CN109608168A - A kind of wear-resisting high-hardness ceramic product and preparation method thereof - Google Patents
A kind of wear-resisting high-hardness ceramic product and preparation method thereof Download PDFInfo
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- 239000000919 ceramic Substances 0.000 title claims abstract description 73
- 238000002360 preparation method Methods 0.000 title claims abstract description 20
- 238000004519 manufacturing process Methods 0.000 title abstract description 12
- 239000002994 raw material Substances 0.000 claims abstract description 72
- 229910052573 porcelain Inorganic materials 0.000 claims abstract description 35
- 239000005995 Aluminium silicate Substances 0.000 claims abstract description 28
- 235000012211 aluminium silicate Nutrition 0.000 claims abstract description 28
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims abstract description 28
- DLHONNLASJQAHX-UHFFFAOYSA-N aluminum;potassium;oxygen(2-);silicon(4+) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Al+3].[Si+4].[Si+4].[Si+4].[K+] DLHONNLASJQAHX-UHFFFAOYSA-N 0.000 claims abstract description 17
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000002699 waste material Substances 0.000 claims abstract description 16
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims abstract description 15
- 229910052656 albite Inorganic materials 0.000 claims abstract description 15
- 229910052744 lithium Inorganic materials 0.000 claims abstract description 15
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 claims abstract description 15
- 239000002893 slag Substances 0.000 claims abstract description 15
- 239000004575 stone Substances 0.000 claims abstract description 15
- 229910001928 zirconium oxide Inorganic materials 0.000 claims abstract description 15
- 229910021532 Calcite Inorganic materials 0.000 claims abstract description 14
- CNLWCVNCHLKFHK-UHFFFAOYSA-N aluminum;lithium;dioxido(oxo)silane Chemical compound [Li+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O CNLWCVNCHLKFHK-UHFFFAOYSA-N 0.000 claims abstract description 14
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 claims abstract description 14
- 229910010271 silicon carbide Inorganic materials 0.000 claims abstract description 14
- 229910052642 spodumene Inorganic materials 0.000 claims abstract description 14
- 229910052581 Si3N4 Inorganic materials 0.000 claims abstract description 13
- 239000000440 bentonite Substances 0.000 claims abstract description 13
- 229910000278 bentonite Inorganic materials 0.000 claims abstract description 13
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims abstract description 13
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 claims abstract description 13
- 238000000498 ball milling Methods 0.000 claims description 40
- 235000015895 biscuits Nutrition 0.000 claims description 34
- 238000000034 method Methods 0.000 claims description 34
- 238000010304 firing Methods 0.000 claims description 33
- 239000007788 liquid Substances 0.000 claims description 28
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 26
- 239000002002 slurry Substances 0.000 claims description 22
- 238000000227 grinding Methods 0.000 claims description 21
- 238000003825 pressing Methods 0.000 claims description 11
- 238000001035 drying Methods 0.000 claims description 9
- 238000000465 moulding Methods 0.000 claims description 9
- 238000012545 processing Methods 0.000 claims description 9
- 239000003595 mist Substances 0.000 claims description 3
- 238000001125 extrusion Methods 0.000 claims description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims 1
- 239000010433 feldspar Substances 0.000 claims 1
- 229910052708 sodium Inorganic materials 0.000 claims 1
- 239000011734 sodium Substances 0.000 claims 1
- 230000006835 compression Effects 0.000 abstract description 3
- 238000007906 compression Methods 0.000 abstract description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical group O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 15
- 238000012360 testing method Methods 0.000 description 11
- 238000002156 mixing Methods 0.000 description 10
- 238000005096 rolling process Methods 0.000 description 10
- 239000012634 fragment Substances 0.000 description 6
- 238000002386 leaching Methods 0.000 description 6
- 230000015556 catabolic process Effects 0.000 description 5
- 238000005245 sintering Methods 0.000 description 5
- 238000010521 absorption reaction Methods 0.000 description 4
- 230000003111 delayed effect Effects 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 3
- 239000010453 quartz Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 208000037656 Respiratory Sounds Diseases 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 238000005336 cracking Methods 0.000 description 2
- 239000012153 distilled water Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000006424 Flood reaction Methods 0.000 description 1
- KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 1
- 229910003978 SiClx Inorganic materials 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 238000007545 Vickers hardness test Methods 0.000 description 1
- 229910010293 ceramic material Inorganic materials 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 229910052593 corundum Inorganic materials 0.000 description 1
- 239000010431 corundum Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000036314 physical performance Effects 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 238000004513 sizing Methods 0.000 description 1
- 238000012430 stability testing Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
