CN109678988A - Agricultural-forestry biomass classified use and low-carbon combined production device and its green technology - Google Patents

Agricultural-forestry biomass classified use and low-carbon combined production device and its green technology Download PDF

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Publication number
CN109678988A
CN109678988A CN201910109771.7A CN201910109771A CN109678988A CN 109678988 A CN109678988 A CN 109678988A CN 201910109771 A CN201910109771 A CN 201910109771A CN 109678988 A CN109678988 A CN 109678988A
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China
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hemicellulose
stalk
alcohol
biomass
production
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CN201910109771.7A
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Inventor
张德志
汪春焕
冯胜利
张智
朱智慧
都基峻
汪琼洋
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Beijing Xinze Qingyuan Plant Straw Technology Co Ltd
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Beijing Xinze Qingyuan Plant Straw Technology Co Ltd
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Priority to CN201910109771.7A priority Critical patent/CN109678988A/en
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08BPOLYSACCHARIDES; DERIVATIVES THEREOF
    • C08B37/00Preparation of polysaccharides not provided for in groups C08B1/00 - C08B35/00; Derivatives thereof
    • C08B37/0003General processes for their isolation or fractionation, e.g. purification or extraction from biomass
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08HDERIVATIVES OF NATURAL MACROMOLECULAR COMPOUNDS
    • C08H6/00Macromolecular compounds derived from lignin, e.g. tannins, humic acids
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21CPRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
    • D21C3/00Pulping cellulose-containing materials
    • D21C3/20Pulping cellulose-containing materials with organic solvents or in solvent environment
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H11/00Pulp or paper, comprising cellulose or lignocellulose fibres of natural origin only
    • D21H11/12Pulp from non-woody plants or crops, e.g. cotton, flax, straw, bagasse
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/10Process efficiency
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/10Greenhouse gas [GHG] capture, material saving, heat recovery or other energy efficient measures, e.g. motor control, characterised by manufacturing processes, e.g. for rolling metal or metal working

Abstract

Agricultural-forestry biomass classified use and low-carbon combined production device and its green technology feature of the invention: change for agricultural abandoned biomass resource and agricultural crop straw five and comprehensively utilize, it is mainly utilized respectively according to following three types: one is the more stalk cleaning coproduction cellulose of hemicellulose level and paper pulp, hemicellulose and xylan and wooden cellulose product, the second is the less stalk of hemicellulose level prepares ethyl alcohol, the third is slag object supplies biomass thermoelectricity after discarded forest and stalk production;And cellulose prepared by agricultural abandoned biomass classification, the hydrolysis of biological medicament base thermoelectricity stalk, separation of solid and liquid and paper pulp, alcohol method prepare hemicellulose and recycle that alcohol, dilute liquid medicine prepares alkali lignin, straw lignocellulose prepares ethyl alcohol, agricultural abandoned biomass thermoelectricity, collect plant ash preparation biology base medical fluid, the process units that flue gas subtracts based on carbon Recovery Purifying plant ash is constituted.Beneficial effects of the present invention: by classified use agricultural abandoned biomass resource, low-carbon production and circular economy mechanism are innovated, not only economizes on resources but also improves production and Additional Value of Commodities, to realize the sustainable development of green ecological.

Description

Agricultural-forestry biomass classified use and low-carbon combined production device and its green technology
Technical field
The present invention relates to biomass resource utilization, stalks five to change the fields such as comprehensive utilization, biomass thermoelectricity and circular economy, Specifically agricultural-forestry biomass classified use and low-carbon combined production device and its green technology.
Technical background
It is reported that the annual agricultural crop straw yield in China is up to 800,000,000 tons, and it is practical to only have a small number of parts to be utilized, wherein big absolutely Majority is to be smashed to return field by machinery, causes serious soil pest and disease damage because that cannot degrade in time, so while government puts into effect Severeer environmental improvement and prohibit burning policy, but burns phenomenon and happen occasionally.
