above-mentioned commutator, comprises after described each component is mixed into screw extrusion press and extruding, wherein, three sections of temperature settings of screw extrusion press are respectively: one section of 20-60 ℃, two sections of 60-115 ℃, three sections of 75-125 ℃.
In the present invention, resol softening temperature is 90-100 ℃ (GB/T8146-2003), free phenol content is 0.5%-8%(ISO8974-2002), low softening point has ensured that product is softening smoothly in injector machine barrel, do not block machine barrel, low-free phenol, ensures product sticking to mould not in machine barrel and mould, reduces the corrosion to injection cylinder and mould.
In the present invention, select alkali free glass fibre as fortifying fibre, optimum fiber mean diameter is 8-9 μ m, and mean length is 2-2.9mm, has ensured that reverser endoporus fraising time ratio is easier to, and meets the use of small-sized reverser (external diameter 10mm is following).
In the present invention, when selecting urethane to ensure product fraising and last item as toughner, do not ftracture.
Commutator of the present invention can be used for injection moulding machine with injection molding phenolaldehyde moulding compound, thereby has greatly improved shaping efficiency, and more than after moulding, flexural strength reaches 180Mpa, heat-drawn wire is greater than 240 ℃, and insulation resistance is greater than 10 11ohm.Compared with pressure roller technique, the present invention can uninterruptedly produce continuously, because being completes in extruder barrel inside, and production process environmental protection, and in production process, quality product, processing parameter are easily controlled, and efficiency is high, good product consistency.
Embodiment
Below in conjunction with preferred embodiment, the present invention is described in further details.
Embodiment mono-
By weight, by 24 parts of resol, (softening temperature is 90-100 ℃ of GB/T8146-2003, free phenol content is 0.5%-8% ISO8974-2002), 8 parts of vulkacit Hs, 2 parts of magnesium oxide, (mean diameter is 8-9 μ m to 26 parts of alkali free glass fibres, mean length is 2-6mm), 1 part of stearic acid, 36 parts of wollastonites and 3 parts of urethane (model MH-T80, particulate state, order number is 75-300 order) prepare burden after mixing, (machine models is WF100 to enter single screw extrusion machine, warm area is divided into three sections, first paragraph feeding preheating, second segment is mediated plasticizing, mediate homogenizing and discharging for the 3rd section) extrude, wherein, three sections of temperature of screw extrusion press are set to respectively: one section 45 ℃, two sections 98 ℃, three sections 85 ℃, after extruding through compressing tablet, cooling, pulverizing obtains the following particle of diameter 2cm, be commutator injection molding phenolaldehyde moulding compound.
Embodiment bis-
By weight, 20 parts of resol, 7 parts of vulkacit Hs, 1 part of magnesium oxide, 1 part of calcium oxide, 30 parts of alkali free glass fibres, 0.5 part of stearic acid, 1 part of calcium stearate, 36.5 parts of mica powders and 3 parts of urethane batchings are mixed, and production process is identical with embodiment mono-.
Embodiment tri-
By weight, 15 parts of resol, 6 parts of vulkacit Hs, 2 parts of magnesium oxide, 33 parts of alkali free glass fibres, 1 part of Zinic stearas, 36 parts of talcum powder, 3 parts of urethane batchings are mixed, production process is identical with embodiment mono-.
Commutator by above embodiment mono-to three gained is made test strip (batten is with reference to phenolaldehyde moulding compound GB GB1401.3-2008 compacting) with injection molding phenolaldehyde moulding compound particle through sampling, through after fixing, (oven temperature is set 150 degree 3 hours, 190 degree 3 hours, 210 degree 3 hours) process to obtain test sample, test result is as follows.
Figure 2014100529227100002DEST_PATH_IMAGE001
Parameters meets phenolaldehyde moulding compound GB GB1401.3-2008.
By injection molding phenolaldehyde moulding compound finished product production test on injection moulding machine for commutator (producing external diameter is the commutator of 8.0mm and 5.6mm) of above embodiment gained, meet design requirements completely through test, and produce continuously not stifled machine, not sticking to mould, fraising is not ftractureed.
Injector processing parameter:
Barrel temperature is set: 70-95 ℃, injection pressure is 80-120Mpa, die temperature: 180 ℃, set inject time: 25-120 second.