- C04B33/132—Waste materials; Refuse; Residues
- C04B33/1324—Recycled material, e.g. tile dust, stone waste, spent refractory material
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
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- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
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- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/5022—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with vitreous materials
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- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/85—Coating or impregnation with inorganic materials
- C04B41/86—Glazes; Cold glazes
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- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3201—Alkali metal oxides or oxide-forming salts thereof
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- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3231—Refractory metal oxides, their mixed metal oxides, or oxide-forming salts thereof
- C04B2235/3244—Zirconium oxides, zirconates, hafnium oxides, hafnates, or oxide-forming salts thereof
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- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3427—Silicates other than clay, e.g. water glass
- C04B2235/3463—Alumino-silicates other than clay, e.g. mullite
- C04B2235/3472—Alkali metal alumino-silicates other than clay, e.g. spodumene, alkali feldspars such as albite or orthoclase, micas such as muscovite, zeolites such as natrolite
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- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/38—Non-oxide ceramic constituents or additives
- C04B2235/3852—Nitrides, e.g. oxynitrides, carbonitrides, oxycarbonitrides, lithium nitride, magnesium nitride
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- C04B2235/656—Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes characterised by specific heating conditions during heat treatment
- C04B2235/6567—Treatment time
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Abstract
The invention discloses a kind of wear-resisting high-hardness ceramic product and preparation method thereof, which includes green body and imposes on the glaze layer on green body；Green body includes following raw material by weight: 45~55 parts of kaolin, 5~10 parts of zirconium oxide, 12~18 parts of bentonite, 15~25 parts of waste porcelain slag, 10~15 parts of silicon nitride, 17~23 parts of potassium feldspar, 8~16 parts of albite；Glaze layer includes following raw material by weight: 25~35 parts of kaolin, 12~16 parts of talcum powder, 10~15 parts of spodumene, 6~12 parts of lithium porcelain stone, quartzy 10~15 parts, 5~10 parts of silicon carbide, 7~14 parts of calcite.In the above manner, ceramic of the present invention has high rigidity and wearability, and compression strength is high, and thermal stability is strong.
Description
Technical field
The present invention relates to ceramic technology fields, and in particular to a kind of wear-resisting high-hardness ceramic product and preparation method thereof.
Background technique
Ceramics are indispensable a kind of particular products in human lives and production, on it has in human being's production history
History in thousand！In the historical floods of human development, people make full use of the physics and chemical property of ceramic material, develop
The a variety of ceramics such as domestic ceramics, architectural pottery, sanitary ceramics, the art pottery and special cermacis.Wherein, domestic ceramics
Most ancient and common traditional ceramics in ceramic various in style, this kind of ceramic have widest practicability and
Appreciating.And existing most domestic ceramicses have that wear-resistant pressure-resistant intensity is inadequate, these ceramic ware for daily uses are usually
In use process, be inevitably squeezed, collide with, delineate or wear, wear-resistant pressure-resistant intensity be not enough then easily damaged or
Person leaves scratch, crack or notch on product, causes flaw, influence ceramic it is beautiful even with.
Summary of the invention
In order to solve the above technical problem, the present invention provides a kind of wear-resisting high-hardness ceramic products and preparation method thereof, should
Ceramic has high rigidity and wearability, and compression strength is high, and thermal stability is strong.
The technical scheme adopted by the invention is that: a kind of wear-resisting high-hardness ceramic product, the raw material including following parts by weight
Component: the green body includes following raw material by weight: 45~55 parts of kaolin, 5~10 parts of zirconium oxide, bentonite 12~18
Part, 15~25 parts of waste porcelain slag, 10~15 parts of silicon nitride, 17~23 parts of potassium feldspar, 8~16 parts of albite；
The glaze layer includes following raw material by weight: 25~35 parts of kaolin, 12~16 parts of talcum powder, spodumene 10
~15 parts, 6~12 parts of lithium porcelain stone, quartzy 10~15 parts, 5~10 parts of silicon carbide, 7~14 parts of calcite.
Preferably, the green body includes following raw material by weight: 48~52 parts of kaolin, 7~9 parts of zirconium oxide, swollen
Moisten native 14~16 parts, 17~22 parts of waste porcelain slag, 12~14 parts of silicon nitride, 19~21 parts of potassium feldspar, 10~14 parts of albite；
The glaze layer includes following raw material by weight: 27~32 parts of kaolin, 13~15 parts of talcum powder, spodumene 12
~14 parts, 8~10 parts of lithium porcelain stone, quartzy 12~14 parts, 7~9 parts of silicon carbide, 10~12 parts of calcite.
