CN109682508A - A kind of sensitive ink material and pliable pressure thin film sensor and preparation method thereof - Google Patents

A kind of sensitive ink material and pliable pressure thin film sensor and preparation method thereof Download PDF

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Publication number
CN109682508A
CN109682508A CN201811640091.XA CN201811640091A CN109682508A CN 109682508 A CN109682508 A CN 109682508A CN 201811640091 A CN201811640091 A CN 201811640091A CN 109682508 A CN109682508 A CN 109682508A
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China
Prior art keywords
layer
insulating protective
protective layer
sensitive ink
thin film
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CN201811640091.XA
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Inventor
李万新
孙爱军
李彦坤
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New Material Technology (shanghai) Co Ltd
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New Material Technology (shanghai) Co Ltd
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Priority to CN201811640091.XA priority Critical patent/CN109682508A/en
Publication of CN109682508A publication Critical patent/CN109682508A/en
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    • GPHYSICS
    • G01MEASURING; TESTING
    • G01LMEASURING FORCE, STRESS, TORQUE, WORK, MECHANICAL POWER, MECHANICAL EFFICIENCY, OR FLUID PRESSURE
    • G01L1/00Measuring force or stress, in general
    • G01L1/18Measuring force or stress, in general using properties of piezo-resistive materials, i.e. materials of which the ohmic resistance varies according to changes in magnitude or direction of force applied to the material
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/03Printing inks characterised by features other than the chemical nature of the binder
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/10Printing inks based on artificial resins
    • C09D11/102Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/52Electrically conductive inks
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01LMEASURING FORCE, STRESS, TORQUE, WORK, MECHANICAL POWER, MECHANICAL EFFICIENCY, OR FLUID PRESSURE
    • G01L1/00Measuring force or stress, in general
    • G01L1/26Auxiliary measures taken, or devices used, in connection with the measurement of force, e.g. for preventing influence of transverse components of force, for preventing overload

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Push-Button Switches (AREA)

Abstract

The present invention provides a kind of sensitive ink material and pliable pressure thin film sensor and preparation method thereof.Pliable pressure thin film sensor includes the first insulating protective layer, conductive electrode layer, support adhesive layer, sensitive ink layer and the second insulating protective layer;Conductive electrode layer and sensitive ink layer are arranged between the first insulating protective layer and the second insulating protective layer;Sensitive ink layer has the conductive sensitive ink material composition of convex-concave surface micro-structure;Adhesive layer is supported to be between the first insulating protective layer and the second insulating protective layer.First insulating protective layer and the second insulating protective layer are sticky by support adhesive layer.The advantage is that improves power-resistance change curve relationship, can carry out a degree of identification to the size of outside stimulus power, be distributed and detect in human pressure, and safety chair seats of car system and man-machine touch-control field have application well.

Description

A kind of sensitive ink material and pliable pressure thin film sensor and preparation method thereof
Technical field
The present invention relates to a kind of sensitive ink material and pliable pressure thin film sensors and preparation method thereof.
Background technique
Main performance characteristic is when the fexible film for having sale on the market at present is switched by external drive, i.e., by When one very small and weak external force movement, resistance can be strongly reduced, and can only judge that external force has after signal acquisition, processing Without presence, and it can not accomplish the identification of external force size degree.
Summary of the invention
The purpose of the present invention is intended to provide a kind of sensitive ink material and pliable pressure thin film sensor and its preparation Method;Above-mentioned technical problem is solved, fundamentally to overcome the existing defects of the above-mentioned prior art.
The present invention provides a kind of pliable pressure thin film sensor, including, the first insulating protective layer, conductive electrode layer, support Adhesive layer, sensitive ink layer and the second insulating protective layer;Conductive electrode layer and sensitive ink layer are arranged in the first insulating protective layer And second between insulating protective layer;Sensitive ink layer has the conductive sensitive ink material composition of convex-concave surface micro-structure;Branch Adhesive layer is supportted to be between the first insulating protective layer and the second insulating protective layer.Support adhesive layer by the first insulating protective layer and the Two insulating protective layers are sticky.
