CN109693451A - A kind of thermal printing head heating base plate and its manufacturing method - Google Patents

A kind of thermal printing head heating base plate and its manufacturing method Download PDF

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Publication number
CN109693451A
CN109693451A CN201910080450.9A CN201910080450A CN109693451A CN 109693451 A CN109693451 A CN 109693451A CN 201910080450 A CN201910080450 A CN 201910080450A CN 109693451 A CN109693451 A CN 109693451A
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CN
China
Prior art keywords
layer
printing head
thermal printing
base plate
protective layer
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Pending
Application number
CN201910080450.9A
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Chinese (zh)
Inventor
赵继凤
孙华刚
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Shandong Hualing Electronics Co Ltd
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Shandong Hualing Electronics Co Ltd
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Filing date
Publication date
Application filed by Shandong Hualing Electronics Co Ltd filed Critical Shandong Hualing Electronics Co Ltd
Priority to CN201910080450.9A priority Critical patent/CN109693451A/en
Publication of CN109693451A publication Critical patent/CN109693451A/en
Pending legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41JTYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS
    • B41J2/00Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed
    • B41J2/315Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed characterised by selective application of heat to a heat sensitive printing or impression-transfer material
    • B41J2/32Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed characterised by selective application of heat to a heat sensitive printing or impression-transfer material using thermal heads
    • B41J2/335Structure of thermal heads
    • B41J2/33505Constructional details
    • B41J2/33535Substrates
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41JTYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS
    • B41J2/00Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed
    • B41J2/315Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed characterised by selective application of heat to a heat sensitive printing or impression-transfer material
    • B41J2/32Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed characterised by selective application of heat to a heat sensitive printing or impression-transfer material using thermal heads
    • B41J2/335Structure of thermal heads
    • B41J2/33505Constructional details
    • B41J2/3351Electrode layers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41JTYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS
    • B41J2/00Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed
    • B41J2/315Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed characterised by selective application of heat to a heat sensitive printing or impression-transfer material
    • B41J2/32Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed characterised by selective application of heat to a heat sensitive printing or impression-transfer material using thermal heads
    • B41J2/335Structure of thermal heads
    • B41J2/33505Constructional details
    • B41J2/33515Heater layers

Abstract

The present invention proposes a kind of thermal printing head heating base plate, including insulating substrate, comprehensively or partial ground glaze layer is equipped on the surface of insulating substrate, public electrode and individual electrode are equipped on the surface of insulating substrate and ground glaze layer, heating resistor configures between electrodes along main Print direction, one end of public electrode is connected along secondary Print direction with heating resistor, and the other end is connected with printing power supply;One end of individual electrode is connected along secondary Print direction with heating resistor, and the other end is connected with control IC;Insulating protective layer is covered on the surface of heating resistor, public electrode and part individual electrode; it is equipped with transition zone on the protection layer; the functional layer of hydrophobic oleophobic is equipped on transition zone, functional layer is made of inorganic material, and protective layer, transition zone and functional layer constitute surface composite layer.Above-mentioned thermal printing head is strong with heating base plate hydrophobic oleophobic ability, can improve carbon distribution and sticky paper phenomenon in print procedure, extend the service life of thermal printing head.

