CN109638639A - A kind of semiconductor laser chip and preparation method thereof - Google Patents

A kind of semiconductor laser chip and preparation method thereof Download PDF

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Publication number
CN109638639A
CN109638639A CN201811538852.0A CN201811538852A CN109638639A CN 109638639 A CN109638639 A CN 109638639A CN 201811538852 A CN201811538852 A CN 201811538852A CN 109638639 A CN109638639 A CN 109638639A
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China
Prior art keywords
epitaxial structure
semiconductor laser
solar battery
twin polishing
polishing substrate
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CN201811538852.0A
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Chinese (zh)
Inventor
颜建
蒋培
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SUZHOU MATRIX OPTICAL Co Ltd
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SUZHOU MATRIX OPTICAL Co Ltd
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Priority to CN201811538852.0A priority Critical patent/CN109638639A/en
Publication of CN109638639A publication Critical patent/CN109638639A/en
Withdrawn legal-status Critical Current

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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01SDEVICES USING THE PROCESS OF LIGHT AMPLIFICATION BY STIMULATED EMISSION OF RADIATION [LASER] TO AMPLIFY OR GENERATE LIGHT; DEVICES USING STIMULATED EMISSION OF ELECTROMAGNETIC RADIATION IN WAVE RANGES OTHER THAN OPTICAL
    • H01S5/00Semiconductor lasers
    • H01S5/04Processes or apparatus for excitation, e.g. pumping, e.g. by electron beams
    • H01S5/042Electrical excitation ; Circuits therefor
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01SDEVICES USING THE PROCESS OF LIGHT AMPLIFICATION BY STIMULATED EMISSION OF RADIATION [LASER] TO AMPLIFY OR GENERATE LIGHT; DEVICES USING STIMULATED EMISSION OF ELECTROMAGNETIC RADIATION IN WAVE RANGES OTHER THAN OPTICAL
    • H01S5/00Semiconductor lasers
    • H01S5/04Processes or apparatus for excitation, e.g. pumping, e.g. by electron beams
    • H01S5/042Electrical excitation ; Circuits therefor
    • H01S5/0421Electrical excitation ; Circuits therefor characterised by the semiconducting contacting layers
    • H01S5/0422Electrical excitation ; Circuits therefor characterised by the semiconducting contacting layers with n- and p-contacts on the same side of the active layer
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01SDEVICES USING THE PROCESS OF LIGHT AMPLIFICATION BY STIMULATED EMISSION OF RADIATION [LASER] TO AMPLIFY OR GENERATE LIGHT; DEVICES USING STIMULATED EMISSION OF ELECTROMAGNETIC RADIATION IN WAVE RANGES OTHER THAN OPTICAL
    • H01S5/00Semiconductor lasers
    • H01S5/30Structure or shape of the active region; Materials used for the active region
    • H01S5/32Structure or shape of the active region; Materials used for the active region comprising PN junctions, e.g. hetero- or double- heterostructures
    • H01S5/323Structure or shape of the active region; Materials used for the active region comprising PN junctions, e.g. hetero- or double- heterostructures in AIIIBV compounds, e.g. AlGaAs-laser, InP-based laser

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  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Electromagnetism (AREA)
  • Optics & Photonics (AREA)
  • Photovoltaic Devices (AREA)

Abstract

The present invention relates to technical field of semiconductors, and in particular to a kind of semiconductor laser chip and preparation method thereof, wherein semiconductor laser chip includes: twin polishing substrate, laser epitaxial structure and solar battery epitaxial structure;Laser epitaxial structure is set to the front of twin polishing substrate;Solar battery epitaxial structure is set to the back side of twin polishing substrate;Metal heat sink is set to side of the laser epitaxial structure far from twin polishing substrate, connect with the electrode of laser epitaxial structure;The p side electrode of solar battery epitaxial structure is connect by gold thread with metal heat sink, and twin polishing substrate is the GaAs or InP of n-type doping, and with a thickness of 300-400 μm, and its doping concentration is greater than 1E19cm3.Semiconductor laser epitaxial structure and solar battery epitaxial structure are grown respectively in the front and back sides of twin polishing substrate, it is electrically connected with gold thread and heat sink realization, enable semiconductor laser chip by the solar cell for supplying power in self structure, improves the integrated level of device.

