CN109666544A - A kind of highly enriched main washing lotion and preparation method thereof with low-temperature catalyzed bleaching effect - Google Patents
A kind of highly enriched main washing lotion and preparation method thereof with low-temperature catalyzed bleaching effect Download PDFInfo
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- CN109666544A CN109666544A CN201811438007.6A CN201811438007A CN109666544A CN 109666544 A CN109666544 A CN 109666544A CN 201811438007 A CN201811438007 A CN 201811438007A CN 109666544 A CN109666544 A CN 109666544A
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
- C11D1/831—Mixtures of non-ionic with anionic compounds of sulfonates with ethers of polyoxyalkylenes without phosphates
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/06—Phosphates, including polyphosphates
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/30—Amines; Substituted amines ; Quaternized amines
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/33—Amino carboxylic acids
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3707—Polyethers, e.g. polyalkyleneoxides
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/373—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicones
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/04—Carboxylic acids or salts thereof
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- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
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Abstract
The present invention relates to detergent technical fields, disclose a kind of highly enriched main washing lotion with low-temperature catalyzed bleaching effect, the highly enriched main washing lotion with low-temperature catalyzed bleaching effect, by weight, including following components: 15-40 parts of neopelex, 30-50 parts of fatty alcohol polyoxyethylene ether, 20-45 parts of alkyl polyglucoside, 5-12 parts of bleaching catalyst, 6-25 parts of potassium oleate, 5-15 parts of potassium stearate, 5-15 parts of chelating agent, 3-8 parts of foam in hibitors, 8-15 parts of dispersing agent；The present invention discloses a kind of preparation methods of the highly enriched main washing lotion with low-temperature catalyzed bleaching effect.The highly enriched main washing lotion with low-temperature catalyzed bleaching effect of the invention have strong detergency, formula rationally, preparation process is simple, manufacturing cost is low, be easy to rinsing, easily biological-degradable, environmentally protective; also has effects that catalytically bleaching at low ambient temperatures simultaneously; be conducive to protect the fibre structure of institute's washing articles, use scope is wide.
Description
Technical field
The present invention relates to detergent technical fields, more particularly to a kind of with the highly concentrated of low-temperature catalyzed bleaching effect
Contract main washing lotion and preparation method thereof.
Background technique
With the fast development of Chinese economy, the resources costs pressure of domestic washing industry becomes increasing, while state
The appearance successively of the energy-saving and environmental protection restriction of family, country's washing industry are also faced with the new transition and integration of a wave.As guest
The biggish place of washing amounts such as shop, hotel, hospital, school or laundry, laundry factory improves efficiency for cost squeeze, is badly in need of
Large-scale, advanced washing facility is introduced, under these circumstances, the production for dragon of doing washing and using the impetus for having " in full flourish " greatly.
" laundry dragon " is a kind of large-scale laundry facilities, also referred to as tunnel-type washing machine, is that the state-of-the-art large size in the world today is washed
Clothing equipment is the optimum solution for washing industry energy-saving emission reduction, reducing resource consumption, reducing recruitment, improve efficiency, cut operating costs
The characteristic of certainly scheme, laundry dragon itself has the binding site agreed with downstream industry development trend perfection, represents more " section
Can, environmental protection, it is efficient " developing direction.And large scale equipment as dragon of doing washing, dosage form and characteristic to detergent have new want
It asks, although predominantly civilian liquid detergent, concentration is low, at high cost and wash at present on the market there are many liquid detergent of brand
Effect is limited, and pH is in neutrality or alkalescent, incompatible with industrial washing mode and wash conditions.Dedicated the washing of cooperation laundry dragon
The development for washing agent just starts to walk at home, therefore very of practical meaning and market prospects.
Meanwhile the fabrics such as towel, sheet that color can be selected shallower as hotel, hospital, it completely relaxes to customer
Suitable feeling, still, the spot on light fabric are clearly, and more difficult to remove, even if having removed clean can also leave
Coloured stains, so also to be bleached after generally being cleaned to towel, sheet etc., and common chlorine system bleaching agent chemistry taste
Road is heavier, and bleached towel, sheet have remaining taste, there is certain health hazard to user, so now more next
More selection is non-toxic, and the oxygen system bleaching agent without chlorine taste, it is suitable for all fibres and colored fabric, and with various tables
Face activating agent and enzyme all have good compatibility.However, common oxygen system bleaching agent needs could be sent out at a higher temperature
Blanching effect is waved, but temperature is high and can destroy the fibre structure of the fabrics such as towel, sheet, reduces its service life.
