CN109652215A - A kind of efficient clothing lasting pearl and preparation method thereof of low cost - Google Patents
A kind of efficient clothing lasting pearl and preparation method thereof of low cost Download PDFInfo
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- CN109652215A CN109652215A CN201811290001.9A CN201811290001A CN109652215A CN 109652215 A CN109652215 A CN 109652215A CN 201811290001 A CN201811290001 A CN 201811290001A CN 109652215 A CN109652215 A CN 109652215A
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/04—Carboxylic acids or salts thereof
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/65—Mixtures of anionic with cationic compounds
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/046—Salts
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3707—Polyethers, e.g. polyalkyleneoxides
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/50—Perfumes
- C11D3/502—Protected perfumes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/62—Quaternary ammonium compounds
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- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
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- Fats And Perfumes (AREA)
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Abstract
The invention belongs to detergent technical fields, and in particular to a kind of efficient clothing lasting pearl and preparation method thereof of low cost.The clothing lasting pearl includes that following parts by weight prepare raw material: 50~60 parts of polyethylene glycol, 25~35 parts of stearyl lactate, 10~20 parts of inorganic salts, 0.3~1 part of essence microcapsule and 1~3 part of essence.Clothing lasting pearl of the present invention is when with articles for washing mixing, washing clothing, essence therein can be with certain speed slow release, prevent essence that washing machine is largely discharged during washing and rinsing, it is attached to essence more effectively on clothing for a long time, lasting is more longlasting, and the dosage that essence is reduced while reducing lasting pearl matrix cost starts with from many aspects under the premise of obtaining same lasting degree and greatly reduces production cost.
Description
Technical field
The invention belongs to detergent technical fields, and in particular to a kind of efficient clothing lasting pearl of low cost and its preparation side
Method.
Background technique
As the improvement of people's living standards, amusement food and drink activity and various heathful forms of exercise are gradually by more next
The concern of more people, but the problem of many embarrassments is also brought simultaneously, such as eats up the tastes such as chafing dish, barbecue than heavier food
Later, whole body all remains the taste that food is carried over；For the personage for liking movement, as some high-intensitive instructions
Passion when practicing, when the sweat odor of whole body can all influence movement when movement.On the other hand, for areas some for China, often
All there are more plum rain season periods year, overcast and rainy continuous, clothing and bedding are all very moist, and not contacting sunlight for a long time will also result in clothing
Serious musty, therefore persistently add fragrance for clothes and be very important.
The product for currently playing lasting to clothing mainly has liquid detergent, laundry sheet and softener, but liquid detergent and laundry
The major function of piece is removal spot, and its alkalinity is stronger, needs to carry out 1~3 rinsing after washing again, is caused therein big absolutely
Washing machine is discharged with rinse water in part essence, therefore the lasting served to clothing is not strong；And softener popularity rate is not high, and
Mainly for the fabric of the materials such as cotton, hair, using above there is certain limitation.For example, Chinese patent literature CN 106434019
A discloses a kind of laundry sheet that can be used for underwear sterilizing, which includes polyvinyl alcohol, sulfonic acid, sodium sulphate, emulsifier, two
Silica, starch, essence, sodium bicarbonate, fungicide, water etc. are main component, and hyperconcetration effect is realized from physical behavior,
It is easy to carry, and decontamination sterilizing is two-in-one, it is bad to the aroma retaining effect of clothing although being added to essence in laundry sheet.China
107034039 A of patent document CN discloses a kind of preparation method of compound laundry sheet, and the laundry sheet is with polyvinyl alcohol, 12
Sodium alkyl sulfate, fabric softening agent, sodium chloride, adhesive, essence, antioxidant, sodium citrate and chelating agent are main component,
Wherein the dosage of essence is up to 5 parts, which can make clothing more compliant, and can sterilizing, but essence use
It is bad to measure the effect of excessively high however lasting, causes the waste of essence, takes very big cost.The main function of above-mentioned laundry sheet
It is decontamination, it is therefore desirable to have and meets the molten characteristic of water speed, although and wherein joined a certain amount of essence, it is rinsing
Washing machine is discharged with rinse water in essence in the process, and lasting effect is bad, and the usage amount of essence is very big, higher cost.In addition,
Most people can also select the mode to spray perfume over sth to add fragrance for clothing, but the taste of perfume inferior experiences bad, high-quality perfume (or spice)
The price of water is again sufficiently expensive, it is most important that, perfume is extremely difficult to lasting effect.