Begin within 2008, domestic extensive starting agricultural crop straw five changes comprehensive utilization, thus National Development and Reform Committee and the Ministry of Agriculture Joint publication " stalk comprehensive utilization technology (2014) " notice, clearly encourage and specification stalk ' Fertilizer Transformed, fodder, raw material, Energy, base-material ' etc. five change comprehensive utilization techniques and industry.
Stalk essential characteristic: first is that Main Components cellulose 35~50%, hemicellulose 15~40%, lignin 15~ 35%;Second is that classification is containing the more stalk of hemicellulose and the less stalk containing hemicellulose.
At the same time, the biomass thermoelectricity industry development in China is very fast at present, and manufacturing enterprise is up to thousand or more, agriculture therein Woods abandoned biomass thermoelectricity project and number of the enterprise occupy significant proportion.
However, reality is the biomass thermal power technology compared with photovoltaic+energy storage generation of electricity by new energy has been approached the marketization Simple and resource is devalued to be utilized seriously, and professional is caused still to rely on public subsidies existence.
In practice, in the biomass fuel that agricultural abandoned biomass thermoelectricity project and enterprise are stored up, existing crops are soft Lightweight and all kinds of stalks of hard heavy, there are also discarded leaf, branch and tree roots, also there is discarded construction timber and production packaging wood Material.
As it can be seen that agricultural abandoned biomass thermoelectricity project and enterprise, all simple by the biomass for all kinds of different specialities stored up Singly extensive burning is not only unreasonable but also serious waste resource, so very necessary coproduction utilizes.
Said from economy and technical standpoint, biomass resource by it is extensive it is devalued as fuel use, be to cause current agricultural The lower benefit of waste biomass thermoelectricity and the principal element for relying on public subsidies.
Conversely, if agriculture and forestry organic waste material thermoelectricity project and enterprise can size up the current situation and improve and extend pollution-free industry The biomass resource stored up is carried out classification utilization and fine design, produces height by low-carbon energy advantage by chain Agriculture and forestry organic waste material thermoelectricity comprehensive benefit had not only can be improved in value biomaterial, but also can save valuable biomass resource.
Containing the more stalk of hemicellulose, mainly there are the crops such as wheat, corn and jowar;Firstly, stalk hemicellulose is Human society obtains the main path and biomass resource and agriculture of big healthy xylan and sweet taste product from nature so far The high-valued important channel of crop material;Secondly, the lignocellulosic and its structure of stalk are the natural materials of green paper, Therefore develop the papermaking of stalk cleaning pulping for protecting existing forest tree resource and earth vegetation particularly important.
Containing the less stalk of hemicellulose, mainly there are the crops such as beans and cotton;Hemicellulose contained by its stalk is few, this It is the important measures for improving the enzymeization and fermentation production efficiency of current lignocellulosic ethyl alcohol.
Building and packing timber are more in the discarded forest of biomass resource, are mainly characterized by pollution greatly and rubbish is more, will Its reproduction difficulty greatly and higher cost, so is burned generation thermoelectricity be relatively inexpensive and feasible production method.
In short, utilizing by biomass resource classification and low-carbon coproduction, the added value of biomass not only can be improved, but also can Commodity are made in abundant biomass, especially contribute to explore Technology Ways and Nei Sheng that the subsidy of agricultural abandoned biomass thermoelectricity is exited Mechanism.
It can be seen that developing agricultural abandoned biomass resource classification utilizes and extends low-carbon industry chain (supply chain), it is that solution is existing The insufficient important directions of agricultural abandoned biomass thermoelectricity;For this purpose, the present invention remolds agricultural abandoned biomass element and industrial chain industry State has innovated new model, new technology, new process and new equipment that agricultural-forestry biomass coupling stalk five changes comprehensive utilization, it is expected that into One step pushes the fast development of green technology and industry.