Further, the present invention provides a kind of pliable pressure thin film sensor, can also have the feature that the first insulation is protected The material of sheath is 10um~300um including but not limited to PET film, PVC film, PE film, preferred thickness;Second insulating protective layer Material is 10um~300um including but not limited to PET film, PVC film, PE film, preferred thickness;The material of conductive electrode layer includes not Contain but be not limited to metallic silver, metallic aluminium, metallic copper, preferred thickness is in 0.01mm-0.05mm;Support adhesive layer preferred thickness exists 0.05mm-0.25mm, material is including but not limited to commercially available double-sided adhesive, screen printing brush coating.
Further, the present invention provides a kind of pliable pressure thin film sensor, can also have the feature that the first insulation is protected The shape of sheath and the second insulating protective layer is that round and rectangle is composed;The shape of conductive electrode layer and the first insulation Protective layer matches, and one end is annulus, and annulus has a notch, has several round strings in annulus;The other end is that two root longs are rectangular It is composed;Sensitive ink layer is circle;Support adhesive layer is annulus, is matched with the annulus of conductive electrode layer;Conductive electrode layer The upper position for being overlapped area with sensitive ink floor has venthole.
In addition, the present invention also provides a kind of sensitive ink materials, the mass percentage including following components and each component Respectively, binder 0.01%-35%;Conductive filler 0.1%-80%;Metal oxide particles 5%-40%;Solvent 5%- 90%;Auxiliary agent 0.02%-10%.
Further, the present invention provides a kind of sensitive ink material, can also have the feature that bonding agent includes natural tree Rouge and/or synthetic resin;Synthetic resin is epoxy resin, phenolic resin, polyester resin, organic siliconresin, fluorocarbon resin, polyester Resin, acrylic resin, alkyd resin, vinylite, synthetic cellulose, polyamide, phenoxy resin, polyurethane tree Rouge, chlorosulfonated polyethylene, thermoplastic plastic, synthetic rubber, modified rosin resin etc. or at least one of its copolymer;Metal Oxidation particles include at least one in or mixtures thereof copper oxide, iron oxide, molybdenum oxide, nickel oxide, stannous oxide, magnesia etc. Kind;Preferred size is in 0.1um-500um;Solvent includes aliphatic hydrocarbon solvents, alcohol solvent, ketone solvent, aromatic hydrocarbon solvent, ester At least one of class solvent, alcohol ethers solvent, vegetable and animals oils, mineral oil;Auxiliary agent includes thickener, dispersing agent, coupling agent, disappears In infusion, colorant, wetting agent, levelling agent, crosslinking agent, stabilizer, ultraviolet absorbing agent, antioxidant, glass powder etc. extremely Few one kind.
In addition, the present invention provides a kind of preparation method of sensitive ink material, comprising the following steps:
Step A, prepared by liquid phase: it is molten that binder and solvent be put into container for stirring according to the component of sensitive ink material Solution, until being uniformly mixed until transparent clear state.
Step B, disperse: liquid phase material, conductive filler, metal oxide particles and auxiliary agent that step A is prepared are placed on Stirring stirring together, mixing is pre-dispersed uniformly, and ink is made and slightly starches.
Step C, grind: the ink that step B is obtained, which is slightly starched, carries out grinding 0.1-50 hours.
Step D, by ground material filtering, required sensitive ink material is obtained.
Further, the present invention provides a kind of preparation method of sensitive ink material, can also have the feature that step A In, the speed of stirring is 600rpm, and temperature is maintained at 60 DEG C;In step B, the speed of stirring is 800rpm, and temperature is maintained at 40 DEG C or less.
In addition, the present invention also provides a kind of preparation methods of pliable pressure thin film sensor, comprising the following steps:
Step I, conductive electrode layer is prepared on the first insulating protective layer, obtains first assembly;
Step II, sensitive ink layer is set on the second insulating protective layer, obtains the second component;
Step III, using the support adhesive layer of non-sensitive thin film region by the above-mentioned steps I first assembly prepared and step II Second component joint of preparation;During fitting, conductive electrode layer and the fitting of sensitive ink layer, support adhesive layer are applied to first Between insulating protective layer and the second insulating protective layer;
Step IV, according to the specification requirement of pliable pressure thin film sensor, the component excision forming that step III is obtained.