With the development of science and technology, occurring special clothing lasting pearl on current market, it is also known as clothes perfume, and is washed
Clothing powder, liquid detergent or laundry soap matching purge clothing together have same perfume general but compare perfume after clothes can be allowed to wash
Persistently more times of natural faint scent, but joined the high polymer, essence and perfume (or spice) of larger proportion in clothing lasting pearl on the market at present
Precise and tiny capsule, expensive, production cost is higher.In addition, other lasting product such as washing powder, liquid detergent and laundry sheet fragrance
It is impermanent to keep, and usually disappears with the secretion of sweat or is easy to be covered by other smells.Therefore, it is necessary to overcome
The problems such as the problems such as current lasting product aroma retaining effect is bad, expensive and high production cost, provides one as people
Essence can be with slow release, the lasting uniform and low-cost clothing of fragrance attachment when with articles for washing mixing, washing clothing for kind
Object lasting pearl and preparation method thereof.
Summary of the invention
The purpose of the present invention is intended to overcome the shortcomings of the prior art, provides a kind of efficient clothing lasting pearl of low cost
And preparation method thereof, for the clothing lasting pearl when with articles for washing mixing, washing clothing, essence therein can be with certain speed
Slow release is spent, and fragrance attachment is persistently uniform, it is cheap to prepare cost of material, significantly reduces production cost, is suitble to work
Industry metaplasia produces.
To achieve the goals above, technical scheme is as follows:
A kind of efficient clothing lasting pearl of low cost, prepares raw material including following parts by weight: polyethylene glycol 50~60
Part, 25~35 parts of stearyl lactate, 10~20 parts of inorganic salts, 0.3~1 part of essence microcapsule and 1~3 part of essence.
As a preferred embodiment of the present invention, the efficient clothing lasting pearl of the low cost, including following parts by weight
Prepare raw material: 51~56 parts of polyethylene glycol, 30 parts of stearyl lactate, 12 parts of inorganic salts, 0.7 part of essence microcapsule and essence
2 parts.
Further, the polyethylene glycol is PEG 8000.
Further, the inorganic salts are sodium chloride and sodium sulphate.
Further, the efficient clothing lasting pearl of the low cost, further includes dimethyl diallyl ammonium chloride or methyl
3~5 parts by weight of acrylyl oxy-ethyl-trimethyl salmiac.
Further, the efficient clothing lasting pearl of the low cost, further includes 4 weight of dimethyl diallyl ammonium chloride
Part.
Further, the efficient clothing lasting pearl of the low cost further includes the customary adjuvants such as water colo(u)r, for adjusting
Save the appearance of product.
The preparation method of the efficient clothing lasting pearl of above-mentioned low cost, comprising the following steps:
S1, the stearyl lactate of formula ratio and polyethylene glycol are put into heating kettle in advance and heated, melted to be formed and glue
Thick liquid,
The inorganic salts of formula ratio are added in S2, Xiang Suoshu thick liquid, stirring keeps inorganic salts evenly dispersed, while being added and matching
The essence microcapsule and essence just measured form preparation solution；
S3, the preparation solution is added in mold, is cooled rapidly to 25 DEG C, clothing lasting pearl is made.
Further, the polyethylene glycol is PEG 8000.
Further, the temperature of the heating is 65~75 DEG C.
Further, the inorganic salts are sodium chloride and sodium sulphate.
Further, dimethyl diallyl ammonium chloride or first are also added into before inorganic salts are added in the step S2
Base acrylyl oxy-ethyl-trimethyl salmiac.
Further, dimethyl diallyl ammonium chloride 3 is also added into before inorganic salts are added in the step S2
~5 parts by weight；Still further, the additive amount of the dimethyl diallyl ammonium chloride is 4 parts by weight.