Description

A kind of thermal printing head heating base plate and its manufacturing method
Technical field
The present invention relates to thermal printing field more particularly to a kind of thermal printing head heating base plate and its manufacturing methods.
Background technique
It is well known that print head fever makes thermal media be heated color development, thermal media when heated when thermal printing head works Chromonic layer it is in a molten state, not only containing organic/inorganic substance but also organic matter is contained in the fusant of chromonic layer, thermal media is in cooling It is contacted always with print head in the process, the fusant meeting adhesion of chromonic layer on the print head, forms carbon distribution, influences gradation of drop-out colour With product service life;In addition the cooling of thermal media fusant also will cause thermal printing head sticky paper, be embodied in temperature-sensitive Medium can be with the different degrees of adhesion of print head, cannot be smooth by print head, causes scarce line and noise of lettering etc..Carbon distribution and viscous Paper problem influences gradation of drop-out colour, lettering quality and the service life of thermal printing head, and more universal.
Related art is as follows:
Publicity forms ditch close to the position of raised line on the surface of print head paper delivery side protective film on special open 2000-246934 The method that slot reduces carbon distribution, but the product mentioned in the patent, the opening breadth of ditch is small, depth as shallow, once the bigger meeting of carbon deposition quantity So that the segment difference of ditch is disappeared, cannot sufficiently take carbon distribution out of by the crimping of record media.
The utility model patent of Patent No. 201520630708.5 proposes one kind and sets hydrophilic layer, in paper delivery in paper feed side Side sets the thermal printing head of hydrophobic layer, which can improve the carbon deposition phenomenon of thermal printing head, but not consider in the utility model The presence of organic matter in carbon distribution, does not provide film layer preparation method yet.
The application for a patent for invention that number of patent application is 201510101328.7 discloses a kind of wear-resisting dewatering nano THIN COMPOSITE The preparation method of film, but it is conductive metal that the laminated film in the patent application, which prepares matrix, is not mentioned in similar thermal printing The method that wear-resisting hydrophobic film layer is prepared on the insulating substrate of head, does not mention the oleophobic performance of film layer yet.
Summary of the invention
In order to solve the problems in the existing technology, the invention proposes a kind of thermal printing head heating base plate and its Manufacturing method extends the service life of thermal printing head to improve the carbon distribution and sticky paper phenomenon in print procedure.
To achieve the goals above, an aspect of of the present present invention proposes a kind of thermal printing head heating base plate, including exhausted Edge substrate, the surface of the insulating substrate comprehensively or it is partial be equipped with ground glaze layer, in the insulating substrate and ground glaze layer Surface be equipped with public electrode and individual electrode, heating resistor along main Print direction configure public electrode and individual electrode it Between, as the heater for generating Joule heat, one end of the public electrode is connected along secondary Print direction with the heating resistor It connects, the other end is connected with printing power supply;One end of the individual electrode is along secondary Print direction and the heating resistor phase Connection, the other end are connected with control IC;It is covered on the surface of the heating resistor, public electrode and part individual electrode There is the protective layer of insulation, transition zone is equipped on the protective layer, the functional layer of hydrophobic oleophobic, institute are equipped on the transition zone It states functional layer to be made of inorganic material, the protective layer, transition zone and functional layer constitute surface composite layer.
Preferably, the protective layer is SiAlON, SiON or SiO2, the protective layer with a thickness of 1 μm~6 μm.
Preferably, the transition zone be Cr, Ti or combination, the transition zone with a thickness of 0.4 μm~1.4 μm。
Preferably, the functional layer is mixture, simple substance which is made of Ti, Cu, Si, O, N element, chemical combination Object is composed, the functional layer with a thickness of 0.8 μm~2 μm.
Preferably, hydrophobic angle > 120 ° of the functional layer, oleophobic angle > 100 °.
Preferably, the overlay area of the transition zone and functional layer is no more than the overlay area of protective layer.
Preferably, the adhesive force of the surface composite layer is 37N~50N;The nano hardness of surface composite layer is 25GPa ~35GPa.