Further, the present invention provides a kind of preparation method of pliable pressure thin film sensor, can also have the feature that
In step I, the method for conductive electrode layer includes silk-screen printing silver electrode, etching aluminium (copper) foil electrode, Vacuum Deposition Aluminium (copper) electrode;
In step II, the method for setting sensitive ink layer includes silk-screen printing sensitive ink, coating composite sensing ink;
In step III, support adhesive layer uses the commercially available pressure-sensitive solid-state double-sided adhesive containing release film or silk-screen printing one It is laminated quick liquid double-sided glue, is bonded after cured.
Advantageous effect of the invention
The present invention provides a kind of pliable pressure thin film sensor, and the flexible thin film sensor based on sensitive ink passes through ink Modification technology forms concave-convex surface topography on nano ink surface by the metal oxide particles of addition electric conductivity, each other it Between be mutually unified into horizontal and vertical numerous conductive paths, improve power-resistance change curve relationship, can be to external force size It is identified.
In addition, the present invention provides a kind of pliable pressure thin film sensor, led using the above-mentioned transverse direction that sensitive ink is formed of receiving Electric pathway optimizes sensor structure, simplifies process flow, greatly reduces production cost.
Detailed description of the invention
Fig. 1 is the cross-sectional view of pliable pressure thin film sensor.
Fig. 2 is the explosive view of pliable pressure thin film sensor.
Fig. 3 is the SEM figure of sensitive ink material.
Fig. 4 is pliable pressure thin film sensor output resistance VS external force relation curve.
Specific embodiment
The present invention will be further described in the following with reference to the drawings and specific embodiments.
Fig. 1 is the cross-sectional view of pliable pressure thin film sensor.
Fig. 2 is the explosive view of pliable pressure thin film sensor.
As depicted in figs. 1 and 2, pliable pressure thin film sensor includes: the first insulating protective layer 101, conductive electrode layer 102, adhesive layer 103, sensitive ink layer 104 and the second insulating protective layer 105 are supported.
The material of first insulating protective layer 101 including but not limited to PET film, PVC film, PE film, preferred thickness be 10um~ 300um.The material of second insulating protective layer 105 including but not limited to PET film, PVC film, PE film, preferred thickness be 10um~ 300um.The shape of first insulating protective layer 101 and the second insulating protective layer 105 is that round and rectangle is composed, similar Microphone shape.
Conductive electrode layer 102 and sensitive ink layer 104 are arranged in the first insulating protective layer 101 and the second insulating protective layer Between 105.The material of conductive electrode layer 102 includes to be free of but be not limited to metallic silver, metallic aluminium, metallic copper, and preferred thickness exists 0.01mm-0.05mm.Sensitive ink layer 104 has the conductive sensitive ink material composition of convex-concave surface micro-structure.Sensitive oil Ink material is made of components such as bonding agent, conductive filler, metal oxide particles, solvent and auxiliary agents.The shape of conductive electrode layer 102 Match with the first insulating protective layer 101, one end is annulus, and annulus has a notch, there are several round strings in annulus;The other end It is formed for two root long square combinations.Sensitive ink layer 104 is circle.
Support adhesive layer 103 is annulus, is matched with the annulus of conductive electrode layer 102, and be in the first insulating protective layer 101 And second between insulating protective layer 105.Support 103 preferred thickness of adhesive layer in 0.05mm-0.25mm, material includes but unlimited In commercially available double-sided adhesive, screen printing brush coating.Support adhesive layer 103 glues the first insulating protective layer 101 and the second insulating protective layer 105 It links up, plays the role of support and protection to conductive electrode layer 102 and sensitive ink layer 104.Conductive electrode layer 102 and sensitivity The upper position that ink layer 104 is overlapped area has venthole 106, passes through venthole 106 when the air stress of the coincidence section gap It transfers out and, so that conductive electrode layer and sensitive ink layer well contact.
Sensitive ink material in pliable pressure thin film sensor, the mass percentage including following components and each component It is respectively as follows: binder 0.01%-35%;Conductive filler 0.1%-80%;Metal oxide particles 5%-40%;Solvent 5%- 90%;Auxiliary agent 0.02%-10%.