Preferably, the green body includes following raw material by weight: 50 parts of kaolin, 8 parts of zirconium oxide, bentonite 15
Part, 20 parts of waste porcelain slag, 13 parts of silicon nitride, 20 parts of potassium feldspar, 12 parts of albite；
The glaze layer includes following raw material by weight: 30 parts of kaolin, 14 parts of talcum powder, 13 parts of spodumene, lithium porcelain
9 parts of stone, quartzy 12 parts, 8 parts of silicon carbide, 10 parts of calcite.
The present invention also provides the preparation methods of more than one wear-resisting high-hardness ceramic products, comprising the following steps:
S1, each raw material is taken according to parts by weight as above, it is spare；
S2, the raw material of green body is mixed, green body slurry is then prepared using wet ball grinding；It is carried out using the green body slurry
Molding prepares green body；Repaired biscuit is carried out to the green body, it is dry；Biscuiting is carried out to green body after drying again, biscuit is made；
S3, the raw material of glaze layer is mixed, glaze liquid is then prepared using wet ball grinding；Again using the glaze liquid to the biscuit
Carry out glazing；
S4, firing processing is carried out to the green body after glazing.
Preferably, the process of green body slurry, blank raw material: ball: the weight ratio of water are prepared in step S2 using wet ball grinding
For 1:(1~3): (0.5~2) crosses 100~200 mesh screens after ball milling.It is further preferred that ball-milling medium is agate ball, ball milling
Speed is 200~250r/min, and Ball-milling Time is 10~15 hours.
Preferably, it is formed described in step S2 are as follows: the green body slurry is subjected to mist projection granulating, it is dry-pressing formed that base is made
Body；Or by the green body slurry filters pressing pugging, green body is made in extrusion forming.Wherein, by squeezing green body slurry filters pressing pugging
Green body slurry specifically first can be carried out pugging, preparation by pug mill at clod, then by clod by filter press filters pressing by molding
The blank of mass moisture content 20~22% or so；Roll forming is then carried out using roller head machine, roll-forming process can
Using delay rolling depression method, the rolling time of single product is extended into 30~35s, to improve the density and intensity of green body.
Preferably, in step S2, biscuiting temperature is 900~950 DEG C；The biscuiting time is 4~6h.
Preferably, in step S3, the concentration of the glaze liquid is 45~55 Baume degrees.
Preferably, prepare the process of glaze liquid in step S3 using wet ball grinding, blank raw material: ball: the weight ratio of water is 1:
(1~3): (1~2) crosses 200~300 mesh screens after ball milling, then is tuned into the glaze liquid that concentration is 45~55 Baume degrees.It is further excellent
Selection of land, ball-milling medium are agate ball, and ball milling speed is 100~150r/min, and Ball-milling Time is 15~20 hours.Using the glaze
Liquid carries out glazing to the biscuit, and glazing specifically can be used leaching glaze method, biscuit is soaked in 3~10s in glaze liquid, makes biscuit table
Glaze liquid is adsorbed in face, forms the glaze layer with a thickness of 0.3~1.5mm.
Preferably, in step S4, the firing temperature of the firing processing is 1050~1150 DEG C, and firing time is 3~5h.
The method have the benefit that: the present invention provides a kind of wear-resisting high-hardness ceramic product and preparation method thereof,
Kaolin, zirconium oxide, bentonite, waste porcelain slag, nitrogen of the green body of the wear-resisting high-hardness ceramic product using specified weight part proportion
SiClx, potassium feldspar and albite are raw material, wherein kaolin is primary raw material, and viscosity is big, and plasticity is strong, and property is stablized,
Green body can be made to be easy to sizing and consistency height before firing；Zirconium oxide chemical stability is good, corrosion resistance is high, can increase ceramics
Hardness, intensity, water-resistance, heat resistance and the resistance to pressure of product；Bentonite is the plasticizer of ceramic batch, and can improve blank can
Plasticity and caking property improve the dry tenacity and firing intensity of green body；Use waste porcelain slag for raw material, it can be achieved that waste follows bad benefit
With being good for the environment, and waste porcelain slag is the material through being burnt into, then can suitably reduce firing temperature using it for raw material, shorten burning
At the time；Silicon nitride coefficient of friction is small, good physical performance, and chemical stability is high, and the hardness and anti-corruption of green body can be improved in addition
Corrosion helps not shrink when ceramic post sintering in conjunction with zirconium oxide, keeps high-intensitive；Potassium feldspar and albite all have fluxing
Effect, can reduce firing temperature；Potassium feldspar can guarantee provides enough glass phases at a temperature of at porcelain, and green body is well burnt
Knot, green body are indeformable；Albite high temperature viscosity is small, and mobility is big, easily-deformable, and firing is not easy to control, but albite is conducive to crystal
Growing, the effect for reducing firing temperature are greater than potassium feldspar, by arranging in pairs or groups with potassium feldspar by specific proportion, it is ensured that green body is not
On the basis of deformation, firing temperature, energy saving are reduced.It is combined by the above blank raw material, it is ensured that green body has high rigidity
And high compressive strength.
