CN112608031A - Formula and method of antifouling and antibacterial ceramic glaze - Google Patents

Formula and method of antifouling and antibacterial ceramic glaze Download PDF

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Publication number
CN112608031A
CN112608031A CN202110082387.XA CN202110082387A CN112608031A CN 112608031 A CN112608031 A CN 112608031A CN 202110082387 A CN202110082387 A CN 202110082387A CN 112608031 A CN112608031 A CN 112608031A
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parts
ball milling
glaze
raw materials
powder
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苏智君
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Fujian Dehua Bole Ceramics Co ltd
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Fujian Dehua Bole Ceramics Co ltd
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    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • C03C8/14Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
    • C03C8/20Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions containing titanium compounds; containing zirconium compounds
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C1/00Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2204/00Glasses, glazes or enamels with special properties
    • C03C2204/02Antibacterial glass, glaze or enamel

Abstract

The invention relates to the technical field of ceramic production, and discloses a ceramic glaze formula with good antifouling and antibacterial properties, which comprises the following components in part by weight: 10-20 parts of frit, 6-12 parts of magnetic powder, 210-20 parts of nano TiO, 12-16 parts of talcum powder, 6-10 parts of zinc oxide, 5-14 parts of zirconium silicate, 7-15 parts of nano zinc oxide powder and 10-15 parts of spodumene; the invention also provides a production method of the ceramic glaze with good antifouling and antibacterial properties, which comprises the following steps: s1: ball milling; s2: stirring and mixing. The glaze produced by the formula can improve the mechanical strength of the glaze layer, and the glaze liquid contains a large amount of negative ions, the negative ion release capacity of the glaze liquid can greatly improve the antibacterial performance of the ceramic product, can release far infrared rays, is beneficial to air purification and human health, can whiten the surface of a blank, and improves the glossiness of the surface of the blank.

Description

Formula and method of antifouling and antibacterial ceramic glaze
Technical Field
The invention relates to the technical field of ceramic production, in particular to a ceramic glaze formula with good antifouling and antibacterial properties and a method.
Background
The ware fired with pottery clay is called pottery, and the ware fired with porcelain clay is called porcelain. The pottery is a general name of pottery, stoneware and porcelain, ancient people refer to the pottery as Ou, all the pottery is made of two kinds of clay with different properties, namely pottery clay and porcelain clay, and the pottery is made by the method processes of proportioning, forming, drying, roasting and the like.
In order to enhance adaptability, ceramic enterprises not only need to greatly improve the scientific and technical application level and the research capability of new products and continuously update the products, but also need to adopt advanced production organization methods such as a plan review method, a grouping method, multi-variety mixed flow production and the like.
The ceramic product is inevitably polluted in the normal use process, and the polluted ceramic can affect the health of people if being used frequently, but the antifouling and antibacterial performance of the common ceramic is not good enough and can not meet the requirements of people.
Disclosure of Invention
Technical problem to be solved
Aiming at the defects of the prior art, the invention provides a ceramic glaze formula with good antifouling and antibacterial properties and a method thereof, and mainly aims to solve the problems that the ceramic product produced by the prior method is inevitably polluted in the normal use process, the polluted ceramic influences the health of people if being frequently used, but the antifouling and antibacterial properties of the common ceramic are not good enough and cannot meet the requirements of people.
(II) technical scheme
In order to achieve the purpose, the invention provides the following technical scheme:
the formula of the ceramic glaze with good antifouling and antibacterial properties comprises the following components: 10-20 parts of frit, 6-12 parts of magnetic powder, 210-20 parts of nano TiO, 12-16 parts of talcum powder, 6-10 parts of zinc oxide, 5-14 parts of zirconium silicate, 7-15 parts of nano zinc oxide powder, 10-15 parts of spodumene, 6-12 parts of laponite, 3-12 parts of titanium dioxide, 5-15 parts of neodymium ore, 8-16 parts of dysprosium ore, 10-30 parts of rare earth, 10-30 parts of aluminum oxide, 10-18 parts of zirconium oxide, 12-18 parts of bentonite, 15-25 parts of quartz, 12-18 parts of feldspar and 15-80 parts of kaolin.