Description

A kind of semiconductor laser chip and preparation method thereof
Technical field
The present invention relates to technical field of semiconductors, and in particular to a kind of semiconductor laser chip and preparation method thereof.
Background technique
It is the group-III element of such as Al, Ga or In and the chemical combination of V group element N due to its band structure and chemical stability The nitride-based semiconductor of object is promising semiconductor material for light-emitting component and power component etc..Therefore, it has attempted to The various applications of nitride-based semiconductor, one of these applications are used as the light of the optical information recording device of such as CD drive The nitride semiconductor laser device in source.In recent years, due to the use of GaN substrate, the progress of crystal technique, well set The component structure of meter, improved wafer processing techniques and other factors, nitride semiconductor Laser device has been realized in can It is reduced by property and cost, and has produced the market as commercial product.
Phase due to the short oscillation wavelength of nitride-based semiconductor, for nitride-based semiconductor as fluorescent material excitation light source Hope to be also very high.The typical case of fluorescent material excitation light source is the white light LEDs using nitride-based semiconductor.In recent years, The superpower laser made by nitride system semiconductor is needing directionality and high-power next-generation oriented lamp (directionallight) and the use in television set etc. also results in the attention of people.In such applications, semiconductor swashs Light device needs additional external power supply to power, and is unfavorable for the integrated of discrete device in this way.
Summary of the invention
Therefore, the technical problem to be solved in the present invention is that overcoming chip of laser need of work in the prior art additional External power supply power supply, leads to the lower defect of device integration degree, to provide a kind of semiconductor laser chip and its system Make method.
Above-mentioned technical purpose of the invention has the technical scheme that
According in a first aspect, the embodiment of the invention provides a kind of semiconductor laser chips, comprising:
Twin polishing substrate;
Laser epitaxial structure is set to the front of the twin polishing substrate;
Solar battery epitaxial structure is set to the back side of the twin polishing substrate;
Metal heat sink is set to side of the laser epitaxial structure far from the twin polishing substrate, swashs with described The electrode of light device epitaxial structure connects;
The p side electrode of gold thread, the solar battery epitaxial structure is connect by gold thread with the metal heat sink;
Wherein, the twin polishing substrate is the GaAs or InP of n-type doping, and with a thickness of 300 μm to 400 μm, and it is adulterated Concentration is greater than 1E19cm3
Optionally, the lattice constant and twin polishing of solar battery epitaxial structure and the epitaxial layer of laser epitaxial structure The lattice constant of substrate is consistent.
Optionally, when twin polishing substrate is GaAs substrate, laser epitaxial structure is the semiconductor of AlGaAs structure Laser.
Optionally, solar battery epitaxial structure is the multi-junction solar electricity of the sub- battery of GaAs and the sub- battery composition of GaInP Pond.
Optionally, ridge waveguide area is formed on laser epitaxial structure surface.
Optionally, antireflective coating is formed on solar battery epitaxial structure upper layer.
Optionally, semiconductor laser chip is consistent with the size of solar battery epitaxial structure.
According to second aspect, the embodiment of the invention provides a kind of production methods of semiconductor laser chip, including such as Lower step:
Choose twin polishing substrate;
Generate laser epitaxial structure and solar battery epitaxial structure, wherein laser epitaxial structure is set to double The front of face polishing substrate;Solar battery epitaxial structure is set to the back side of twin polishing substrate;
Metal heat sink is set, and metal heat sink is set to side of the laser epitaxial structure far from twin polishing substrate, and swashs The electrode of light device epitaxial structure connects;
Gold thread is set, and the p side electrode of solar battery epitaxial structure is connect by gold thread with metal heat sink.
Technical solution of the present invention has the advantages that
