CN109627860A - A kind of modified geopolymer interfacial agents and its in the old quick renovation method in ceramic tile wall surface - Google Patents
A kind of modified geopolymer interfacial agents and its in the old quick renovation method in ceramic tile wall surface Download PDFInfo
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- CN109627860A CN109627860A CN201811584087.6A CN201811584087A CN109627860A CN 109627860 A CN109627860 A CN 109627860A CN 201811584087 A CN201811584087 A CN 201811584087A CN 109627860 A CN109627860 A CN 109627860A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D125/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
- C09D125/02—Homopolymers or copolymers of hydrocarbons
- C09D125/04—Homopolymers or copolymers of styrene
- C09D125/08—Copolymers of styrene
- C09D125/14—Copolymers of styrene with unsaturated esters
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
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- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
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- Inorganic Chemistry (AREA)
- Finishing Walls (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention discloses a kind of modified geopolymer interfacial agents and its in the old quick renovation method of ceramic tile metope, the interfacial agents include two kinds of components of geopolymer slurries and lotion, contain group in geopolymer slurries and are divided into slag micropowder, flyash, SILICA FUME, metakaolin, fine sand, additive and water；It is divided into waterglass, lotion and mould inhibitor containing group in lotion.Two components are uniformly mixed by two-component slurries again after mixing evenly respectively, a kind of old ceramic tile metope can be obtained and quickly renovate with modified geopolymer interfacial agents, cooperate corresponding construction technology, can be used to old ceramic tile metope interface processing.Modified geopolymer interfacial agents provided by the invention, with good shear bonding strength and tensile bond strength, while there is good corrosion resistance, can have extremely strong durability under various extreme climate environments, it can be directly used for ceramic tile surface processing, be suitble to the quick renovation of old ceramic tile metope.
Description
Technical field
The present invention relates to a kind of geopolymer more particularly to a kind of modified geopolymer interfacial agents and old ceramic tile metope are quick
Renovation method.
Background technique
Interfacial agents are by handling body surface, which may be the absorption or cladding of physical action, also often
It is physicochemical effect.Effect is to improve or change completely the physical technique performance and surface chemistry of material surface.?
Building trade be usually used in concrete, air entrained concrete, one hand tile, light partition wall, brick mix metope, putty batch is scraped, tile bonding,
Masonry carries on the back base interface pretreatment of painting and heat preservation plate material etc. etc..
There is part ceramic tile surface inorganic agent on the market,.Current interfacial agents common on the market are divided into dry-type and emulsion-type
Two kinds.1, the powdery that dried powder boundary agent is made of the inorganic coagulation materials such as cement, filler, polymer glue powder and relevant additive
Object.The stirring of water mixing by a certain percentage uses when use.2, emulsion-type interfacial agents are main component by chemical high molecular material, are aided with
Other fillers are made.Emulsion-type is divided into one-component and two-component by its composition and suitable substrate again, needs when two-component product uses
Cement is added in proportion.Due to the difference of material selection and the shortcoming of relevant criterion, performance is very different.
The renewal and reform of current old ceramic tile metope is frequently with traditional mode stuck up except old wall brick, due to commonly using interfacial agents material
The performance shortcomings such as that there are adhesive properties is lower for material, resistance to ag(e)ing is poor, durability is poor；Therefore, old ceramic tile metope renovation has the duration
The disadvantages of long, at high cost, building castoff is more.
Summary of the invention
Technical problem to be solved by the invention is to provide a kind of modified geopolymer interfacial agents, have good shear bond
Intensity and tensile bond strength, while there is good corrosion resistance, can have under various extreme climate environments extremely strong
Durability can be directly used for ceramic tile surface processing, be suitble to the quick renovation of old ceramic tile metope.
The present invention to solve above-mentioned technical problem and the technical solution adopted is that provide a kind of modified geopolymer interfacial agents,
Comprising geopolymer slurries and lotion feed liquid, each component matches as follows in parts by weight:
70~80 parts by weight of geopolymer slurries；
20~30 parts by weight of lotion feed liquid.