Summary of the invention
The present invention provides agricultural-forestry biomass classified uses and low-carbon combined production device and its green technology, it is characterized in that: (1) Change comprehensive utilization for agricultural abandoned biomass resource and agricultural crop straw five, be mainly utilized respectively according to following three types: One is the more stalk cleaning coproduction cellulose of hemicellulose level and paper pulp, hemicellulose and xylan and wooden cellulose product, The second is the less stalk of hemicellulose level prepares ethyl alcohol, the third is slag object supplies biomass thermal after discarded forest and stalk production Electricity;(2) thermal energy, electric energy, ashes and the flue gas of the biomass thermal electricity output described in, both can be recycled in the hemicellulose The production process of the more stalk cleaning coproduction cellulose of content and paper pulp, hemicellulose and xylan and wooden cellulose product, can also It is recycling in the production process that the less stalk of hemicellulose level prepares ethyl alcohol;(3) hemicellulose level described in Biomass ashes are recycled in more stalk cleaning coproduction cellulose and paper pulp, hemicellulose and xylan and wooden cellulose product That is plant ash and alkaline solution preparation biology base hydrolysis medical fluid and solid phase salt desulfurizing agent or building materials;(4) hemicellulose described in Flue gas is recycled in the more stalk cleaning coproduction cellulose of content and paper pulp, hemicellulose and xylan and wooden cellulose product Carbon dioxide and other sour gas recycling medicament regeneration plant ash class salt are simultaneously reduced carbon row and purifying smoke;(5) described in Essence is created in the more stalk cleaning coproduction cellulose of hemicellulose level and paper pulp, hemicellulose and xylan and wooden cellulose product Standardization biological medicament base heat and electric stalk hydrolyze energy-saving environmental protection device, had not only protected fibre length and intensity but also hemicellulose is precipitated with alcohol And xylan and reduce and reduce lignin liquid viscosity make production system energy conservation with it is water-saving;(6) the above production process described in All solid content complete set commercialization utilize and the closed circulation of liquid phase complete set and recycling;(7) the above production process described in is not Generate sewage and solid waste and production zero-emission;(8) hydrolyzed by agricultural abandoned biomass classification, biological medicament base thermoelectricity stalk, Separation of solid and liquid prepares cellulose and paper pulp, alcohol method prepare hemicellulose and recycling alcohol, dilute liquid medicine prepare alkali lignin, stalk wood Matter cellulose prepares ethyl alcohol, agricultural abandoned biomass thermoelectricity, collection plant ash preparation biology base medical fluid, flue gas and subtracts carbon Recovery Purifying Nine some processes contents and process units based on plant ash are constituted.
The agricultural abandoned biomass classification content and process units, mainly by the more stalk of hemicellulose level Store up and handle machinery, the less stalk of hemicellulose level is stored up and handled mechanical, discarded forest and stores up and handle the works such as machinery Skill and equipment are constituted, and major function is to complete agricultural waste biomass qualitative classification to store up, load chopping, raw material storage and thickness dedusting Process, and prevention dust pollution.
The biological medicament base thermoelectricity stalk hydrolysis content and process units, it is mainly raw by the more stalk of hemicellulose level Produce feedstock transportation mechanical, hydrolysis infusion set, thermal energy loader, electric energy loader, hot ionization or electromagnetism with electric energy or The techniques such as electric wave or inductance hydrolyzer, cooler with slurry, slurries follower and waste-heat recoverer and equipment are constituted;More than described Equipment by machinery, solution conduit, slurry conduit, be connected for heat pipe and electric energy circuit;Its major function is with low medicine, low When warm, low, the integrated technology hydrolyzing straw raw material and circulation of low consumption and low pollution;Further, can add other medicaments hydrolysis and In conjunction with other physics catalytic units and facility.
The separation of solid and liquid prepares cellulose and paper pulp content and process units, is mainly starched by slurries loader, electric mill Liquid machine, slurries filter press, hydrolysis liquid phase follower, hydrolysis solid phase plasm scouring machine, solid phase starch screening machine, solid phase starches bleaching machine, solid Mutually the techniques such as slurry output machine, ejected wash water loader and washing dope follower and equipment are constituted;The above equipment passes through machine Tool, slurry conduit and solution conduit are connected;Its major function is to be separated by solid-liquid separation and prepare lignocellulosic and paper pulp;Into one Step, can intensive and integrated lignocellulosic deep processing and paper production equipment and facility.