In addition, kaolin, talcum powder, lithium brightness of the glaze layer of the wear-resisting high-hardness ceramic product using specified weight part proportion
Stone, lithium porcelain stone, quartz, silicon carbide and calcite are raw material, wherein kaolin viscosity is big, plasticity is strong, property is stable, is easy to
Molding；Talcum powder fusing point is low, and in ceramic firing process, the talcum powder of fusing be can be filled in other feed particles gaps, makes glaze
Layer consistency is high, reduces the generation of crackle, improves the water-resistance of ceramic；Spodumene property is stablized, and heat resistance is strong, addition
The thermal stability that glaze layer can be improved avoids cracking in sintering process；Spodumene and lithium porcelain stone have preferable hydrotropy ability, hydrotropy
K is compared in effect2O、Na2O is strong, and addition can reduce the thermal expansion coefficient and sintering temperature of glaze layer, shortens sintering time；Quartz strength
Height can promote the wearability of glaze layer, and the also controllable mobility of glaze layer under the high temperature conditions is not too big, guarantee firing ceramic glaze
The uniformity of thickness degree；Silicon carbide helps to improve anti-skidding friction, capability, with quartz, in conjunction with talcum powder after, can also promote burning
At the shock resistance and thermal stability of ceramic, reinforce the adherence of glaze layer and green body, reduces ceramic in sintering procedure
The probability of middle cracking promotes firing rate；The glossiness of glaze can be improved in calcite, increases the transparency of product.By with glazing
Layer raw material combines, it is ensured that and ceramic glaze layer and green body adherence are strong, have high-compactness, high-wearing feature and thermal stability,
And glossiness and transparency are good.
To sum up, by using the above material matching, coordinated, it is high hard to may make that product ceramic product has each other
Degree and wearability, compression strength is high, and thermal stability is strong.
Specific embodiment
Present invention will be further explained below with reference to specific examples.It should be understood that these embodiments are merely to illustrate the present invention
Rather than it limits the scope of the invention.In addition, it should also be understood that, after reading the content taught by the present invention, those skilled in the art
Member can make various changes or modifications the present invention, and such equivalent forms equally fall within the application the appended claims and limited
Range.
Embodiment 1
A kind of preparation method of wear-resisting high-hardness ceramic product, comprising the following steps:
S1, blank raw material is taken according to following parts by weight: 45 parts of kaolin, 5 parts of zirconium oxide, 18 parts of bentonite, waste porcelain slag 15
Part, 15 parts of silicon nitride, 17 parts of potassium feldspar, 8 parts of albite；
S2, blank raw material being mixed, wet ball grinding then is carried out to blank raw material after mixing, ball-milling medium is agate ball,
Blank raw material: ball: the weight ratio of water sieved with 100 mesh sieve net for 1:1:0.5 with speed ball milling 10 hours of 200r/min after ball milling,
Green body slurry is made；
S3, green body slurry is prepared into mass by clod by pug mill progress pugging at clod by filter press filters pressing
The blank of moisture content 20% or so；Roll forming is then carried out using roller head machine and prepares green body, roll-forming process uses
Be delayed rolling depression method, and the rolling time of single product is extended to 30s；
S4, the conventional repaired biscuit technique using household porcelain production, modify molding blank surface；After again will be trimmed
Green body deposit in shady place make spontaneously dry 8 hours；
S5, biscuiting is carried out to green body after drying using conventional ceramic kiln, biscuiting temperature is 900 DEG C, element
The burning time is 6h, and biscuit is made；
S6, glaze layer raw material: 25 parts of kaolin, 12 parts of talcum powder, 10 parts of spodumene, lithium porcelain stone 12 is taken according to following parts by weight
Part, quartzy 10 parts, 5 parts of silicon carbide, 14 parts of calcite；
S7, the raw material of glaze layer is mixed, wet ball grinding then is carried out to blank raw material after mixing；Ball-milling medium is agate
Ball, blank raw material: ball: the weight ratio of water is 1:1:1, and with speed ball milling 15 hours of 150r/min, 200 meshes are crossed after ball milling
Net, then it is tuned into the glaze liquid that concentration is 45 Baume degrees；
S8, glazing is carried out to biscuit；Biscuit is specifically soaked in 3s in glaze liquid, is made biscuit table by glazing using leaching glaze method
Glaze liquid is adsorbed in face, forms the glaze layer with a thickness of 0.3mm；
S9, firing processing is carried out to the green body after glazing using conventional ceramic kiln；Firing temperature is 1050
DEG C, firing time 3h.
