CN109603525B - Denitration partition ammonia spraying control method based on non-uniformity judgment - Google Patents

Denitration partition ammonia spraying control method based on non-uniformity judgment Download PDF

Info

Publication number
CN109603525B
CN109603525B CN201811607377.8A CN201811607377A CN109603525B CN 109603525 B CN109603525 B CN 109603525B CN 201811607377 A CN201811607377 A CN 201811607377A CN 109603525 B CN109603525 B CN 109603525B
Authority
CN
China
Prior art keywords
ammonia
delta
ammonia spraying
nox
partition
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201811607377.8A
Other languages
Chinese (zh)
Other versions
CN109603525A (en
Inventor
李文华
刘春红
丁乙崟
陈彪
陈雨帆
刘文新
沈利
黄永杰
王洁
杨毅均
谭晓涛
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Zhejiang Zheneng Wenzhou Power Generation Co ltd
Zhejiang Energy Group Research Institute Co Ltd
Original Assignee
Zhejiang Zheneng Wenzhou Power Generation Co ltd
Zhejiang Energy Group Research Institute Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Zhejiang Zheneng Wenzhou Power Generation Co ltd, Zhejiang Energy Group Research Institute Co Ltd filed Critical Zhejiang Zheneng Wenzhou Power Generation Co ltd
Priority to CN201811607377.8A priority Critical patent/CN109603525B/en
Publication of CN109603525A publication Critical patent/CN109603525A/en
Application granted granted Critical
Publication of CN109603525B publication Critical patent/CN109603525B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86Catalytic processes
    • B01D53/8621Removing nitrogen compounds
    • B01D53/8625Nitrogen oxides
    • B01D53/8631Processes characterised by a specific device
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86Catalytic processes
    • B01D53/8696Controlling the catalytic process

Abstract

The invention relates to automatic control in the technical field of coal-fired power generation, in particular to a denitration partition ammonia spraying control method based on non-uniformity judgment. The existing automatic denitration zone ammonia injection control cannot meet the real-time automatic regulation requirement of an ammonia injection regulating valve, delay and hysteresis exist in ammonia injection quantity control, the ammonia injection quantity and NOx concentration are not well matched, and the NOx control effect at the outlet of the reactor is poor. The invention provides a denitration partition ammonia spraying control method based on non-uniformity judgment, which comprises the steps of dividing a plurality of ammonia spraying partitions according to the concentration level of NOx at an outlet of an SCR reactor according to trends, sampling smoke at an extending position corresponding to each ammonia spraying partition in a flue, calculating non-uniformity CV of the concentration of NOx at a sampling section of the flue, combining the size of the ammonia spraying amount and the concentration distribution of the NOx at each area, accurately adjusting a partition ammonia spraying regulating valve and an ammonia spraying branch regulating valve according to different conditions, and meeting the matching requirements of the ammonia spraying amount and the concentration of the NOx, thereby realizing the accurate control and uniform distribution of the NOx at the outlet of the SCR denitration reactor in real time, quickly, stably and effectively.

Description

Denitration partition ammonia spraying control method based on non-uniformity judgment
Technical Field
The invention relates to automatic control in the technical field of coal-fired power generation, in particular to a denitration partition ammonia spraying control method based on non-uniformity judgment.
Background
Most of thermal power plants for coal-fired power generation in China adopt a Selective Catalytic Reduction (SCR) denitration technology to treat NOx pollutants. The core equipment of the SCR denitration technology is an SCR reactor, and as shown in fig. 1, the technological process of the SCR denitration reaction is as follows: the raw flue gas from the economizer is firstly mixed with diluted ammonia gas at a zoned ammonia spraying grid, the ammonia spraying grid consists of a plurality of evenly arranged nozzles (see figure 2), each ammonia spraying branch is provided with a manual butterfly valve to adjust the ammonia spraying amount of one zone, the mixed flue gas vertically passes through an SCR reactor, two or three layers of catalysts are arranged in the reactor, the mixed ammonia-containing flue gas is contacted with the surface of the catalyst, and NOx and NH are contacted with each other 3 Reduction reaction takes place on the surface of the catalyst to produce N which is harmless to the environment 2 And water, thus achieve the goal of removing NOx in the flue gas, therefore the concentration distribution uniformity of NOx in the original flue gas is very important to the denitration reaction under the aforesaid ammonia injection grid configuration mode, once the valve opening size of the ammonia injection grid valve station of the existing ammonia injection control system is adjusted, the ammonia injection grid valve station is not adjusted in the subsequent operation. In the denitration reaction, ammonia gas supplied by an ammonia zone is firstly mixed with dilution air sent by a dilution fan, then is uniformly sprayed into a flue to be mixed with raw flue gas after passing through a manual butterfly valve on an ammonia spraying branch. The ammonia injection amount on the ammonia supply main pipe is automatically adjusted according to the unit load, the original flue gas NOx concentration value and the denitration efficiency to be achieved, when the denitration efficiency requirement is higher, the ammonia injection amount is increased, and when the denitration requirement is lower, the ammonia injection amount is reduced; when the load is fixed, the running state of the denitration reactor depends on the fixed ammonia injection under a certain working conditionThe amount is uniformly and reasonably distributed on the spraying section, and under ideal conditions, the original flue gas NOx is uniformly distributed and the flow velocity is uniform, only ammonia is required to be uniformly sprayed on the section, and the state of each manual butterfly valve on the ammonia spraying branch is not required to be adjusted, so that the method is also adopted by the existing denitration system of all coal-fired units.
In actual operation, due to poor uniformity of NOx distribution in raw flue gas, especially the NOx distribution rule of the raw flue gas of a boiler in a butt-fired mode can be changed greatly in the coal mill switching process and after the coal mill switching process, especially after the coal mill switching process or the load change, the opening of a manual butterfly valve of each ammonia spraying branch is not adjusted, so that the ammonia spraying amount of each region of a flue in actual operation is not matched with the actual concentration distribution of NOx, and further, the problems of large deviation between a NOx concentration monitoring value of a denitration outlet and a concentration monitoring value on a chimney, increased ammonia escape amount in operation, equipment blockage of an air preheater and the like, increased unit consumption of a fan, reduced unit output and the like are caused. The invention application No. 2016106049468 discloses a denitration refinement control method suitable for a hedging type coal-fired boiler, which can change the quick adjustment of the opening of an ammonia supply branch regulating valve according to the load and the running state change of a coal mill, but the control still can not meet the real-time control of an ammonia injection regulating valve; and because of the hysteresis of the NOx concentration measurement at the inlet and outlet of the SCR denitration reactor and the self characteristics of a control system, the ammonia injection amount control process of the denitration system becomes a large delay link, so that the automatic control is difficult to obtain the expected good effect, and particularly the matching effect of the ammonia injection amount and the NOx concentration is poor. In addition, the load fluctuation of the unit and the start-stop switching of the coal mill have large fluctuation amplitude and high fluctuation speed of the NOx at the inlet of the reactor, and the control effect of the NOx at the outlet of the reactor can be seriously influenced.
Disclosure of Invention
The invention aims to solve the technical problems and the technical task of solving the problems that the existing automatic denitration partition ammonia injection control cannot meet the real-time automatic adjustment of an ammonia injection regulating valve and obvious delay exists in ammonia injection quantity control, so that the ammonia injection quantity and NOx concentration are not well matched, the NOx control effect at the outlet of a reactor is poor, and the like.
The invention solves the technical problems by adopting the technical scheme that: a denitration partition ammonia spraying control method based on non-uniformity judgment comprises the following steps in sequence:
(1) Setting an electric regulating valve with an automatic regulating function as an ammonia spraying branch regulating valve in each ammonia spraying branch;
(2) Confirming the position of a partition corresponding to an ammonia spraying grid with an ammonia spraying section, making a fixed number on a region corresponding to each ammonia spraying branch, defining the opening of a valve with n ammonia spraying branches as Y= (Y11, Y12, Y13, Y21, Y22, Y23 … yij … yhm), yij being the opening of a corresponding regulating valve of the j-th ammonia spraying branch of the i-th group, wherein the valve of each three ammonia spraying branches is a group, and j and m are 1,2,3 and n are integer multiples of 3;
(3) Dividing a plurality of ammonia spraying subareas according to the concentration level of NOx at an outlet of the SCR reactor and trends, uniformly distributing the subareas according to the number of ammonia spraying branches, and arranging a subarea ammonia supply regulating valve in each ammonia spraying subarea;
(4) Carrying out fixed numbering on each partition coefficient amplifying module in the partition ammonia spraying control system, and defining the proportionality coefficient K of each coefficient amplifying module as K= (K1, K2, K3 … … kM), wherein M is the ammonia spraying partition number;
(5) Assuming that a certain boiler with opposite combustion has 5 coal mills, namely, a mill, B mill, C mill, D mill and E mill, defining an operation signal of the coal mill of the boiler and a load W of a unit as a variable X, wherein the load is divided into two load sections W1 and W2 in combination with actual conditions, and when the unit keeps at least 3 coal mills running above the minimum technical output, the operation combination working conditions of the coal mills are discretized as follows:
from this, the vector can be obtained:
X=(X1,X2,X3···Xn);
(6) Under the operation condition of each coal mill, manually adjusting the ammonia supply quantity of each ammonia injection branch according to an ammonia injection grid adjusting method to ensure that the NOx concentration distribution of the cross section of the denitration outlet is uniform, and obtaining the functional relation among the opening Y of the ammonia supply branch valve, the scaling factor K of the coefficient amplifying module and the operation combination condition X of the coal mill:
Y=F(X),K=G(X);
(7) The opening of the motor adjusting partition ammonia supply regulating valve or the ammonia spraying branch regulating valve is circularly calculated and adjusted through the following control steps;
(71) At the setting step, a set value of the NOx concentration of 273.15K and 1.013X10 at the outlet is given 5 The conversion value of the NOx concentration when the oxygen content is 6% under the Pa condition is entered into a timing module;
(72) Setting a Y pulse signal in a timing step through a set time, and entering a non-uniformity judging module; otherwise, the N signal is always given, the unevenness judging module is skipped, and the first to fourth deviation calculating modules are directly entered;
(73) When the timing module gives a Y signal, the system enters an unevenness judging module; at the unevenness judging module, receiving the CV signals transmitted by the calculating module, judging whether the CV signals are less than or equal to 15 percent, and entering the first to fourth deviation calculating modules if the CV signals are Y; otherwise 'N' and rapidly adjusting an ammonia injection branch regulating valve through mapping F (X);
(74) At the first to fourth deviation calculation modules, PVn output from the calculation module is input, respectively, where n=1, 2,3, 4 and the NOx set value given in the setting step; respectively calculating to obtain deviations delta 1, delta 2, delta 3 and delta 4, and correspondingly entering a first coefficient amplifying module to a fourth coefficient amplifying module;
(75) In the first to fourth coefficient amplifying modules, corresponding to K determined by the input mapping G (X) and delta obtained in the step (74), wherein K is K1, K2, K3 and K4 respectively, delta is delta 1, delta 2, delta 3 and delta 4 respectively, proportion calculation is carried out in the four coefficient amplifying modules, and K1 delta 1, K2 delta 2, K3 delta 3 and K4 delta 4 respectively enter four PID control modules;
(76) The inputs of each PID control module are k1 delta 1, k2 delta 2, k3 delta 3, k4 delta 4 and zero respectively, so that the opening degree of the partition ammonia supply regulating valve is regulated by regulating the motor;
(77) Sampling smoke corresponding to the extending positions of the ammonia spraying partitions on a flue after the denitration reactor, outputting the smoke to a sample acquisition and analysis module, and acquiring the smoke in real time and analyzing to obtain the concentration Cs of NOx and the oxygen content O of the NOx 2 The percent, the temperature Ts and the moisture content Xs are transmitted to a calculation module for calculation;
(78) In the calculation module, the original data obtained by sampling analysis is calculated to 273.15K and 1.013X10 by the following formulas 5 The calculated value Csn of the oxygen amount of NOx when the oxygen amount is 6% under the Pa condition, and the corresponding NOx concentration PVn (n=1, 2, 3. I. N) of each partition, the average value PV of the NOx concentration of the whole section and the non-uniformity CV of the NOx concentration of the sampling section are obtained through calculation of a partition ammonia injection control system;
in the i-th partition:
the SP is a set value of the concentration of NOx at the outlet of the reactor; CV,%; PV, mg/Nm 3
(79) And the PVn, the PV and the CV obtained by the calculation module are transmitted to an upper computer, wherein the PVn is divided into one path to the first to fourth deviation calculation modules, and the CV is divided into one path to the unevenness judgment module.
The invention provides a denitration zone ammonia spraying control method based on non-uniformity judgment, which comprises the steps of dividing a plurality of ammonia spraying zones according to the concentration level of NOx at an outlet of an SCR reactor, sampling smoke at an extending position corresponding to each ammonia spraying zone in a flue, calculating the non-uniformity CV of the concentration of NOx at a sampling section of the flue, combining the size of ammonia spraying quantity and the concentration distribution of NOx at each zone, accurately adjusting a zone ammonia spraying regulating valve and an ammonia spraying branch regulating valve according to different conditions, meeting the matching requirement of the ammonia spraying quantity and the concentration of NOx, realizing the accurate control and uniform distribution of the NOx at the outlet of the SCR denitration reactor in real time, quickly, stably and effectively, specifically, referring to the prior invention application for quickly adjusting the ammonia spraying branch regulating valve when the non-uniformity CV is 15% as a critical point and adjusting the zone ammonia supplying regulating valve when the non-uniformity CV is more than 15%.
Drawings
Fig. 1: the invention provides a schematic diagram for partitioning and finely adjusting a denitration ammonia injection grid.
Fig. 2: the control method is a flow chart.
Fig. 3: the invention is schematically used in an SCR reactor.
Detailed Description
The invention is further described with reference to the accompanying drawings and detailed description.
As shown in fig. 1 to 3, a denitration partition ammonia injection control method based on non-uniformity judgment includes the following steps sequentially performed:
(1) Setting an electric regulating valve with an automatic regulating function as an ammonia spraying branch regulating valve in each ammonia spraying branch;
(2) Confirming the position of a partition corresponding to an ammonia spraying grid with an ammonia spraying section, making a fixed number on a region corresponding to each ammonia spraying branch, defining the opening of a valve with n ammonia spraying branches as Y= (Y11, Y12, Y13, Y21, Y22, Y23 … yij … yhm), wherein yij is the opening of a corresponding regulating valve of the j-th ammonia spraying branch of the i-th group, the valves of each three ammonia spraying branches are in one group, and j and m are 1,2 and 3; in fig. 1, only 24 ammonia spraying branches are drawn, and the actual SCR denitration reactor generally has 20-40 branches according to the capacity of the unit, which is not drawn one by one for simplicity in this embodiment;
(3) Dividing a plurality of ammonia spraying subareas according to the concentration level of NOx at an outlet of the SCR reactor according to trend, uniformly distributing the subareas according to the number of ammonia spraying branches, and arranging a subarea ammonia supply regulating valve for each ammonia spraying subarea, wherein in the embodiment, the subareas are divided into 4 ammonia spraying subareas shown in fig. 1 for simplicity;
(4) Carrying out fixed numbering on each partition coefficient amplifying module in the partition ammonia spraying control system, and defining the proportionality coefficient K of each coefficient amplifying module as K= (K1, K2, K3 … … kM), wherein M is the ammonia spraying partition number;
(5) Assuming that a certain boiler with opposite combustion has 5 coal mills, namely, a mill, B mill, C mill, D mill and E mill, defining an operation signal of the coal mill of the boiler and a load W of a unit as a variable X, wherein the load is divided into two load sections W1 and W2 in combination with actual conditions, and when the unit keeps at least 3 coal mills running above the minimum technical output, the operation combination working conditions of the coal mills are discretized as follows:
from this, the vector can be obtained:
X=(X1,X2,X3···Xn);
(6) Under the operation condition of each coal mill, manually adjusting the ammonia supply quantity of each ammonia injection branch according to an ammonia injection grid adjusting method to ensure that the NOx concentration distribution of the cross section of the denitration outlet is uniform, and obtaining the functional relation among the opening Y of the ammonia supply branch valve, the scaling factor K of the coefficient amplifying module and the operation combination condition X of the coal mill:
Y=F(X),K=G(X);
(7) The opening of the motor adjusting partition ammonia supply regulating valve or the ammonia spraying branch regulating valve is circularly calculated and adjusted through the following control steps;
(71) At the setting step, the outlet N is givenSetting value of Ox concentration, the NOx concentration is 273.15K, 1.013X10 5 The conversion value of the NOx concentration when the oxygen content is 6% under the Pa condition is entered into a timing module;
(72) Setting a Y pulse signal in a timing step through a set time, and entering a non-uniformity judging module; otherwise, the N signal is always given, the unevenness judging module is skipped, and the first to fourth deviation calculating modules are directly entered;
(73) When the timing module gives a Y signal, the system enters an unevenness judging module; at the unevenness judging module, receiving the CV signals transmitted by the calculating module, judging whether the CV signals are less than or equal to 15 percent, and entering the first to fourth deviation calculating modules if the CV signals are Y; otherwise 'N' and rapidly adjusting an ammonia injection branch regulating valve through mapping F (X);
(74) At the first to fourth deviation calculation modules, PVn output from the calculation module is input, respectively, where n=1, 2,3, 4 and the NOx set value given in the setting step; respectively calculating to obtain deviations delta 1, delta 2, delta 3 and delta 4, and correspondingly entering a first coefficient amplifying module to a fourth coefficient amplifying module;
(75) In the first to fourth coefficient amplifying modules, corresponding to K determined by the input mapping G (X) and delta obtained in the step (74), wherein K is K1, K2, K3 and K4 respectively, delta is delta 1, delta 2, delta 3 and delta 4 respectively, proportion calculation is carried out in the four coefficient amplifying modules, and K1 delta 1, K2 delta 2, K3 delta 3 and K4 delta 4 respectively enter four PID control modules;
(76) The inputs of each PID control module are k1 delta 1, k2 delta 2, k3 delta 3, k4 delta 4 and zero respectively, so that the opening degree of the partition ammonia supply regulating valve is regulated by regulating the motor;
(77) Sampling smoke corresponding to the extending positions of the ammonia spraying partitions on a flue after the denitration reactor, outputting the smoke to a sample acquisition and analysis module, and acquiring the smoke in real time and analyzing to obtain the concentration Cs of NOx and the oxygen content O of the NOx 2 The percent, the temperature Ts and the moisture content Xs are transmitted to a calculation module for calculation;
(78) In the calculation module, the original data obtained by sampling analysis is passed through273.15K, 1.013X10 were calculated by the following formula 5 The calculated value Csn of the oxygen amount of NOx when the oxygen amount is 6% under the Pa condition, and the corresponding NOx concentration PVn (n=1, 2, 3. I. N) of each partition, the average value PV of the NOx concentration of the whole section and the non-uniformity CV of the NOx concentration of the sampling section are obtained through calculation of a partition ammonia injection control system;
in the i-th partition:
the SP is a set value of the concentration of NOx at the outlet of the reactor; CV,%; PV, mg/Nm 3
(79) And the PVn, the PV and the CV obtained by the calculation module are transmitted to an upper computer, wherein the PVn is divided into one path to the first to fourth deviation calculation modules, and the CV is divided into one path to the unevenness judgment module.
The invention provides a denitration zone ammonia spraying control method based on non-uniformity judgment, which comprises the steps of dividing a plurality of ammonia spraying zones according to the concentration level of NOx at an outlet of an SCR reactor, sampling smoke at an extending position corresponding to each ammonia spraying zone in a flue, calculating the non-uniformity CV of the concentration of NOx at a sampling section of the flue, combining the size of ammonia spraying quantity and the concentration distribution of NOx at each zone, accurately adjusting a zone ammonia spraying regulating valve and an ammonia spraying branch regulating valve according to different conditions, meeting the matching requirement of the ammonia spraying quantity and the concentration of NOx, realizing the accurate control and uniform distribution of the NOx at the outlet of the SCR denitration reactor in real time, quickly, stably and effectively, specifically, referring to the prior invention application for quickly adjusting the ammonia spraying branch regulating valve when the non-uniformity CV is 15% as a critical point and adjusting the zone ammonia supplying regulating valve when the non-uniformity CV is more than 15%.

Claims (1)

1. A denitration partition ammonia spraying control method based on non-uniformity judgment comprises the following steps in sequence:
(1) Setting an electric regulating valve with an automatic regulating function as an ammonia spraying branch regulating valve in each ammonia spraying branch;
(2) Confirming the position of a partition corresponding to an ammonia spraying grid with an ammonia spraying section, making a fixed number on a region corresponding to each ammonia spraying branch, defining the opening of a valve with n ammonia spraying branches as Y= (Y11, Y12, Y13, Y21, Y22, Y23 … yij … yhm), yij being the opening of a corresponding regulating valve of the j-th ammonia spraying branch of the i-th group, wherein the valve of each three ammonia spraying branches is a group, and j and m are 1,2,3 and n are integer multiples of 3;
(3) Dividing a plurality of ammonia spraying subareas according to the concentration level of NOx at an outlet of the SCR reactor and trends, uniformly distributing the subareas according to the number of ammonia spraying branches, and arranging a subarea ammonia supply regulating valve in each ammonia spraying subarea;
(4) Carrying out fixed numbering on each partition coefficient amplifying module in the partition ammonia spraying control system, and defining the proportionality coefficient K of each coefficient amplifying module as K= (K1, K2, K3 … … kM), wherein M is the ammonia spraying partition number;
(5) Assuming that a certain boiler with opposite combustion has 5 coal mills, namely, a mill, B mill, C mill, D mill and E mill, defining an operation signal of the coal mill of the boiler and a load W of a unit as a variable X, wherein the load is divided into two load sections W1 and W2 in combination with actual conditions, and when the unit keeps at least 3 coal mills running above the minimum technical output, the operation combination working conditions of the coal mills are discretized as follows:
from this, the vector can be obtained:
X=(X1,X2,X3···Xn);
(6) Under the operation condition of each coal mill, manually adjusting the ammonia supply quantity of each ammonia injection branch according to an ammonia injection grid adjusting method to ensure that the NOx concentration distribution of the cross section of the denitration outlet is uniform, and obtaining the functional relation among the opening Y of the ammonia supply branch valve, the scaling factor K of the coefficient amplifying module and the operation combination condition X of the coal mill:
Y=F(X),K=G(X);
(7) The opening of the motor adjusting partition ammonia supply regulating valve or the ammonia spraying branch regulating valve is circularly calculated and adjusted through the following control steps;
(71) At the setting step, a set value SP of the NOx concentration of 273.15K, 1.013X10 is given 5 The conversion value of the NOx concentration when the oxygen content is 6% under the Pa condition is entered into a timing module;
(72) Setting a Y pulse signal in a timing step through a set time, and entering a non-uniformity judging module; otherwise, the N signal is always given, the unevenness judging module is skipped, and the first to fourth deviation calculating modules are directly entered;
(73) When the timing module gives a Y signal, the system enters an unevenness judging module; at the unevenness judging module, receiving the CV signals transmitted by the calculating module, judging whether the CV signals are less than or equal to 15 percent, and entering the first to fourth deviation calculating modules if the CV signals are Y; otherwise 'N' and rapidly adjusting an ammonia injection branch regulating valve through mapping F (X);
(74) At the first to fourth deviation calculation modules, PVn output from the calculation module is input, respectively, where n=1, 2,3, 4 and the NOx set value given in the setting step; respectively calculating to obtain deviations delta 1, delta 2, delta 3 and delta 4, and correspondingly entering a first coefficient amplifying module to a fourth coefficient amplifying module;
(75) In the first to fourth coefficient amplifying modules, corresponding to K determined by the input mapping G (X) and delta obtained in the step (74), wherein K is K1, K2, K3 and K4 respectively, delta is delta 1, delta 2, delta 3 and delta 4 respectively, proportion calculation is carried out in the four coefficient amplifying modules, and K1 delta 1, K2 delta 2, K3 delta 3 and K4 delta 4 respectively enter four PID control modules;
(76) The inputs of each PID control module are k1 delta 1, k2 delta 2, k3 delta 3, k4 delta 4 and zero respectively, so that the opening degree of the partition ammonia supply regulating valve is regulated by regulating the motor;
(77) Sampling smoke corresponding to the extending positions of the ammonia spraying partitions on a flue after the denitration reactor, outputting the smoke to a sample acquisition and analysis module, and acquiring the smoke in real time and analyzing to obtain the concentration Cs of NOx and the oxygen content O of the NOx 2 The percent, the temperature Ts and the moisture content Xs are transmitted to a calculation module for calculation;
(78) In the calculation module, the original data obtained by sampling analysis is calculated to 273.15K and 1.013X10 by the following formulas 5 The calculated value Csn of the oxygen amount of NOx when the oxygen amount is 6% under the Pa condition, and the corresponding NOx concentration PVn (n=1, 2, 3. I. N) of each partition, the average value PV of the NOx concentration of the whole section and the non-uniformity CV of the NOx concentration of the sampling section are obtained through calculation of a partition ammonia injection control system;
in the i-th partition:
CV,%;PV,mg/Nm 3
(79) And the PVn, the PV and the CV obtained by the calculation module are transmitted to an upper computer, wherein the PVn is divided into one path to the first to fourth deviation calculation modules, and the CV is divided into one path to the unevenness judgment module.
CN201811607377.8A 2018-12-27 2018-12-27 Denitration partition ammonia spraying control method based on non-uniformity judgment Active CN109603525B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201811607377.8A CN109603525B (en) 2018-12-27 2018-12-27 Denitration partition ammonia spraying control method based on non-uniformity judgment

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201811607377.8A CN109603525B (en) 2018-12-27 2018-12-27 Denitration partition ammonia spraying control method based on non-uniformity judgment

Publications (2)

Publication Number Publication Date
CN109603525A CN109603525A (en) 2019-04-12
CN109603525B true CN109603525B (en) 2023-11-03

Family

ID=66011782

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201811607377.8A Active CN109603525B (en) 2018-12-27 2018-12-27 Denitration partition ammonia spraying control method based on non-uniformity judgment

Country Status (1)

Country Link
CN (1) CN109603525B (en)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110568129B (en) * 2019-09-26 2024-03-12 国能龙源环保有限公司 SCR denitration outlet mixing and zoning flue gas NOx concentration detection system and method thereof
CN111426796B (en) * 2019-12-23 2021-06-15 国能龙源环保有限公司 Detection method using gas measurement system
CN112717670A (en) * 2020-12-18 2021-04-30 华能陇东能源有限责任公司 Control device and control method for ammonia injection grid of denitration system
CN112669268B (en) * 2020-12-21 2023-06-06 昆明理工大学 Multiphase mixed concentration field distribution uniformity evaluation method, system and terminal
CN113069919B (en) * 2021-04-27 2022-09-27 国能南京电力试验研究有限公司 Calculation method for accurately correcting continuous hour-average value of NOx concentration
CN114259855A (en) * 2021-12-27 2022-04-01 国能神皖安庆发电有限责任公司 Denitration system and control method thereof
CN114870627B (en) * 2022-05-30 2023-08-01 西安热工研究院有限公司 SCR denitration partition accurate ammonia injection control method and system for coal-fired power plant

Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001198438A (en) * 2000-01-18 2001-07-24 Hitachi Zosen Corp Ammonia injection amount control method for denitration apparatus
JP2009236693A (en) * 2008-03-27 2009-10-15 Kyushu Univ Ammonia concentration measuring sensor element, ammonia concentration measuring instrument, and ammonia concentration measuring method
JP2013176733A (en) * 2012-02-28 2013-09-09 Mitsubishi Heavy Ind Ltd Denitration device and reducing agent distribution adjusting method of denitration device
JP2015075277A (en) * 2013-10-09 2015-04-20 三菱日立パワーシステムズ株式会社 Ammonia injection quantity control device and ammonia injection quantity control method
CN105854597A (en) * 2016-04-14 2016-08-17 国网河南省电力公司电力科学研究院 Ammonia spraying grating intelligent optimization and adjustment system and method for SCR denitration device
CN106237850A (en) * 2016-07-28 2016-12-21 浙江浙能技术研究院有限公司 A kind of it is applicable to the denitration Precise control method to stamp coal-burning boiler
CN106345298A (en) * 2016-10-14 2017-01-25 南京博沃科技发展有限公司 SCR denitration device as well as ammonia spraying adjustment device and ammonia spraying adjustment method thereof
CN207036795U (en) * 2017-06-06 2018-02-23 江西沃能电力科技有限公司 A kind of SCR flue gas denitration reactors section subregion flue gas sampler
CN108664006A (en) * 2018-07-02 2018-10-16 大唐环境产业集团股份有限公司 It is a kind of that ammonia optimization method and system are intelligently sprayed based on the SCR denitration of zonal control and Dynamic matrix control
CN207996570U (en) * 2018-01-04 2018-10-23 湖南华电常德发电有限公司 A kind of SCR denitration system

Patent Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001198438A (en) * 2000-01-18 2001-07-24 Hitachi Zosen Corp Ammonia injection amount control method for denitration apparatus
JP2009236693A (en) * 2008-03-27 2009-10-15 Kyushu Univ Ammonia concentration measuring sensor element, ammonia concentration measuring instrument, and ammonia concentration measuring method
JP2013176733A (en) * 2012-02-28 2013-09-09 Mitsubishi Heavy Ind Ltd Denitration device and reducing agent distribution adjusting method of denitration device
JP2015075277A (en) * 2013-10-09 2015-04-20 三菱日立パワーシステムズ株式会社 Ammonia injection quantity control device and ammonia injection quantity control method
CN105854597A (en) * 2016-04-14 2016-08-17 国网河南省电力公司电力科学研究院 Ammonia spraying grating intelligent optimization and adjustment system and method for SCR denitration device
CN106237850A (en) * 2016-07-28 2016-12-21 浙江浙能技术研究院有限公司 A kind of it is applicable to the denitration Precise control method to stamp coal-burning boiler
CN106345298A (en) * 2016-10-14 2017-01-25 南京博沃科技发展有限公司 SCR denitration device as well as ammonia spraying adjustment device and ammonia spraying adjustment method thereof
CN207036795U (en) * 2017-06-06 2018-02-23 江西沃能电力科技有限公司 A kind of SCR flue gas denitration reactors section subregion flue gas sampler
CN207996570U (en) * 2018-01-04 2018-10-23 湖南华电常德发电有限公司 A kind of SCR denitration system
CN108664006A (en) * 2018-07-02 2018-10-16 大唐环境产业集团股份有限公司 It is a kind of that ammonia optimization method and system are intelligently sprayed based on the SCR denitration of zonal control and Dynamic matrix control

Also Published As

Publication number Publication date
CN109603525A (en) 2019-04-12

Similar Documents

Publication Publication Date Title
CN109603525B (en) Denitration partition ammonia spraying control method based on non-uniformity judgment
CN105597537B (en) Denitration control method based on Prediction and Control Technology
CN108380043B (en) Selective ammonia injection regulation control method for SCR (Selective catalytic reduction) denitration device
CN106621804B (en) Flue gas ammonia injection mixing device and SCR flue gas denitration system
CN105126616B (en) SCR denitration system ammonia spraying optimization method based on weight valve regulation and control
CN205461808U (en) SCR denitration catalyst on -line measuring with spout ammonia and optimize automatic regulating system
CN111359432B (en) NOx mass flow difference distribution-based denitration ammonia injection system and method capable of realizing flexible partition
CN104102138B (en) Soft measurement based ammonia injection grid partition control method
CN104226110A (en) Coal-fired boiler SCR (Selective Catalytic Reduction) denitration control method and system
CN107544288A (en) A kind of denitration optimal control method and system
CN110585921A (en) Double-ammonia-injection grid selective catalytic reduction denitration device and ammonia injection optimization method thereof
CN110263452B (en) Flue gas time distribution characteristic analysis method and system in flue and denitration system
CN109876658B (en) Partition vortex entrainment ammonia spraying system and ammonia spraying adjusting method
CN107670474A (en) A kind of SNCR denitration system control device and denitration control method
CN105498530B (en) The method that search gas instructs spray ammonia adjustment is introduced in SCR system simulation
CN110038426A (en) A kind of frequency modulation type is intelligent to control ammonia system and method
CN114307627A (en) Denitration adjusting method based on theoretical ammonia consumption
CN113578007A (en) Coal-fired flue gas SCR denitration regulation and control system and method based on partitioned ammonia injection
CN216604710U (en) Accurate ammonia spraying automatic control device for thermal generator set
CN112569785A (en) SCR ammonia injection control system and method based on ammonia escape monitoring
CN112221323A (en) NOx partition measuring method based on flow velocity weighting
CN110960983A (en) Grid method optimization partition control method and denitration ammonia injection subsystem obtained through partition
CN113984458A (en) CEMS sampling system and method for horizontal flue of main discharge port of coal-fired unit
CN214151507U (en) Structure for rapidly measuring and feedback-controlling SCR ammonia injection amount based on concentration of NOx at outlet of induced draft fan
CN212091698U (en) Denitration ammonia injection system capable of realizing flexible partition based on NOx mass flow difference distribution

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant