CN109629060A - A kind of blended looping composite yarn of the wear-resisting antistatic of high-strength fire-retarding anti-dropping and preparation method thereof - Google Patents

A kind of blended looping composite yarn of the wear-resisting antistatic of high-strength fire-retarding anti-dropping and preparation method thereof Download PDF

Info

Publication number
CN109629060A
CN109629060A CN201910022858.0A CN201910022858A CN109629060A CN 109629060 A CN109629060 A CN 109629060A CN 201910022858 A CN201910022858 A CN 201910022858A CN 109629060 A CN109629060 A CN 109629060A
Authority
CN
China
Prior art keywords
fire
long filament
drafting
retardant
preparation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201910022858.0A
Other languages
Chinese (zh)
Other versions
CN109629060B (en
Inventor
冯新星
张华�
梁高勇
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Institute of Quartermaster Engineering Technology Institute of Systems Engineering Academy of Military Sciences
Original Assignee
Institute of Quartermaster Engineering Technology Institute of Systems Engineering Academy of Military Sciences
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Institute of Quartermaster Engineering Technology Institute of Systems Engineering Academy of Military Sciences filed Critical Institute of Quartermaster Engineering Technology Institute of Systems Engineering Academy of Military Sciences
Priority to CN201910022858.0A priority Critical patent/CN109629060B/en
Publication of CN109629060A publication Critical patent/CN109629060A/en
Application granted granted Critical
Publication of CN109629060B publication Critical patent/CN109629060B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • DTEXTILES; PAPER
    • D02YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02GCRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/02Yarns or threads characterised by the material or by the materials from which they are made
    • D02G3/04Blended or other yarns or threads containing components made from different materials
    • D02G3/045Blended or other yarns or threads containing components made from different materials all components being made from artificial or synthetic material
    • DTEXTILES; PAPER
    • D02YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02GCRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/22Yarns or threads characterised by constructional features, e.g. blending, filament/fibre
    • D02G3/36Cored or coated yarns or threads
    • DTEXTILES; PAPER
    • D02YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02GCRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/44Yarns or threads characterised by the purpose for which they are designed
    • D02G3/441Yarns or threads with antistatic, conductive or radiation-shielding properties
    • DTEXTILES; PAPER
    • D02YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02GCRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/44Yarns or threads characterised by the purpose for which they are designed
    • D02G3/442Cut or abrasion resistant yarns or threads
    • DTEXTILES; PAPER
    • D02YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02GCRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/44Yarns or threads characterised by the purpose for which they are designed
    • D02G3/443Heat-resistant, fireproof or flame-retardant yarns or threads
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M10/00Physical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. ultrasonic, corona discharge, irradiation, electric currents, or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements
    • D06M10/02Physical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. ultrasonic, corona discharge, irradiation, electric currents, or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements ultrasonic or sonic; Corona discharge
    • D06M10/025Corona discharge or low temperature plasma
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16Synthetic fibres, other than mineral fibres
    • D06M2101/30Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/34Polyamides
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2201/00Cellulose-based fibres, e.g. vegetable fibres
    • D10B2201/20Cellulose-derived artificial fibres
    • D10B2201/22Cellulose-derived artificial fibres made from cellulose solutions
    • D10B2201/24Viscose
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2331/00Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D10B2331/02Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamides
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2331/00Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D10B2331/02Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamides
    • D10B2331/021Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamides aromatic polyamides, e.g. aramides
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2401/00Physical properties
    • D10B2401/06Load-responsive characteristics
    • D10B2401/063Load-responsive characteristics high strength

Abstract

The invention discloses a kind of blended looping composite yarns of the wear-resisting antistatic of high-strength fire-retarding anti-dropping and preparation method thereof.The preparation method successively obtains rove through combing, drafting and rove after including the following steps: aramid fiber, flame retardant viscose fiber and antistatic fibre mixing;By the rove, using non-flame resistant Tynex as core, fire-retardant nylon long filament is wound in outer layer, spins spun yarn, then through winder to get arriving the blended looping composite yarn.Present invention ingredient based on aramid fiber, flame retardant viscose fiber, fire-retardant nylon long filament, high-strength non-flame resistant Tynex, conductive fiber, pass through blended spinning, weaving process, prepare the fabric of flame-retardant and anti-dripping, the fabric has many advantages, such as that fire-retardant, anti-dropping, intensity height, easy dyeing, antistatic, wear-resisting, at low cost, process is simple, yarn qualities are excellent, it can be not only used for the demand in terms of special operations, moreover it is possible to meet the needs of other overalls etc..