The alcohol method prepares hemicellulose and recycling alcohol content and process units, mainly by hydrolysis liquid phase loader, alcohol Loader, alcohol and hydrolysis liquid-phase precipitation and solid-liquid separator plus solid phase hemicellulose and xylan clarifier, inspissator, are done Dry device and crystallization collector, along with thermal energy solution liquid alcohol vaporizer, alcohol vapour condenser, alcohol reservoir and lignin medical fluid follower etc. Technique and equipment are constituted;The above equipment passes through machinery, solution conduit, for heat pipe, cryoablation catheter and vacuum pipeline phase Connection;Its basic technology has two methods of evaporation and freezing, and major function is to extract hemicellulose from hydrolysis liquid phase with alcohol method precipitating And xylan, the recycling for being completed at the same time alcohol use;Further, can be used meet technical requirements other are organic molten in addition to alcohol Agent;Further, intensive xylose and xylitol production equipment and facility can also be converted with integrated hemicellulose.
The dilute liquid medicine prepares alkali lignin content and process units, mainly by lignin infusion set, dilution Water loader, dilution precipitating and solid-liquid separator, dilute liquid medicine follower, solid phase lignin inspissator, alkali lignin it is dry and The techniques such as collector and equipment are constituted;The above equipment is connected by mechanical, slurry conduit and solution conduit;It is main Function is to prepare alkali lignin product;It further, can intensive and the wooden preparation compound fertilizer of integrated alkali, soil-repairing agent and water-reducing agent And the production technology and equipments facility such as binder.
The straw lignocellulose prepares ethyl alcohol content and process units, mainly by the less stalk of hemicellulose level Raw materials for production conveying machinery, thermal energy loader, raw materials for production preprocessor, lignocellulolyticenzymes hydrolyzer, monosaccharide fermentor, second The techniques such as alcohol rectifier, ethyl alcohol reservoir and slag object follower and equipment are constituted;The above equipment is led by mechanical, slurries Pipe and is connected solution conduit for heat pipe;Its major function is to prepare ethyl alcohol, while recycling and handling slag object;Further, may be used It is intensive to process and comprehensively utilize production equipment and facility with collection slagging object depth.
The agricultural abandoned biomass thermoelectricity content and process units, mainly by discarded forest fuel input machinery, second The input of alcohol production slag object is mechanical, biomass boiler and pyrolysis oven and waste heat boiler or heat exchanger, cogeneration unit, at chemical water The techniques such as reason and energy-saving environmental protection device and equipment are constituted;The above equipment passes through machinery, solution conduit, for heat pipe and electricity Energy circuit is connected;Its major function is converted the fuel into as thermal energy, electric energy, vegetation ashes, flue gas and combustion gas.
The collection plant ash preparation biology base medical fluid content and process units, mainly by disengaging flue, biomass cigarette Gas plant ash bag collector, plant ash conveyer, plant ash and alkaline solution reactor, liquid-phase precipitation and solid-liquid separator, It hydrolyzes the techniques such as medical fluid follower and solid phase salt follower and equipment is constituted;The above equipment passes through mechanical, solution conduit And it is connected for heat pipe;Its major function be collect plant ash and prepare biology base hydrolysis medical fluid, while using solid phase salt as Fume desulfurizing agent or building materials use.
The flue gas subtracts carbon Recovery Purifying plant ash content and process units, mainly by dilute liquid medicine loader, bypass Disengaging flue, flue gas subtract the techniques such as carbon purification and dilute liquid medicine generator, dilution water follower and plant ash class salt follower with Equipment is constituted;The above equipment is connected by mechanical, solution conduit and smoke pipe;Its major function is by flue gas Carbon dioxide is reacted with the medicament in dilute liquid medicine generates plant ash class salt, while reaching flue gas decrement carbon emission effect.
Beneficial effects of the present invention: it by classified use agricultural abandoned biomass resource, innovates low-carbon production and is passed through with circulation Ji mechanism not only economizes on resources but also improves production and Additional Value of Commodities, to realize the sustainable development of green ecological.