In the experiment of early period, inventor joined the polyethylene glycol of larger proportion in the preparation process of clothing lasting pearl
8000, although prepared clothing lasting pearl have good lasting persistence, PEG 8000 it is expensive,
Higher cost can be spent when mass production, therefore in the inventive solutions, inventor is by largely touching
Using PEG 8000 as base-material main body, while a certain proportion of stearyl lactate and inorganic salts are added as auxiliary in rope
Filler obtains a kind of clothing lasting pearl, which, which is met water and can be dissolved with slow speed, disperses, therefore can make to be wrapped in wherein
Essence in laundry processes slow release, prevent that washing machine is largely discharged during washing and rinsing, it is same obtaining
In the persistent situation of lasting, production cost is greatly reduced.
Secondly, stearyl lactate is a kind of anionic emulsifier, have a negative electrical charge, and clothes fiber surface with
A large amount of negative electrical charge, therefore the attachment in washing process for essence on clothing can generate certain influence, therefore this hair
Bright selection cationic surfactant dimethyl diallyl ammonium chloride and stearyl lactate mixed processing, by electrical property
With, avoid stearyl lactate anionic property confrontation essence attachment generate influence, while electrically neutralize be formed by object
Matter will not generate apparent influence to the dissolubility of lasting pearl, and essence is adhered to efficiently avoid stearyl lactate
Influence, so that essence is adhered more efficiently on clothes fiber, lasting is more longlasting；Furthermore it is inorganic used in the present invention
Salt be sodium chloride and sodium sulphate, it is extremely cheap as the matrix filler material of lasting pearl, it is soluble easily in water, with stearoyl lactylates
Calcium is compounded in certain proportion, can be adjusted the dispersing and dissolving speed of lasting pearl in water, be prevented in product use process
Lead to pollution clothes since dispersing and dissolving is bad, significantly reduces production cost.
Compared with prior art, the invention has the following advantages:
(1) for clothing lasting pearl of the present invention when with articles for washing mixing, washing clothing, essence therein can be with certain
Speed slow release makes to wash clothing uniformly by perfume (or spice), prevents essence that washing machine is largely discharged during washing and rinsing, make perfume (or spice)
Essence is more effectively attached on clothing for a long time, and lasting is more longlasting.
(2) clothing lasting pearl of the present invention during the preparation process, reduces the dosage of PEG 8000, and pass through addition valence
The cheap stearyl lactate of lattice and inorganic salts are compounded as matrix auxiliary filler with it, and the use effect of essence is improved
Rate reduces essence dosage while reducing lasting pearl matrix cost under the premise of obtaining same lasting degree, from multiple
Aspect is started with, and production cost is greatly reduced, and is suitble to industrialized production.
(3) clothing lasting pearl of the present invention during the preparation process, by cationic surfactant dimethyl diallyl chlorination
Ammonium or MethacryloyloxyethylTrimethyl Trimethyl Ammonium Chloride and stearyl lactate mixed processing, efficiently avoid stearoyl lactylates
The influence that calcium adheres to essence is attached to essence more effectively on clothing for a long time, and lasting is more longlasting.
Specific embodiment
The following describes the present invention further through the description of specific embodiments, but it is to limit of the invention that this, which is not,
System, those skilled in the art's basic thought according to the present invention can make various modifications or improvements, but without departing from this
The basic thought of invention, is all within the scope of the present invention.
It is conventional commercial commodity that raw material is prepared used in the present invention, such as essence microcapsule is purchased from fragrant kindness fragrance (China)
Co., Ltd, 802180 Sunshine Popscent of model.
The efficient clothing lasting pearl of embodiment 1, present invention low cost
The efficient clothing lasting pearl of 1 low cost of the embodiment of the present invention is made of the raw material for preparing of following weight: polyethylene glycol
800050kg, stearyl lactate 26kg, sodium chloride 7kg, sodium sulphate 13kg, essence microcapsule 1kg and essence 3kg.
The preparation method of the efficient clothing lasting pearl of 1 low cost of the embodiment of the present invention, comprising the following steps:
S1, the stearyl lactate of formula ratio and PEG 8000 are put into heating kettle in advance and heated, heating temperature
Degree is 70 DEG C, and thawing forms thick liquid；
Sodium chloride and sodium sulphate are added in S2, Xiang Suoshu thick liquid, stirring keeps sodium chloride and sodium sulphate evenly dispersed, together
When be added formula ratio essence microcapsule and essence, formed preparation solution；
S3, the preparation solution is added in mold, is cooled rapidly to 25 DEG C, clothing lasting pearl is made.
The efficient clothing lasting pearl of embodiment 2, present invention low cost
The efficient clothing lasting pearl of 2 low cost of the embodiment of the present invention is made of the raw material for preparing of following weight: polyethylene glycol
800055.3kg, stearyl lactate 30kg, sodium chloride 7kg, sodium sulphate 5kg, essence microcapsule 0.7kg and essence 2kg.
The preparation method of the efficient clothing lasting pearl of 2 low cost of the embodiment of the present invention, comprising the following steps:
S1, the stearyl lactate of formula ratio and PEG 8000 will be put into heating kettle in advance and is heated, heated
Temperature is 70 DEG C, and thawing forms thick liquid,
Sodium chloride and sodium sulphate are added in S2, Xiang Suoshu thick liquid, stirring keeps sodium chloride and sodium sulphate evenly dispersed, together
When be added formula ratio essence microcapsule and essence, formed preparation solution；
S3, the preparation solution is added in mold, is cooled rapidly to 25 DEG C, clothing lasting pearl is made.
The efficient clothing lasting pearl of embodiment 3, present invention low cost
The efficient clothing lasting pearl of 3 low cost of the embodiment of the present invention is made of the raw material for preparing of following weight: polyethylene glycol
800060kg, stearyl lactate 27kg, sodium chloride 7kg, sodium sulphate 3kg, essence microcapsule 1kg and essence 2kg.
The preparation method of the efficient clothing lasting pearl of 3 low cost of the embodiment of the present invention, comprising the following steps:
S1, the stearyl lactate of formula ratio and PEG 8000 are put into heating kettle in advance and heated, heating temperature
Degree is 70 DEG C, and thawing forms thick liquid,
Sodium chloride and sodium sulphate are added in S2, Xiang Suoshu thick liquid, stirring keeps sodium chloride and sodium sulphate evenly dispersed, together
When be added formula ratio essence microcapsule and essence, formed preparation solution；
S3, the preparation solution is added in mold, is cooled rapidly to 25 DEG C, clothing lasting pearl is made.
The efficient clothing lasting pearl of embodiment 4, present invention low cost
The efficient clothing lasting pearl of 4 low cost of the embodiment of the present invention is made of the raw material for preparing of following weight: polyethylene glycol
800052.3kg, stearyl lactate 30kg, dimethyl diallyl ammonium chloride 3kg, sodium chloride 7kg, sodium sulphate 5kg, essence
Microcapsules 0.7kg and essence 2kg.
The preparation method of the efficient clothing lasting pearl of 4 low cost of the embodiment of the present invention, comprising the following steps:
S1, the stearyl lactate of formula ratio and PEG 8000 are put into heating kettle in advance and heated, heating temperature
Degree is 70 DEG C, and thawing forms thick liquid,
S2, according to formula ratio, dimethyl diallyl ammonium chloride is added in Xiang Suoshu thick liquid, sodium chloride is then added
And sodium sulphate, stirring keeps sodium chloride and sodium sulphate evenly dispersed, while essence microcapsule and essence is added, and forms preparation solution；
S3, the preparation solution is added in mold, is cooled rapidly to 25 DEG C, clothing lasting pearl is made.
The efficient clothing lasting pearl of embodiment 5, present invention low cost
The efficient clothing lasting pearl of 5 low cost of the embodiment of the present invention is made of the raw material for preparing of following weight: polyethylene glycol
800051.3kg, stearyl lactate 30kg, dimethyl diallyl ammonium chloride 4kg, sodium chloride 7kg, sodium sulphate 5kg, essence
Microcapsules 0.7kg and essence 2kg.
The preparation method of the efficient clothing lasting pearl of 5 low cost of the embodiment of the present invention, comprising the following steps:
S1, the stearyl lactate of formula ratio and PEG 8000 are put into heating kettle in advance and heated, heating temperature
Degree is 70 DEG C, and thawing forms thick liquid,
S2, according to formula ratio, dimethyl diallyl ammonium chloride is added in Xiang Suoshu thick liquid, sodium chloride is then added
And sodium sulphate, stirring keeps sodium chloride and sodium sulphate evenly dispersed, while essence microcapsule and essence is added, and forms preparation solution；
S3, the preparation solution is added in mold, is cooled rapidly to 25 DEG C, clothing lasting pearl is made.
The efficient clothing lasting pearl of embodiment 6, present invention low cost
The efficient clothing lasting pearl of 6 low cost of the embodiment of the present invention is made of the raw material for preparing of following weight: polyethylene glycol
800051.3kg, stearyl lactate 30kg, MethacryloyloxyethylTrimethyl Trimethyl Ammonium Chloride 4kg, sodium chloride 7kg, sodium sulphate
5kg, essence microcapsule 0.7kg and essence 2kg.
The preparation method of the efficient clothing lasting pearl of 6 low cost of the embodiment of the present invention, comprising the following steps:
S1, the stearyl lactate of formula ratio and PEG 8000 are put into heating kettle in advance and heated, heating temperature
Degree is 70 DEG C, and thawing forms thick liquid,
S2, according to formula ratio, MethacryloyloxyethylTrimethyl Trimethyl Ammonium Chloride is added in Xiang Suoshu thick liquid, then plus
Enter sodium chloride and sodium sulphate, stirring keeps sodium chloride and sodium sulphate evenly dispersed, while essence microcapsule and essence is added, and forms system
Standby liquid；
S3, the preparation solution is added in mold, is cooled rapidly to 25 DEG C, clothing lasting pearl is made.
Comparative example 1
Compared with Example 2, the difference of this comparative example is only that: the additive amount of essence is 10kg, stearyl lactate
Additive amount is 22kg.
Comparative example 2
Compared with Example 2, the difference of this comparative example is only that: the additive amount of PEG 8000 is 65.3kg, stearic
The additive amount of acyl calcium lactate is 20kg.
Comparative example 3
Compared with Example 2, the difference of this comparative example is only that: the additive amount of stearyl lactate is 37kg, sodium chloride
Additive amount 3kg, the additive amount of sodium sulphate is 2kg.
Comparative example 4
Compared with Example 2, the difference of this comparative example is only that: the additive amount of stearyl lactate is 20kg, sodium chloride
Additive amount 12kg, the additive amount of sodium sulphate is 10kg.
Comparative example 5
Compared with Example 5, the difference of this comparative example is only that: the additive amount of polyethylene glycol is 47.3kg, dimethyl two
The additive amount of allyl ammonium chloride is 8kg.
Comparative example 6
Compared with Example 5, the difference of this comparative example is only that: replacing dimethyl using dodecyl trimethyl ammonium chloride
Diallyl ammonium chloride.
Test example one, laundry lasting pearl solution rate test
Clothing lasting pearl prepared by Example 1~6, comparative example 1~4 and comparative example 6, diameter 1cm, use are identical respectively
The water that volume and temperature are 10 DEG C is dissolved, and is placed naturally, while being pressed stopwatch and being started timing, and the dissolution feelings of lasting pearl are observed
Condition presses stopwatch when lasting pearl is completely dissolved and stops timing, the dissolution time of lasting pearl recorded respectively, when the washing of washing machine
Between generally 40min.
1 clothing lasting pearl of table is completely dissolved the time
(1) as shown in Table 1, the embodiment of the present invention 1~6 prepare clothing lasting pearl be completely dissolved the time be suitable for, with laundry
The time that machine washing washs clothing is almost the same, makes to be wrapped in essence therein and achievees the effect that slow release；
(2) compared with Example 2, comparative example 1 increases the additive amount of essence, reduces the addition of stearyl lactate
Amount, the clothing lasting pearl of preparation are completely dissolved time shortening；Comparative example 2 increases the additive amount of PEG 8000, reduces
The additive amount of stearyl lactate, the clothing lasting pearl of preparation are completely dissolved time shortening, illustrate PEG 8000 of the present invention
Be suitable for dispersing lasting pearl with certain solution rate in water with stearyl lactate compound proportion, allow be wrapped in it is therein
Essence slow release；
(3) compared with Example 2, comparative example 3 increases the additive amount of stearyl lactate, reduces the addition of inorganic salts
Amount, the clothing lasting pearl of preparation are completely dissolved the time and greatly increase, this is because matrix filling of the inorganic salts as lasting pearl
Material, the dispersing and dissolving speed of adjustable lasting pearl in water, very few can slow down of the additive amount of inorganic salts stay to a certain extent
The dispersing and dissolving speed of fragrant pearl in water；Comparative example 4 reduces the additive amount of stearyl lactate, increases the addition of inorganic salts
Amount, the clothing lasting pearl of preparation are completely dissolved the time and are obviously shortened.Therefore, the present invention selects inorganic salts as the base of lasting pearl
Body filler material, compounds with stearyl lactate, and ratio is suitable for making the certain solution rate dispersion in water of lasting pearl, it can
Make to be wrapped in essence slow release therein, can also prevent dispersing and dissolving speed in lasting pearl use process from causing to pollute clothing slowly excessively
Object；
(4) compared with Example 5, comparative example 6 replaces dimethyl diallyl chlorine using dodecyl trimethyl ammonium chloride
Changing ammonium, the clothing lasting pearl of preparation is completely dissolved the time and obviously increases, and dispersing and dissolving speed may result in pollution clothes slowly excessively,
Illustrate the present invention select specific dimethyl diallyl ammonium chloride cationic surfactant be it is suitable, will not be to lasting pearl
Dissolubility generate apparent influence.
Test example two, laundry lasting pearl lasting persistence test
Same clothes is respectively put into same washing machine to and is added the water of same volume, is then respectively adding through reality
Apply clothing lasting pearl prepared by example 1~6 and comparative example 1~6, wash after the identical time equal ambient and under the conditions of dry,
Then clothes is respectively placed under identical environment (staying in the seal box there are two aperture, temperature is 25 DEG C) and is placed, to its fragrance
Persistence is assessed.Test result is as shown in table 2 below.
The lasting persistence test result of 2 clothing lasting pearl of table
| Project | Lasting situation |
| Embodiment 1 | Substantially without fragrance after 63 days |
| Embodiment 2 | Substantially without fragrance after 66 days |
| Embodiment 3 | Substantially without fragrance after 64 days |
| Embodiment 4 | Substantially without fragrance after 74 days |
| Embodiment 5 | Substantially without fragrance after 78 days |
| Embodiment 6 | Substantially without fragrance after 70 days |
| Comparative example 1 | Substantially without fragrance after 63 days |
| Comparative example 2 | Substantially without fragrance after 64 days |
| Comparative example 3 | Substantially without fragrance after 55 days |
| Comparative example 4 | Substantially without fragrance after 40 days |
| Comparative example 5 | Substantially without fragrance after 60 days |
| Comparative example 6 | Substantially without fragrance after 61 days |
(1) as can be seen from the results, the lasting persistence of the clothing of the laundry lasting pearl washing prepared using Examples 1 to 3 is very
It is good, wherein the lasting persistence with embodiment 2 is best；
(2) compared with Example 2, embodiment 4~6 is added to dimethyl diallyl ammonium chloride or methacryloxypropyl second
The lasting persistence of base trimethyl ammonium chloride, the clothing of the laundry lasting pearl washing of preparation significantly improves；Compared with Example 5,
Embodiment 6 selects cationic surface MethacryloyloxyethylTrimethyl Trimethyl Ammonium Chloride, the laundry lasting pearl lasting persistence of preparation
It decreases, illustrates dimethyl diallyl ammonium chloride of the present invention and stearyl lactate mixed processing, efficiently avoid hard
