CN109593407A - Formula high-efficiency cleaning film liquid and preparation method thereof is easily torn in one spray of one kind - Google Patents
Formula high-efficiency cleaning film liquid and preparation method thereof is easily torn in one spray of one kind Download PDFInfo
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- CN109593407A CN109593407A CN201811405799.7A CN201811405799A CN109593407A CN 109593407 A CN109593407 A CN 109593407A CN 201811405799 A CN201811405799 A CN 201811405799A CN 109593407 A CN109593407 A CN 109593407A
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- film liquid
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D129/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal, or ketal radical; Coating compositions based on hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Coating compositions based on derivatives of such polymers
- C09D129/02—Homopolymers or copolymers of unsaturated alcohols
- C09D129/04—Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/20—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for coatings strippable as coherent films, e.g. temporary coatings strippable as coherent films
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
Abstract
The invention discloses one sprays of one kind easily to tear formula high-efficiency cleaning film liquid, and it includes the components of following mass fraction: polyvinyl alcohol 10~15%, plasticizer 1~6%, surfactant 0.5~3%, deionized water complements to 100%.Cleaning film liquid of the invention is macromolecule emulsion film forming, by the concentration, plasticizer type and additive amount, kinds of surfactants and additive amount that are changed to membrane environment temperature, polyvinyl alcohol, determine that best film-forming process temperature is 60 DEG C, optimum proportioning polyvinyl alcohol 12%, glycerol 3.40%, sodium carboxymethylcellulose 1.35%.The Novel clean film liquid have many advantages, such as to carry and use conveniently, an environmentally friendly, at low cost, highly-safe, spray easily tears, is not necessarily to photoinitiator.
Description
Technical field
The invention belongs to detergent technical fields, and in particular to formula high-efficiency cleaning film liquid and its preparation side are easily torn in one spray of one kind
Method.
Background technique
Cleaning behavior is indispensable in industry and life, and every country is also more paid attention to for cleaning relevant research and development,
Wherein detergent is exactly an important research.From by and large, cleaning is divided into three classes: chemical cleaning, physical cleaning, micro- life
Object cleaning.
Chemical cleaning refers to the chemical method that dirt is removed from material surface.It is the most numerous with the chemical cleaning of industrial machinery
It is miscellaneous.But present chemical cleaning is primarily present the problem of security protection and liquid waste processing aspect.It is at the scene of chemical cleaning
Open fire must not be used, fire is otherwise be easy to cause；Especially when pickling, cleaning scene cannot nearby rest, and drink
Otherwise food and water are it has to be noticed that be easy to cause poisoning.In terms of liquid waste processing, alkali wash water, pickling solution and passivating solution needs are done
Some middle and high concentration waste liquids are had to neutralize, therefore can not only spend a large amount of manpower and material resources by corresponding post-processing,
And water resource can be polluted.
Physical cleaning is valued by people, and physical cleaning mode has an identical point: it is high-efficient, corrosion it is low, safety
Property it is high.Since the advanced precision instrument in industry and life now is more and more, the mode of chemically cleaning is not only easy to human body
It damages, and is easier damage instrument surface or part, therefore people are mostly used physical cleaning.But the side of physical cleaning
Formula still has some problems: (1) being rinsed with water, which will lead to, is easy corrosion by clean equipment tool, so as to shorten these tools
The service life of equipment, or even the failure and accident of equipment will be caused, the more unsuitable use of especially valuable instrument and equipment
Water rinses；(2) mode of physical cleaning is not suitable for the more complicated equipment in surface yet, will cause cleaning and is not enough；(3)
The mode of physical cleaning will cause secondary pollution toward contact.
The catalytic laundry agent that biology cleaning is generated using microorganism inner cell carries out decomposition to the dirt of cleaning object and turns
Change, reaches the lossless purpose of environmental protection.Biology cleaning is mainly used for clothes washing, cleaning of teeth, fabric desizing and eliminating sludge in pipe etc..But
It is that there is also some problems for micro-organism washing, such as: it spends the time longer using micro-organism washing, and be easy to cause microorganism
Residual, unnecessary influence may be caused on the cleaning of environment and equipment.
There are residue toxicity in existing civilian and industrial cleaners big, volatile matter atmosphere easy to pollute, damage are cleaned
The problems such as object, the cleaning of dead angle difficulty.Therefore, clear in order to study that easy to operate, effect is obvious, nontoxic corrosion-free, secondary pollution is few
Clean mode, it is necessary to find a kind of green cleaning products of suitable many-sided application, be carried out with a kind of clean quick way
Cleaning.
Summary of the invention
Goal of the invention: present invention aims in view of the deficiencies of the prior art, provide it is a kind of it is easy to use, environmentally protective,
Formula high-efficiency cleaning film liquid and preparation method thereof is easily torn in a highly-safe spray；The clean film liquid-based is in the macromolecule latex of polyvinyl alcohol
Film-forming after liquid polymerization, sprinkling or smearing, gained clean film have rippability.
Technical solution: the purpose of the invention is achieved by the following technical solution:
The present invention provides one sprays of one kind easily to tear formula high-efficiency cleaning film liquid, the component comprising following mass fraction:
Preferably, the plasticizer is selected from glycerol, polyethylene glycol, phthalic acid two (2- ethyl hexyl) ester, O-phthalic
One or more of sour di-isooctyl, dicyclohexyl phthalate DCHP.The addition of plasticizer can increase solution system
Viscosity；The addition of plasticizer reduces the hardness, brittle temperature and softening temperature of polymer, also improves the soft of polymer
Toughness and elongation shorten film formation time, and increase the flexibility of film so as to enhance the physico-chemical property of clean film.
Preferably, the surfactant is selected from sodium carboxymethylcellulose, sodium n-alkylbenzenesulfonate LAS, poly alkyl alcohol
One or more of ethylene oxide ether sodium sulfate AES, fatty alcohol polyoxyethylene ether ammonium sulfate AESA.The material tool that the present invention selects
Have and the functions such as glue and thicken, enhance, emulsify, be retained, suspend, addition surfactant can be improved system penetrating power and suction
Attached ability.
The present invention also provides the preparation methods that formula high-efficiency cleaning film liquid is easily torn in an above-mentioned spray, comprising the following steps:
(1) polyvinyl alcohol 10~15%, plasticizer 1~6%, surfactant 0.5~3% are weighed, deionized water is added
100% is complemented to, based on mass fraction；
(2) raw material of step (1) is stirred, until solid is uniformly dispersed in the solution；
The solution of (3) 10~50 DEG C of heating stepses (2), stirring to polyvinyl alcohol crystal are completely dissolved；
(4) cooling after heating, defoaming is stood to get the cleaning film liquid.
The present invention also provides the application that formula high-efficiency cleaning film liquid is easily torn in a spray, the cleaning film liquid sprinkling or smearing
In object surface to be cleaned, film-forming temperature is controlled at 30~90 DEG C, and 60~120min of film formation time is solidified into clean film.
Cleaning film liquid of the invention can form a film on object surface to be cleaned or inside.Film liquid ingredient includes film forming agent, plasticising
Agent, surfactant etc. have adhesion strength after film liquid solidification, can be by fine particle (such as dust on object surface to be cleaned or inside
Deng) absorption, while the surfactant for cleaning film liquid itself and containing can dissolve object surface and oil contaminant to be cleaned.Therefore the cleaning film liquid
Have the characteristics that carry and use conveniently, an environmentally protective, spray easily tears, is highly-safe.
The present invention is cured as clean film for film liquid is cleaned, and carries out performance detection；Wherein, clean film the preparation method is as follows:
A release film is taken, respectively puts one piece of aluminium flake with a thickness of 1mm in release film periphery.Cleaning film liquid is drawn with disposable dropper,
Slowly on release film of the drop between aluminium flake.It after the completion of dropping liquid, is covered with another release film, sample is made.By gained sample
Dry, temperature control is at 30~90 DEG C, 60~120min of film formation time.After film forming, clean film is removed from release film, is tested
The performance of clean film.