Description

A kind of blended looping composite yarn of the wear-resisting antistatic of high-strength fire-retarding anti-dropping and its preparation Method
Technical field
The present invention relates to a kind of blended looping composite yarns of the wear-resisting antistatic of high-strength fire-retarding anti-dropping and preparation method thereof, belong to In field of textiles.
Background technique
In flame-resistant garment, material of main part usually mostly uses aramid fiber, and aramid fiber is the very mature height of current technique Performance fibers, its chemical name is poly (being commonly called as aramid fiber 1313) and poly(p-phenylene terephthalamide) (being commonly called as Fanglun l414), both fibers all have good heat-resisting quantity and anti-flammability, but the glass transition temperature of aramid fiber Height, dyeing is difficult, and water imbibition is also poor, therefore kevlar fabric is difficult to possess the color of higher quality, it is difficult to which camouflage printing meets Bu Liao army camouflage painting demand;Electrostatic problem, cannot be in gunpowder processing factory, inflammable powder processing factory etc. to anti-also than more prominent The demanding occasion of static behaviour uses.
Aramid fiber is generally also mostly used in operation fabric, the amount ratio of aramid fiber accounts in U.S. army's earlier generations operation fabric 50% or more, due to aramid fiber dyeing difficulty, causes that the camouflage printing of entire operation fabric is difficult, intensity is low, comfort is poor etc. and ask Topic.The fire-retardant operation fabric of U.S. army's latest generation uses Fanglun l414/anti-flaming viscose/high-strength nylon66 fiber (25:65;10) three kinds of fibers It is blended to form, its advantage is that fire-retardant, anti-dropping, camouflage printing are relatively good, wearability is appropriate, comfortable;But it still remains durable The problems such as property is poor, intensity is low and price is high, and 25% Fanglun l414 fiber makes fabric that must use a part of pigment printing, causes Feel difference problem still remains.How in retention property, the content of high-performance fiber is further decreased, and then improve face Comfort, camouflage printing of material etc. are always research puzzle.
Summary of the invention
The object of the present invention is to provide a kind of blended looping composite yarn of wear-resisting antistatic of high-strength fire-retarding anti-dropping and its systems Preparation Method, the fire-retardant nylon long filament that the present invention uses need to carry out anti-molten drop processing, since the core of the blended looping covering yarn is adopted With high-strength non-flame resistant Tynex, the high-strength performance of yarn ensure that;And outer layer uses the Tynex packet of fire-retardant anti-molten droplet It twines, the wearability of entire yarn is also improved while further increasing the strength of yarn.The blended looping composite yarn of the present invention Have many advantages, such as that fire-retardant, anti-dropping, intensity height, easy dyeing, antistatic, wear-resisting, at low cost, process is simple, yarn qualities are excellent, Demand in terms of especially suitable for special operations, moreover it is possible to meet the needs of other overalls etc..
The preparation method of the blended looping composite yarn of the wear-resisting antistatic of high-strength fire-retarding anti-dropping provided by the present invention, packet Include following steps:
Rove successively is obtained through combing, drafting and rove after aramid fiber, flame retardant viscose fiber and antistatic fibre mixing;
By the rove, using non-flame resistant Tynex as core, fire-retardant nylon long filament is wound in outer layer, is spun thin Yarn, then through winder to get arrive the blended looping composite yarn.
In above-mentioned preparation method, the mass percent of each raw material is as follows:
Aramid fiber 15~17%, fire-retardant nylon long filament 20~25%, non-flame resistant Tynex 8~10%, antistatic fibre Tie up 2~3%, flame retardant viscose fiber 45~55%;It is concretely following any:
1) aramid fiber 15~16.5%, fire-retardant nylon long filament 20~22%, non-flame resistant Tynex 8~9%, antistatic Fiber 2~2.5%, flame retardant viscose fiber 45~50%;
2) aramid fiber 16.5~17%, fire-retardant nylon long filament 22~25%, non-flame resistant Tynex 9~10%, resist it is quiet Electric fiber 2.5~3%, flame retardant viscose fiber 50~55%;
3) aramid fiber 16%, fire-retardant nylon long filament 25%, non-flame resistant Tynex 8%, antistatic fibre 3%, fire-retardant Viscose rayon 48%;