Bonding agent is the film forming matter in modified ink, plays the role of skeleton connection.Including but not limited to natural resin;Or Person includes but is not limited to synthetic resin such as epoxy resin, phenolic resin, polyester resin, organic siliconresin, fluorocarbon resin, polyester tree Rouge, acrylic resin, alkyd resin, vinylite, synthetic cellulose, polyamide, phenoxy resin, polyurethane resin, Chlorosulfonated polyethylene, thermoplastic plastic, synthetic rubber, modified rosin resin etc. or at least one of its copolymer;It can also be with It is the combination of natural resin and synthetic resin.
Conductive filler is dispersed in the carrier that electric current is conducted in ink.Conductive filler includes two major classes, and one kind is conductive micro- Grain, including conductive black, carbon nanotube and graphene;Preferred size is in 0.01um-100um;One kind is electrically conductive ink magma, Preferred viscosities are in 10000-50000CPS, and resistance value is less than 50 Ω/sq@0.0254mm.
Metal oxide particles feature is to be dispersed in ink to form surface relief structure, including but not limited to copper oxide, oxygen Change at least one of or mixtures thereof iron, molybdenum oxide, nickel oxide, stannous oxide, magnesia etc..Preferred size is in 0.1um- 500um。
Solvent is characterized by the ability with energy dissolving resin, and filler and dissolution aids in energy disperse ink improve oil The printability of ink, and adjust viscosity and rate of drying.Including but not limited to aliphatic hydrocarbon solvents, alcohol solvent, ketone solvent, At least one of aromatic hydrocarbon solvent, esters solvent, alcohol ethers solvent, vegetable and animals oils, mineral oil, such as ethyl alcohol, isopropanol, second two Alcohol, two polyethylene glycol, butyl carbitol, butyric acid butyl carbitol, acetone, butanone (MEK), methyl second butyl ketone, methyl tert-butyl Base ketone (MIBK), N-Methyl pyrrolidone (NMP), methyl amyl ketone, melilotal, hexamethylene, toluene, dimethylbenzene, two Methylformamide (DMF), dimethyl acetamide (DMAC), dimethyl sulfoxide (DMSO), terpinol, butyl acetate, DEB (succinic acid Dimethyl ester, dimethyl glutarate, dimethyl adipate mixture), ethylene glycol monomethyl ether, ethylene glycol ethyl ether, glycol propyl ether, second At least one of glycol ether acetic acid esters etc..
Auxiliary agent is ink area common dosage forms.It is characterized in that being capable of electric conductivity, stability, printing product surface to ink Energy, printability etc. play the role of improvement, including but not limited to thickener, dispersing agent, coupling agent, defoaming agent, colorant, wetting At least one of agent, levelling agent, crosslinking agent, stabilizer, ultraviolet absorbing agent, antioxidant, glass powder etc..It is set in the present invention The selection of rouge, solvent and auxiliary agent, the conductivity according to needed for electrically conductive ink, viscosity, rheological characteristic, substrate, printing process, heat treatment The requirements such as temperature are selected and are adjusted.
Sensitive ink material optimization formula one, mass fraction is as follows:
Bonding agent is phenoxy resin 20.0-40.0 parts, and solvent is 65.0-90.0 parts of butyl glycol ether acetic acid esters, metal oxygen Changing particle is nickel oxide 21.8-39.2 parts, and conductive filler is conductive black 7.6-20.1 parts, and auxiliary agent is dispersing agent 0.08-0.15 Part, 0.10-0.35 parts of defoaming agent, 0.15-0.43 parts of coupling agent.
Sensitive ink material optimization formula two, mass fraction is as follows:
60.0-80.0 parts of bonding agent polyurethane resin, solvent is acetone 100.0-250.0 parts, and metal oxide particles are oxygen Change stannous 50.2-80.5 parts, 55.3-82.4 parts of Electrodag 423SS of conductive filler (commercially available), auxiliary agent is dispersing agent 0.10-0.35 parts, 0.12-0.45 parts of defoaming agent, 0.24-0.66 parts of levelling agent.
The preparation method of sensitive ink material, comprising the following steps:
Step A, prepared by liquid phase: binder and solvent being put into round-bottomed flask according to the component of sensitive ink material and stirred The speed of dissolution, stirring is 600rpm, and temperature is maintained at 60 DEG C, is uniformly mixed until transparent clear state.
Step B, disperse: by remaining component of the step A liquid phase material being prepared and sensitive ink material, (conduction is filled out Material, metal oxide particles and auxiliary agent) be put into stirring in Scattered Kettle, the speed of stirring is 800rpm, temperature be maintained at 40 DEG C hereinafter, Mix it is pre-dispersed uniformly, be made ink slightly starch.
Step C, it grinds: the ink that step B is obtained slightly being starched to be transferred in grinder and is ground 0.1-50 hours.
Step D, ground material filtering is obtained into required sensitive ink material through inspection and packaging process.It is quick The SEM figure for feeling ink material is as shown in Figure 3.
The preparation method of pliable pressure thin film sensor, comprising the following steps:
Step I, conductive electrode layer 102 is prepared on the first insulating protective layer 101, obtains first assembly.The conductive electricity of preparation Pole layer 102 method including but not limited to: 1) silk-screen printing silver electrode, 2) etch aluminium (copper) foil electrode, 3) vacuum aluminum-coated (copper) Electrode.
Step II, sensitive ink layer 104 is set on the second insulating protective layer 105, obtains the second component.The sensitive oil of setting The method of layer of ink 104 including but not limited to 1) silk-screen printing sensitive ink, 2) be coated with composite sensing ink.
Step III, using the support adhesive layer 103 of non-sensitive thin film region by the above-mentioned steps I first assembly prepared and step Second component joint of rapid II preparation, during fitting, conductive electrode layer 102 and sensitive ink layer 104 are bonded, and support adhesive layer 103 are applied between the first insulating protective layer 101 and the second insulating protective layer 105.
Support the use of adhesive layer 103 including but not limited to 1) the commercially available pressure-sensitive solid-state double-sided adhesive containing release film of use, 2) Silk-screen printing one is laminated quick liquid double-sided glue, bonds after cured.
Step IV, excision forming: according to the specification requirement of pliable pressure thin film sensor, by said modules excision forming.
As shown in figure 4, a kind of flexible thin film sensor provided by the invention improves power-electricity by ink modification technology The change curve relationship of resistance can carry out a degree of identification to the size of outside stimulus power, be distributed and detect in human pressure, Safety chair seats of car system and man-machine touch-control field have application well.

Claims (9)

1. a kind of pliable pressure thin film sensor, it is characterised in that: including the first insulating protective layer, conductive electrode layer, support are viscous Tie layer, sensitive ink layer and the second insulating protective layer;
Conductive electrode layer and sensitive ink layer are arranged between the first insulating protective layer and the second insulating protective layer;
Sensitive ink layer has the conductive sensitive ink material composition of convex-concave surface micro-structure;
Adhesive layer is supported to be between the first insulating protective layer and the second insulating protective layer;Support adhesive layer by the first insulation protection Layer and the second insulating protective layer are sticky.
2. pliable pressure thin film sensor as described in claim 1, it is characterised in that:
Wherein, the material of the first insulating protective layer is including but not limited to PET film, PVC film, PE film, preferred thickness be 10um~ 300um;
The material of second insulating protective layer is 10um~300um including but not limited to PET film, PVC film, PE film, preferred thickness;
The material of conductive electrode layer includes to be free of but be not limited to metallic silver, and metallic aluminium, metallic copper, preferred thickness is in 0.01mm- 0.05mm;
Support adhesive layer preferred thickness in 0.05mm-0.25mm, material is including but not limited to commercially available double-sided adhesive, silk-screen printing Glue.
3. pliable pressure thin film sensor as described in claim 1, it is characterised in that:
Wherein, the shape of the first insulating protective layer and the second insulating protective layer is that round and rectangle is composed;
The shape of conductive electrode layer and the first insulating protective layer match, and one end is annulus, and annulus has a notch, has in annulus Several round strings;The other end is that two root long square combinations form;Sensitive ink layer is circle;
Support adhesive layer is annulus, is matched with the annulus of conductive electrode layer;Conductive electrode layer and sensitive ink floor are overlapped the upper of area Portion position has venthole.