The influence that acyl calcium lactate adheres to essence is attached to essence more effectively on clothing for a long time, and lasting is more longlasting；
(3) compared with Example 2, the additive amount of essence is 10kg in comparative example 1, and the additive amount of stearyl lactate is
The additive amount of 22kg, essence increase and the additive amount of stearyl lactate is reduced, the clothing of the clothing lasting pearl washing of preparation
Substantially without fragrance after placing 63 days；The additive amount of PEG 8000 is 65.3kg in comparative example 2, and stearyl lactate adds
Dosage is 20kg, and the additive amount of PEG 8000 increases and the additive amount of stearyl lactate is reduced, and the clothing of preparation stays
The clothing of fragrant pearl washing does not have fragrance after placing 64 days substantially, it follows that clothing prepared by comparative example 1 and comparative example 2 stays
The lasting persistence effect of the clothing of clothing lasting pearl washing prepared by the lasting persistence and embodiment 2 of the clothing of fragrant pearl washing
It remains basically stable, thus illustrates in the case where keeping much the same lasting degree, the usage amount of PEG 8000 and essence of the present invention drops
It is low, reduce production cost；
(4) compared with Example 2, the additive amount of 3 stearyl lactate of comparative example be 37kg, the additive amount 3kg of sodium chloride,
The additive amount of sodium sulphate is 2kg, and the additive amount of stearyl lactate increases, and the additive amount of inorganic salts is reduced, and the clothing of preparation stays
The clothing of fragrant pearl washing does not have fragrance after placing 55 days substantially；The additive amount of 4 stearyl lactate of comparative example is 20kg, chlorination
The additive amount 12kg of sodium, the additive amount of sodium sulphate are 10kg, and the additive amount of stearyl lactate is reduced, and the additive amount of inorganic salts increases
Add, the clothing of the clothing lasting pearl washing of preparation does not have fragrance after placing 40 days substantially, illustrates inorganic salts of the present invention and hard
Acyl calcium lactate compounding, ratio are suitable for that the clothing lasting pearl lasting persistence of preparation is good；
(5) compared with Example 5, the additive amount of 5 polyethylene glycol of comparative example is 47.3kg, dimethyl diallyl ammonium chloride
Additive amount be 8kg, preparation clothing lasting pearl washing clothing place 60 days after substantially without fragrance；Comparative example 6 uses ten
Dialkyl group trimethyl ammonium chloride replaces dimethyl diallyl ammonium chloride, and the clothing of the clothing lasting pearl washing of preparation is placed 61 days
There is no fragrance substantially afterwards, illustrates that this specific cationic surfactant selection of dimethyl diallyl ammonium chloride of the present invention is closed
It is suitable, and additive amount is suitable for, the clothing lasting pearl lasting persistence of preparation is good.
The above-described embodiments merely illustrate the principles and effects of the present invention, and is not intended to limit the present invention.It is any ripe
The personage for knowing this technology all without departing from the spirit and scope of the present invention, carries out modifications and changes to above-described embodiment.Cause
This, institute is complete without departing from the spirit and technical ideas disclosed in the present invention by those of ordinary skill in the art such as
At all equivalent modifications or change, should be covered by the claims of the present invention.
Claims (10)
1. a kind of efficient clothing lasting pearl of low cost, which is characterized in that prepare raw material including following parts by weight: poly- second two
50~60 parts of alcohol, 25~35 parts of stearyl lactate, 10~20 parts of inorganic salts, 0.3~1 part of essence microcapsule and essence 1~3
Part.
2. the efficient clothing lasting pearl of low cost as described in claim 1, which is characterized in that the preparation including following parts by weight
Raw material: 51~56 parts of polyethylene glycol, 30 parts of stearyl lactate, 12 parts of inorganic salts, 0.7 part of essence microcapsule and 2 parts of essence.
3. the efficient clothing lasting pearl of low cost as claimed in claim 1 or 2, which is characterized in that the polyethylene glycol is poly- second
Glycol 8000.
4. the efficient clothing lasting pearl of low cost as claimed in claim 1 or 2, which is characterized in that the inorganic salts are sodium chloride
And sodium sulphate.
5. the efficient clothing lasting pearl of low cost as claimed in claim 1 or 2, which is characterized in that further include two allyl of dimethyl
3~5 parts by weight of ammonium chloride or MethacryloyloxyethylTrimethyl Trimethyl Ammonium Chloride.
6. the efficient clothing lasting pearl of low cost as claimed in claim 5, which is characterized in that further include dimethyl diallyl chlorine
Change 4 parts by weight of ammonium.
7. a kind of preparation method of the efficient clothing lasting pearl of low cost as claimed in claim 1 or 2, which is characterized in that including
Following steps:
S1, the stearyl lactate of formula ratio and polyethylene glycol are put into heating kettle in advance and heated, thawing forms viscous fluid
Body；
The inorganic salts of formula ratio are added in S2, Xiang Suoshu thick liquid, stirring keeps inorganic salts evenly dispersed, formula ratio is then added
Essence microcapsule and essence, formed preparation solution；
S3, the preparation solution is added in mold, is cooled rapidly to 25 DEG C, clothing lasting pearl is made.
8. the preparation method of the efficient clothing lasting pearl of low cost as claimed in claim 7, which is characterized in that the temperature of the heating
Degree is 65~75 DEG C.
9. the preparation method of the efficient clothing lasting pearl of low cost as claimed in claim 7, which is characterized in that in the step S2
Dimethyl diallyl ammonium chloride or MethacryloyloxyethylTrimethyl Trimethyl Ammonium Chloride are also added into before inorganic salts are added.
10. the preparation method of the efficient clothing lasting pearl of low cost as claimed in claim 9, which is characterized in that the dimethyl
The additive amount of diallyl ammonium chloride or MethacryloyloxyethylTrimethyl Trimethyl Ammonium Chloride is 3~5 parts by weight.
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| CN109652215B CN109652215B (en) | 2020-08-14 |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN111518637A (en) * | 2020-03-18 | 2020-08-11 | 威莱(广州)日用品有限公司 | Strong-effect sterilization long-acting bacteriostatic washing fragrance retaining bead and preparation method thereof |
| CN112522040A (en) * | 2020-12-14 | 2021-03-19 | 广州立白企业集团有限公司 | Clothing aroma-enhancing bead composition and preparation method thereof |
| CN116726544A (en) * | 2023-06-29 | 2023-09-12 | 馨博格(广州)香精科技有限公司 | Fragrance retaining agent and preparation method and application thereof |
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| CN103205328A (en) * | 2013-03-04 | 2013-07-17 | 广州立白企业集团有限公司 | Cloth fragrant granule and preparation method thereof |
| CN104902960A (en) * | 2012-07-26 | 2015-09-09 | 索莱有限责任公司 | Emulsifying agent for use in personal care products and industrial products |
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2018
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Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104902960A (en) * | 2012-07-26 | 2015-09-09 | 索莱有限责任公司 | Emulsifying agent for use in personal care products and industrial products |
| CN103205328A (en) * | 2013-03-04 | 2013-07-17 | 广州立白企业集团有限公司 | Cloth fragrant granule and preparation method thereof |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111518637A (en) * | 2020-03-18 | 2020-08-11 | 威莱(广州)日用品有限公司 | Strong-effect sterilization long-acting bacteriostatic washing fragrance retaining bead and preparation method thereof |
| CN111518637B (en) * | 2020-03-18 | 2021-07-20 | 威莱(广州)日用品有限公司 | Strong-effect sterilization long-acting bacteriostatic washing fragrance retaining bead and preparation method thereof |
| CN112522040A (en) * | 2020-12-14 | 2021-03-19 | 广州立白企业集团有限公司 | Clothing aroma-enhancing bead composition and preparation method thereof |
| CN112522040B (en) * | 2020-12-14 | 2022-02-08 | 广州立白企业集团有限公司 | Clothing aroma-enhancing bead composition and preparation method thereof |
| CN116726544A (en) * | 2023-06-29 | 2023-09-12 | 馨博格(广州)香精科技有限公司 | Fragrance retaining agent and preparation method and application thereof |
| CN116726544B (en) * | 2023-06-29 | 2024-05-28 | 青岛春田食品科技有限公司 | Fragrance retaining agent and preparation method and application thereof |
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| CN109652215B (en) | 2020-08-14 |
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