Clean the performance indicator of film liquid:
Film liquid is cleaned as a kind of novel product, it should which properties required for meeting in the market, cleaning film liquid are main
The angle of clean film is tested after film forming, and the main performance of film has mechanical property, shock resistance etc., and the following are five kinds
The test of performance indicator.
(1) tensile property-film detects its tensile strength and extension at break by universal testing machine under tension test
Rate, using standard GB/T/T13022-1991 " stretched plastic film method for testing performance ", which is adopting by equivalent national standard
ISO1184-1983 " measurement of stretched plastic film performance ".
(2) film formation time --- in an experiment, since solvent deploy complete smear after start to be fully cured film forming used in the time
As film formation time.
(3) film-forming temperature -- temperature has a major impact macromolecule emulsion film-forming process.Detergent should have season general
Adaptive, therefore clean film liquid and need normally form a film under various circumstances.
(4) qualitative analysis -- every composition in analysis sample is better understood by the performance of sample, according to GB/
The method of preparing sample of solid is prepared experimental sample in T32198-2015 " IR spectrum quantitative analysis technology general rule ", from red
The data detected in external spectrum analyzer can form image in computer, then be divided using spectral subtraction method data
Analysis first calculates data using matrix inversion, is then adjusted with the curvature correction in Beer law figure to deviation data, finally
Statistical estimation.
(5) clean-up performance -- the detersive efficiency of detection cleaning film liquid, simulation clean film effect in use.This index
There has been no unification of the motherland standard, project team uses following detection method by experiment repeatedly: smearing in bright and clean article surface dirty
Object is contaminated, by gross mass after cleaning and the difference for cleaning preceding quality than upper pollutant quality, obtains detersive efficiency.It is better understood by clear
The actual conditions of clean film liquid promote the improvement of product.
The invention proposes cleaning film liquid new concept, the preparation method for the cleaning film liquid having studied simultaneously examines its performance
It surveys.It is believed that cleaning film liquid can be widely applied in civilian, industrial or even military industry field after follow-up study improves, society is given
Huge change and convenience can be brought, people's lives, the quality of production are improved；And since its material is environment friendly and pollution-free, performance
Good, cleaning film liquid has great application prospect.
Cleaning most of used in the preparation process of film liquid is all nontoxic raw material, and after acquired solution film forming
Volatility substantially reduces, safety when having ensured research, having used.
In use, only cleaning film liquid of the invention need to be sprayed on stained surface using watering can or be applied to object table with utensil
Face, spot can be removed by solidifying latter tear, and this product has preferable cleaning effect to oils, industrial instrumentation, easy to operate, be used
It is convenient.
The utility model has the advantages that
(1) cleaning film liquid of the invention is easy to use, clean and environmental protection, does not all injure to human body, machine and environment.It will be clear
The clean spray of film liquid one (or one brush) one, which is torn, can be completed cleaning, relative to the risk of chemical cleaning, the environmental pollution of physical cleaning
With damage machine, there are also the residuals of micro-organism washing, clean the cleaning mode very simple of film liquid, and it is next auxiliary not need other equipment
It helps.
(2) cleaning film liquid of the invention is macromolecule emulsion film forming.In macromolecule emulsion film forming, by changing film-forming ring
Border temperature, the concentration of polyvinyl alcohol, plasticizer type and additive amount, kinds of surfactants and additive amount determine best film forming
Technological temperature is 60 DEG C, film formation time 80min, optimum proportioning: deionized water 83.25%, polyvinyl alcohol 12%, glycerol
3.40%, the tensile strength of sodium carboxymethylcellulose 1.35%, gained clean film is 3.5MPa, and elongation at break is
216.54%.The Novel clean film liquid have carry and use conveniently, it is environmentally friendly, highly-safe, at low cost, one spray easily tear, be not necessarily to
The advantages that photoinitiator.
Specific embodiment
Technical solution of the present invention is described in detail below by specific embodiment, but protection scope of the present invention is not
It is confined to the embodiment.
Test method as used in the following examples is conventional method unless otherwise specified, used raw material, reagent
Deng unless otherwise specified, being can raw materials and reagents obtained from commercial sources such as regular market purchases.
Primary raw material and its source:
Polyvinyl alcohol (AR): Anhui Province ties up new high-tech material Co., Ltd.
Plasticizer glycerol (AR): Shandong Fu Fu new material Science and Technology Ltd..
Sodium carboxymethylcellulose (AR): Xuzhou Li Yuan cellulose Science and Technology Ltd..
Embodiment 1
(1) polyvinyl alcohol 10g, glycerol 1g, sodium carboxymethylcellulose 0.5g are weighed, deionized water 88.5g is added；
(2) raw material of step (1) is stirred 10min, until solid is uniformly dispersed in the solution；
The solution 5min of (3) 10 DEG C of heating stepses (2), stirring to polyvinyl alcohol crystal are completely dissolved；
(4) cooling after heating, 5min defoaming is stood to get the cleaning film liquid.Have in solution after being vigorously stirred
A large amount of microbubble must wait until completely eliminating, otherwise will affect into film outward appearance and performance.
Performance test:
A release film is taken, respectively puts one piece of aluminium flake with a thickness of 1mm in release film periphery.It is drawn with disposable dropper clear
Clean film liquid, slowly on release film of the drop between aluminium flake.It after the completion of dropping liquid, is covered with another release film, sample is made.By institute
Samples dried, temperature control is at 30 DEG C, film formation time 120min.After film forming, clean film is removed from release film, test is clear
The performance of clean film.
Test result: elongation at break 135.44%, tensile strength 3.85MPa.Detersive efficiency 71.57%.
Embodiment 2
(1) polyvinyl alcohol 12g, glycerol 1g, polyethylene glycol 200 2g, sodium carboxymethylcellulose 1g are weighed, deionized water is added
84g；
(2) raw material of step (1) is stirred 12min, until solid is uniformly dispersed in the solution；
The solution 6min of (3) 20 DEG C of heating stepses (2), stirring to polyvinyl alcohol crystal are completely dissolved；
(5) cooling after heating, 7min defoaming is stood to get the cleaning film liquid.Have in solution after being vigorously stirred
A large amount of microbubble must wait until completely eliminating, otherwise will affect into film outward appearance and performance.
Performance test:
Using the cleaning membrane preparation method of embodiment 1, temperature control is at 50 DEG C, film formation time 100min.Test clean film
Performance.
It measures: elongation at break 201.41%, tensile strength 3.73MPa.Detersive efficiency 74.44%.
Embodiment 3
(1) polyvinyl alcohol 15g, glycerol 4g, polyethylene glycol 200 2g, sodium carboxymethylcellulose 3g are weighed, deionized water is added
76g；
(2) raw material of step (1) is stirred 15min, until solid is uniformly dispersed in the solution；
The solution 8min of (3) 40 DEG C of heating stepses (2), stirring to polyvinyl alcohol crystal are completely dissolved；
(6) cooling after heating, 10min defoaming is stood to get the cleaning film liquid.In solution after being vigorously stirred
There is a large amount of microbubble, must wait until completely eliminating, otherwise will affect into film outward appearance and performance.
Performance test:
Using the cleaning membrane preparation method of embodiment 1, temperature control is at 90 DEG C, film formation time 60min.Test clean film
Performance.
It measures: elongation at break 275.49%, tensile strength 3.04MPa.Detersive efficiency 73.11%.
Embodiment 4
(1) polyvinyl alcohol 10g, glycerol 2g, polyethylene glycol 400 2g, diisooctyl phthalate 2g, poly alkyl alcohol are weighed
Deionized water 81g is added in ethylene oxide ether sodium sulfate AES 3g；
(2) raw material of step (1) is stirred 10min, until solid is uniformly dispersed in the solution；
The solution 10min of (3) 50 DEG C of heating stepses (2), stirring to polyvinyl alcohol crystal are completely dissolved；
(7) cooling after heating, 10min defoaming is stood to get the cleaning film liquid.In solution after being vigorously stirred
There is a large amount of microbubble, must wait until completely eliminating, otherwise will affect into film outward appearance and performance.
Performance test:
Using the cleaning membrane preparation method of embodiment 1, temperature control is at 60 DEG C, film formation time 90min.Test clean film
Performance.
It measures: elongation at break 221.36%, tensile strength 2.84MPa.Detersive efficiency 78.74%.
Embodiment 5
(1) polyvinyl alcohol 10g, glycerol 3g, sodium carboxymethylcellulose 1g, sodium n-alkylbenzenesulfonate LAS 1g, rouge are weighed
Deionized water 84g is added in fat alcohol polyethenoxy ether sodium sulfate AES 1g；
(2) raw material of step (1) is stirred 12min, until solid is uniformly dispersed in the solution；
(3) 30 DEG C of heating.The solution 8min of step (2), stirring to polyvinyl alcohol crystal are completely dissolved；
(8) cooling after heating, 8min defoaming is stood to get the cleaning film liquid.Have in solution after being vigorously stirred
A large amount of microbubble must wait until completely eliminating, otherwise will affect into film outward appearance and performance.
Performance test:
Using the cleaning membrane preparation method of embodiment 1, temperature control is at 40 DEG C, film formation time 110min.Test clean film
Performance.
It measures: elongation at break 174.23%, tensile strength 3.66MPa.Detersive efficiency 76.92%.
Embodiment 6
(1) polyvinyl alcohol 12g, glycerol 3.4g, sodium carboxymethylcellulose 1.35g are weighed, deionized water 83.25g is added；
(2) raw material of step (1) is stirred 10min, until solid is uniformly dispersed in the solution；
The solution 10min of (3) 20 DEG C of heating stepses (2), stirring to polyvinyl alcohol crystal are completely dissolved；
(4) cooling after heating, 10min defoaming is stood to get the cleaning film liquid.In solution after being vigorously stirred
There is a large amount of microbubble, must wait until completely eliminating, otherwise will affect into film outward appearance and performance.
Performance test:
Using the cleaning membrane preparation method of embodiment 1, temperature control is at 60 DEG C, film formation time 80min.Test clean film
Performance.
It measures: elongation at break 216.54%, tensile strength 3.5MPa.Detersive efficiency 80.28%.
Reference examples 1
In this reference examples, plasticizer and surfactant are not added in technique, other components and technique are same as Example 1.
It measures: elongation at break 135.78%, tensile strength 1.73MPa.Detersive efficiency 5.28%.
High-efficiency cleaning film liquid of the invention using watering can in use, only need to be sprayed on stained surface or be applied to object with utensil
Surface, spot can be removed by solidifying latter tear, and this product has preferable cleaning effect to oils, industrial instrumentation, easy to operate, peace
Quan Xinggao, it is environmentally protective, it is easy to use.
As described above, must not be explained although the present invention has been indicated and described referring to specific preferred embodiment
For the limitation to invention itself.It without prejudice to the spirit and scope of the invention as defined in the appended claims, can be right
Various changes can be made in the form and details for it.
Claims (5)
1. formula high-efficiency cleaning film liquid is easily torn in one spray of one kind, which is characterized in that the component comprising following mass fraction:
2. formula high-efficiency cleaning film liquid is easily torn in a spray according to claim 1, which is characterized in that the plasticizer is selected from sweet
Oil, polyethylene glycol, phthalic acid two (2- ethyl hexyl) ester, diisooctyl phthalate, dicyclohexyl phthalate
One or more of DCHP.
3. formula high-efficiency cleaning film liquid is easily torn in a spray according to claim 1, which is characterized in that the surfactant is selected from
Sodium carboxymethylcellulose, sodium n-alkylbenzenesulfonate LAS, sodium sulfate of polyethenoxy ether of fatty alcohol AES, fatty alcohol polyoxyethylene ether
One or more of ammonium sulfate AESA.
4. the preparation method of formula high-efficiency cleaning film liquid is easily torn in described in any item sprays according to claim 1~3, feature exists
In, comprising the following steps:
(1) polyvinyl alcohol 10~15%, plasticizer 1~6%, surfactant 0.5~3% are weighed, deionized water is added and supplies
To 100%, based on mass fraction；
(2) raw material of step (1) is stirred, until solid is uniformly dispersed in the solution；
The solution of (3) 10~50 DEG C of heating stepses (2), stirring to polyvinyl alcohol crystal are completely dissolved；
(4) cooling after heating, defoaming is stood to get the cleaning film liquid.
5. the application of formula high-efficiency cleaning film liquid is easily torn in described in any item sprays according to claim 1~3, which is characterized in that institute
It states the sprinkling of cleaning film liquid or is applied to object surface to be cleaned, film-forming temperature is controlled at 30~90 DEG C, 60~120min of film formation time,
It is solidified into clean film.
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| CN201811405799.7A CN109593407A (en) | 2018-11-23 | 2018-11-23 | Formula high-efficiency cleaning film liquid and preparation method thereof is easily torn in one spray of one kind |
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Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3325312A1 (en) * | 1983-07-13 | 1985-01-24 | Agfa-Gevaert Ag, 5090 Leverkusen | Method of cleaning the surface of information carriers |
| GB2191717A (en) * | 1986-06-19 | 1987-12-23 | Gramos Chemicals International | Preparing a coated product having at least one strippable coating |
| EP0681875A1 (en) * | 1994-05-06 | 1995-11-15 | Kajima Corporation | Method for peeling off dirt from wall surface by using peelable polymer membrane |
| JP2002045811A (en) * | 2000-05-22 | 2002-02-12 | Shimizu Corp | Method for cleaning surface |
| CN101394942A (en) * | 2006-02-28 | 2009-03-25 | 细胞生物工程有限公司 | Polymer composition and method for removing contaminates from a substrate |
| CN103214903A (en) * | 2013-03-27 | 2013-07-24 | 北京鸿业润升科技有限公司 | Peelable nano-grade decontamination coating |
| CN106635498A (en) * | 2016-12-15 | 2017-05-10 | 南京工业职业技术学院 | Recyclable environment-friendly cleaning agent, and preparation and application method thereof |
-
2018
- 2018-11-23 CN CN201811405799.7A patent/CN109593407A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3325312A1 (en) * | 1983-07-13 | 1985-01-24 | Agfa-Gevaert Ag, 5090 Leverkusen | Method of cleaning the surface of information carriers |
| GB2191717A (en) * | 1986-06-19 | 1987-12-23 | Gramos Chemicals International | Preparing a coated product having at least one strippable coating |
| EP0681875A1 (en) * | 1994-05-06 | 1995-11-15 | Kajima Corporation | Method for peeling off dirt from wall surface by using peelable polymer membrane |
| JP2002045811A (en) * | 2000-05-22 | 2002-02-12 | Shimizu Corp | Method for cleaning surface |
| CN101394942A (en) * | 2006-02-28 | 2009-03-25 | 细胞生物工程有限公司 | Polymer composition and method for removing contaminates from a substrate |
| CN103214903A (en) * | 2013-03-27 | 2013-07-24 | 北京鸿业润升科技有限公司 | Peelable nano-grade decontamination coating |
| CN106635498A (en) * | 2016-12-15 | 2017-05-10 | 南京工业职业技术学院 | Recyclable environment-friendly cleaning agent, and preparation and application method thereof |
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Application publication date: 20190409 |