The invention also provides a production method of the ceramic glaze with good antifouling and antibacterial properties, which comprises the following steps:
s1: ball milling, namely weighing the raw materials, carrying out ball milling in a wet ball milling mode, and then carrying out standby application;
s2: stirring and mixing, namely respectively putting the raw materials in the glaze layer formula into a stirrer for stirring and mixing;
s3: screening, namely screening by using a sieve with 300 meshes of 150 meshes after mixing, filtering unqualified raw materials without complete ball milling, then carrying out ball milling filtration again on the filtered raw materials, and mixing again the qualified raw materials after secondary ball milling into the previous raw materials;
s4: removing iron, mixing, removing iron impurities by using a wet magnetic separator, performing screening and iron removal processes for 3-4 times, performing inspection after iron removal, performing the next process when the inspection is qualified, and continuously screening and removing iron when the inspection is unqualified;
s5: and (3) drying, namely drying the glaze subjected to iron removal for later use, wherein the drying time is 5-10 hours, and the temperature is between 100 ℃ and 500 ℃.
Further, in the ball milling in S1, different raw materials are separately ball milled.
On the basis of the scheme, when the ball milling is carried out in the S1, each raw material is wet-milled for 0.1-1 hour in a ball mill, the grinding medium is water, and the raw materials: ball: water 1-1.5:1-5: 2-7.
In a still further embodiment of the present invention, after iron removal in S3, 0.1 to 0.2 parts of a binder and 0.15 to 0.25 parts of a defoaming agent are added and mixed.
Further, the binder in S3 is one or more of methylcellulose, sodium tripolyphosphate, water-soluble acrylic resin, polyvinyl alcohol, and gum arabic.
On the basis of the scheme, 20-50 parts of transparent glaze frit, 6-12 parts of dolomite, 3-6 parts of bone meal, 4-8 parts of calcined strontium carbonate and 10-28 parts of whitening agent are added in the S1 during ball milling.
In a further scheme of the invention, the whitening agent in the S1 comprises 2-5 parts of fluorescent powder, 3-7 parts of nano silver powder, 1-6 parts of nano platinum powder and 4-10 parts of shell powder.
(III) advantageous effects
Compared with the prior art, the invention provides a ceramic glaze formula with good antifouling and antibacterial properties and a method, and the ceramic glaze formula has the following beneficial effects:
1. the addition of the adhesive can increase the adhesiveness of the glaze, thereby facilitating glazing, preventing chapping during glazing and firing and having good stability.
2. According to the invention, the strength of the glaze can be improved by dolomite, bone meal and calcined strontium carbonate, the blank body has better stability and higher mechanical strength during firing, and the whitening component can be increased by the glaze through the addition of the whitening agent, so that the surface of the blank body is whitened after glazing and firing, and the glossiness of the surface of the blank body is improved.
3. According to the invention, screening can be carried out to prevent the condition that the subsequent preparation work is influenced by the raw materials which are not completely ball-milled after mixing, so that the ceramic surface is not flat, the integral effect is influenced, and the screened raw materials cannot be reused, so that the components of different components are influenced, and the integral structure is influenced.
4. The formula adopted by the invention is the raw materials specified in national standard, the cost is low, the mechanical strength and the thermal stability of the glaze layer can be improved, the glaze liquid prepared by mixing the nano zinc oxide powder, the zirconium silicate and the like contains a large amount of negative ions, the antibacterial performance of the ceramic product can be greatly improved by the negative ion release capacity, and the titanium dioxide, the neodymium ore, the dysprosium ore and the rare earth ore can release far infrared rays, thereby being beneficial to air purification and human health.
