CN109604652B - 一种含有纤维材料的pmi泡沫夹芯复合板的制作方法 - Google Patents
一种含有纤维材料的pmi泡沫夹芯复合板的制作方法 Download PDFInfo
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- CN109604652B CN109604652B CN201811383032.9A CN201811383032A CN109604652B CN 109604652 B CN109604652 B CN 109604652B CN 201811383032 A CN201811383032 A CN 201811383032A CN 109604652 B CN109604652 B CN 109604652B
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- fiber material
- fiber
- pmi foam
- composite board
- sandwich composite
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Links
- 229920007790 polymethacrylimide foam Polymers 0.000 title claims abstract description 60
- 239000002131 composite material Substances 0.000 title claims abstract description 52
- 239000002657 fibrous material Substances 0.000 title claims abstract description 45
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 13
- 238000010030 laminating Methods 0.000 claims abstract description 18
- 239000000463 material Substances 0.000 claims abstract description 17
- 239000011162 core material Substances 0.000 claims abstract description 11
- 238000013329 compounding Methods 0.000 claims abstract description 9
- 229920002748 Basalt fiber Polymers 0.000 claims description 89
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 claims description 54
- 239000005011 phenolic resin Substances 0.000 claims description 54
- 229920001568 phenolic resin Polymers 0.000 claims description 54
- 239000004744 fabric Substances 0.000 claims description 39
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 37
- 239000003795 chemical substances by application Substances 0.000 claims description 31
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 claims description 30
- 229910052733 gallium Inorganic materials 0.000 claims description 30
- 239000002216 antistatic agent Substances 0.000 claims description 29
- 239000007822 coupling agent Substances 0.000 claims description 29
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 25
- 150000001875 compounds Chemical class 0.000 claims description 23
- 239000000314 lubricant Substances 0.000 claims description 22
- 229920005989 resin Polymers 0.000 claims description 21
- 239000011347 resin Substances 0.000 claims description 21
- 238000003756 stirring Methods 0.000 claims description 21
- 238000005406 washing Methods 0.000 claims description 21
- 238000001816 cooling Methods 0.000 claims description 20
- 239000002245 particle Substances 0.000 claims description 17
- 239000003995 emulsifying agent Substances 0.000 claims description 15
- 239000000835 fiber Substances 0.000 claims description 15
- 238000000034 method Methods 0.000 claims description 15
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 14
- 239000004809 Teflon Substances 0.000 claims description 14
- 229920006362 Teflon® Polymers 0.000 claims description 14
- 239000002134 carbon nanofiber Substances 0.000 claims description 14
- 238000004140 cleaning Methods 0.000 claims description 14
- 239000002105 nanoparticle Substances 0.000 claims description 14
- 238000007711 solidification Methods 0.000 claims description 14
- 230000008023 solidification Effects 0.000 claims description 14
- 238000006243 chemical reaction Methods 0.000 claims description 13
- 239000003822 epoxy resin Substances 0.000 claims description 12
- 229920000647 polyepoxide Polymers 0.000 claims description 12
- 239000000853 adhesive Substances 0.000 claims description 11
- 230000001070 adhesive effect Effects 0.000 claims description 11
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 10
- PLVPPLCLBIEYEA-AATRIKPKSA-N (E)-3-(indol-3-yl)acrylic acid Chemical compound C1=CC=C2C(/C=C/C(=O)O)=CNC2=C1 PLVPPLCLBIEYEA-AATRIKPKSA-N 0.000 claims description 8
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 8
- HXKCUQDTMDYZJD-UHFFFAOYSA-N Methyl selenac Chemical compound CN(C)C(=S)S[Se](SC(=S)N(C)C)(SC(=S)N(C)C)SC(=S)N(C)C HXKCUQDTMDYZJD-UHFFFAOYSA-N 0.000 claims description 8
- RLVZHWWAGSWRBR-UHFFFAOYSA-N tri(propan-2-yloxy)gallane Chemical compound [Ga+3].CC(C)[O-].CC(C)[O-].CC(C)[O-] RLVZHWWAGSWRBR-UHFFFAOYSA-N 0.000 claims description 8
- 239000004593 Epoxy Substances 0.000 claims description 7
- 239000006087 Silane Coupling Agent Substances 0.000 claims description 7
- 239000012752 auxiliary agent Substances 0.000 claims description 7
- 238000000498 ball milling Methods 0.000 claims description 7
- 238000005520 cutting process Methods 0.000 claims description 7
- 239000008367 deionised water Substances 0.000 claims description 7
- 229910021641 deionized water Inorganic materials 0.000 claims description 7