4) aramid fiber 15%, fire-retardant nylon long filament 20%, non-flame resistant Tynex 8%, antistatic fibre 2%, fire-retardant Viscose rayon 55%;
5) aramid fiber 16.5%, fire-retardant nylon long filament 22%, non-flame resistant Tynex 9%, antistatic fibre 2.5%, Flame retardant viscose fiber 50%;
6) aramid fiber 17%, fire-retardant nylon long filament 25%, non-flame resistant Tynex 10%, antistatic fibre 3%, fire-retardant Viscose rayon 45%.
In above-mentioned preparation method, the aramid fiber is the mixing fibre of Fanglun l414 or aramid fiber 1313 and Fanglun l414 Dimension;
In the composite fibre, the mass content of the Fanglun l414 is not less than 60%.
In above-mentioned preparation method, the conventional viscose rayon with flame retardant property of the flame retardant viscose fiber selection is It can.
In above-mentioned preparation method, the antistatic fibre can be electrically conductive organic fibre.
In above-mentioned preparation method, the fire-retardant nylon long filament is fire-retardant Nylon 66 long filament or fire-retardant Nylon 6 long filament;
The intensity of the fire-retardant nylon long filament is 3.5~5cN/dtex;
Phosphorus content is 4000~6000ppm in the fire-retardant nylon long filament;
The non-flame resistant Tynex is 6 long filament of non-flame resistant nylon66 fiber long filament or non-flame resistant nylon;
The intensity of the non-flame resistant Tynex is 7~8cN/dtex.
In above-mentioned preparation method, the fire-retardant nylon long filament is by the anti-molten drop processing of electron beam irradiation;
The anti-molten drop processing of electron beam irradiation includes the following steps:
The fire-retardant nylon long filament is padded in the ethanol solution of the compound containing at least trifunctional, electronics is carried out Beam irradiation, then through being combed into item;
The compound containing at least trifunctional can be glycerine, pentaerythrite, triethanolamine, trihydroxy methyl third It is any in alkane, dipropylene glycol, xylitol and sorbierite;
The treatment temperature padded is 55~90 DEG C;
Band liquid measure through the fire-retardant nylon long filament that pads that treated is 50%~200%;
The electron beam irradiation carries out graft crosslinking reaction, and the dosage of the electron beam irradiation is 100~400kGy.
In above-mentioned preparation method, the condition of the combing is as follows:
Sliver exporting speed is 550~650m/min, 5~7g/m of shaping weight;
The drafting includes the drafting successively carried out, secondary drafting and drafting three times;
The condition of the drafting is as follows:
Sliver exporting speed is 200~250m/min, and shaping weight is 5~7g/m.
In above-mentioned preparation method, the condition of the rove is as follows:
Drafting multiple control in Distribution Area is 1.15~1.2, and the control of first break draft multiple is 1.2-1.3, primary area drafting multiple control 6~7 are made as, total draft multiple is 8~9, the rove that the spinning twist is 60~70t/m.
In above-mentioned preparation method, the condition of the spun yarn is as follows:
Drafting multiple control in Distribution Area is 1.2~1.3, and the control of first break draft multiple is 1.5~1.6, primary area drafting multiple control 10~12 are made as, total draft multiple is 20~25, and the spun yarn that the spinning twist is 80~90t/m, spun spun yarn yarn count is 26/2 ~32/2S.
Composite yarn prepared by the present invention obtains that high-strength fire-retarding is anti-to melt drop antistatic fabric through weaving;" high-strength " refers to be Fabric intensity with higher of the present invention especially meets fire-retardant, anti-dropping, easy dyeing, antistatic, wear-resisting property at the same time There is high intensity simultaneously.
The present invention is with aramid fiber, flame retardant viscose fiber, fire-retardant nylon long filament, high-strength non-flame resistant Tynex, conductive fibre Ingredient based on dimension prepares the fabric of flame-retardant and anti-dripping by blended spinning, weaving process, which has fire-retardant, anti-molten Drop, intensity height, easy dyeing, the advantages that antistatic, wear-resisting, at low cost, process is simple, yarn qualities are excellent, can be not only used for Demand in terms of special operations, moreover it is possible to meet the needs of other overalls etc..
Specific embodiment
Experimental method used in following embodiments is conventional method unless otherwise specified.
The materials, reagents and the like used in the following examples is commercially available unless otherwise specified.
Percentage composition in following embodiments refers to mass percentage.
The preparation of embodiment 1, high-strength fire-retarding anti-dropping antistatic fabric 1