Therefore, it is actually necessary to research and develop a kind of highly enriched main washing lotion with low-temperature catalyzed bleaching effect.
Summary of the invention
(deficiency) in order to overcome at least one of the drawbacks of the prior art described above, the present invention provide a kind of with low-temperature catalyzed
The highly enriched main washing lotion and preparation method thereof of effect is bleached, the highly enriched main washing lotion with low-temperature catalyzed bleaching effect is gone
Dirty power is strong, formula is reasonable, preparation process is simple, manufacturing cost is low, environmentally protective, while also having catalysis drift at low ambient temperatures
Contour painting effect, is conducive to the fibre structure for protecting institute's washing articles, and use scope is wide.
To achieve the above object, The technical solution adopted by the invention is as follows:
A kind of highly enriched main washing lotion with low-temperature catalyzed bleaching effect, which is characterized in that by weight, the highly enriched master
Washing lotion includes following components:
15-40 parts of neopelex；
30-50 parts of fatty alcohol polyoxyethylene ether；
20-45 parts of alkyl polyglucoside；
5-12 parts of bleaching catalyst；
6-25 parts of potassium oleate；
5-15 parts of potassium stearate；
5-15 parts of chelating agent；
3-8 parts of foam in hibitors；
8-15 parts of dispersing agent.
As a preferred solution, the highly enriched main washing lotion with low-temperature catalyzed bleaching effect, by weight,
Including following components:
20 parts of neopelex；
40 parts of fatty alcohol polyoxyethylene ether；
35 parts of alkyl polyglucoside；
5 parts of bleaching catalyst；
15 parts of potassium oleate；
10 parts of potassium stearate；
10 parts of chelating agent；
5 parts of foam in hibitors；
10 parts of dispersing agent.
As a preferred solution, the highly enriched main washing lotion with low-temperature catalyzed bleaching effect, by weight,
Including following components:
15 parts of neopelex；
30 parts of fatty alcohol polyoxyethylene ether；
45 parts of alkyl polyglucoside；
10 parts of bleaching catalyst；
20 parts of potassium oleate；
15 parts of potassium stearate；
5 parts of chelating agent；
3 parts of foam in hibitors；
8 parts of dispersing agent.
As a preferred solution, the highly enriched main washing lotion with low-temperature catalyzed bleaching effect, by weight,
Including following components:
35 parts of neopelex；
45 parts of fatty alcohol polyoxyethylene ether；
25 parts of alkyl polyglucoside；
8 parts of bleaching catalyst；
25 parts of potassium oleate；
8 parts of potassium stearate；
12 parts of chelating agent；
7 parts of foam in hibitors；
12 parts of dispersing agent.
As a preferred solution, the highly enriched main washing lotion with low-temperature catalyzed bleaching effect, by weight,
Including following components:
40 parts of neopelex；
50 parts of fatty alcohol polyoxyethylene ether；
20 parts of alkyl polyglucoside；
12 parts of bleaching catalyst；
6 parts of potassium oleate；
5 parts of potassium stearate；
15 parts of chelating agent；
8 parts of foam in hibitors；
15 parts of dispersing agent.
Further, in above-mentioned each technical solution, the preferred tetraacetyl ethylene diamine of bleaching catalyst.
The chelating agent is selected from one of disodium ethylene diamine tetraacetate, four sodium of glutamic acid diacetic acid and sodium citrate.
The foam in hibitors is using the Polyether Modified Polysiloxanes Defoaming Agent bought on the market.
The dispersing agent is selected from one of triethanolamine, calgon, polyethylene glycol.
A kind of preparation method of above-mentioned highly enriched main washing lotion with low-temperature catalyzed bleaching effect, specifically includes following step
It is rapid:
1. measures neopelex, fatty alcohol polyoxyethylene ether, alkyl polyglucoside, bleaching catalyst, oil by formula
Sour potassium, potassium stearate, chelating agent, foam in hibitors and dispersing agent；
2. by step 1. in weighed neopelex, fatty alcohol polyoxyethylene ether, alkyl polyglucoside, potassium oleate,
Potassium stearate, chelating agent, dispersing agent are added in stirred tank, by stirring, are uniformly mixed, obtain mixture A；
3. step 2. obtained in bleaching catalyst is added in mixture A, continue to stir, make it dissolve, obtain mixture B；
4. step 3. in obtain in mixture B, by the way that 0.1mol/L potassium hydroxide solution is added, the pH of mixture B is adjusted
To 9-10, foam in hibitors is added, is stirred evenly to get the highly enriched main washing lotion with low-temperature catalyzed bleaching effect.