- 229940008099 dimethicone Drugs 0.000 claims description 7
- 235000013870 dimethyl polysiloxane Nutrition 0.000 claims description 7
- 239000004205 dimethyl polysiloxane Substances 0.000 claims description 7
- 238000001914 filtration Methods 0.000 claims description 7
- 125000002485 formyl group Chemical class [H]C(*)=O 0.000 claims description 7
- 238000010438 heat treatment Methods 0.000 claims description 7
- 238000002156 mixing Methods 0.000 claims description 7
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims description 7
- 229920002689 polyvinyl acetate Polymers 0.000 claims description 7
- 239000011118 polyvinyl acetate Substances 0.000 claims description 7
- 150000003242 quaternary ammonium salts Chemical group 0.000 claims description 7
- 229920006337 unsaturated polyester resin Polymers 0.000 claims description 7
- 238000001035 drying Methods 0.000 claims description 6
- 239000004814 polyurethane Substances 0.000 claims description 6
- 229920002635 polyurethane Polymers 0.000 claims description 6
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 5
- 229910052749 magnesium Inorganic materials 0.000 claims description 5
- 239000011777 magnesium Substances 0.000 claims description 5
- 229920000049 Carbon (fiber) Polymers 0.000 claims description 4
- 229960000583 acetic acid Drugs 0.000 claims description 4
- 239000004917 carbon fiber Substances 0.000 claims description 4
- 239000012362 glacial acetic acid Substances 0.000 claims description 4
- 229910021392 nanocarbon Inorganic materials 0.000 claims description 3
- 238000002791 soaking Methods 0.000 claims description 3
- 229920006231 aramid fiber Polymers 0.000 claims description 2
- 239000003365 glass fiber Substances 0.000 claims description 2
- 230000003301 hydrolyzing effect Effects 0.000 claims description 2
- 239000010453 quartz Substances 0.000 claims description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 2
- 238000009736 wetting Methods 0.000 claims description 2
- SHXHPUAKLCCLDV-UHFFFAOYSA-N 1,1,1-trifluoropentane-2,4-dione Chemical compound CC(=O)CC(=O)C(F)(F)F SHXHPUAKLCCLDV-UHFFFAOYSA-N 0.000 claims 1
- 239000006260 foam Substances 0.000 abstract description 22
- 238000002360 preparation method Methods 0.000 abstract description 8
- 239000003063 flame retardant Substances 0.000 abstract description 3
- 238000012805 post-processing Methods 0.000 abstract description 2
- 238000004381 surface treatment Methods 0.000 abstract description 2
- 239000010410 layer Substances 0.000 description 60
- 238000002474 experimental method Methods 0.000 description 14
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 13
- 230000000052 comparative effect Effects 0.000 description 9
- 230000000694 effects Effects 0.000 description 6
- 238000009413 insulation Methods 0.000 description 6
- 239000002344 surface layer Substances 0.000 description 4
- 238000004378 air conditioning Methods 0.000 description 3
- 239000012792 core layer Substances 0.000 description 3
- 229910000831 Steel Inorganic materials 0.000 description 2
- 239000012790 adhesive layer Substances 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 238000005187 foaming Methods 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920006327 polystyrene foam Polymers 0.000 description 2
- 239000000779 smoke Substances 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- 239000002023 wood Substances 0.000 description 2
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
- 239000007983 Tris buffer Substances 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 239000004088 foaming agent Substances 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 239000011491 glass wool Substances 0.000 description 1
- 239000002608 ionic liquid Substances 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 239000011490 mineral wool Substances 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000002341 toxic gas Substances 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23B—TURNING; BORING
- B23B27/00—Tools for turning or boring machines; Tools of a similar kind in general; Accessories therefor
- B23B27/08—Cutting tools with blade- or disc-like main parts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C65/00—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
- B29C65/48—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor using adhesives, i.e. using supplementary joining material; solvent bonding
- B29C65/50—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor using adhesives, i.e. using supplementary joining material; solvent bonding using adhesive tape, e.g. thermoplastic tape; using threads or the like
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/28—Layered products comprising a layer of synthetic resin comprising synthetic resins not wholly covered by any one of the sub-groups B32B27/30 - B32B27/42
- B32B27/281—Layered products comprising a layer of synthetic resin comprising synthetic resins not wholly covered by any one of the sub-groups B32B27/30 - B32B27/42 comprising polyimides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/42—Layered products comprising a layer of synthetic resin comprising condensation resins of aldehydes, e.g. with phenols, ureas or melamines
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/18—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by features of a layer of foamed material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/04—Interconnection of layers
- B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2250/00—Layers arrangement
- B32B2250/24—All layers being polymeric
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
- B32B2262/02—Synthetic macromolecular fibres
- B32B2262/0261—Polyamide fibres
- B32B2262/0269—Aromatic polyamide fibres
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
- B32B2262/10—Inorganic fibres
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
- B32B2262/10—Inorganic fibres
- B32B2262/101—Glass fibres
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
- B32B2262/10—Inorganic fibres
- B32B2262/106—Carbon fibres, e.g. graphite fibres
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/30—Properties of the layers or laminate having particular thermal properties
- B32B2307/304—Insulating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/30—Properties of the layers or laminate having particular thermal properties
- B32B2307/306—Resistant to heat
- B32B2307/3065—Flame resistant or retardant, fire resistant or retardant
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Laminated Bodies (AREA)
Abstract
Description
Claims (5)
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CN201811383032.9A CN109604652B (zh) | 2018-11-20 | 2018-11-20 | 一种含有纤维材料的pmi泡沫夹芯复合板的制作方法 |
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CN201811383032.9A CN109604652B (zh) | 2018-11-20 | 2018-11-20 | 一种含有纤维材料的pmi泡沫夹芯复合板的制作方法 |
Publications (2)
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CN109604652A CN109604652A (zh) | 2019-04-12 |
CN109604652B true CN109604652B (zh) | 2021-01-05 |
Family
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CN201811383032.9A Active CN109604652B (zh) | 2018-11-20 | 2018-11-20 | 一种含有纤维材料的pmi泡沫夹芯复合板的制作方法 |
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Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110328915A (zh) * | 2019-07-05 | 2019-10-15 | 鲁东大学 | 一种碳纤维材料船舶壳体及其制造方法 |
CN111421852B (zh) * | 2020-04-01 | 2021-11-16 | 国际竹藤中心 | 一种多壁层耐候性植物纤维增强风管的制备方法 |
CN114605688A (zh) * | 2022-04-07 | 2022-06-10 | 江苏中科聚合新材料产业技术研究院有限公司 | 一种超临界环氧预浸料发泡板材及其制备方法 |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0197639A (ja) * | 1987-10-08 | 1989-04-17 | Japan Synthetic Rubber Co Ltd | 積層体 |
CN102898044A (zh) * | 2012-10-19 | 2013-01-30 | 四川航天拓鑫玄武岩实业有限公司 | 玄武岩纤维表面改性浸润剂及其制备方法 |
CN103072284A (zh) * | 2012-12-06 | 2013-05-01 | 中国船舶重工集团公司第七二五研究所 | 一种含增强筋的夹芯结构复合材料及其制造方法 |
CN104692674A (zh) * | 2015-02-10 | 2015-06-10 | 四川省西玄科技有限公司 | 玄武岩纤维专用环氧型浸润剂及其制备方法 |
CN104926158A (zh) * | 2015-06-30 | 2015-09-23 | 四川航天五源复合材料有限公司 | 用于玄武岩纤维的纳米改性浸润剂 |
CN104927307A (zh) * | 2015-06-30 | 2015-09-23 | 四川航天五源复合材料有限公司 | 用于玄武岩纤维的纳米改性浸润剂的制备方法 |
CN107856379A (zh) * | 2017-10-17 | 2018-03-30 | 浙江石金玄武岩纤维股份有限公司 | 一种玄武岩纤维增强酚醛夹芯复合板及其成型工艺 |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP3371119A4 (en) * | 2015-11-04 | 2019-07-03 | Sibelco North America, Inc. | CLEANED, FOR PUNCHING A FIBER CABLE MODIFIED QUARTZ POWDER |
-
2018
- 2018-11-20 CN CN201811383032.9A patent/CN109604652B/zh active Active
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0197639A (ja) * | 1987-10-08 | 1989-04-17 | Japan Synthetic Rubber Co Ltd | 積層体 |
CN102898044A (zh) * | 2012-10-19 | 2013-01-30 | 四川航天拓鑫玄武岩实业有限公司 | 玄武岩纤维表面改性浸润剂及其制备方法 |
CN103072284A (zh) * | 2012-12-06 | 2013-05-01 | 中国船舶重工集团公司第七二五研究所 | 一种含增强筋的夹芯结构复合材料及其制造方法 |
CN104692674A (zh) * | 2015-02-10 | 2015-06-10 | 四川省西玄科技有限公司 | 玄武岩纤维专用环氧型浸润剂及其制备方法 |
CN104926158A (zh) * | 2015-06-30 | 2015-09-23 | 四川航天五源复合材料有限公司 | 用于玄武岩纤维的纳米改性浸润剂 |
CN104927307A (zh) * | 2015-06-30 | 2015-09-23 | 四川航天五源复合材料有限公司 | 用于玄武岩纤维的纳米改性浸润剂的制备方法 |
CN107856379A (zh) * | 2017-10-17 | 2018-03-30 | 浙江石金玄武岩纤维股份有限公司 | 一种玄武岩纤维增强酚醛夹芯复合板及其成型工艺 |
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