Detailed description of the invention
Fig. 1 is agricultural-forestry biomass classified use and low-carbon combined production device and its green technology schematic diagram of the invention;
Wherein: the more stalk machine raw materials for production conveyer of agricultural abandoned biomass classification device 1, hemicellulose level Tool 2, biological medicament base heat and electric stalk hydrolysis device 3, machinery 4 is led in slurries conveying, separation of solid and liquid prepares cellulose and paper pulp device 5, liquid phase delivery conduit 6, alcohol method prepare hemicellulose and recycling alcohol device 7, solution phase delivery conduit 8, dilute liquid medicine prepare alkali The less stalk raw materials for production conveying machinery 10 of lignin device 9, hemicellulose level, straw lignocellulose prepare ethyl alcohol device 11, slag object conveying machinery 12, discarded forest fuel input mechanical 13, agriculture and forestry organic waste material thermoelectric device 14, thermal energy conduit 15, thermal energy branch pipe 16, electric energy circuit 17, smoke tube 18, plant ash bag collector 19, plant ash conveying machinery 20, preparation Biology base medical fluid device 21, medical fluid delivery conduit 22, solid salt desulfurizing agent conveyer 23, flue gas subtract carbon Recovery Purifying medicament device 24, dilute liquid medicine input pipe 25, dilution water output duct 26.
Specific implementation
It of the invention is further analyzed for 1 pair with reference to the accompanying drawing.
As shown in Figure 1, agricultural-forestry biomass classified use of the invention and low-carbon combined production device and its green technology, specific Implement and production process be as follows:
It is the agricultural abandoned biomass resource that will be stored up by agricultural abandoned biomass classification device 1 first, handles and be The three classes raw materials for production such as the more stalk of hemicellulose level, the less stalk of hemicellulose level and discarded forest.
Followed by, by the more stalk machine raw materials for production conveying machinery 2 of hemicellulose level, biological medicament base heat and electric stalk water Solution device 3, machinery 4 is led in slurries conveying, separation of solid and liquid prepares cellulose and paper pulp device 5, liquid phase delivery conduit 6, the preparation of alcohol method Hemicellulose and recycling alcohol device 7, solution phase delivery conduit 8, dilute liquid medicine prepare the process system of the composition of alkali lignin device 9 Process mainly undertakes hemicellulose level more stalk cleaning coproduction cellulose and paper pulp, hemicellulose and xylan and wooden Cellulose product production task.
Third is to prepare second by the less stalk raw materials for production conveying machinery 10 of hemicellulose level, straw lignocellulose The technical process of alcohol device 11,12 composition of slag object conveying machinery, mainly undertakes the less stalk of hemicellulose level i.e. wood fibre Element ethyl alcohol production task.
The fourth is that, mechanical 13, agriculture and forestry organic waste material thermoelectric device 14, thermal energy conduit are inputted by discarded forest fuel 15, thermal energy branch pipe 16, electric energy circuit 17, smoke tube 18, plant ash bag collector 19, plant ash conveying machinery 20, preparation Biology base medical fluid device 21, medical fluid delivery conduit 22, solid salt desulfurizing agent conveyer 23, flue gas subtract carbon Recovery Purifying medicament device 24, the technical process that dilute liquid medicine input pipe 25, dilution water output duct 26 form, mainly undertakes discarded forest and stalk is raw Postpartum slag object conversion of biomass thermoelectricity production task;Also, both by plant ash preparation hydrolysis medical fluid in flue gas, further through flue gas The medicament of middle carbon dioxide recovery dilute liquid medicine regenerates plant ash;Especially, adaptation to local conditions forms low-carbon and cleans mechanism, thus Realize that sustainable agricultural abandoned biomass utilizes green ecological effect.