In formula of the invention, the characteristic of each component is as follows:
Neopelex (abbreviation LAS): not oxidizable for anionic surfactant, solution rate is fast, has good
Emulsification, foaming, infiltration, decontamination and dispersion performance, there is significant decontamination to imitate particulate fouling, albumen dirt and oily dirt
Fruit, neopelex are linear alkylbenzene sulfonate (LAS), and biodegradability is good, and cost is relatively low, and synthesis technology is mature,
Application field is extensive.
Fatty alcohol polyoxyethylene ether (abbreviation AEO-9): fatty alcohol polyoxyethylene ether is nonionic surfactant, in molecule
Ehter bond be not easy to be destroyed by acid, alkali, so high stability, water-soluble preferably electrolyte-resistant is readily biodegradable, and foam is small,
For in liquid detergent, it is the main of liquid detergent that cold washing performance is good, has good emulsification, dispersion, foaming, clean effect
Active constituent.
Alkyl polyglucoside (APG for short): alkyl polyglucoside is that a kind of more comprehensive new non-ionic surface of performance is living
Property agent, has both the characteristic of conventional nonionic and anionic surfactant.Alkyl polyglucoside surface tension is low, without cloud point, wet
Profit power is strong, strong detergency, foaming abundancy are fine and smooth, and compatibility is good, can compound with various ionics, nonionic surface active agent
It generates synergistic effect, can improve the mildness being formulated, foaming characteristic is good, and foaming abundancy exquisiteness, dissolubility is good, and resistance to highly basic, resistance to
Strong acid, resistance to hard water, salt-resistance are strong, there is good thickening capabilities, nontoxic, non-stimulated to skin, and biodegrade is thorough rapidly,
Can be with any type surfactant compound, synergistic effect is obvious.Tetraacetyl ethylene diamine (abbreviation TAED): being a kind of efficient low
Warm oxygen system bleach activator, is equivalent to bleaching catalyst, is made of ethylenediamine and aceticanhydride, has superior cold bleaching reactivity
Can, oxygen system bleaching agent can be promoted to give full play to the unique effects for brightening, increasing gorgeous, antivirus, sterilization under cryogenic, with various enzymes
There is good compatibility with other surfactants.It is used cooperatively with oxygen system bleaching agent, it is completely anti-in 30 DEG C -60 DEG C of water temperature
Active oxygen should be decomposed and release, thus achieve the effect that energy conservation, efficiently bleach, wash safely, meanwhile, tetraacetyl ethylene diamine ring
Guaranteed cost is good, can be biodegradable, to environment without any harm.
Potassium oleate: being a kind of preferable emulsifier, be conducive to mutually merge between each component in liquid detergent, enhances decontamination energy
Power.
Potassium stearate: for having the effects that raising agent, foaming agent, anticaking agent, emulsifier, stabilizer in liquid detergent.
Chelating agent: chelating agent used in the present invention is selected from disodium ethylene diamine tetraacetate, four sodium of glutamic acid diacetic acid and lemon
One of lemon acid sodium, preferably four sodium of glutamic acid diacetic acid.The effect of addition chelating agent is that neopelex is to water
Hardness is more sensitive, and resistance to hard water is poor, and detergency ability is reduced with the raising of the water hardness, therefore take it as the detergent of main activating agent
It must be used cooperatively with appropriate chelating agent, chelating agent can adsorb calcium, magnesium plasma, and demineralized water prevents metal ion from participating in
Chemical reaction, improves the washing effect of liquid detergent, while chelating agent can also chelate the calcium ion on bacterial cell membrane, to make
Preservative is easier to penetrate into the inside of bacterium, reaches better fungi-proofing effect.
Foam in hibitors: the foam in hibitors used in the present invention defoams for the organic silicon modified by polyether bought on the market
Agent is a kind of high effective antifoaming agent for water phase system, and good dispersion, good with all kinds of additive compatibilities, foam inhibition is of long duration.Due to
Highly enriched main washing lotion of the invention can generate foam in use, although foam volume is conducive to remove spot, bubble greatly
Foam amount is excessive, by its rinsed clean, it is necessary to and a large amount of water is used, while can also extend rinsing time, increases washing cost,
Therefore foam in hibitors is added in system, can control foam yield, is easy to rinse, reduce water consume, energy conservation and environmental protection.