Claims (9)

1. a commutator injection molding phenolaldehyde moulding compound, is characterized in that, by weight, comprises following component:
Resol 15-24 part, solidifying agent 3-8 part, curing catalyst 1-3 part, fortifying fibre 25-33 part, releasing agent 0.5-2 part, mineral filler 10-45 part and toughner 1-5 part.
2. commutator according to claim 1 injection molding phenolaldehyde moulding compound, is characterized in that, the softening temperature of described resol is that 90-100 ℃, free phenol content are 0.5-8%.
3. commutator according to claim 1 injection molding phenolaldehyde moulding compound, is characterized in that, described solidifying agent is vulkacit H.
4. commutator according to claim 1 injection molding phenolaldehyde moulding compound, is characterized in that, described curing catalyst is at least one in calcium oxide, magnesium oxide, calcium hydroxide and magnesium hydroxide.
5. commutator according to claim 1 injection molding phenolaldehyde moulding compound, is characterized in that, described fortifying fibre is alkali free glass fibre.
6. commutator according to claim 1 injection molding phenolaldehyde moulding compound, is characterized in that, described releasing agent is at least one in stearic acid, Zinic stearas, calcium stearate, Magnesium Stearate, aluminum stearate, silicone release and paraffin.
7. commutator according to claim 1 injection molding phenolaldehyde moulding compound, is characterized in that, described mineral filler is at least one in wollastonite, mica powder and talcum powder.
8. commutator according to claim 1 injection molding phenolaldehyde moulding compound, is characterized in that, described toughner is urethane.
9. the preparation method of commutator use injection molding phenolaldehyde moulding compound described in claim 1, it is characterized in that, comprise after described each component is mixed into screw extrusion press and extruding, wherein, three sections of temperature settings of screw extrusion press are respectively: one section of 20-60 ℃, two sections of 60-115 ℃, three sections of 75-125 ℃.
CN201410052922.7A 2014-02-17 2014-02-17 Commutator injection molding phenolaldehyde moulding compound Expired - Fee Related CN103804851B (en)

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Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
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CN103804851B CN103804851B (en) 2015-09-02

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Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104559042A (en) * 2014-12-30 2015-04-29 浙江嘉民塑胶有限公司 Phenolic resin injection molding material for bakelite brush carrier
CN105017713A (en) * 2015-07-28 2015-11-04 广西信和新合成材料有限公司 High-glass-fiber extrusion die head granulation-type phenol formaldehyde molding compound for motor commutators
CN107226995A (en) * 2017-07-25 2017-10-03 常州信息职业技术学院 A kind of light-duty phenoplasts power check well and preparation method thereof
CN107236247A (en) * 2017-07-25 2017-10-10 常州信息职业技术学院 A kind of light-duty phenoplasts inspection shaft and preparation method thereof
CN107266854A (en) * 2017-07-25 2017-10-20 常州信息职业技术学院 A kind of plain edition or heavy phenoplasts inspection shaft and preparation method thereof
CN107903581A (en) * 2017-12-19 2018-04-13 广西信和新合成材料有限公司 Square particle benzoxazine moulding compound
CN109912926A (en) * 2019-03-29 2019-06-21 昆山森华化工有限公司 One kind is for molding phenolaldehyde moulding compound of automobile component and preparation method thereof
CN113337076A (en) * 2021-05-12 2021-09-03 瑞安市恒丰机电有限公司 Bakelite flour material for manufacturing commutator
CN116376216A (en) * 2023-03-27 2023-07-04 宁波安力电子材料有限公司 Preparation method of phenolic resin molding material for commutator

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101781441A (en) * 2009-01-21 2010-07-21 上海欧亚合成材料有限公司 Phenolic moulding plastics for commutator
CN102775723A (en) * 2012-06-07 2012-11-14 广西信和新合成材料有限公司 Phenolic aldehyde moulding compound with high flexural strength

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CN101781441A (en) * 2009-01-21 2010-07-21 上海欧亚合成材料有限公司 Phenolic moulding plastics for commutator
CN102775723A (en) * 2012-06-07 2012-11-14 广西信和新合成材料有限公司 Phenolic aldehyde moulding compound with high flexural strength

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Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104559042A (en) * 2014-12-30 2015-04-29 浙江嘉民塑胶有限公司 Phenolic resin injection molding material for bakelite brush carrier
CN105017713A (en) * 2015-07-28 2015-11-04 广西信和新合成材料有限公司 High-glass-fiber extrusion die head granulation-type phenol formaldehyde molding compound for motor commutators
CN107226995A (en) * 2017-07-25 2017-10-03 常州信息职业技术学院 A kind of light-duty phenoplasts power check well and preparation method thereof
CN107236247A (en) * 2017-07-25 2017-10-10 常州信息职业技术学院 A kind of light-duty phenoplasts inspection shaft and preparation method thereof
CN107266854A (en) * 2017-07-25 2017-10-20 常州信息职业技术学院 A kind of plain edition or heavy phenoplasts inspection shaft and preparation method thereof
CN107903581A (en) * 2017-12-19 2018-04-13 广西信和新合成材料有限公司 Square particle benzoxazine moulding compound
CN109912926A (en) * 2019-03-29 2019-06-21 昆山森华化工有限公司 One kind is for molding phenolaldehyde moulding compound of automobile component and preparation method thereof
CN113337076A (en) * 2021-05-12 2021-09-03 瑞安市恒丰机电有限公司 Bakelite flour material for manufacturing commutator
CN116376216A (en) * 2023-03-27 2023-07-04 宁波安力电子材料有限公司 Preparation method of phenolic resin molding material for commutator

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