Drawings
Fig. 1 is a schematic flow structure diagram of a production method of a ceramic glaze with good antifouling and antibacterial properties provided by the invention.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the drawings in the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
Example 1
Referring to fig. 1, a ceramic glaze formula with good antifouling and antibacterial properties comprises: 10-20 parts of frit, 6-12 parts of magnetic powder, 210-20 parts of nano TiO, 12-16 parts of talcum powder, 6-10 parts of zinc oxide, 5-14 parts of zirconium silicate, 7-15 parts of nano zinc oxide powder, 10-15 parts of spodumene, 6-12 parts of hectorite, 3-12 parts of titanium dioxide, 5-15 parts of neodymium ore, 8-16 parts of dysprosium ore, 10-30 parts of rare earth, 10-30 parts of aluminum oxide, 10-18 parts of zirconium oxide, 12-18 parts of bentonite, 15-25 parts of quartz, 12-18 parts of feldspar and 15-80 parts of kaolin, the formula adopted by the invention is a national standard raw material, the cost is low, the mechanical strength and the thermal stability of a glaze layer can be improved, and the glaze liquid prepared by mixing the nano zinc oxide powder, the zirconium silicate and the like contains a large amount of negative ions, the anion releasing capacity of the ceramic product can greatly improve the antibacterial performance of the ceramic product, the far infrared rays can be released by adding titanium dioxide, neodymium ore, dysprosium ore and rare earth ore, so that heat is released, the pathological process of inflammation is eliminated through the question-answer reaction of nerve body fluid, the original damaged physiological equilibrium state is recovered, the local and whole body disease resistance is improved, the anti-inflammatory and antibacterial effects are finally achieved, and the air purification and the health of a human body are facilitated.
The invention also provides a ceramic glaze formula with good antifouling and antibacterial properties and a method, and the ceramic glaze formula comprises the following steps:
s1: ball milling, namely weighing the raw materials, carrying out ball milling in a wet ball milling mode, and then carrying out standby application;
s2: stirring and mixing, namely respectively putting the raw materials in the glaze layer formula into a stirrer for stirring and mixing;
s3: screening, namely screening by using a 150-mesh and 300-mesh screen after mixing, filtering unqualified raw materials without complete ball milling, then performing ball milling filtration again on the filtered raw materials, putting the qualified raw materials after secondary ball milling into the previous raw materials for secondary mixing, and screening to prevent the raw materials without complete ball milling from influencing the subsequent preparation work, so that the ceramic surface is uneven and the overall effect is influenced, and the screened raw materials cannot be reused and also influence the components of different components and the overall structure;
s4: removing iron, mixing, removing iron impurities by using a wet magnetic separator, performing screening and iron removing processes for 3-4 times, performing inspection after iron removal, performing the next process when the inspection is qualified, and continuously screening and removing iron when the inspection is unqualified, wherein the iron in the raw materials is removed, so that iron elements can be prevented from reacting to form iron oxide at high temperature and attaching to a fired product to generate black spots to influence the appearance;
s5: and (3) drying, namely drying the glaze subjected to iron removal for later use, wherein the drying time is 5-10 hours, and the temperature is between 100 ℃ and 500 ℃.
In the ball milling process of S1, different raw materials are subjected to separate ball milling to prevent the different raw materials from influencing each other, so that the ball milling effect is influenced, in the ball milling process of S1, each raw material is wet-milled in a ball mill for 0.1-1 hour, the grinding medium is water, and the raw materials: ball: the raw materials can be fully ball-milled by ball milling in the proportion of 1-1.5:1-5:2-7, the ball milling efficiency can be improved, after iron is removed in S3, 0.1-0.2 part of adhesive and 0.15-0.25 part of defoaming agent are added for mixing, the adhesive in S3 is one or more of methylcellulose, sodium tripolyphosphate, water-soluble acrylic resin, polyvinyl alcohol and Arabic gum, the adhesiveness of glaze can be improved by adding the adhesive, glazing is convenient, chapping is not easy to occur during glazing and the stability is good.
Particularly, 20-50 parts of transparent glaze frit, 6-12 parts of dolomite, 3-6 parts of bone meal, 4-8 parts of calcined strontium carbonate and 10-28 parts of whitening agent are added in S1 during ball milling, the strength of the glaze can be improved through the dolomite, the bone meal and the calcined strontium carbonate, the blank body is better in stability during firing and higher in mechanical strength, the whitening agent in S1 comprises 2-5 parts of fluorescent powder, 3-7 parts of nano silver powder, 1-6 parts of nano platinum powder and 4-10 parts of shell powder, and the whitening component can be increased through the glaze by adding the whitening agent, so that the surface of the blank body is whitened after glazing and firing, and the glossiness of the surface of the blank body is improved.