Dispersing agent: the dispersing agent used in the present invention is selected from one of triethanolamine, calgon, polyethylene glycol,
It can prevent each component in highly enriched main washing lotion of the invention from sedimentation occurs, keeps system stability, while can also be by dirt
Dispersed, prevents from gathering deposition, improve washing effect.
The principle that highly enriched main washing lotion with low-temperature catalyzed bleaching effect of the invention uses is as follows: according to laundry dragon
The status and trend of feature and its special purpose detergent, using anionic surfactant-neopelex, nonionic table
Face activating agent-fatty alcohol polyoxyethylene ether, new non-ionic surfactants-alkyl polyglucoside compound system, utilize it
Excellent lubricating capacity, emulsifying ability and foaming detergency ability, the effects of soaked, permeated to dirt, being emulsified, being dispersed, is solubilized, from
And the spot on fabric is removed, after three kinds of surfactants assemble, dirt-removing power is significantly increased；Due to meeting between dirt and fabric
Very firm calcium alkali is formed, is difficult to spot clean by surfactant washing, so chelating agent is added in system, chelating agent
Calcium alkali can be destroyed, to increase the cleaning effect of surfactant；Potassium oleate, potassium stearate are added in system, as
Surfactant and softening agent for fibres enhanced foaming decontamination effect and can play a protective role to the fabric washed；
Make highly enriched main washing lotion of the invention in alkalinity by the way that a small amount of potassium hydroxide is added, the highly enriched main washing lotion described in this way can be with grease
Saponification occurs and removes oils spot, and protein dirt also can resolve into substance soluble easily in water and take off under alkaline condition
From fabric, thus enhance clean effect, meanwhile, main washing lotion has certain protective effect to fabric is washed, is able to maintain that in alkalinity
The intensity of fabric reduces fabric damage rate, can be effectively prevented washing facility metallic article and corrode.
Since existing most of detergent do not have catalytically bleaching effect, common bleaching agent does not have decontamination energy yet
Power, and require to be bleached in general industrial washing, using highly enriched main washing lotion of the invention, enter bleaching in laundry dragon
When process, can be used cooperatively oxygen system bleaching agent such as sodium perborate or SODIUM PERCARBONATE, to the fabrics such as towel, the sheet washed into
Row bleaching.However, only the use of temperature being more than 70 DEG C or more and having release nascent state since oxygen system bleach stability is high
When oxygen, its bleaching effect could be effectively played, and a large amount of synthetic fibers and wool fabric do not adapt to this temperature, at this moment, this
Tetraacetyl ethylene diamine in the highly enriched main washing lotion of invention can play its catalytic performance, promote oxygen system bleaching agent in cryogenic conditions
As played good bleaching effect at 25-40 DEG C, to reduce the temperature for imperial detergent bleach of doing washing, energy saving reduces simultaneously
Detergent bleach cost.
Main washing lotion of the invention be highly concentrated miniature, meet the requirement of the direct auto feed of various distributors, can also by appoint
Meaning ratio is directly watered rear various leviathans, with foam is small, be easy to rinse, dirt removal and rate of dispersion are fast, reduce
Wash temperature and it is hard water resistance the features such as, strong applicability, save washing and rinsing water usage amount and reduce washing heating energy consumption,
Particularly for imperial better effect of doing washing.
At washing initial stage, main washing lotion through the invention, which washs the general spot dirt on fabric, to be removed, in laundry dragon
When into bleaching process, oxygen system bleaching agent such as sodium perborate or SODIUM PERCARBONATE can be added into laundry dragon, in four acetyl second two
Under the catalytic action of amine, oxygen system bleaching agent cryogenic conditions such as good bleaching effect can be played at 25-40 DEG C, can remove
Stain dirt bleaches the fabrics such as towel, the sheet washed, to show good washing effect.
Compared with prior art, the beneficial effect of technical solution of the present invention is:
1. strong detergency, each main component is all made of surfactant, and foam performance is good, is conducive to remove spot；
2. rationally, compatibility is good between each component for formula, synergistic effect, effect enhancing；
3. preparation process is simple, manufacturing cost is low, use easy to spread；
4. having low-temperature catalyzed bleaching effect at low ambient temperatures, is conducive to the fibre structure for protecting institute's washing articles, uses model
It encloses wide；
5. easily rinsing can control foam and generate excessively, be easy to rinse after making fabric washing, drop since foam in hibitors is added
Low water consumption；
It is the characteristics of primary raw material used all has easily biological-degradable, small to environmental hazard 6. environmentally protective.