1, the present invention implement provide semiconductor laser chip, comprising: twin polishing substrate, laser epitaxial structure with And solar battery epitaxial structure;Wherein, laser epitaxial structure is set to the front of twin polishing substrate;Outside solar battery Prolong structure setting in the back side of twin polishing substrate;Metal heat sink is set to laser epitaxial structure far from twin polishing substrate Side, connect with the electrode of laser epitaxial structure;The p side electrode of solar battery epitaxial structure passes through gold thread and metal fever Heavy connection.Semiconductor laser epitaxial structure and solar battery epitaxy junction are grown respectively in the front and back sides of twin polishing substrate Structure is electrically connected with gold thread and heat sink realization device, enables semiconductor laser chip by the solar-electricity in self structure Pond power supply, improves the integrated level of device.
2, the present invention implements semiconductor laser chip provided and preparation method thereof, and twin polishing substrate is n-type doping GaAs or InP, with a thickness of 300 μm to 400 μm.Using n-type doping GaAs or InP the twin polishing substrate with a thickness of 350 μm, Substrate thickness is controlled, on the one hand reduces resistance, on the other hand reduces the semiconductor laser chip for being integrated with solar battery Volume.
3, the present invention implements semiconductor laser chip provided and preparation method thereof, the doping concentration of twin polishing substrate Greater than 1E19cm3, the conductivity of substrate can be improved by carrying out n-type doping to semiconductor substrate, therefore the n-type doping of high concentration is two-sided Polishing substrate has good conductive property.
4, the present invention implements semiconductor laser chip provided and preparation method thereof, 30 He of solar battery epitaxial structure The lattice constant of the epitaxial layer of laser epitaxial structure 20 is consistent with the lattice constant of twin polishing substrate 10, use and high concentration GaAs the or InP consistent epitaxial layer of twin polishing substrate lattice constant of n-type doping come formed solar battery epitaxial structure and Laser epitaxial structure, reducing lattice mismatch bring influences, and improves the reliable of the semiconductor laser chip in the present embodiment Property.
5, the present invention implements semiconductor laser chip provided and preparation method thereof, and solar battery epitaxial structure is The multijunction solar cell of the sub- battery of GaAs and the sub- battery composition of GaInP.The sub- battery of growth GaAs and GaInP on gaas substrates The multijunction solar cell of sub- battery composition compares unijunction solar cell, possesses higher photoelectric conversion efficiency.
6, the present invention implements semiconductor laser chip provided and preparation method thereof, on solar battery epitaxial structure Layer forms antireflective coating.Increase light transmission capacity by the way that antireflective coating is arranged in solar cell surface, reduces the reflection damage of light It loses.
7, the present invention implements semiconductor laser chip provided and preparation method thereof, semiconductor laser chip and the sun The size of energy battery epitaxial structure is consistent.The size of chip of laser is consistent with solar battery chip size, is guaranteed most Laser scribing and sliver operation will not damage solar battery chip afterwards.
Detailed description of the invention
It, below will be to specific in order to illustrate more clearly of the specific embodiment of the invention or technical solution in the prior art Embodiment or attached drawing needed to be used in the description of the prior art be briefly described, it should be apparent that, it is described below Attached drawing is some embodiments of the present invention, for those of ordinary skill in the art, before not making the creative labor It puts, is also possible to obtain other drawings based on these drawings.
Fig. 1 is a kind of structural schematic diagram of semiconductor laser chip in the embodiment of the present invention;
Fig. 2 is a kind of production method flow chart of semiconductor laser chip in the embodiment of the present invention;
Fig. 3 is a structural representation during the production method of semiconductor laser chip a kind of in the embodiment of the present invention Figure;
Fig. 4 shows for another structure during the production method of semiconductor laser chip a kind of in the embodiment of the present invention It is intended to;
Fig. 5 shows for another structure during the production method of semiconductor laser chip a kind of in the embodiment of the present invention It is intended to.
Description of symbols:
10, twin polishing substrate;20, laser epitaxial structure;21, electrode;22, ridge waveguide area;30, solar battery Epitaxial structure;31, p side electrode;32, antireflective coating;40, metal heat sink;50, gold thread;60, adhesive;70, support substrate.
Specific embodiment
In order to make the objectives, technical solutions, and advantages of the present invention clearer, with reference to the accompanying drawings and embodiments, right The present invention is further elaborated.It should be appreciated that the specific embodiments described herein are merely illustrative of the present invention, and It is not used in the restriction present invention.