1) by aramid fiber 15% (wherein Fanglun l414 fiber accounts for 60%), flame retardant viscose fiber (Austrian Lenzin company The FR fiber of offer) 55% and electrically conductive organic fibre (Japanese Zhong Fang company provide conductive fiber) 2% be uniformly mixed, will mix Uniform fiber combed, drafting, secondary drafting, three times drafting, rove, for use;Wherein, sliver exporting speed when combing is 550m/min, shaping weight are 7g/m;The sliver exporting speed of drafting is 250m/min, and shaping weight is 5g/m.
2) anti-molten drop processing: fire-retardant nylon long filament is padded in glycerin solution, and the treatment temperature of padding liquid is 90 DEG C, The band liquid measure for the fire resistance fibre that pads that treated is 50%;Carry out the reaction of electron beam irradiation graft crosslinking, electron beam irradiation dosage For 100kGy, wash clean is finally combed into item, spare.
3) second step spins spun yarn: the rove that will have been weaved, with strength be 7cN/dtex, weight is 8% high-strength non-flame resistant Buddhist nun Imperial 6 long filaments are core;It is 4000ppm, intensity 5cN/dtex, the fire-retardant anti-molten droplet nylon66 fiber long filament that weight is 20% with phosphorus content It is wound in outer layer, spins the spun yarn of needs, then through winding procedure, obtain blended cored wrap yarn.Wherein, fly frame is whole The control of area's drafting multiple is managed 1.15, the control of first break draft multiple is 1.3, and drafting multiple control in primary area is 7, total draft multiple 9, Spin the rove that the twist is 70t/m;Drafting multiple control in spinning frame Distribution Area is 1.2, and the control of first break draft multiple is 1.6, primary area Drafting multiple control is 12, and total draft multiple 25, the spun yarn that the spinning twist is 90t/m, last spun spun yarn yarn count is 32/ 2S, then woven fabric obtains fabric 1.
The preparation of embodiment 2, high-strength fire-retarding anti-dropping antistatic fabric 2
1) by aramid fiber 17% (wherein Fanglun l414 proportion of fibers is 80%), flame retardant viscose fiber (Austrian Lenzin The FR fiber that company provides) 45% and electrically conductive organic fibre (Japanese Zhong Fang company provide conductive fiber) 3% be uniformly mixed, into Row combing, drafting, secondary drafting, three times drafting, rove, for use;Wherein, sliver exporting speed when combing is 650m/min, shaping Weight is 5g/m;The sliver exporting speed of drafting is 200m/min, and shaping weight is 7g/m.
2) anti-molten drop processing: fire-retardant nylon long filament is padded in pentaerythrite solution, the treatment temperature of padding liquid is 55 DEG C, the band liquid measure for the fire resistance fibre that pads that treated is 200%;Carry out the reaction of electron beam irradiation graft crosslinking, electron beam irradiation Dosage is 400kGy, and wash clean is finally combed into item, spare.
3) second step spins spun yarn: the rove that will have been weaved, with strength be 8cN/dtex, weight is 10% high-strength non-flame resistant Buddhist nun Imperial 66 long filaments are core;It is 6000PPM, intensity 3.5cN/dtex with phosphorus content, the fire-retardant anti-molten droplet nylon 6 that weight is 25% is long Silk is wound in outer layer, spins the spun yarn of needs, then through winding procedure, obtain blended cored wrap yarn.Wherein, fly frame 1.2, the control of first break draft multiple is the control of Distribution Area drafting multiple in 6, total draft multiple in 1.2, the control of primary area drafting multiple 8, the rove that the spinning twist is 60t/m;The control of spinning frame Distribution Area drafting multiple 1.3, lead 1.5 by the control of first break draft multiple For the control of area's drafting multiple 10, total draft multiple 20, the spinning twist is the spun yarn of 80t/m, and finally spun spun yarn yarn count is 28/2S, then woven fabric obtains fabric 2.
The preparation of embodiment 3, high-strength fire-retarding anti-dropping antistatic fabric 3
1) by aramid fiber 16.5% (wherein Fanglun l414 fiber is 100%), flame retardant viscose fiber (Austrian Lenzin public affairs The FR fiber provided is provided) 50% and electrically conductive organic fibre (Japanese Zhong Fang company provide conductive fiber) 2.5% be uniformly mixed, into Row combing, drafting, secondary drafting, three times drafting, rove, for use;Wherein, sliver exporting speed when combing is 600m/min, shaping Weight 6g/m;The sliver exporting speed of drafting is 230m/min, and shaping weight is 6g/m.