Claims (10)

1. agricultural-forestry biomass classified use of the invention and low-carbon combined production device and its green technology, it is characterized in that: (1) is directed to agriculture Woods abandoned biomass resource and agricultural crop straw five change comprehensive utilization, are mainly utilized respectively according to following three types: one is The more stalk cleaning coproduction cellulose of hemicellulose level and paper pulp, hemicellulose and xylan and wooden cellulose product, the second is The less stalk of hemicellulose level prepares ethyl alcohol, the third is slag object supplies biomass thermoelectricity after discarded forest and stalk production;(2) Thermal energy, electric energy, ashes and the flue gas of the biomass thermal electricity output, both can be recycled in the hemicellulose level compared with The production process of more stalk cleaning coproduction celluloses and paper pulp, hemicellulose and xylan and wooden cellulose product, is also recycled benefit The production process of ethyl alcohol is prepared for the less stalk of hemicellulose level;(3) the more straw of hemicellulose level described in Biomass ashes i.e. vegetation is recycled in stalk cleaning coproduction cellulose and paper pulp, hemicellulose and xylan and wooden cellulose product Ash and alkaline solution preparation biology base hydrolysis medical fluid and solid phase salt desulfurizing agent or building materials;(4) hemicellulose level described in compared with The titanium dioxide of flue gas is recycled in more stalk cleaning coproduction celluloses and paper pulp, hemicellulose and xylan and wooden cellulose product Carbon and other sour gas recycling medicament regeneration plant ash class salt are simultaneously reduced carbon row and purifying smoke;(5) hemicellulose described in Accurate metaplasia is created in the more stalk cleaning coproduction cellulose of cellulose content and paper pulp, hemicellulose and xylan and wooden cellulose product Object medicine base heat and electric stalk hydrolyze energy-saving environmental protection device, have not only protected fibre length and intensity but also poly- with alcohol precipitation hemicellulose and wood Sugar and reduce and reduce lignin liquid viscosity make production system energy conservation with it is water-saving;(6) the above production process described in is all solid Shape object complete set commercialization utilizes and the closed circulation of liquid phase complete set and recycling;(7) the above production process described in does not generate dirt Water and solid waste and production zero-emission;(8) by agricultural abandoned biomass classification, the hydrolysis of biological medicament base thermoelectricity stalk, solid-liquid point From preparing cellulose and paper pulp, alcohol method prepare hemicellulose and recycling alcohol, dilute liquid medicine prepare alkali lignin, stalk wood fibre Element prepares ethyl alcohol, agricultural abandoned biomass thermoelectricity, collection plant ash preparation biology base medical fluid, flue gas and subtracts carbon Recovery Purifying plant ash Based on nine some processes contents and process units constitute.
Agricultural abandoned biomass classification content and process units described in 2. are mainly received by the more stalk of hemicellulose level Storage and processing are mechanical, machinery is stored up and handled to the less stalk of hemicellulose level, the techniques such as machinery are stored up and handled to discarded forest And equipment is constituted, major function is to complete agricultural waste biomass qualitative classification to store up, load chopping, raw material storage and thickness dedusting Journey, and prevention dust pollution.
Biological medicament base thermoelectricity stalk hydrolysis content and process units described in 3., are mainly produced by the more stalk of hemicellulose level Feedstock transportation is mechanical, hydrolyzes infusion set, thermal energy loader, electric energy loader, hot ionization or electromagnetism or electricity with electric energy The techniques such as wave or inductance hydrolyzer, cooler with slurry, slurries follower and waste-heat recoverer and equipment are constituted;The above dress It is standby by machinery, solution conduit, slurry conduit, be connected for heat pipe and electric energy circuit;Its major function is with low medicine, low When warm, low, the integrated technology hydrolyzing straw raw material and circulation of low consumption and low pollution;Further, can add other medicaments hydrolysis and In conjunction with other physics catalytic units and facility.
4. separation of solid and liquid described in prepares cellulose and paper pulp content and process units, mainly by slurries loader, electric mill slurries Machine, slurries filter press, hydrolysis liquid phase follower, hydrolysis solid phase plasm scouring machine, solid phase slurry screening machine, solid phase starch bleaching machine, solid phase It starches the techniques such as output machine, ejected wash water loader and washing dope follower and equipment is constituted;The above equipment by it is mechanical, Slurry conduit and solution conduit are connected;Its major function is to be separated by solid-liquid separation and prepare lignocellulosic and paper pulp;Further, may be used Intensive and integrated lignocellulosic deep processing and paper production equipment and facility.
5. alcohol method described in prepares hemicellulose and recycling alcohol content and process units, mainly defeated by hydrolysis liquid phase loader, alcohol Enter device, alcohol and hydrolysis liquid-phase precipitation and solid-liquid separator, in addition solid phase hemicellulose and xylan clarifier, inspissator, drying Device and crystallization collector, along with works such as thermal energy solution liquid alcohol vaporizer, alcohol vapour condenser, alcohol reservoir and lignin medical fluid followers Skill and equipment are constituted;The above equipment is connected by machinery, solution conduit, for heat pipe, cryoablation catheter and vacuum pipeline It connects;Its basic technology have evaporation and freezing two methods, major function be with alcohol method precipitating from hydrolysis liquid phase in extract hemicellulose and Xylan, the recycling for being completed at the same time alcohol use;Further, other organic solvents in addition to alcohol for meeting technical requirements can be used; Further, intensive xylose and xylitol production equipment and facility can also be converted with integrated hemicellulose.
6. dilute liquid medicine described in prepares alkali lignin content and process units, mainly by lignin infusion set, dilution water Loader, dilution precipitating and solid-liquid separator, dilute liquid medicine follower, solid phase lignin inspissator, alkali lignin drying and receipts The techniques such as storage and equipment are constituted;The above equipment is connected by mechanical, slurry conduit and solution conduit;Its main function Can prepare alkali lignin product;Further, can it is intensive with the wooden preparation compound fertilizer of integrated alkali, soil-repairing agent and water-reducing agent and The production technology and equipments facility such as binder.
7. straw lignocellulose described in prepares ethyl alcohol content and process units, mainly raw by the less stalk of hemicellulose level Produce feedstock transportation machinery, thermal energy loader, raw materials for production preprocessor, lignocellulolyticenzymes hydrolyzer, monosaccharide fermentor, ethyl alcohol The techniques such as rectifier, ethyl alcohol reservoir and slag object follower and equipment are constituted;The above equipment by machinery, slurry conduit, Solution conduit and it is connected for heat pipe;Its major function is to prepare ethyl alcohol, while recycling and handling slag object;Further, can collect Production equipment and facility are about processed and comprehensively utilized with collection slagging object depth.
Agricultural abandoned biomass thermoelectricity content and process units described in 8., mainly by discarded forest fuel input machinery, ethyl alcohol Produce mechanical slag object input, biomass boiler and pyrolysis oven and waste heat boiler or heat exchanger, cogeneration unit, Water Treatment And the techniques such as energy-saving environmental protection device and equipment are constituted;The above equipment passes through machinery, solution conduit, for heat pipe and electric energy Circuit is connected;Its major function is converted the fuel into as thermal energy, electric energy, vegetation ashes, flue gas and combustion gas.
Collection plant ash preparation biology base medical fluid content and process units described in 9., mainly by disengaging flue, biomass flue gas Plant ash bag collector, plant ash conveyer, plant ash and alkaline solution reactor, liquid-phase precipitation and solid-liquid separator, water It solves the techniques such as medical fluid follower and solid phase salt follower and equipment is constituted;The above equipment by mechanical, solution conduit and It is connected for heat pipe;Its major function is to collect plant ash and prepare biology base hydrolysis medical fluid, while using solid phase salt as cigarette Gas desulfurizer or building materials use.
10. flue gas described in subtracts carbon Recovery Purifying plant ash content and process units, mainly by dilute liquid medicine loader, bypass into Flue, flue gas subtract the techniques such as carbon purification and dilute liquid medicine generator, dilution water follower and plant ash class salt follower and dress out It is standby to constitute;The above equipment is connected by mechanical, solution conduit and smoke pipe;Its major function is by two in flue gas Carbonoxide is reacted with the medicament in dilute liquid medicine generates plant ash class salt, while reaching flue gas decrement carbon emission effect.
CN201910109771.7A 2019-02-11 2019-02-11 Agricultural-forestry biomass classified use and low-carbon combined production device and its green technology Withdrawn CN109678988A (en)

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