Another aspect of the present invention proposes a kind of manufacturing method based on above-mentioned thermal printing head heating base plate, described Method the following steps are included:
Step 1, on the insulating substrate print comprehensively or partial unleaded amorphous glass ground glaze layer, 1200 DEG C~ The insulating substrate of sintering belt ground glaze layer at a temperature of 1300 DEG C, then conductive paste is sintered in the surface printing of insulating substrate and ground glaze layer Material, sintering temperature are 800 DEG C -920 DEG C, form public electrode and individual electrode with photoetching technique later, then along thermal printing head Main Print direction carries out band-like coating, and sintering forms the heating resistor of 4 μm~8 μ m-thicks at a temperature of 780 DEG C -850 DEG C;
Step 2 is plated using magnetron sputtering technique on the surface of the heating resistor, public electrode and part individual electrode The protective layer of insulation is made, the protective layer is SiAlON, SiON or SiO2
The thermal printing head for being coated with insulating protective layer after cleaning is put into multi-arc ion coating chamber with heating base plate by step 3 In body, by being evacuated so that pressure reaches 1 × 10 in cavity-3Pa hereinafter, heating make cavity temperature to 120 DEG C~200 DEG C, be passed through Argon gas makes pressure in cavity reach 1Pa~2Pa, and back bias voltage 700V~1000V is added to generate heat the thermal printing head with protective layer Substrate carries out bias cleaning, and scavenging period is 5min~15min, is passed through argon gas later, and flow is 100sccm~150sccm, adjusts For the whole intracorporal pressure of chamber to 0.3Pa~1.0Pa, setting arc ource electric current is 50A~80A, and back bias voltage is 200V~400V, using more Arc ion plating technique prepares transition zone on the surface of protective layer, and the transition zone is Cr, Ti or combination;
Step 4, in multi-arc ion coating cavity, be passed through the mixture of nitrogen, oxygen or the two, flow be 60sccm~ 110sccm, for the adjustment intracorporal pressure of chamber to 0.3Pa~1.0Pa, setting arc ource electric current is 50A~80A, back bias voltage for 150V~ 250V, using multi sphere ion plating technology transition zone surface prepare functional layer, the functional layer be mixture, the mixture by Ti, Cu, Si, O, the simple substance of N element composition, compound combination form.
Preferably, in the step 2, the protective layer with a thickness of 1 μm~6 μm;It is described in the step 3 Transition zone with a thickness of 0.4 μm~1.4 μm;In the step 4, the functional layer with a thickness of 0.8 μm~2 μm.
Preferably, in the step 3, the overlay area of the transition zone is no more than the overlay area of protective layer;? In the step 4, the overlay area of the functional layer is no more than the overlay area of protective layer.
The beneficial effect of the program of the present invention is that the thermal printing head manufactured by the above method is dredged with heating base plate Water oleophobic ability is strong, can improve carbon distribution and sticky paper phenomenon in print procedure, extend the service life of thermal printing head.
Detailed description of the invention
Fig. 1 shows the structural schematic diagram of thermal printing head heating base plate according to the present invention.
Appended drawing reference: 1- insulating substrate, 2- ground glaze layer, 3a- public electrode, 3b- individual electrode, 4- heating resistor, 5- Surface composite layer, 5a- protective layer, 5b- transition zone, 5c- functional layer.
Specific embodiment
A specific embodiment of the invention is further described with reference to the accompanying drawing.
As shown in Figure 1, thermal printing head heating base plate according to the present invention includes insulating substrate 1, in the insulation The surface of substrate 1 comprehensively or it is partial be equipped with ground glaze layer 2, be equipped on the surface of the insulating substrate 1 and ground glaze layer 2 public Electrode 3a and individual electrode 3b, heating resistor 4 configure between public electrode 3a and individual electrode 3b along main Print direction, make For the heater for generating Joule heat, one end of the public electrode 3a is connected along secondary Print direction with the heating resistor 4, Its other end is connected with printing power supply;One end of the individual electrode 3b is along secondary Print direction and 4 phase of heating resistor Connection, the other end are connected with control IC;In the heating resistor 4, the table of public electrode 3a and part individual electrode 3b Face is covered with the protective layer 5a of insulation, and transition zone 5b is equipped on the protective layer 5a, is equipped on the transition zone 5b hydrophobic The functional layer 5c of oleophobic, the functional layer 5c are made of inorganic material, the protective layer 5a, transition zone 5b and functional layer 5c structure At surface composite layer 5.
The protective layer 5a and bottom (namely heating resistor 4, public electrode 3a and part individual electrode 3b of the insulation Surface) binding force is strong, in the present embodiment, the protective layer 5a is SiAlON, SiON or SiO2, preferably SiAlON, institute State protective layer 5a with a thickness of 1 μm~6 μm.
The transition zone 5b can be combined preferably with protective layer 5a and functional layer 5c, the transition zone 5b be Cr, Ti or Person's combination, preferably Cr, the transition zone 5b with a thickness of 0.4 μm~1.4 μm.
The functional layer 5c and transition zone 5b binding force are strong, have hydrophobic, fuel shedding quality, hydrophobic angle > 120 °, oleophobic angle > 100 °, by be arranged functional layer 5c make thermal media in print procedure precipitate be difficult thermal printing head surface deposit, Bonding.The functional layer 5c is mixture, simple substance, compound combination which is made of Ti, Cu, Si, O, N element and At, the functional layer 5c with a thickness of 0.8 μm~2 μm.
In the present embodiment, the overlay area of the transition zone 5b and functional layer 5c is no more than the covering of protective layer 5a Region.
Due to hydrophobic angle > 120 ° of the functional layer 5c, oleophobic angle > 100 °, this makes thermal media in print procedure Precipitate is difficult in thermal printing head surface deposition, bonding;Due to the presence of insulating protective layer 5a and transition zone 5b, functional layer 5c It is greatly improved with the adhesive force of thermal printing head heating base plate, the adhesive force of the surface composite layer 5 is 37N~50N;Surface The nano hardness of composite layer 5 is 25GPa~35GPa.
The manufacturing method of specific thermal printing head heating base plate according to the present invention the following steps are included:
Step 1, on the insulating substrate 1 print comprehensively or partial unleaded amorphous glass ground glaze layer 2,1200 DEG C~ The insulating substrate 1 of sintering belt ground glaze layer 2 at a temperature of 1300 DEG C, then led in the sintering of the surface printing of insulating substrate 1 and ground glaze layer 2 Plasma-based material, sintering temperature are 800 DEG C -920 DEG C, form public electrode 3a and individual electrode 3b with photoetching technique later, then pass through The methods of describe and to carry out band-like coating along the main Print direction of thermal printing head, at a temperature of 780 DEG C -850 DEG C sintering formed 4 μm~ The heating resistor 4 of 8 μ m-thicks.
Step 2, using magnetron sputtering technique in the heating resistor 4, public electrode 3a and part individual electrode 3b Surface is coated with the protective layer 5a of insulation.The protective layer 5a is SiAlON, SiON or SiO2, preferably SiAlON, the protection Layer 5a with a thickness of 1 μm~6 μm.
The thermal printing head for being coated with insulating protective layer 5a after cleaning is put into multi-arc ion coating with heating base plate by step 3 In cavity, by being evacuated so that pressure reaches 1 × 10 in cavity-3Pa hereinafter, heating make cavity temperature to 120 DEG C~200 DEG C, lead to Enter argon gas, pressure in cavity is made to reach 1Pa~2Pa, back bias voltage 700V~1000V is added to use the thermal printing head with protective layer 5a Heating base plate carries out bias cleaning, and scavenging period is 5min~15min, is passed through argon gas later, flow be 100sccm~ 150sccm, for the adjustment intracorporal pressure of chamber to 0.3Pa~1.0Pa, setting arc ource electric current is 50A~80A, back bias voltage for 200V~ 400V prepares transition zone 5b on the surface of protective layer 5a using multi sphere ion plating technology.The transition zone 5b is Cr, Ti or two The combination of person, preferably Cr, the transition zone 5b with a thickness of 0.4 μm~1.4 μm.The overlay area of the transition zone 5b does not surpass The overlay area of overprotection layer 5a.
Step 4, in multi-arc ion coating cavity, be passed through the mixture of nitrogen, oxygen or the two, flow be 60sccm~ 110sccm, for the adjustment intracorporal pressure of chamber to 0.3Pa~1.0Pa, setting arc ource electric current is 50A~80A, back bias voltage for 150V~ 250V prepares functional layer 5c on the surface of transition zone 5b using multi sphere ion plating technology.
The functional layer 5c has hydrophobic, fuel shedding quality, and hydrophobic angle > 120 °, oleophobic angle > 100 °, the functional layer 5c is Mixture, simple substance which is made of Ti, Cu, Si, O, N element, compound combination form, the thickness of the functional layer 5c It is 0.8 μm~2 μm.The overlay area of the functional layer 5c is no more than the overlay area of protective layer 5a.
The thermal printing head manufactured by the above method strong, surface composite layer hardness with heating base plate hydrophobic oleophobic ability Height, it is strong with bottom binding force, carbon distribution and sticky paper phenomenon in print procedure can be improved, extend thermal printing head uses the longevity Life.