2) anti-molten drop processing: fire-retardant nylon long filament is padded in dipropyleneglycol solution, the treatment temperature of padding liquid It is 70 DEG C, the band liquid measure for the fire resistance fibre that pads that treated is 100%;Carry out the reaction of electron beam irradiation graft crosslinking, electron beam Irradiation dose is 300kGy, and wash clean is finally combed into item, spare.
3) second step spins spun yarn: the rove that will have been weaved, with strength be 7.5cN/dtex, weight is 9% high-strength non-flame resistant 6 long filament of nylon is core;It is 4500PPM, intensity 4cN/dtex with phosphorus content, the fire-retardant anti-molten droplet nylon 6 that weight is 22% is long Silk is wound in outer layer, spins the spun yarn of needs, then through winding procedure, obtain blended cored wrap yarn.Wherein, fly frame Drafting multiple control in Distribution Area is 1.17, and the control of first break draft multiple is 1.25, and drafting multiple control in primary area is 6.5, and total draft is again Number is 8.5, the rove that the spinning twist is 65t/m;1.25, the control of first break draft multiple exists the control of spinning frame Distribution Area drafting multiple 1.55, drafting multiple control in primary area is 11, and total draft multiple 22, the spinning twist is the spun yarn of 85t/m, finally spun spun yarn Yarn count is 30/2S, and then woven fabric obtains fabric 3.
The preparation of embodiment 4, high-strength fire-retarding anti-dropping antistatic fabric 4
1) by aramid fiber 16% (wherein Fanglun l414 fiber is 90%), flame retardant viscose fiber (Austrian Lenzin company The FR fiber of offer) 48% and electrically conductive organic fibre (Japanese Zhong Fang company provide conductive fiber) 3% be uniformly mixed, combed Item, drafting, secondary drafting, three times drafting, rove, for use;Wherein, sliver exporting speed when combing is 600m/min, shaping weight For 6g/m;The sliver exporting speed of drafting is 230m/min, and shaping weight is 6g/m.
2) anti-molten drop processing: fire-retardant nylon long filament is padded in trimethylolpropane solution, the treatment temperature of padding liquid It is 80 DEG C, the band liquid measure for the fire resistance fibre that pads that treated is 150%;Carry out the reaction of electron beam irradiation graft crosslinking, electron beam Irradiation dose is 400kGy, and wash clean is finally combed into item, spare.
3) second step spins spun yarn: the rove that will have been weaved, with strength be 7.5cN/dtex, weight is 8% high-strength non-flame resistant Nylon66 fiber long filament is core;It is 5500PPM, intensity 4cN/dtex, the fire-retardant anti-molten droplet nylon66 fiber that weight is 25% with phosphorus content Long filament is wound in outer layer, spins the spun yarn of needs, then through winding procedure, obtain blended cored wrap yarn.Wherein, rove Drafting multiple control in machine Distribution Area is 1.17, and the control of first break draft multiple is 1.25, and drafting multiple control in primary area is 6.5, total draft Multiple is 8.5, the rove that the spinning twist is 65t/m;1.25, first break draft multiple controls the control of spinning frame Distribution Area drafting multiple 1.55, drafting multiple control in primary area spins the spun yarn that the twist is 85t/m in 11, total draft multiple 22, last spun thin Yarn yarn count is 26/2S, and then woven fabric obtains fabric 4.
The performance indicator of the looping composite yarn of 1-4 of embodiment of the present invention preparation is as shown in table 1.
Yarn strength prepared by the present invention is high it can be seen from the data in table 1, and uniformity is good, and filoplume is few, resultant yarn It is high-quality.
The performance indicator of 1 cored fasciated yarn of table
The performance indicator of the fabric of 1-4 of embodiment of the present invention preparation is as shown in table 2.
It can be seen from the data in table 2 char length of fabric in 81mm hereinafter, glow after flame time 1 second with Under, there is extraordinary flame retardant property;And the state after burning is direct carbonization, it was demonstrated that has extraordinary anti-dropping; The intensity of fabric is through to 1510N is greater than, broadwise is greater than 1030N or more, and trapezoidal tear is all larger than 120 or more, shows very high Intensity;For dyefastness at 4 grades or more, dyeing effect is all very good;Fabric surface density of charge is respectively less than 2 μ C/ ㎡, shows non- Often good antistatic property, the number of resistance to plain grinding are greater than 4250 times or more, have extraordinary wear-resisting property.To sum up, system of the present invention Standby fabric has the excellent properties such as fire-retardant, anti-dropping, intensity height, easy dyeing, wear-resisting, antistatic.
The test of 2 fabric performance of table