Example 2
Referring to fig. 1, a ceramic glaze formula with good antifouling and antibacterial properties comprises: 10-20 parts of frit, 6-12 parts of magnetic powder, 210-20 parts of nano TiO, 12-16 parts of talcum powder, 6-10 parts of zinc oxide, 5-14 parts of zirconium silicate, 7-15 parts of nano zinc oxide powder, 10-15 parts of spodumene, 6-12 parts of hectorite, 3-12 parts of titanium dioxide, 5-15 parts of neodymium ore, 8-16 parts of dysprosium ore, 10-30 parts of rare earth, 10-30 parts of aluminum oxide, 10-18 parts of zirconium oxide, 12-18 parts of bentonite, 15-25 parts of quartz, 12-18 parts of feldspar and 15-80 parts of kaolin, the formula adopted by the invention is a national standard raw material, the cost is low, the mechanical strength and the thermal stability of a glaze layer can be improved, and the glaze liquid prepared by mixing the nano zinc oxide powder, the zirconium silicate and the like contains a large amount of negative ions, the anion releasing capacity of the ceramic product can greatly improve the antibacterial performance of the ceramic product, the far infrared rays can be released by adding titanium dioxide, neodymium ore, dysprosium ore and rare earth ore, so that heat is released, the pathological process of inflammation is eliminated through the question-answer reaction of nerve body fluid, the original damaged physiological equilibrium state is recovered, the local and whole body disease resistance is improved, the anti-inflammatory and antibacterial effects are finally achieved, and the air purification and the health of a human body are facilitated.
The invention also provides a ceramic glaze formula with good antifouling and antibacterial properties and a method, and the ceramic glaze formula comprises the following steps:
s1: ball milling, namely weighing the raw materials, carrying out ball milling in a wet ball milling mode, and then carrying out standby application;
s2: stirring and mixing, namely respectively putting the raw materials in the glaze layer formula into a stirrer for stirring and mixing;
s3: screening, namely screening by using a 150-mesh and 300-mesh screen after mixing, filtering unqualified raw materials without complete ball milling, then performing ball milling filtration again on the filtered raw materials, putting the qualified raw materials after secondary ball milling into the previous raw materials for secondary mixing, and screening to prevent the raw materials without complete ball milling from influencing the subsequent preparation work, so that the ceramic surface is uneven and the overall effect is influenced, and the screened raw materials cannot be reused and also influence the components of different components and the overall structure;
s4: removing iron, mixing, removing iron impurities by using a wet magnetic separator, performing screening and iron removing processes for 3-4 times, performing inspection after iron removal, performing the next process when the inspection is qualified, and continuously screening and removing iron when the inspection is unqualified, wherein the iron in the raw materials is removed, so that iron elements can be prevented from reacting to form iron oxide at high temperature and attaching to a fired product to generate black spots to influence the appearance;
s5: and (3) drying, namely drying the glaze subjected to iron removal for later use, wherein the drying time is 5-10 hours, and the temperature is between 100 ℃ and 500 ℃.
In the ball milling process of S1, different raw materials are subjected to separate ball milling to prevent the different raw materials from influencing each other, so that the ball milling effect is influenced, in the ball milling process of S1, each raw material is wet-milled in a ball mill for 0.1-1 hour, the grinding medium is water, and the raw materials: ball: the raw materials can be fully ball-milled by ball milling in the proportion of 1-1.5:1-5:2-7, the ball milling efficiency can be improved, after iron is removed in S3, 0.1-0.2 part of adhesive and 0.15-0.25 part of defoaming agent are added for mixing, the adhesive in S3 is one or more of methylcellulose, sodium tripolyphosphate, water-soluble acrylic resin, polyvinyl alcohol and Arabic gum, the adhesiveness of glaze can be improved by adding the adhesive, glazing is convenient, chapping is not easy to occur during glazing and the stability is good.
Example 3
Referring to fig. 1, a ceramic glaze formula with good antifouling and antibacterial properties comprises: 10-30 parts of frit, 6-12 parts of magnetic powder, 210-20 parts of nano TiO, 12-16 parts of talcum powder, 6-8 parts of zinc oxide, 5-14 parts of zirconium silicate, 7-15 parts of nano zinc oxide powder, 10-15 parts of spodumene, 6-12 parts of laponite, 3-12 parts of titanium dioxide, 8-15 parts of neodymium ore, 8-16 parts of dysprosium ore, 10-25 parts of rare earth, 10-30 parts of aluminum oxide, 10-18 parts of zirconium oxide, 12-18 parts of bentonite, 15-35 parts of quartz, 12-18 parts of feldspar and 15-80 parts of kaolin, the formula adopted by the invention is national standard raw materials, the cost is low, the mechanical strength and the thermal stability of a glaze layer can be improved, and the glaze liquid prepared by mixing the nano zinc oxide powder, the zirconium silicate and the like contains a large amount of negative ions, the anion releasing capacity of the ceramic product can greatly improve the antibacterial performance of the ceramic product, the far infrared rays can be released by adding titanium dioxide, neodymium ore, dysprosium ore and rare earth ore, so that heat is released, the pathological process of inflammation is eliminated through the question-answer reaction of nerve body fluid, the original damaged physiological equilibrium state is recovered, the local and whole body disease resistance is improved, the anti-inflammatory and antibacterial effects are finally achieved, and the air purification and the health of a human body are facilitated.