Claims (10)

1. a kind of thermal printing head heating base plate, including insulating substrate, the surface of the insulating substrate comprehensively or part Be equipped with ground glaze layer, the surface of the insulating substrate and ground glaze layer be equipped with public electrode and individual electrode, heating resistor Along the configuration of main Print direction between public electrode and individual electrode, as the heater for generating Joule heat, the public electrode One end be connected along secondary Print direction with the heating resistor, the other end with printing power supply be connected;Individual electricity One end of pole is connected along secondary Print direction with the heating resistor, and the other end is connected with control IC;It is characterized by: It is covered with the protective layer of insulation on the surface of the heating resistor, public electrode and part individual electrode, in the protective layer It is equipped with transition zone, the functional layer of hydrophobic oleophobic is equipped on the transition zone, the functional layer is made of inorganic material, described Protective layer, transition zone and functional layer constitute surface composite layer.
2. thermal printing head heating base plate according to claim 1, it is characterised in that: the protective layer be SiAlON, SiON or SiO2, the protective layer with a thickness of 1 μm~6 μm.
3. thermal printing head heating base plate according to claim 2, it is characterised in that: the transition zone be Cr, Ti or Person's combination, the transition zone with a thickness of 0.4 μm~1.4 μm.
4. thermal printing head heating base plate according to claim 3, it is characterised in that: the functional layer is mixture, Simple substance that the mixture is made of Ti, Cu, Si, O, N element, compound combination form, the functional layer with a thickness of 0.8 μm~ 2μm。
5. thermal printing head heating base plate according to claim 4, it is characterised in that: the hydrophobic angle of the functional layer > 120 °, oleophobic angle > 100 °.
6. thermal printing head heating base plate as claimed in any of claims 1 to 5, it is characterised in that: the mistake The overlay area for crossing layer and functional layer is no more than the overlay area of protective layer.
7. thermal printing head heating base plate according to claim 6, it is characterised in that: the attachment of the surface composite layer Power is 37N~50N;The nano hardness of surface composite layer is 25GPa~35GPa.
8. a kind of manufacturing method based on thermal printing head heating base plate described in claim 1, it is characterised in that: the side Method the following steps are included:
Step 1 prints comprehensive or partial unleaded amorphous glass ground glaze layer on the insulating substrate, at 1200 DEG C~1300 DEG C At a temperature of sintering belt ground glaze layer insulating substrate, then the surface printing of insulating substrate and ground glaze layer be sintered electrocondution slurry, burn Junction temperature is 800 DEG C -920 DEG C, forms public electrode and individual electrode with photoetching technique later, then along the leading print of thermal printing head Direction carries out band-like coating, and sintering forms the heating resistor of 4 μm~8 μ m-thicks at a temperature of 780 DEG C -850 DEG C;
Step 2 is coated with absolutely using magnetron sputtering technique on the surface of the heating resistor, public electrode and part individual electrode The protective layer of edge, the protective layer are SiAlON, SiON or SiO2
The thermal printing head for being coated with insulating protective layer after cleaning is put into multi-arc ion coating cavity by step 3 with heating base plate, By being evacuated so that pressure reaches 1 × 10 in cavity-3Pa hereinafter, heating make cavity temperature to 120 DEG C~200 DEG C, be passed through argon gas, So that pressure in cavity is reached 1Pa~2Pa, adds back bias voltage 700V~1000V to the thermal printing head heating base plate with protective layer Bias cleaning is carried out, scavenging period is 5min~15min, is passed through argon gas later, and flow is 100sccm~150sccm, adjusts chamber For intracorporal pressure to 0.3Pa~1.0Pa, setting arc ource electric current is 50A~80A, and back bias voltage is 200V~400V, using multi sphere from Sub- coating technology prepares transition zone on the surface of protective layer, and the transition zone is Cr, Ti or combination;
Step 4, in multi-arc ion coating cavity, be passed through the mixture of nitrogen, oxygen or the two, flow be 60sccm~ 110sccm, for the adjustment intracorporal pressure of chamber to 0.3Pa~1.0Pa, setting arc ource electric current is 50A~80A, back bias voltage for 150V~ 250V, using multi sphere ion plating technology transition zone surface prepare functional layer, the functional layer be mixture, the mixture by Ti, Cu, Si, O, the simple substance of N element composition, compound combination form.
9. the manufacturing method of thermal printing head heating base plate according to claim 8, it is characterised in that: in the step In 2, the protective layer with a thickness of 1 μm~6 μm;In the step 3, the transition zone with a thickness of 0.4 μm~1.4 μm; In the step 4, the functional layer with a thickness of 0.8 μm~2 μm.
10. the manufacturing method of thermal printing head heating base plate according to claim 8 or claim 9, it is characterised in that: described In step 3, the overlay area of the transition zone is no more than the overlay area of protective layer;In the step 4, the functional layer Overlay area is no more than the overlay area of protective layer.
CN201910080450.9A 2019-01-28 2019-01-28 A kind of thermal printing head heating base plate and its manufacturing method Pending CN109693451A (en)