As shown in Figure 1, the embodiment of the invention provides a kind of semiconductor laser chips, comprising: twin polishing substrate 10, Laser epitaxial structure 20 and solar battery epitaxial structure 30;Wherein, laser epitaxial structure 20 is set to twin polishing The front of substrate 10;Solar battery epitaxial structure 30 is set to the back side of twin polishing substrate 10;Metal heat sink 40, is set to Side of the laser epitaxial structure 20 far from twin polishing substrate 10 is connect with the electrode 21 of laser epitaxial structure 20;The sun The p side electrode 31 of energy battery epitaxial structure 30 is connect by gold thread 50 with metal heat sink 40.
In the present embodiment, using the substrate of twin polishing, half is generated in the obverse and reverse of twin polishing substrate respectively Conductor laser epitaxial structure and solar battery epitaxial structure;The electrode side of semiconductor laser is arranged in metal heat sink, And it is electrically connected with the formation of the electrode of semiconductor laser;Gold thread connects the p side electrode and metal heat sink of solar battery, makes the sun It can battery and semiconductor laser forming circuit.In a particular embodiment, the p side electrode of solar battery is anode, semiconductor The electrode of laser is also anode, and the two is connect by gold thread with metal heat sink;And solar battery and semiconductor laser lean on Nearly twin polishing one side of substrate is all cathode, and the two realizes electrical connection by twin polishing substrate.According to provided in this embodiment Semiconductor laser chip grows semiconductor laser epitaxial structure and solar-electricity in the front and back sides of twin polishing substrate respectively Pond epitaxial structure is electrically connected with gold thread and heat sink realization device, enables semiconductor laser chip by self structure Solar cell for supplying power improves the integrated level of device.
As optional embodiment, twin polishing substrate 10 is the GaAs or InP of n-type doping, extremely with a thickness of 300 μm 400μm。
In the present embodiment, using n-type doping GaAs or InP the twin polishing substrate with a thickness of 350 μm, it is thick to control substrate On the one hand degree reduces resistance, on the other hand reduces the volume for being integrated with the semiconductor laser chip of solar battery.
As optional embodiment, the doping concentration of twin polishing substrate 10 is greater than 1E19cm3
In the present embodiment, the conductivity of substrate, therefore the N of high concentration can be improved by carrying out n-type doping to semiconductor substrate Type doping twin polishing substrate has good conductive property.
As optional embodiment, the crystalline substance of the epitaxial layer of solar battery epitaxial structure 30 and laser epitaxial structure 20 Lattice constant is consistent with the lattice constant of twin polishing substrate 10.
In the present embodiment, using consistent with GaAs the or InP twin polishing substrate lattice constant of high concentration n-type doping Epitaxial layer forms solar battery epitaxial structure and laser epitaxial structure, and reducing lattice mismatch bring influences, improve this The reliability of semiconductor laser chip in embodiment.
As optional embodiment, when twin polishing substrate 10 is GaAs substrate, laser epitaxial structure 20 is The semiconductor laser of AlGaAs structure.
In the present embodiment, the laser structure that epitaxial growth active layer is AlGaAs on gaas substrates.
As optional embodiment, solar battery epitaxial structure 30 is the sub- battery of GaAs and the sub- battery composition of GaInP Multijunction solar cell.
In the present embodiment, the multi-junction solar of GaAs battery and the sub- battery composition of GaInP is grown on gaas substrates Battery compares unijunction solar cell, possesses higher photoelectric conversion efficiency.
As optional embodiment, ridge waveguide area 22 is formed on 20 surface of laser epitaxial structure.
In the present embodiment, ridge waveguide area 22 is formed in laser epitaxial structure 20, is controlled by the shape of waveguide The effective refractive index of waveguide processed, so that light field to be limited in the central location of active area.
As optional embodiment, antireflective coating 32 is formed on 30 upper layer of solar battery epitaxial structure.
In the present embodiment, antireflective coating is set to increase light transmission capacity in solar cell surface, reduces the reflection of light Loss.
As optional embodiment, semiconductor laser chip is consistent with the size of solar battery epitaxial structure 30.
In the present embodiment, the size of chip of laser is consistent with solar battery chip size, is guaranteed last sharp The scribing of light device and sliver operation will not damage solar battery chip.