Specific embodiment
Further illustrate that the present invention, following embodiment are the preferable embodiment party of the present invention below by specific embodiment
Formula, but embodiments of the present invention are not limited by following embodiments, therefore the scope of protection of present invention is not limited to
In described.
Embodiment 1:
A kind of highly enriched main washing lotion with low-temperature catalyzed bleaching effect, which is characterized in that by weight, the highly enriched master
Washing lotion includes following components:
20 parts of neopelex；
40 parts of fatty alcohol polyoxyethylene ether；
35 parts of alkyl polyglucoside；
5 parts of tetraacetyl ethylene diamine；
15 parts of potassium oleate；
10 parts of potassium stearate；
10 parts of chelating agent；
5 parts of foam in hibitors；
10 parts of dispersing agent.
The chelating agent is disodium ethylene diamine tetraacetate.
The foam in hibitors is Polyether Modified Polysiloxanes Defoaming Agent.
The dispersing agent is triethanolamine.
A kind of preparation method of above-mentioned highly enriched main washing lotion with low-temperature catalyzed bleaching effect, comprising the following steps:
1. by formula measure neopelex, fatty alcohol polyoxyethylene ether, alkyl polyglucoside, tetraacetyl ethylene diamine,
Potassium oleate, potassium stearate, disodium ethylene diamine tetraacetate, Polyether Modified Polysiloxanes Defoaming Agent and triethanolamine；
2. by step 1. in weighed neopelex, fatty alcohol polyoxyethylene ether, alkyl polyglucoside, potassium oleate,
Potassium stearate, disodium ethylene diamine tetraacetate, triethanolamine are added in stirred tank, by stirring, are uniformly mixed, obtain mixture A；
3. step 2. obtained in tetraacetyl ethylene diamine is added in mixture A, continue to stir, make it dissolve, obtain mixture
B；
4. step 3. in obtain in mixture B, by the way that 0.1mol/L potassium hydroxide solution is added, the pH of mixture B is adjusted
To 9-10, Polyether Modified Polysiloxanes Defoaming Agent is added, is stirred evenly to get the highly enriched master with low-temperature catalyzed bleaching effect
Washing lotion.
Embodiment 2:
A kind of highly enriched main washing lotion with low-temperature catalyzed bleaching effect, which is characterized in that by weight, the highly enriched master
Washing lotion includes following components:
15 parts of neopelex；
30 parts of fatty alcohol polyoxyethylene ether；
45 parts of alkyl polyglucoside；
10 parts of tetraacetyl ethylene diamine；
20 parts of potassium oleate；
15 parts of potassium stearate；
5 parts of chelating agent；
3 parts of foam in hibitors；
8 parts of dispersing agent.
The chelating agent is four sodium of glutamic acid diacetic acid.
The foam in hibitors is Polyether Modified Polysiloxanes Defoaming Agent.
The dispersing agent is calgon.
A kind of preparation method of above-mentioned highly enriched main washing lotion with low-temperature catalyzed bleaching effect, comprising the following steps:
1. by formula measure neopelex, fatty alcohol polyoxyethylene ether, alkyl polyglucoside, tetraacetyl ethylene diamine,
Potassium oleate, potassium stearate, four sodium of glutamic acid diacetic acid, Polyether Modified Polysiloxanes Defoaming Agent and calgon；
2. by step 1. in weighed neopelex, fatty alcohol polyoxyethylene ether, alkyl polyglucoside, potassium oleate,
Potassium stearate, four sodium of glutamic acid diacetic acid, calgon are added in stirred tank, by stirring, are uniformly mixed, obtain mixture
A；
3. step 2. obtained in tetraacetyl ethylene diamine is added in mixture A, continue to stir, make it dissolve, obtain mixture
B；
4. step 3. in obtain in mixture B, by the way that 0.1mol/L potassium hydroxide solution is added, the pH of mixture B is adjusted
To 9-10, Polyether Modified Polysiloxanes Defoaming Agent is added, is stirred evenly to get the highly enriched master with low-temperature catalyzed bleaching effect
Washing lotion.
Embodiment 3:
A kind of highly enriched main washing lotion with low-temperature catalyzed bleaching effect, which is characterized in that by weight, the highly enriched master
Washing lotion includes following components:
35 parts of neopelex；
45 parts of fatty alcohol polyoxyethylene ether；
25 parts of alkyl polyglucoside；
8 parts of tetraacetyl ethylene diamine；
25 parts of potassium oleate；
8 parts of potassium stearate；
12 parts of chelating agent；
7 parts of foam in hibitors；
12 parts of dispersing agent.
The chelating agent is sodium citrate.
The foam in hibitors is Polyether Modified Polysiloxanes Defoaming Agent.
The dispersing agent is polyethylene glycol.
A kind of preparation method of above-mentioned highly enriched main washing lotion with low-temperature catalyzed bleaching effect, comprising the following steps:
1. by formula measure neopelex, fatty alcohol polyoxyethylene ether, alkyl polyglucoside, tetraacetyl ethylene diamine,
Potassium oleate, potassium stearate, sodium citrate, foam in hibitors and polyethylene glycol；
2. by step 1. in weighed neopelex, fatty alcohol polyoxyethylene ether, alkyl polyglucoside, potassium oleate,
Potassium stearate, sodium citrate, polyethylene glycol are added in stirred tank, by stirring, are uniformly mixed, obtain mixture A；
3. step 2. obtained in tetraacetyl ethylene diamine is added in mixture A, continue to stir, make it dissolve, obtain mixture
B；
4. step 3. in obtain in mixture B, by the way that 0.1mol/L potassium hydroxide solution is added, the pH of mixture B is adjusted
To 9-10, Polyether Modified Polysiloxanes Defoaming Agent is added, is stirred evenly to get the highly enriched master with low-temperature catalyzed bleaching effect
Washing lotion.
Embodiment 4:
A kind of highly enriched main washing lotion with low-temperature catalyzed bleaching effect, which is characterized in that by weight, the highly enriched master
Washing lotion includes following components:
40 parts of neopelex；
50 parts of fatty alcohol polyoxyethylene ether；
20 parts of alkyl polyglucoside；
12 parts of tetraacetyl ethylene diamine；
6 parts of potassium oleate；
5 parts of potassium stearate；
15 parts of chelating agent；
8 parts of foam in hibitors；
15 parts of dispersing agent.
The chelating agent is four sodium of glutamic acid diacetic acid.
The foam in hibitors is Polyether Modified Polysiloxanes Defoaming Agent.
The group of the dispersing agent becomes polyethylene glycol.
A kind of preparation method of above-mentioned highly enriched main washing lotion with low-temperature catalyzed bleaching effect, comprising the following steps:
1. by formula measure neopelex, fatty alcohol polyoxyethylene ether, alkyl polyglucoside, tetraacetyl ethylene diamine,
Potassium oleate, potassium stearate, four sodium of glutamic acid diacetic acid, Polyether Modified Polysiloxanes Defoaming Agent and polyethylene glycol；
2. by step 1. in weighed neopelex, fatty alcohol polyoxyethylene ether, alkyl polyglucoside, potassium oleate,
Potassium stearate, four sodium of glutamic acid diacetic acid, polyethylene glycol are added in stirred tank, by stirring, are uniformly mixed, obtain mixture A；
3. step 2. obtained in tetraacetyl ethylene diamine is added in mixture A, continue to stir, make it dissolve, obtain mixture
B；
4. step 3. in obtain in mixture B, by the way that 0.1mol/L potassium hydroxide solution is added, the pH of mixture B is adjusted
To 9-10, Polyether Modified Polysiloxanes Defoaming Agent is added, is stirred evenly to get the highly enriched master with low-temperature catalyzed bleaching effect
Washing lotion.
It is height no matter using which kind of above-mentioned embodiment highly enriched main washing lotion obtained with low-temperature catalyzed bleaching effect
Concentrated type, will by highly enriched main washing lotion at imperial washing initial stage of doing washing for dragon of doing washing after being directly watered in any proportion
General spot dirt on fabric, which washs, to be removed, and when laundry dragon enters bleaching process, the drift of oxygen system can be added into laundry dragon
White dose of such as sodium perborate or SODIUM PERCARBONATE, under the catalytic action of tetraacetyl ethylene diamine, oxygen system bleaching agent is in cryogenic conditions such as 25-
Good bleaching effect can be played at 40 DEG C, can remove stain dirt, to the fabrics such as towel, the sheet washed into
Row bleaching, to show good washing effect.
In order to there is the detergency of the low-temperature catalyzed highly enriched main washing lotion for bleaching effect and stability to carry out of the invention
Comparative example 1 is arranged in comparative analysis, spy, and liquid detergent used in comparative example 1 is according to GB/T13174-2008 " dress material detergent decontamination
Power and recycle scourability measurement " in standard laundry liquid formulation prepared.
The detergency test of the embodiment of the present invention 1-4 and comparative example 1 in GB/T13174-2008 standard using advising
Fixed test method, the specific steps are as follows:
1. carbon black greasy dirt cloth (JB01), albumen soiled cotton (JB02), sebum soiled cotton (JB03) are cut into the circle that diameter is 6cm size
Piece, referred to as test piece.Test piece leucometer is read to the whiteness value before washing one by one at 457nm, and carries out number record.
2. weighing calcium chloride 1.67g and magnesium sulfate 2.47g, deionized water is added to be configured to 1L aqueous solution, as 2500mg/kg
Hard water, when use, take 0.1L, are diluted to 1L, as 250mg/kg standard hard water with deionized water.
3. 5 test groups are arranged, every group is correspondingly arranged 1 decontamination cylinder, and each decontamination cylinder marks, and then gives each decontamination
1L standard hard water (being preheated to about 30 DEG C in advance) is added in cylinder, then matches respectively to 3.0g liquid detergent sample is added in each decontamination cylinder
It is set to test fluid, conditioning instrumentation makes decantation test temperature be maintained at 30 DEG C ± 1 DEG C.
4. test piece is added into each decontamination cylinder, every group of test piece includes 5 carbon black greasy dirt cloth, 5 albumen soiled cottons and 5 sebums
Soiled cotton.Starting stirring, and it is kept stirring speed 120r/min, washing process stops after continuing 20min.
5. taking out test piece with tweezers to be put in shallow bid, the general 10s of test piece, water dumping then are rinsed with the tap water for stablizing flow velocity
It spreads in pallet in order afterwards, the whiteness value of similar soiled cotton in each test group is measured after drying, is averaged.Decontamination index is
The difference of whiteness before soiled cotton is washed rear whiteness and washed, difference is bigger, and detergency is better.
Detergency and stability contrast result are as follows:
Table 1
The liquid phase as it can be seen from table 1 the highly enriched main washing lotion of embodiment of the present invention 1-4 preparation and the standard of comparative example 1 are done washing
Than there is better clean effect, while with good stability.
The above embodiment of the present invention be only to clearly illustrate example of the present invention, and not be to the present invention
Embodiment restriction.For those of ordinary skill in the art, it can also be made on the basis of the above description
Its various forms of variation or variation, there is no need and unable to be exhaustive to all embodiments.It is all in spirit of the invention
With any modifications, equivalent replacements, and improvements made within principle etc., the protection scope of the claims in the present invention should be included in
Within.
Claims (10)
1. a kind of highly enriched main washing lotion with low-temperature catalyzed bleaching effect, which is characterized in that by weight, described highly enriched
Main washing lotion includes following components: 15-40 parts of neopelex, 30-50 parts of fatty alcohol polyoxyethylene ether, the poly- glucose of alkyl
20-45 parts of glycosides, 5-12 parts of bleaching catalyst, 6-25 parts of potassium oleate, 5-15 parts of potassium stearate, 5-15 parts of chelating agent, foam inhibit
3-8 parts of agent, 8-15 parts of dispersing agent.
2. a kind of highly enriched main washing lotion with low-temperature catalyzed bleaching effect according to claim 1, which is characterized in that press
Parts by weight meter, the highly enriched main washing lotion includes following components: 20 parts of neopelex, fatty alcohol polyoxyethylene ether 40
Part, 35 parts of alkyl polyglucoside, 5 parts of bleaching catalyst, 15 parts of potassium oleate, 10 parts of potassium stearate, 10 parts of chelating agent, foam inhibit
5 parts of agent, 10 parts of dispersing agent.
3. a kind of highly enriched main washing lotion with low-temperature catalyzed bleaching effect according to claim 1, which is characterized in that press
Parts by weight meter, the highly enriched main washing lotion includes following components: 15 parts of neopelex, fatty alcohol polyoxyethylene ether 30
Part, 45 parts of alkyl polyglucoside, 10 parts of bleaching catalyst, 20 parts of potassium oleate, 15 parts of potassium stearate, 5 parts of chelating agent, foam inhibit
3 parts of agent, 8 parts of dispersing agent.
4. a kind of highly enriched main washing lotion with low-temperature catalyzed bleaching effect according to claim 1, which is characterized in that press
Parts by weight meter, the highly enriched main washing lotion includes following components: 35 parts of neopelex, fatty alcohol polyoxyethylene ether 45
Part, 25 parts of alkyl polyglucoside, 8 parts of bleaching catalyst, 25 parts of potassium oleate, 8 parts of potassium stearate, 12 parts of chelating agent, foam inhibit
7 parts of agent, 12 parts of dispersing agent.
5. a kind of highly enriched main washing lotion with low-temperature catalyzed bleaching effect according to claim 1, which is characterized in that press
Parts by weight meter, the highly enriched main washing lotion includes following components: 40 parts of neopelex, fatty alcohol polyoxyethylene ether 50
Part, 20 parts of alkyl polyglucoside, 12 parts of bleaching catalyst, 6 parts of potassium oleate, 5 parts of potassium stearate, 15 parts of chelating agent, foam inhibit
8 parts of agent, 15 parts of dispersing agent.
6. a kind of highly enriched main washing lotion with low-temperature catalyzed bleaching effect according to claim 1-5, special
Sign is that the bleaching catalyst is tetraacetyl ethylene diamine.
7. a kind of highly enriched main washing lotion with low-temperature catalyzed bleaching effect according to claim 6, which is characterized in that institute
Stating chelating agent is one of disodium ethylene diamine tetraacetate, four sodium of glutamic acid diacetic acid and sodium citrate.
8. a kind of highly enriched main washing lotion with low-temperature catalyzed bleaching effect according to claim 7, which is characterized in that institute
Stating foam in hibitors is organic silicon modified by polyether.
9. a kind of highly enriched main washing lotion with low-temperature catalyzed bleaching effect according to claim 8, which is characterized in that institute
Stating dispersing agent is one of triethanolamine, calgon, polyethylene glycol.
10. a kind of preparation method of the highly enriched main washing lotion with low-temperature catalyzed bleaching effect, which is characterized in that including following step
It is rapid:
1. weighs desired amount of neopelex, fatty alcohol polyoxyethylene ether, alkyl polyglucoside, bleaching respectively
Catalyst, potassium oleate, potassium stearate, chelating agent, foam in hibitors and dispersing agent；
2. by step 1. in weighed neopelex, fatty alcohol polyoxyethylene ether, alkyl polyglucoside, potassium oleate,
Potassium stearate, chelating agent, dispersing agent are added in stirred tank, by stirring, are uniformly mixed, obtain mixture A；
3. step 2. obtained in bleaching catalyst is added in mixture A, continue to stir, make it dissolve, obtain mixture B；
4. step 3. in obtain in mixture B, by the way that 0.1mol/L potassium hydroxide solution is added, the pH of mixture B is adjusted
To 9-10, foam in hibitors is added, is stirred evenly to get the highly enriched main washing lotion with low-temperature catalyzed bleaching effect.
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101210212A (en) * | 2006-12-29 | 2008-07-02 | 上海和黄白猫有限公司 | Special-purpose cleaning agent for washing machine |
| CN103131552A (en) * | 2013-03-15 | 2013-06-05 | 广州立白企业集团有限公司 | Detergent composition containing low-temperature bleaching and activation system |
| CN103131542A (en) * | 2013-03-20 | 2013-06-05 | 广州立白企业集团有限公司 | Active oxygen washing machine tank cleaning agent and preparation method thereof |
| CN106318686A (en) * | 2016-08-16 | 2017-01-11 | 中轻日化科技有限公司 | Efficient and environment-friendly concentrated hard surface cleaning agent |
-
2018
- 2018-11-29 CN CN201811438007.6A patent/CN109666544A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101210212A (en) * | 2006-12-29 | 2008-07-02 | 上海和黄白猫有限公司 | Special-purpose cleaning agent for washing machine |
| CN103131552A (en) * | 2013-03-15 | 2013-06-05 | 广州立白企业集团有限公司 | Detergent composition containing low-temperature bleaching and activation system |
| CN103131542A (en) * | 2013-03-20 | 2013-06-05 | 广州立白企业集团有限公司 | Active oxygen washing machine tank cleaning agent and preparation method thereof |
| CN106318686A (en) * | 2016-08-16 | 2017-01-11 | 中轻日化科技有限公司 | Efficient and environment-friendly concentrated hard surface cleaning agent |
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