Above-mentioned modification geopolymer interfacial agents, wherein the geopolymer slurries match as follows in parts by weight:
Above-mentioned modification geopolymer interfacial agents, wherein the slag micropowder is that the slag of 95% or more activity index is micro-
Powder；The flyash is the second class powered coal ash of 70% or more activity index；The SILICA FUME mesh number is 800~2000.
Above-mentioned modification geopolymer interfacial agents, wherein the water-reducing agent is in polycarboxylate water-reducer and naphthalene water reducer
One kind；The thickener is the mixing of one or more of cellulose ether, amylase, guar gum and polyacrylamide.
Above-mentioned modification geopolymer interfacial agents, wherein the lotion feed liquid matches as follows in parts by weight:
5~20 parts by weight of lotion；
4~30 parts by weight of waterglass；
0.01~0.1 parts by weight of mould inhibitor.
Above-mentioned modification geopolymer interfacial agents, wherein the waterglass is one of potassium water glass and sodium silicate；
The lotion is one of styrene-acrylate emulsion, pure-acrylic emulsion and styrene-butadiene emulsion；The mould inhibitor is biphenyl and zinc
One of ion mould inhibitor.
The present invention also provides a kind of old quick renovation method of ceramic tile metope to solve above-mentioned technical problem, wherein including such as
Lower step: old ceramic tile surface dust and dirt step S1: are cleaned；Step S2: the ceramic tile loosened except hollowing is stuck up, and viscous using ceramic tile
It is levelling to tie agent；Step S3: above-mentioned interfacial agents are brushed in clean old ceramic tile surface using spraying or brushing mode；Step S4:
After the molding of interfacial agents surface drying, the construction of new walling can be carried out.
The above-mentioned old quick renovation method of ceramic tile metope, wherein when being used for normal concrete interface, control 7d shear bond
Intensity is 2.0~3.5MPa, and 14d shear bonding strength is 2.5~4.0MPa；7d tensile bond strength is 1.0~2.0MPa,
14d tensile bond strength is 1.2~2.5MPa；Then immersion processing, heat treatment, Frozen-thawed cycled processing and alkali process, control are carried out
Tensile bond strength processed is 1.0~1.8MPa.
The above-mentioned old quick renovation method of ceramic tile metope, wherein when being used for smooth ceramic tile interface, control 7d shear bond is strong
Degree is 1.2~1.8MPa, and 14d shear bonding strength is 1.5~2.0MPa；7d tensile bond strength is 0.5~1.0MPa, 14d
Tensile bond strength is 0.8~1.5MPa；Then immersion processing, heat treatment, Frozen-thawed cycled processing and alkali process, control is carried out to draw
Stretching adhesion strength is 0.6~1.0MPa.
The above-mentioned old quick renovation method of ceramic tile metope, wherein the step S3 is stirred using 1000r/min high speed electric
Stirring 5min or more is bored, after stirring geopolymer slurries, adds lotion feed liquid using 500r/min-1000r/
Min electric stirring bores stirring 5min or more, uses after mixing.
The present invention compare the prior art have it is following the utility model has the advantages that modified geopolymer interfacial agents provided by the invention and old
The quick renovation method of ceramic tile metope, by being modified processing to geopolymer, there is good shear bonding strength and stretching viscous
Knotting strength, while there is good corrosion resistance, can have extremely strong durability under various extreme climate environments, it can be direct
For ceramic tile surface processing, it is suitble to the quick renovation of old ceramic tile metope.
Specific embodiment
The present invention will be further described with reference to the examples below.
Modified geopolymer interfacial agents provided by the invention, include geopolymer slurries and lotion feed liquid, and two-component is modified
Geopolymer interfacial agents each component weight ratio are as follows:
60~90 parts by weight of geopolymer slurries；
10~40 parts by weight of lotion feed liquid；
The geopolymer slurry constituents include:
The weight ratio of the lotion feed liquid component are as follows:
5~20 parts by weight of lotion；
4~30 parts by weight of waterglass
0.01~0.1 parts by weight of mould inhibitor；
In the above-mentioned recipe ingredient of the present invention, it can also be added containing rheological agent, surfactant, other thickeners, gluing
The mixing of one or more of agent.