Claims (10)

1. a kind of preparation method of the blended looping composite yarn of the wear-resisting antistatic of high-strength fire-retarding anti-dropping, includes the following steps:
Rove successively is obtained through combing, drafting and rove after aramid fiber, flame retardant viscose fiber and antistatic fibre mixing;
By the rove, using non-flame resistant Tynex as core, fire-retardant nylon long filament is wound in outer layer, spins spun yarn, then Through winder to get arrive the blended looping composite yarn.
2. preparation method according to claim 1, it is characterised in that: the mass percent of each raw material is as follows:
Aramid fiber 15~17%, fire-retardant nylon long filament 20~25%, non-flame resistant Tynex 8~10%, antistatic fibre 2~ 3%, flame retardant viscose fiber 45~55%.
3. preparation method according to claim 1 or 2, it is characterised in that: the aramid fiber is Fanglun l414 or aramid fiber 1313 with the composite fibre of Fanglun l414;
In the composite fibre, the mass content of the Fanglun l414 is not less than 60%.
4. preparation method according to any one of claim 1-3, it is characterised in that: the fire-retardant nylon long filament is fire-retardant Nylon66 fiber long filament or fire-retardant Nylon 6 long filament;
The intensity of the fire-retardant nylon long filament is 3.5~5cN/dtex;
Phosphorus content is 4000~6000ppm in the fire-retardant nylon long filament;
The non-flame resistant Tynex is 6 long filament of non-flame resistant nylon66 fiber long filament or non-flame resistant nylon;
The intensity of the non-flame resistant Tynex is 7~8cN/dtex.
5. preparation method described in any one of -4 according to claim 1, it is characterised in that: the fire-retardant nylon long filament is by electricity Beamlet irradiates anti-molten drop processing;
The anti-molten drop processing of electron beam irradiation includes the following steps:
The fire-retardant nylon long filament is padded in the solution of the compound containing at least trifunctional, electron beam irradiation is carried out, Then through being combed into item.
6. preparation method according to any one of claims 1-5, it is characterised in that: the condition of the combing is as follows:
Sliver exporting speed is 550~650m/min, 5~7g/m of shaping weight;
The drafting includes the drafting successively carried out, secondary drafting and drafting three times;
The condition of the drafting is as follows:
Sliver exporting speed is 200~250m/min, and shaping weight is 5~7g/m.
7. preparation method according to claim 1 to 6, it is characterised in that: the condition of the rove is as follows:
Drafting multiple control in Distribution Area is 1.15~1.2, and the control of first break draft multiple is 1.2-1.3, and drafting multiple control in primary area is 6 ~7, total draft multiple is 8~9, the rove that the spinning twist is 60~70t/m.
8. preparation method described in any one of -7 according to claim 1, it is characterised in that: the condition of the spun yarn is as follows:
Drafting multiple control in Distribution Area is 1.2~1.3, and the control of first break draft multiple is 1.5~1.6, and drafting multiple control in primary area is 10~12, total draft multiple is 20~25, and the spun yarn that the spinning twist is 80~90t/m, spun spun yarn yarn count is 26/2~32/ 2S。
9. the blended looping composite yarn of any one of claim 1-8 the method preparation.
10. a kind of high-strength fire-retarding is anti-to melt drop antistatic fabric, the spinning looping composite yarn as described in claim 9 is weaved to obtain.
CN201910022858.0A 2019-01-10 2019-01-10 High-strength flame-retardant anti-dripping wear-resistant anti-static blending wrapping core-spun yarn and preparation method thereof Active CN109629060B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201910022858.0A CN109629060B (en) 2019-01-10 2019-01-10 High-strength flame-retardant anti-dripping wear-resistant anti-static blending wrapping core-spun yarn and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201910022858.0A CN109629060B (en) 2019-01-10 2019-01-10 High-strength flame-retardant anti-dripping wear-resistant anti-static blending wrapping core-spun yarn and preparation method thereof