Embodiment 2
A kind of preparation method of wear-resisting high-hardness ceramic product, comprising the following steps:
S1, blank raw material is taken according to following parts by weight: 48 parts of kaolin, 9 parts of zirconium oxide, 16 parts of bentonite, waste porcelain slag 17
Part, 12 parts of silicon nitride, 21 parts of potassium feldspar, 10 parts of albite；
S2, blank raw material being mixed, wet ball grinding then is carried out to blank raw material after mixing, ball-milling medium is agate ball,
Blank raw material: ball: the weight ratio of water is 1:2:1, and with speed ball milling 12 hours of 220r/min, 120 mesh screens, system are crossed after ball milling
Obtain green body slurry；
S3, green body slurry is prepared into mass by clod by pug mill progress pugging at clod by filter press filters pressing
The blank of moisture content 22% or so；Roll forming is then carried out using roller head machine and prepares green body, roll-forming process uses
Be delayed rolling depression method, and the rolling time of single product is extended to 32s；
S4, the conventional repaired biscuit technique using household porcelain production, modify molding blank surface；After again will be trimmed
Green body deposit in shady place make spontaneously dry 10 hours；
S5, biscuiting is carried out to green body after drying using conventional ceramic kiln, biscuiting temperature is 920 DEG C, element
The burning time is 6h, and biscuit is made；
S6, glaze layer raw material: 27 parts of kaolin, 13 parts of talcum powder, 12 parts of spodumene, lithium porcelain stone 10 is taken according to following parts by weight
Part, quartzy 14 parts, 9 parts of silicon carbide, 10 parts of calcite；
S7, the raw material of glaze layer is mixed, wet ball grinding then is carried out to blank raw material after mixing；Ball-milling medium is agate
Ball, blank raw material: ball: the weight ratio of water is 1:3:1, and with speed ball milling 18 hours of 120r/min, 230 meshes are crossed after ball milling
Net, then it is tuned into the glaze liquid that concentration is 50 Baume degrees；
S8, glazing is carried out to biscuit；Biscuit is specifically soaked in 5s in glaze liquid, is made biscuit table by glazing using leaching glaze method
Glaze liquid is adsorbed in face, forms the glaze layer with a thickness of 0.8mm；
S9, firing processing is carried out to the green body after glazing using conventional ceramic kiln；Firing temperature is 1080
DEG C, firing time 5h.
Embodiment 3
A kind of preparation method of wear-resisting high-hardness ceramic product, comprising the following steps:
S1, blank raw material is taken according to following parts by weight: 50 parts of kaolin, 8 parts of zirconium oxide, 15 parts of bentonite, waste porcelain slag 20
Part, 13 parts of silicon nitride, 20 parts of potassium feldspar, 12 parts of albite；
S2, blank raw material being mixed, wet ball grinding then is carried out to blank raw material after mixing, ball-milling medium is agate ball,
Blank raw material: ball: the weight ratio of water is 1:2:1, and with speed ball milling 12 hours of 230r/min, 150 mesh screens, system are crossed after ball milling
Obtain green body slurry；
S3, green body slurry is prepared into mass by clod by pug mill progress pugging at clod by filter press filters pressing
The blank of moisture content 20% or so；Roll forming is then carried out using roller head machine and prepares green body, roll-forming process uses
Be delayed rolling depression method, and the rolling time of single product is extended to 32s；
S4, the conventional repaired biscuit technique using household porcelain production, modify molding blank surface；After again will be trimmed
Green body be placed in 120 DEG C of baking oven and dry 7h hours；
S5, biscuiting is carried out to green body after drying using conventional ceramic kiln, biscuiting temperature is 930 DEG C, element
The burning time is 5h, and biscuit is made；
S6, glaze layer raw material: 30 parts of kaolin, 14 parts of talcum powder, 13 parts of spodumene, lithium porcelain stone 9 is taken according to following parts by weight
Part, quartzy 12 parts, 8 parts of silicon carbide, 10 parts of calcite；
S7, the raw material of glaze layer is mixed, wet ball grinding then is carried out to blank raw material after mixing；Ball-milling medium is agate
Ball, blank raw material: ball: the weight ratio of water is 1:2:1, and with speed ball milling 18 hours of 120r/min, 270 meshes are crossed after ball milling
Net, then it is tuned into the glaze liquid that concentration is 50 Baume degrees；
S8, glazing is carried out to biscuit；Biscuit is specifically soaked in 6s in glaze liquid, is made biscuit table by glazing using leaching glaze method
Glaze liquid is adsorbed in face, forms the glaze layer with a thickness of 1.0mm；
S9, firing processing is carried out to the green body after glazing using conventional ceramic kiln；Firing temperature is 1110
DEG C, firing time 4h.
Embodiment 4
A kind of preparation method of wear-resisting high-hardness ceramic product, comprising the following steps:
S1, blank raw material is taken according to following parts by weight: 52 parts of kaolin, 7 parts of zirconium oxide, 14 parts of bentonite, waste porcelain slag 22
Part, 14 parts of silicon nitride, 19 parts of potassium feldspar, 14 parts of albite；
S2, blank raw material being mixed, wet ball grinding then is carried out to blank raw material after mixing, ball-milling medium is agate ball,
Blank raw material: ball: the weight ratio of water is 1:1:2, and with speed ball milling 14 hours of 230r/min, 170 mesh screens, system are crossed after ball milling
Obtain green body slurry；
S3, green body slurry is prepared into mass by clod by pug mill progress pugging at clod by filter press filters pressing
The blank of moisture content 20% or so；Roll forming is then carried out using roller head machine and prepares green body, roll-forming process uses
Be delayed rolling depression method, and the rolling time of single product is extended to 35s；
S4, the conventional repaired biscuit technique using household porcelain production, modify molding blank surface；After again will be trimmed
Green body be placed in 120 DEG C of baking oven and dry 5h hours；
S5, biscuiting is carried out to green body after drying using conventional ceramic kiln, biscuiting temperature is 950 DEG C, element
The burning time is 4h, and biscuit is made；
S6, glaze layer raw material: 32 parts of kaolin, 15 parts of talcum powder, 14 parts of spodumene, lithium porcelain stone 8 is taken according to following parts by weight
Part, quartzy 12 parts, 7 parts of silicon carbide, 12 parts of calcite；
S7, the raw material of glaze layer is mixed, wet ball grinding then is carried out to blank raw material after mixing；Ball-milling medium is agate
Ball, blank raw material: ball: the weight ratio of water is 1:3:1.5, and with speed ball milling 16 hours of 140r/min, 270 meshes are crossed after ball milling
Net, then it is tuned into the glaze liquid that concentration is 55 Baume degrees；
S8, glazing is carried out to biscuit；Biscuit is specifically soaked in 7s in glaze liquid, is made biscuit table by glazing using leaching glaze method
Glaze liquid is adsorbed in face, forms the glaze layer with a thickness of 1.2mm；
S9, firing processing is carried out to the green body after glazing using conventional ceramic kiln；Firing temperature is 1100
DEG C, firing time 4h.
Embodiment 5
A kind of preparation method of wear-resisting high-hardness ceramic product, comprising the following steps:
S1, blank raw material is taken according to following parts by weight: 55 parts of kaolin, 10 parts of zirconium oxide, 12 parts of bentonite, waste porcelain slag 25
Part, 10 parts of silicon nitride, 23 parts of potassium feldspar, 16 parts of albite；
S2, blank raw material being mixed, wet ball grinding then is carried out to blank raw material after mixing, ball-milling medium is agate ball,
Blank raw material: ball: the weight ratio of water is 1:3:2, and with speed ball milling 15 hours of 250r/min, 200 mesh screens, system are crossed after ball milling
Obtain green body slurry；
S3, green body slurry is subjected to mist projection granulating, it is dry-pressing formed that green body is made；
S4, the conventional repaired biscuit technique using household porcelain production, modify molding blank surface；After again will be trimmed
Green body be placed in 100 DEG C of baking oven and dry 5h hours；
S5, biscuiting is carried out to green body after drying using conventional ceramic kiln, biscuiting temperature is 950 DEG C, element
The burning time is 4h, and biscuit is made；
S6, glaze layer raw material: 35 parts of kaolin, 16 parts of talcum powder, 15 parts of spodumene, lithium porcelain stone 6 is taken according to following parts by weight
Part, quartzy 15 parts, 10 parts of silicon carbide, 7 parts of calcite；
S7, the raw material of glaze layer is mixed, wet ball grinding then is carried out to blank raw material after mixing；Ball-milling medium is agate
Ball, blank raw material: ball: the weight ratio of water is 1:3:2, and with speed ball milling 20 hours of 100r/min, 300 meshes are crossed after ball milling
Net, then it is tuned into the glaze liquid that concentration is 55 Baume degrees；
S8, glazing is carried out to biscuit；Biscuit is specifically soaked in 10s in glaze liquid, is made biscuit table by glazing using leaching glaze method
Glaze liquid is adsorbed in face, forms the glaze layer with a thickness of 1.5mm；
S9, firing processing is carried out to the green body after glazing using conventional ceramic kiln；Firing temperature is 1150
DEG C, firing time 5h.
Strengthen ceramic ware for daily use as a comparison case with certain preferable brand of the sales volume of market purchase, to above-described embodiment 1-
Wear-resisting high-hardness ceramic product obtained and comparative example carry out hardness, breakdown strength, the modulus of rupture, wearability, thermostabilization in 5
Property, water-resistance test, test method is as follows:
Hardness test: taking 5 wear-resisting high-hardness ceramic product fragments as sample, hard according to domestic ceramics device glaze Vickers
It spends method specified in measuring method (QB/T 4780-2015) and carries out vickers hardness test, take its average value；
Breakdown strength test, modulus of rupture test: take 5 wear-resisting high-hardness ceramic product fragments as sample, by sample
The difference weighed twice in succession dried in the drying box of 5 DEG C of 110 DEG C of scholars be spaced to constant weight for 24 hours is put into no more than 0.1%.
Then sample is placed in closed drying box or drier and is cooled to room temperature, GB/T 3810.4- according to national standards after 3h
Regulation in 2006/ISO carries out breakdown strength to sample and the modulus of rupture is tested.
Wearability test: carrying out wearability test using fragment of the wearability test machine to wear-resisting high-hardness ceramic product,
5 wear-resisting high-hardness ceramic product fragments are taken as sample, placed on sample certain granules gradation grinding steel ball, No. 80 it is white
Corundum and quantitative deionized water or distilled water carry out spin finishing according to the speed of rotation of regulation, to worn-out sample with
Unworn sample carries out observation comparison, its wearability is evaluated by the grinding revolution for starting to occur wearing on sample, by 5
The wearability test result of sample averages the wearability test up to ceramic as a result, starting to wear on its sample
Grinding revolution it is higher, the wearability of sample is better.
Heat stability testing: it takes 5 wear-resisting high-hardness ceramic product fragments as sample, is kept the temperature under the conditions of being placed in 280 DEG C
300 minutes, sample was taken out after heat preservation and is calculated, is rapidly put into the water that temperature is 20 DEG C in 15s, impregnates 10 points
Clock then takes out sample and is wiped with cloth dry, and colored red ink checks for crackle, for 24 hours after check again primary, crack more
Few, the thermal stability of sample is better.
Water absorption rate test: it takes 5 wear-resisting high-hardness ceramic product fragments as sample, is dried after cleaning, claim its heavy respectively
Sample separation is placed in distilled water later, boils 3 hours by amount, and during which the water surface is kept above sample 10mm or more, later will
Sample is pulled out, is wiped the water that specimen surface adheres to water saturated cloth has been inhaled, is weighed its weight respectively rapidly, pass through formula later
The water absorption rate for calculating each sample calculates the mean water absorption rate of 5 samples up to the water suction of wear-resisting high-hardness ceramic product product
Rate, water absorption rate is lower, and the water-resistance of sample is better.
Using above method to wear-resisting high-hardness ceramic product obtained in above-described embodiment 1-5 and comparative example domestic ceramics
Product progress hardness, breakdown strength, the modulus of rupture, wearability, thermal stability, test result is as follows for water-resistance shown in table 1:
Table 1
It is breakdown strength, the modulus of rupture, wear-resisting from the foregoing, it will be observed that wear-resisting high-hardness ceramic product obtained by embodiment 1-5
Property, thermal stability and water-resistance be above the reinforcing ceramic that market is bought in comparative example.