4. a kind of sensitive ink material, it is characterised in that:
Mass percentage including following components and each component is respectively,
Binder 0.01%-35%;Conductive filler 0.1%-80%;Metal oxide particles 5%-40%;Solvent 5%-90%;It helps Agent 0.02%-10%.
5. the preparation method of the sensitive ink material as described in any one of Claims 1-4, it is characterised in that:
Bonding agent includes natural resin and/or synthetic resin;
Synthetic resin is epoxy resin, phenolic resin, polyester resin, organic siliconresin, fluorocarbon resin, polyester resin, acrylic acid The poly- second of resin, alkyd resin, vinylite, synthetic cellulose, polyamide, phenoxy resin, polyurethane resin, chlorosulfonation Alkene, thermoplastic plastic, synthetic rubber, modified rosin resin etc. or at least one of its copolymer;
Metal oxide particles include in or mixtures thereof copper oxide, iron oxide, molybdenum oxide, nickel oxide, stannous oxide, magnesia etc. At least one;Preferred size is in 0.1um-500um;
Solvent includes aliphatic hydrocarbon solvents, alcohol solvent, ketone solvent, aromatic hydrocarbon solvent, esters solvent, alcohol ethers solvent, moves At least one of vegetable oil, mineral oil;
Auxiliary agent includes thickener, dispersing agent, coupling agent, defoaming agent, colorant, wetting agent, levelling agent, crosslinking agent, stabilizer, purple At least one of ultraviolet absorbers, antioxidant, glass powder etc..
6. the preparation method of pliable pressure thin film sensor as claimed in claim 4, it is characterised in that:
Step A, prepared by liquid phase: binder and solvent being put into container for stirring dissolution according to the component of sensitive ink material, directly To uniformly mixed until transparent clear state.
Step B, disperse: liquid phase material, conductive filler, metal oxide particles and auxiliary agent that step A is prepared are put together Stirring stirring, mixing is pre-dispersed uniformly, and ink is made and slightly starches.
Step C, grind: the ink that step B is obtained, which is slightly starched, carries out grinding 0.1-50 hours.
Step D, by ground material filtering, required sensitive ink material is obtained.
7. the preparation method of pliable pressure thin film sensor as claimed in claim 6, it is characterised in that:
Wherein, in step A, the speed of stirring is 600rpm, and temperature is maintained at 60 DEG C;
In step B, the speed of stirring is 800rpm, and temperature is maintained at 40 DEG C or less.
8. the preparation method of pliable pressure thin film sensor as described in claim 1, it is characterised in that:
Step I, conductive electrode layer is prepared on the first insulating protective layer, obtains first assembly;
Step II, sensitive ink layer is set on the second insulating protective layer, obtains the second component;
Step III, it using the support adhesive layer of non-sensitive thin film region prepared by the above-mentioned steps I first assembly prepared and step II The second component joint;During fitting, conductive electrode layer and the fitting of sensitive ink layer, support adhesive layer are applied to the first insulation Between protective layer and the second insulating protective layer;
Step IV, according to the specification requirement of pliable pressure thin film sensor, the component excision forming that step III is obtained.
9. the preparation method of pliable pressure thin film sensor as claimed in claim 8, it is characterised in that:
In step I, the method for conductive electrode layer includes silk-screen printing silver electrode, etching aluminium (copper) foil electrode, vacuum aluminum-coated (copper) Electrode;
In step II, the method for setting sensitive ink layer includes silk-screen printing sensitive ink, coating composite sensing ink;
In step III, support adhesive layer is laminated using the commercially available pressure-sensitive solid-state double-sided adhesive containing release film or silk-screen printing one Quick liquid double-sided glue, bonds after cured.
CN201811640091.XA 2018-12-29 2018-12-29 A kind of sensitive ink material and pliable pressure thin film sensor and preparation method thereof Pending CN109682508A (en)

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CN111171570A (en) * 2020-01-15 2020-05-19 常熟理工学院 Quick-response oil-sensitive deformable film and preparation method thereof
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CN113008416A (en) * 2021-01-28 2021-06-22 中科院长春应化所黄埔先进材料研究院 Packaging mechanism and packaging method for microstructure type flexible pressure sensor
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CN111171570A (en) * 2020-01-15 2020-05-19 常熟理工学院 Quick-response oil-sensitive deformable film and preparation method thereof
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