Publications (2)

Publication Number Publication Date
CN109629060A true CN109629060A (en) 2019-04-16
CN109629060B CN109629060B (en) 2021-01-15

Family

ID=66060453

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201910022858.0A Active CN109629060B (en) 2019-01-10 2019-01-10 High-strength flame-retardant anti-dripping wear-resistant anti-static blending wrapping core-spun yarn and preparation method thereof

Country Status (1)

Country Link
CN (1) CN109629060B (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112708980A (en) * 2020-12-31 2021-04-27 福建经纬新纤科技实业有限公司 Flame-retardant and anti-dripping medium-high density fiber
CN113040454A (en) * 2019-12-27 2021-06-29 北京赛欧兰阻燃纤维有限公司 Military uniform fabric
CN114517352A (en) * 2021-12-31 2022-05-20 浙江多元纺织科技(集团)有限公司 Method for manufacturing multi-component blended flame-retardant oil-proof camouflage fabric

Citations (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1847638A2 (en) * 2006-03-29 2007-10-24 Chapman Thermal Products, Inc. Fire retardant and heat resistant yarns and fabrics treated for increased strength and liquid shedding
CN102296408A (en) * 2011-08-09 2011-12-28 绍兴县舒丽乐纺织品有限公司 Aramid fiber 1313 flame-retardant adhesive multifunctional blended and printed camouflage fabric
CN202509191U (en) * 2012-04-23 2012-10-31 济南三江阻燃新材料有限公司 Inflaming retarding yarn
CN102965785A (en) * 2012-12-24 2013-03-13 江苏唐工纺实业有限公司 Method for manufacturing composite yarn for flame-retardant protective clothing
CN103173997A (en) * 2013-03-25 2013-06-26 中国人民解放军总后勤部军需装备研究所 Flame-retardant and anti-fusion fiber or fabric and preparation method thereof
CN104047085A (en) * 2014-07-03 2014-09-17 旌德南玻新材料有限公司 Flame-retardant and anti-static fiberglass core-spun yarn
US20150176160A1 (en) * 2011-10-24 2015-06-25 Best Key Textiles Limited Woven and knitted fabrics with improved properties and core spun yarns for producing the same
CN105506809A (en) * 2015-12-03 2016-04-20 上海曙雀贸易有限公司 Flame retardant molten-drop-resistant high-strength sewing thread
CN206396387U (en) * 2016-10-27 2017-08-11 河南工程学院 Flame-retardant and anti-static rotor spun composite
CN107415385A (en) * 2017-07-31 2017-12-01 圣华盾防护科技股份有限公司 Arc protection clothes
US20180127917A1 (en) * 2014-08-29 2018-05-10 Drifire Llc Lightweight, arc-rated, dyeable fabrics
CN108505170A (en) * 2018-06-15 2018-09-07 苏州市星京泽纤维科技有限公司 A kind of multi-vortex yarn