Although specifically showing and describing the present invention in conjunction with preferred embodiment, those skilled in the art should be bright
It is white, it is not departing from the spirit and scope of the present invention defined by described claims, it in the form and details can be right
The present invention makes a variety of changes, and is protection scope of the present invention.
Claims (10)
1. a kind of wear-resisting high-hardness ceramic product, which is characterized in that including green body and impose on the glaze layer on green body；
The green body includes following raw material by weight: 45~55 parts of kaolin, 5~10 parts of zirconium oxide, bentonite 12~18
Part, 15~25 parts of waste porcelain slag, 10~15 parts of silicon nitride, 17~23 parts of potassium feldspar, 8~16 parts of albite；
The glaze layer includes following raw material by weight: 25~35 parts of kaolin, 12~16 parts of talcum powder, spodumene 10~15
Part, 6~12 parts of lithium porcelain stone, quartzy 10~15 parts, 5~10 parts of silicon carbide, 7~14 parts of calcite.
2. wear-resisting high-hardness ceramic product according to claim 1, which is characterized in that the green body includes by weight
Following raw material: 48~52 parts of kaolin, 7~9 parts of zirconium oxide, 14~16 parts of bentonite, 17~22 parts of waste porcelain slag, silicon nitride 12~
14 parts, 19~21 parts of potassium feldspar, 10~14 parts of albite；
The glaze layer includes following raw material by weight: 27~32 parts of kaolin, 13~15 parts of talcum powder, spodumene 12~14
Part, 8~10 parts of lithium porcelain stone, quartzy 12~14 parts, 7~9 parts of silicon carbide, 10~12 parts of calcite.
3. wear-resisting high-hardness ceramic product according to claim 2, which is characterized in that the green body includes by weight
Following raw material: 50 parts of kaolin, 8 parts of zirconium oxide, 15 parts of bentonite, 20 parts of waste porcelain slag, 13 parts of silicon nitride, 20 parts of potassium feldspar, sodium
12 parts of feldspar；
The glaze layer includes following raw material by weight: 30 parts of kaolin, 14 parts of talcum powder, 13 parts of spodumene, lithium porcelain stone 9
Part, quartzy 12 parts, 8 parts of silicon carbide, 10 parts of calcite.
4. the preparation method of the described in any item wear-resisting high-hardness ceramic products of claim 1-3, which is characterized in that including following
Step:
S1, each raw material is taken according to parts by weight as above, it is spare；
S2, the raw material of green body is mixed, green body slurry is then prepared using wet ball grinding；It is formed using the green body slurry
Prepare green body；Repaired biscuit is carried out to the green body, it is dry；Biscuiting is carried out to green body after drying again, biscuit is made；
S3, the raw material of glaze layer is mixed, glaze liquid is then prepared using wet ball grinding；The biscuit is carried out using the glaze liquid again
Glazing；
S4, firing processing is carried out to the green body after glazing.
5. the preparation method of wear-resisting high-hardness ceramic product according to claim 4, which is characterized in that used in step S2
Wet ball grinding prepares the process of green body slurry, blank raw material: ball: the weight ratio of water is 1:(1~3): (0.5~2), mistake after ball milling
100~200 mesh screens.
6. the preparation method of wear-resisting high-hardness ceramic product according to claim 4, which is characterized in that described in step S2
Molding are as follows: the green body slurry is subjected to mist projection granulating, it is dry-pressing formed that green body is made；Or by the green body slurry filters pressing pugging,
Green body is made in extrusion forming.
7. the preparation method of wear-resisting high-hardness ceramic product according to claim 4, which is characterized in that in step S2, element
Burning temperature is 900~950 DEG C；The biscuiting time is 4~6h.
8. the preparation method of wear-resisting high-hardness ceramic product according to claim 4, which is characterized in that in step S3, institute
The concentration for stating glaze liquid is 45~55 Baume degrees.
9. the preparation method of wear-resisting high-hardness ceramic product according to claim 8, which is characterized in that used in step S3
Wet ball grinding prepares the process of glaze liquid, blank raw material: ball: the weight ratio of water is 1:(1~3): (1~2), cross 200 after ball milling~
300 mesh screens, then it is tuned into the glaze liquid that concentration is 45~55 Baume degrees.
10. the preparation method of wear-resisting high-hardness ceramic product according to claim 4, which is characterized in that in step S4, institute
The firing temperature for stating firing processing is 1050~1150 DEG C, and firing time is 3~5h.
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Application publication date: 20190412 |