Geopolymer is one kind by AlO4And SiO4The inorganic polymeric of tetrahedral structural unit composition 3 D stereo reticular structure
Object has excellent mechanical performance and acid and alkali-resistance, fire resisting, performance resistant to high temperature, in construction material, Materials with High Strength, solid core solid waste
Material, sealing material and heat-resisting material etc. have application.The present invention has by being modified processing to geopolymer
Good shear bonding strength and tensile bond strength, while there is good corrosion resistance, the equal energy under various extreme climate environments
Enough there is extremely strong durability.
Modification geopolymer interfacial agents of the invention can be directly used for ceramic tile surface processing, be suitble to the fast of old ceramic tile metope
Speed renovation；Construction technology includes:
Step S1: old ceramic tile surface dust and dirt are cleaned；
Step S2: it sticks up except hollowing loosens ceramic tile easy to fall off, and levelling using ceramic tile bond；
Step S3: stirring 5min or more is bored using the stirring of 1000r/min high speed electric, geopolymer component is sufficiently stirred
After uniformly, then it is uniformly mixed with lotion feed liquid；
Step S4: brushing 0.5mm left and right thickness interfacial agents in clean old ceramic tile surface using spraying or brushing mode,
Generate plucking effect；After interfacial agents surface drying, the construction of new walling can be carried out.
The present invention is described in more detail below by specific embodiment, for a better understanding of the present invention,
But following embodiments are not intended to limit the scope of the invention.
Embodiment 1
The old ceramic tile metope of the present invention is quickly renovated with modified geopolymer interfacial agents each component weight ratio are as follows:
80 parts by weight of geopolymer slurries；
20 parts by weight of lotion feed liquid；
The geopolymer feed liquid component includes:
The weight fraction ratio of the lotion feed liquid are as follows:
15 parts by weight of styrene-acrylic emulsion；
4.95 parts by weight of sodium silicate
0.05 parts by weight of mould inhibitor；
Embodiment 2
The old ceramic tile metope of the present invention is quickly renovated with modified geopolymer interfacial agents each component weight ratio are as follows:
70 parts by weight of geopolymer slurries；
30 parts by weight of lotion feed liquid；
The geopolymer feed liquid component includes:
The weight fraction ratio of the lotion feed liquid are as follows:
20 parts by weight of styrene-butadiene emulsion；
9.9 parts by weight of sodium silicate
0.1 parts by weight of mould inhibitor；
Embodiment 3
The old ceramic tile metope of the present invention is quickly renovated with modified geopolymer interfacial agents each component weight ratio are as follows:
75 parts by weight of geopolymer slurries；
25 parts by weight of lotion feed liquid；
The geopolymer feed liquid component includes:
The weight ratio of the lotion feed liquid are as follows:
15 parts by weight of pure-acrylic emulsion；
9.9 parts by weight of sodium silicate
0.1 parts by weight of mould inhibitor；
A kind of modified geopolymer interfacial agents of the above embodiment of the present invention preparation, compared with existing generic interface agent, tool
There is higher adhesion strength, better acid-alkali-corrosive-resisting can have extremely strong durable under various extreme climate environments
Property.
Referring to JC/T 907-2002 " concrete interface treating agent " test method, respectively in concrete interface and ceramic tile circle
Face is tested, and modification geopolymer interfacial agents of the invention are compared as follows with normal concrete interfacial agents physicochemical property:
Although the present invention is disclosed as above with preferred embodiment, however, it is not to limit the invention, any this field skill
Art personnel, without departing from the spirit and scope of the present invention, when can make a little modification and perfect therefore of the invention protection model
It encloses to work as and subject to the definition of the claims.
Claims (10)
1. a kind of modified geopolymer interfacial agents, which is characterized in that include geopolymer slurries and lotion feed liquid, each component is by weight
It is as follows to measure number proportion:
70~80 parts by weight of geopolymer slurries；
20~30 parts by weight of lotion feed liquid.
2. modified geopolymer interfacial agents as described in claim 1, which is characterized in that the geopolymer slurries are by weight
Number proportion is as follows:
3. modified geopolymer interfacial agents as claimed in claim 2, which is characterized in that the slag micropowder is activity index
95% or more slag micropowder；The flyash is the second class powered coal ash of 70% or more activity index；The SILICA FUME mesh number is
800~2000.