As shown in Fig. 2, the embodiment of the invention also provides a kind of production methods of semiconductor laser, comprising:
Step S1 chooses twin polishing substrate 10.
In the present embodiment, GaAs the or InP twin polishing substrate of N-type high-concentration dopant is chosen, with a thickness of 350 μm.
Step S2 generates laser epitaxial structure 20 and solar battery epitaxial structure 30.Wherein, laser epitaxial knot Structure 20 is set to the front of twin polishing substrate 10;Solar battery epitaxial structure 30 is set to the back of twin polishing substrate 10 Face.
In the present embodiment, as shown in figure 3, first growing laser epitaxial structure 20 in the front of twin polishing substrate 10, Then in the back side growth for solar battery structure 30 of substrate.It further include step S21 after the completion of growth, as shown in figure 4, swashing 20 surface spin coating a layer of adhesive 60 of light device epitaxial structure, take with the duplicate support substrate 70 of epitaxial growth substrate size, 70 surface of support substrate and 20 surface bonding of laser epitaxial structure.Wherein, adhesive 60 can select wax, and support substrate 70 can Be selected as silicon wafer, the adhesive 60 is compatible with Subsequent semiconductor planar technology, will not the solution used in technique dissolve.
Step S22 forms electrode using conventional solar battery process to the solar battery epitaxial structure 20 at the back side 31.It is specific as follows: to use photolithography method, spin coating photoresist, exposure and imaging obtains gate electrode figure;It is steamed using electron beam Hair evaporated metal layer of equipment, 2 μm of thickness or so;The functional layer that metal has been deposited is immersed in acetone soln, light is removed The metal on photoresist and photoresist surface, without the region of photoresist overlay, metal is retained.
Step S23 forms antireflective coating 32 using solar battery process.Specifically, using photolithography method, spin coating photoetching Glue, exposure and imaging protect electrode metal part with photoresist, with etchant solution by the contact of battery functi on layer surface Layer (GaAs) erodes, then deposited by electron beam evaporation equipment, TiO2 and SiO2 is successively deposited as antireflective coating, then will be deposited The functional layer of reflectance coating is impregnated in acetone, and the antireflective coating on photoresist and photoresist surface is removed, obtain it is as shown in Figure 4 too Positive energy battery structure.
Step S24 is dissolved adhesive using the solution that can remove adhesive 40, is made outside support substrate 5 and laser Prolong layer surface separation.Solution can select toluene.
Step S25, in the surface spin coating adhesive 40 for completing solar battery process, by support substrate 50 and solar-electricity Pool surface bonding, shields, as shown in Figure 5 in technical process.
Step S26 forms ridged in the laser epitaxial structure 20 of substrate face using chip of laser manufacture craft Waveguide section 22.Specifically, using photolithography method, spin coating photoresist, exposure and imaging, by rib region, that is, electrode zone photoetching Glue protects, with the contact layer and part limiting layer of etchant solution corrosion rib region two sides;SiO2 layers are deposited using PECVD 23, the general 100nm-200nm of thickness mainly play insulating effect;It is opened a window later using the method for photoetching, the face P metal electrode is deposited 21, obtain laser structure as shown in Figure 5.
Step S24 is repeated, adhesive 4 and support substrate 5 are removed.
Metal heat sink is arranged in step S3.It is heat sink to be set to side of the laser epitaxial structure far from twin polishing substrate, with The electrode of laser epitaxial structure connects.
In the present embodiment, it as shown in Figure 1, being arranged heat sink in facet surface, is connect with the p side electrode of laser.
Gold thread is arranged in step S4.The p side electrode of solar battery epitaxial structure is connect by gold thread with metal heat sink.
Semiconductor laser chip production method provided by the embodiment, by being given birth to respectively in the front and back sides of twin polishing substrate Long semiconductor laser epitaxial structure and solar battery epitaxial structure are electrically connected with gold thread and heat sink realization device, make partly to lead Body laser chip can improve the integrated level of device by the solar cell for supplying power in self structure.
Obviously, the above embodiments are merely examples for clarifying the description, and does not limit the embodiments.It is right For those of ordinary skill in the art, can also make on the basis of the above description it is other it is various forms of variation or It changes.There is no necessity and possibility to exhaust all the enbodiments.And it is extended from this it is obvious variation or It changes still within the protection scope of the invention.

Claims (8)

1. a kind of semiconductor laser chip characterized by comprising
Twin polishing substrate (10);
Laser epitaxial structure (20) is set to the front of the twin polishing substrate (10);
Solar battery epitaxial structure (30) is set to the back side of the twin polishing substrate (10);
Metal heat sink (40) is set to the side of the laser epitaxial structure (20) far from the twin polishing substrate (10), It is connect with the electrode (21) of the laser epitaxial structure (20);
The p side electrode (31) of gold thread (50), the solar battery epitaxial structure (30) passes through gold thread (50) and the metal fever Heavy (40) connection;
Wherein, the twin polishing substrate (10) is the GaAs or InP of n-type doping, and with a thickness of 300 μm to 400 μm, and it is adulterated Concentration is greater than 1E19cm3
2. a kind of semiconductor laser chip according to claim 1, which is characterized in that the solar battery epitaxy junction The lattice of the lattice constant of structure (30) and the epitaxial layer of the laser epitaxial structure (20) and the twin polishing substrate (10) Constant is consistent.
3. a kind of semiconductor laser chip according to claim 1, which is characterized in that in the twin polishing substrate (10) be GaAs substrate when, the laser epitaxial structure (20) be AlGaAs structure semiconductor laser.
4. a kind of semiconductor laser chip according to claim 1, which is characterized in that the solar battery epitaxy junction Structure (30) is the multijunction solar cell of the sub- battery of GaAs and the sub- battery composition of GaInP.
5. a kind of semiconductor laser chip according to claim 1, which is characterized in that in the laser epitaxial structure (20) surface forms ridge waveguide area (22).
6. a kind of semiconductor laser chip according to claim 1, which is characterized in that in the solar battery extension Structure (30) upper layer forms antireflective coating (32).
7. according to claim 1 to any semiconductor laser chip in 6, which is characterized in that the semiconductor laser Device chip is consistent with the size of the solar battery epitaxial structure (30).
8. a kind of production method of semiconductor laser chip, which comprises the steps of:
It chooses twin polishing substrate (10);
Generate laser epitaxial structure (20) and solar battery epitaxial structure (30);Wherein, the laser epitaxial structure (20), it is set to the front of the twin polishing substrate (10);The solar battery epitaxial structure (20) is set to described double Face polishes the back side of substrate (10);
It is arranged metal heat sink (40);The metal heat sink (40) is set to the laser epitaxial structure (20) far from described two-sided The side for polishing substrate (10), connect with the electrode (21) of the laser epitaxial structure (20);
It is arranged gold thread (50);The p side electrode (31) of the solar battery epitaxial structure (30) passes through the gold thread (50) and institute State metal heat sink (40) connection.
CN201811538852.0A 2018-12-14 2018-12-14 A kind of semiconductor laser chip and preparation method thereof Withdrawn CN109638639A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110190504A (en) * 2019-05-24 2019-08-30 宁波东立创芯光电科技有限公司 Semiconductor laser array encapsulating structure

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CN107749561A (en) * 2017-11-27 2018-03-02 苏州矩阵光电有限公司 A kind of capsulation structure for semiconductor laser and preparation method thereof
CN108512035A (en) * 2018-04-09 2018-09-07 苏州矩阵光电有限公司 A kind of semiconductor laser chip and preparation method thereof
CN208272357U (en) * 2018-04-09 2018-12-21 苏州矩阵光电有限公司 A kind of semiconductor laser chip

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Publication number Priority date Publication date Assignee Title
CN1529902A (en) * 2001-05-09 2004-09-15 ������������Үά�桤�м����� Semiconductor device and method of making same
CN101009347A (en) * 2006-01-27 2007-08-01 中国科学院物理研究所 Non polarity A side nitride film growing on the silicon(102) substrate and its making method and use
CN206194791U (en) * 2016-08-23 2017-05-24 苏州矩阵光电有限公司 Hall element
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Publication number Priority date Publication date Assignee Title
CN110190504A (en) * 2019-05-24 2019-08-30 宁波东立创芯光电科技有限公司 Semiconductor laser array encapsulating structure

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