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Cited By (6)

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CN110091615A (en) * 2019-05-10 2019-08-06 武汉晖印半导体有限公司 A kind of the high-precision heater construction and its manufacturing process of film thermal printing head
CN111409376A (en) * 2020-03-31 2020-07-14 湖南凯通电子有限公司 Printing and manufacturing method for base glaze of heating substrate of thermal printing head
CN114368223A (en) * 2021-01-26 2022-04-19 山东华菱电子股份有限公司 Heating substrate for high-performance thermal printing head
CN114379237A (en) * 2021-01-26 2022-04-22 山东华菱电子股份有限公司 Heating substrate for high-performance thermal printing head
CN114434975A (en) * 2020-10-30 2022-05-06 深圳市博思得科技发展有限公司 Thermal print head and method for manufacturing the same
WO2023120093A1 (en) * 2021-12-24 2023-06-29 京セラ株式会社 Thermal head and thermal printer

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CN110091615A (en) * 2019-05-10 2019-08-06 武汉晖印半导体有限公司 A kind of the high-precision heater construction and its manufacturing process of film thermal printing head
CN111409376A (en) * 2020-03-31 2020-07-14 湖南凯通电子有限公司 Printing and manufacturing method for base glaze of heating substrate of thermal printing head
CN114434975A (en) * 2020-10-30 2022-05-06 深圳市博思得科技发展有限公司 Thermal print head and method for manufacturing the same
CN114434975B (en) * 2020-10-30 2024-01-05 深圳市博思得科技发展有限公司 Thermal print head and method for manufacturing the same
CN114368223A (en) * 2021-01-26 2022-04-19 山东华菱电子股份有限公司 Heating substrate for high-performance thermal printing head
CN114379237A (en) * 2021-01-26 2022-04-22 山东华菱电子股份有限公司 Heating substrate for high-performance thermal printing head
CN114379237B (en) * 2021-01-26 2022-11-15 山东华菱电子股份有限公司 Heating substrate for high-performance thermal printing head
CN114368223B (en) * 2021-01-26 2022-11-15 山东华菱电子股份有限公司 Heating substrate for high-performance thermal printing head
WO2023120093A1 (en) * 2021-12-24 2023-06-29 京セラ株式会社 Thermal head and thermal printer

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