The invention also provides a ceramic glaze formula with good antifouling and antibacterial properties and a method, and the ceramic glaze formula comprises the following steps:
s1: ball milling, namely weighing the raw materials, carrying out ball milling in a wet ball milling mode, and then carrying out standby application;
s2: stirring and mixing, namely respectively putting the raw materials in the glaze layer formula into a stirrer for stirring and mixing;
s3: screening, namely screening by using a 200-mesh and 300-mesh sieve after mixing, filtering unqualified raw materials without complete ball milling, then performing ball milling filtration again on the filtered raw materials, putting the qualified raw materials after secondary ball milling into the previous raw materials for secondary mixing, and screening to prevent the raw materials without complete ball milling from influencing the subsequent preparation work, so that the surface of the ceramic is uneven, the integral effect is influenced, and the screened raw materials cannot be reused, so that the components of different components are influenced, and the integral structure is influenced;
s4: removing iron, mixing, removing iron impurities by using a wet magnetic separator, performing screening and iron removing processes for 3-4 times, performing inspection after iron removal, performing the next process when the inspection is qualified, and continuously screening and removing iron when the inspection is unqualified, wherein the iron in the raw materials is removed, so that iron elements can be prevented from reacting to form iron oxide at high temperature and attaching to a fired product to generate black spots to influence the appearance;
s5: and (3) drying, namely drying the glaze subjected to iron removal for later use, wherein the drying time is 5-8 hours and the temperature is 80-150 ℃.
In the ball milling process of S1, different raw materials are subjected to separate ball milling to prevent the different raw materials from influencing each other, so that the ball milling effect is influenced, in the ball milling process of S1, each raw material is wet-milled in a ball mill for 0.1-1 hour, the grinding medium is water, and the raw materials: ball: the raw materials can be fully ball-milled by ball milling in the proportion of 1-1.5:1-5:2-7, the ball milling efficiency can be improved, after iron is removed in S3, 0.1-0.2 part of adhesive and 0.15-0.3 part of defoaming agent are added for mixing, the adhesive in S3 is one or more of methylcellulose, sodium tripolyphosphate, water-soluble acrylic resin, polyvinyl alcohol and Arabic gum, the adhesiveness of glaze can be improved by adding the adhesive, glazing is convenient, chapping is not easy to occur during glazing and the stability is good.
Particularly, 20-50 parts of transparent glaze frit, 6-12 parts of dolomite, 3-6 parts of bone meal, 4-8 parts of calcined strontium carbonate and 14-28 parts of whitening agent are added in S1 during ball milling, the strength of the glaze can be improved through the dolomite, the bone meal and the calcined strontium carbonate, the blank body is better in stability and higher in mechanical strength during firing, the whitening agent in S1 comprises 2-6 parts of fluorescent powder, 5-8 parts of nano silver powder, 3-6 parts of nano platinum powder and 4-8 parts of shell powder, and the whitening component can be increased through the glaze by adding the whitening agent, so that the surface of the blank body is whitened after glazing and firing, and the glossiness of the surface of the blank body is improved.
In the description herein, it is noted that relational terms such as first and second, and the like, are used solely to distinguish one entity or action from another entity or action without necessarily requiring or implying any actual such relationship or order between such entities or actions. Also, the terms "comprises," "comprising," or any other variation thereof, are intended to cover a non-exclusive inclusion, such that a process, method, article, or apparatus that comprises a list of elements does not include only those elements but may include other elements not expressly listed or inherent to such process, method, article, or apparatus.
Although embodiments of the present invention have been shown and described, it will be appreciated by those skilled in the art that changes, modifications, substitutions and alterations can be made in these embodiments without departing from the principles and spirit of the invention, the scope of which is defined in the appended claims and their equivalents.

Claims (8)

1. The ceramic glaze formula with good antifouling and antibacterial properties is characterized by comprising the following components in parts by weight: 10-20 parts of frit, 6-12 parts of magnetic powder, 210-20 parts of nano TiO, 12-16 parts of talcum powder, 6-10 parts of zinc oxide, 5-14 parts of zirconium silicate, 7-15 parts of nano zinc oxide powder, 10-15 parts of spodumene, 6-12 parts of laponite, 3-12 parts of titanium dioxide, 5-15 parts of neodymium ore, 8-16 parts of dysprosium ore, 10-30 parts of rare earth, 10-30 parts of aluminum oxide, 10-18 parts of zirconium oxide, 12-18 parts of bentonite, 15-25 parts of quartz, 12-18 parts of feldspar and 15-80 parts of kaolin.
2. The production method of the ceramic glaze with good antifouling and antibacterial properties is characterized by comprising the following steps:
s1: ball milling, namely weighing the raw materials, carrying out ball milling in a wet ball milling mode, and then carrying out standby application;
s2: stirring and mixing, namely respectively putting the raw materials in the glaze layer formula into a stirrer for stirring and mixing;
s3: screening, namely screening by using a sieve with 300 meshes of 150 meshes after mixing, filtering unqualified raw materials without complete ball milling, then carrying out ball milling filtration again on the filtered raw materials, and mixing again the qualified raw materials after secondary ball milling into the previous raw materials;
s4: removing iron, mixing, removing iron impurities by using a wet magnetic separator, performing screening and iron removal processes for 3-4 times, performing inspection after iron removal, performing the next process when the inspection is qualified, and continuously screening and removing iron when the inspection is unqualified;
s5: and (3) drying, namely drying the glaze subjected to iron removal for later use, wherein the drying time is 5-10 hours, and the temperature is between 100 ℃ and 500 ℃.
3. The method for producing ceramic glaze according to claim 2, wherein the ball milling in S1 is performed by separate ball milling of different raw materials.
4. The method for producing ceramic glaze material with good antifouling and antibacterial properties as claimed in claim 2, wherein, in the step of ball milling in S1, each raw material is wet-milled in a ball mill for 0.1-1 hour, the milling medium is water, and the raw materials: ball: water 1-1.5:1-5: 2-7.
5. The method for producing antifouling ceramic glaze according to claim 2, wherein 0.1 to 0.2 part of binder and 0.15 to 0.25 part of defoamer are added and mixed after iron removal in S3.
6. The method for producing ceramic glaze material with good antifouling and antibacterial properties as claimed in claim 5, wherein the binder in S3 is one or more of methylcellulose, sodium tripolyphosphate, water-soluble acrylic resin, polyvinyl alcohol and acacia gum.
7. The method for producing ceramic glaze with good antifouling and antibacterial properties according to claim 2, wherein 20-50 parts of transparent glaze frit, 6-12 parts of dolomite, 3-6 parts of bone meal, 4-8 parts of calcined strontium carbonate and 10-28 parts of whitening agent are added during ball milling in S1.
8. The method for producing antifouling ceramic glaze according to claim 7, wherein the whitening agent in S1 comprises 2-5 parts of fluorescent powder, 3-7 parts of nano silver powder, 1-6 parts of nano platinum powder and 4-10 parts of shell powder.
CN202110082387.XA 2021-01-21 2021-01-21 Formula and method of antifouling and antibacterial ceramic glaze Pending CN112608031A (en)

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CN113773115A (en) * 2021-09-26 2021-12-10 陈彩霞 High-strength antibacterial domestic ceramic and preparation method thereof
CN114180838A (en) * 2021-12-17 2022-03-15 福建省威尔陶瓷股份有限公司 Song Jun fancy glaze and reduction firing method thereof
CN114524614A (en) * 2021-12-24 2022-05-24 福建省威尔陶瓷股份有限公司 Yunxiahua glaze and oxidation sintering method thereof
CN117720340A (en) * 2024-02-06 2024-03-19 内蒙古华宸再生资源科技有限公司 High-silicon functional porcelain and preparation method thereof

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Application publication date: 20210406