4. modified geopolymer interfacial agents as claimed in claim 2, which is characterized in that the water-reducing agent is polycarboxylate water-reducer
One of with naphthalene water reducer；The thickener be one of cellulose ether, amylase, guar gum and polyacrylamide or
Several mixing.
5. modified geopolymer interfacial agents as described in claim 1, which is characterized in that the lotion feed liquid is matched in parts by weight
Than as follows:
5~20 parts by weight of lotion；
4~30 parts by weight of waterglass；
0.01~0.1 parts by weight of mould inhibitor.
6. modified geopolymer interfacial agents as claimed in claim 5, which is characterized in that the waterglass is potassium water glass and sodium
One of waterglass；The lotion is one of styrene-acrylate emulsion, pure-acrylic emulsion and styrene-butadiene emulsion；It is described
Mould inhibitor is one of biphenyl and zinc ion mould inhibitor.
7. a kind of old quick renovation method of ceramic tile metope, which comprises the steps of:
Step S1: old ceramic tile surface dust and dirt are cleaned；
Step S2: the ceramic tile loosened except hollowing is stuck up, and levelling using ceramic tile bond；
Step S3: it is brushed in clean old ceramic tile surface such as the interface in claim 1~6 using spraying or brushing mode
Agent；
Step S4: after the molding of interfacial agents surface drying, the construction of new walling can be carried out.
8. the old quick renovation method of ceramic tile metope as claimed in claim 7, which is characterized in that be used for normal concrete interface
When, control 7d shear bonding strength is 2.0~3.5MPa, and 14d shear bonding strength is 2.5~4.0MPa；7d stretch-bonded is strong
Degree is 1.0~2.0MPa, and 14d tensile bond strength is 1.2~2.5MPa；Then immersion processing, heat treatment, Frozen-thawed cycled are carried out
Processing and alkali process, control tensile bond strength are 1.0~1.8MPa.
9. the old quick renovation method of ceramic tile metope as claimed in claim 7, which is characterized in that when being used for smooth ceramic tile interface,
Control 7d shear bonding strength is 1.2~1.8MPa, and 14d shear bonding strength is 1.5~2.0MPa；7d tensile bond strength is
0.5~1.0MPa, 14d tensile bond strength are 0.8~1.5MPa；Then immersion processing, heat treatment, Frozen-thawed cycled processing are carried out
And alkali process, control tensile bond strength are 0.6~1.0MPa.
10. the old quick renovation method of ceramic tile metope as claimed in claim 7, which is characterized in that the step S3 is used
Stirring 5min or more is bored in the stirring of 1000r/min high speed electric, after stirring geopolymer slurries, adds lotion material
Liquid bores stirring 5min or more using 500r/min-1000r/min electric stirring, uses after mixing.
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| CN201811584087.6A CN109627860B (en) | 2018-12-24 | 2018-12-24 | Modified geopolymer interface agent and method for quickly renovating surface of old ceramic tile wall by using same |
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Cited By (3)
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| CN110778041A (en) * | 2019-11-14 | 2020-02-11 | 深圳市美施美克新材料有限公司 | Coating process |
| CN111892837A (en) * | 2020-09-24 | 2020-11-06 | 谭华勇 | Mildew-proof antibacterial putty powder and preparation method and use method thereof |
| CN112094521A (en) * | 2020-09-27 | 2020-12-18 | 谭华勇 | Waterproof and moistureproof putty powder capable of eliminating foaming and leveling as well as preparation method and use method thereof |
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Cited By (3)
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|---|---|---|---|---|
| CN110778041A (en) * | 2019-11-14 | 2020-02-11 | 深圳市美施美克新材料有限公司 | Coating process |
| CN111892837A (en) * | 2020-09-24 | 2020-11-06 | 谭华勇 | Mildew-proof antibacterial putty powder and preparation method and use method thereof |
| CN112094521A (en) * | 2020-09-27 | 2020-12-18 | 谭华勇 | Waterproof and moistureproof putty powder capable of eliminating foaming and leveling as well as preparation method and use method thereof |
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| CN109627860B (en) | 2021-03-26 |
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