Patent Citations (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1847638A2 (en) * 2006-03-29 2007-10-24 Chapman Thermal Products, Inc. Fire retardant and heat resistant yarns and fabrics treated for increased strength and liquid shedding
CN102296408A (en) * 2011-08-09 2011-12-28 绍兴县舒丽乐纺织品有限公司 Aramid fiber 1313 flame-retardant adhesive multifunctional blended and printed camouflage fabric
US20150176160A1 (en) * 2011-10-24 2015-06-25 Best Key Textiles Limited Woven and knitted fabrics with improved properties and core spun yarns for producing the same
CN202509191U (en) * 2012-04-23 2012-10-31 济南三江阻燃新材料有限公司 Inflaming retarding yarn
CN102965785A (en) * 2012-12-24 2013-03-13 江苏唐工纺实业有限公司 Method for manufacturing composite yarn for flame-retardant protective clothing
CN103173997A (en) * 2013-03-25 2013-06-26 中国人民解放军总后勤部军需装备研究所 Flame-retardant and anti-fusion fiber or fabric and preparation method thereof
CN104047085A (en) * 2014-07-03 2014-09-17 旌德南玻新材料有限公司 Flame-retardant and anti-static fiberglass core-spun yarn
US20180127917A1 (en) * 2014-08-29 2018-05-10 Drifire Llc Lightweight, arc-rated, dyeable fabrics
CN105506809A (en) * 2015-12-03 2016-04-20 上海曙雀贸易有限公司 Flame retardant molten-drop-resistant high-strength sewing thread
CN206396387U (en) * 2016-10-27 2017-08-11 河南工程学院 Flame-retardant and anti-static rotor spun composite
CN107415385A (en) * 2017-07-31 2017-12-01 圣华盾防护科技股份有限公司 Arc protection clothes
CN108505170A (en) * 2018-06-15 2018-09-07 苏州市星京泽纤维科技有限公司 A kind of multi-vortex yarn

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113040454A (en) * 2019-12-27 2021-06-29 北京赛欧兰阻燃纤维有限公司 Military uniform fabric
CN112708980A (en) * 2020-12-31 2021-04-27 福建经纬新纤科技实业有限公司 Flame-retardant and anti-dripping medium-high density fiber
CN114517352A (en) * 2021-12-31 2022-05-20 浙江多元纺织科技(集团)有限公司 Method for manufacturing multi-component blended flame-retardant oil-proof camouflage fabric

Also Published As

Publication number Publication date
CN109629060B (en) 2021-01-15

Similar Documents

Publication Publication Date Title
CA1334363C (en) Corespun yarn for fire resistant safety apparel and method
CN106948052B (en) A kind of flame-proof electrostatic resistance yarn and its fabric
CN102906323B (en) Protective clothing cloth and silk and the spinning wherein used
CN109295576A (en) Flame-retardant yarn, protection fabric and its production technology
US5033262A (en) Method of forming a corespun yarn for fire resistant safety apparel
CN108117750B (en) Arc protection flame-retardant mixture and preparation method thereof
CN109629060A (en) A kind of blended looping composite yarn of the wear-resisting antistatic of high-strength fire-retarding anti-dropping and preparation method thereof
CN106283309A (en) A kind of scribbled containing polytetrafluoroethylene fibre and preparation method thereof
CN110273209B (en) High-strength flame-retardant high-temperature-resistant polyimide yarn and preparation method thereof
CN109706572A (en) A kind of flame-retardant and anti-dripping antistatic composite yarn and preparation method thereof
CN104713420A (en) Police fighting and training fabric and manufacturing method thereof
CN106400266A (en) Multi-component low-cost permanent inflaming retarding fabric and preparation method for same
CN108517599A (en) A kind of flame-retarding blended yarn of polyimides and its preparation process
CN105581409A (en) High-comfort protective garment fabric, protective garment and manufacturing method of high-comfort protective garment fabric
CN108166119A (en) The fire-retardant blend of comfort arc protection
CN107557935A (en) Film splits the preparation method of method antibacterial flame-retardant Antistatic radiation-proof fancy complex yarn
CN108611719A (en) Permanent type flame-retardant conductive yarn
JP2008007883A (en) Long and short-compounded spun yarn woven fabric
CN110616489A (en) Color-mixed spinning core-spun yarn and production device and production method thereof
CN110004552A (en) Anti-flaming viscose and the continuous synthetic fibre long filament coated yarn spinning of the blended cladding of aramid fiber and manufacturing process
CN103361870A (en) Blended fabric of Poly-1,3,4-oxadiazole and flame-retardant viscose
CN103710806A (en) Low-elasticity-segment colored filament Sirofil composite yarn and spinning technology
KR101946948B1 (en) Meta-aramid fabric with excellent shirinkge and touch and method of manufacturing the same
CN112030295A (en) Shape-retaining knitting yarn, and method and device for producing same
CN111424353A (en) Flame-retardant sewing thread and production process thereof

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant