CN109577022A - 一种用于户外服装的抗菌染料 - Google Patents

一种用于户外服装的抗菌染料 Download PDF

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CN109577022A
CN109577022A CN201811499605.4A CN201811499605A CN109577022A CN 109577022 A CN109577022 A CN 109577022A CN 201811499605 A CN201811499605 A CN 201811499605A CN 109577022 A CN109577022 A CN 109577022A
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outdoor wear
antibacterial
antibacterial dye
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刘战鹰
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Hefei Yingshibo Outdoor Technology Co Ltd
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Abstract

一种用于户外服装的抗菌染料，由以下重量份数的原料组成：聚酰胺树脂25～35份、甲壳素5～11份、二苯甲酮12～20份、吖啶稠环烃10～16份、微晶纤维素8～12份、有机羧酸化合物11～15份、聚二甲基硅氧烷12～16份、脂肪醇聚氧乙烯醚6～8份、荧光剂2～6份、光稳定剂3～7份、去离子水40～50份。本发明的有益效果为：本发明所述染料不仅环保性强，其给面料带来的抗菌效果也是极佳的；用该抗菌染料所染色的面料不仅无异味，同时还具有在黑暗下发荧光的效果，给夜间户外运动者安全系数得到了一定的保障。

Description

一种用于户外服装的抗菌染料
技术领域
本发明属于户外服装域，具体涉及一种用于户外服装的抗菌染料。
背景技术
户外环境复杂多变，为抵御恶劣环境对人体的伤害，保护身体热量不被散失以及快速排出运动时所产生的汗水，在登山、攀岩及其他户外运动时，应该做到分层着装。
经常在户外的人们知道，户外环境恶劣，晚间行走或者在森林中行走都是常有的事情，所以户外运动者都会选择颜色鲜艳的服装，以便于队友或者救援者发现自己。
现有户外服装染色技术中，一般都会考虑染料的颜色或者环保性，但是都忽略了染料的抗菌性能，由于在户外运动者们都会出现长时间不能更换衣物，衣物上的汗渍等污渍会导致细菌的滋生，给人们健康带来安全隐患。
发明内容
本发明所要解决的技术问题在于：现有户外服装染色技术中都忽略了染料的抗菌性能。为此，提供一种用于户外服装的抗菌染料。
为解决上述技术问题，本发明的技术方案为：
一种用于户外服装的抗菌染料，由以下重量份数的原料组成：聚酰胺树脂25～35份、甲壳素5～11份、二苯甲酮12～20份、吖啶稠环烃10～16份、微晶纤维素8～12份、有机羧酸化合物11～15份、聚二甲基硅氧烷12～16份、脂肪醇聚氧乙烯醚6～8份、荧光剂2～6份、光稳定剂3～7份、去离子水40～50份。
进一步的，由以下重量份数的原料组成：聚酰胺树脂25份、甲壳素5份、二苯甲酮12份、吖啶稠环烃10份、微晶纤维素8份、有机羧酸化合物11份、聚二甲基硅氧烷12份、脂肪醇聚氧乙烯醚6份、荧光剂2份、光稳定剂3份、去离子水40份。
进一步的，由以下重量份数的原料组成：聚酰胺树脂35份、甲壳素11份、二苯甲酮20份、吖啶稠环烃16份、微晶纤维素12份、有机羧酸化合物15份、聚二甲基硅氧烷16份、脂肪醇聚氧乙烯醚8份、荧光剂6份、光稳定剂7份、去离子水50份。
进一步的，由以下重量份数的原料组成：聚酰胺树脂30份、甲壳素8份、二苯甲酮16份、吖啶稠环烃13份、微晶纤维素10份、有机羧酸化合物13份、聚二甲基硅氧烷14份、脂肪醇聚氧乙烯醚7份、荧光剂4份、光稳定剂5份、去离子水45份。
进一步的，所述光稳定剂选自酞菁蓝、酞菁绿中的至少一种。
进一步的，所述荧光剂为荧光增白剂JD-3 。
进一步的，上述户外服装抗菌染料制备方法为：将上述重量份数的原料在常温下经过充分混合40～50min既得上述户外服装抗菌染料。
太阳光中的紫外线是对高分子材料产生老化作用的主要原因。紫外线虽然仅占太阳光的5%左右，但是能量却很大。高分子聚合物制品吸收紫外线后，足以能引发聚合物自我氧化、降解，破坏聚合物的化学键，使其断裂、交联，导致高分子聚合物制品颜色等外观和物理力学性能发生恶变，强度降低、寿命缩短。这一过程称为光氧化还原或光老化作用。紫外线也能穿过人的皮肤表层，破坏皮肤细胞，使皮肤逐渐变硬而失去弹性，出现皱纹和加快衰老。
光稳定剂因自身结构和品种的不同而有不同的功能。有的可以屏蔽、反射紫外线或吸收紫外线并将其转化为无害的热能；有的可猝灭被紫外线激发的分子或基团的激发态，使其回复到基态，排除或减缓了发生光氧化还原反应的可能性；有的因捕获因光氧化还原产生的自由基，从而阻止了导致制品老化的自由基反应，使制品免遭紫外线破坏。
在本发明中加入光稳定剂，具体为一种光屏蔽剂：这是一类能够遮蔽或反射紫外线的物质，使光不能透入高分子内部，从而起到保护高分子的作用。本发明中加入的光屏蔽剂为酞菁蓝、酞菁绿等有机颜料，可以使得染料具有良好的防紫外线能力。
荧光剂，能吸收入射光线产生荧光，使所染物质获得类似荧石的闪闪发光的效应，使肉眼看到的物质很白，达到增白的效果。在本发明中加入荧光剂可以使得户外服装在黑暗环境中能够被容易识别，使穿着者容易被队友发现，提高户外穿着者的安全系数。
甲壳素，甲壳素应用范围很广泛，在工业上可做布料、衣物、染料、纸张和水处理等。在农业上可做杀虫剂、植物抗病毒剂。渔业上做养鱼饲料。它是一种线型的高分子多糖，即天然的中性粘多糖，若经浓碱处理去掉乙酰基即得脱乙酰壳多糖。甲壳质化学上不活泼，不与体液发生变化，对组织不起异物反应，无毒，具有抗血栓、耐高温消毒等特点。甲壳素的吸水率高达1300%，1克的甲壳素吸饱水后可以达到13克，甲壳素具有天然抑菌功效，广谱抗菌率非常高，90%以上的常见细菌在甲壳素纤维上不能存活；因此甲壳素纤维与彩棉货纯棉等纤维制成的面料特别适合做婴幼儿服装及男女高档内衣。在本发明中加入甲壳素可以大大的提高染料的抗菌能力，最终使用该染料的服装在抗菌性能上效果比较好。
本发明的有益效果为：本发明所述染料不仅环保性强，其给面料带来的抗菌效果也是极佳的；用该抗菌染料所染色的面料不仅无异味，同时还具有在黑暗下发荧光的效果，给夜间户外运动者安全系数得到了一定的保障。
具体实施方式
为使对本发明的结构特征及所达成的功效有更进一步的了解与认识，用以较佳的实施例配合详细的说明，说明如下：
实施例1
一种用于户外服装的抗菌染料，由以下重量份数的原料组成：聚酰胺树脂25份、甲壳素5份、二苯甲酮12份、吖啶稠环烃10份、微晶纤维素8份、有机羧酸化合物11份、聚二甲基硅氧烷12份、脂肪醇聚氧乙烯醚6份、荧光剂2份、光稳定剂3份、去离子水40份。
其中，所述光稳定剂选自酞菁蓝、酞菁绿中的至少一种；所述荧光剂为荧光增白剂JD-3 。
上述户外服装抗菌染料制备方法为：将上述重量份数的原料在常温下经过充分混合40min既得上述户外服装抗菌染料。
实施例2
一种用于户外服装的抗菌染料，由以下重量份数的原料组成：聚酰胺树脂35份、甲壳素11份、二苯甲酮20份、吖啶稠环烃16份、微晶纤维素12份、有机羧酸化合物15份、聚二甲基硅氧烷16份、脂肪醇聚氧乙烯醚8份、荧光剂6份、光稳定剂7份、去离子水50份。
其中，所述光稳定剂选自酞菁蓝、酞菁绿中的至少一种；所述荧光剂为荧光增白剂JD-3 。
上述户外服装抗菌染料制备方法为：将上述重量份数的原料在常温下经过充分混合50min既得上述户外服装抗菌染料。
实施例3
一种用于户外服装的抗菌染料，由以下重量份数的原料组成：聚酰胺树脂30份、甲壳素8份、二苯甲酮16份、吖啶稠环烃13份、微晶纤维素10份、有机羧酸化合物13份、聚二甲基硅氧烷14份、脂肪醇聚氧乙烯醚7份、荧光剂4份、光稳定剂5份、去离子水45份。
其中，所述光稳定剂选自酞菁蓝、酞菁绿中的至少一种；所述荧光剂为荧光增白剂JD-3 。
上述户外服装抗菌染料制备方法为：将上述重量份数的原料在常温下经过充分混合45min既得上述户外服装抗菌染料。
使用上述实施例1至3中所得抗菌染料，在抑菌测试上，使用上述实施例1至3中染料染色所得面料和普通染料染色之后的面料，经过相同使用方法、时间等处理之后，检测面料表面细菌含量，发现上述实施例1至3中所得抗菌染料染色的面料比普通染料染色的面料细菌含量要低85～95%。
以上显示和描述了本发明的基本原理、主要特征和本发明的优点。本行业的技术人员应该了解，本发明不受上述实施例的限制，上述实施例和说明书中描述的只是本发明的原理，在不脱离本发明精神和范围的前提下本发明还会有各种变化和改进，这些变化和改进都落入要求保护的本发明的范围内。本发明要求的保护范围由所附的权利要求书及其等同物界定。

Claims (7)

1.一种用于户外服装的抗菌染料，其特征在于：由以下重量份数的原料组成：聚酰胺树脂25～35份、甲壳素5～11份、二苯甲酮12～20份、吖啶稠环烃10～16份、微晶纤维素8～12份、有机羧酸化合物11～15份、聚二甲基硅氧烷12～16份、脂肪醇聚氧乙烯醚6～8份、荧光剂2～6份、光稳定剂3～7份、去离子水40～50份。
2.根据权利要求1所述的一种用于户外服装的抗菌染料，其特征在于：由以下重量份数的原料组成：聚酰胺树脂25份、甲壳素5份、二苯甲酮12份、吖啶稠环烃10份、微晶纤维素8份、有机羧酸化合物11份、聚二甲基硅氧烷12份、脂肪醇聚氧乙烯醚6份、荧光剂2份、光稳定剂3份、去离子水40份。
3.根据权利要求1所述的一种用于户外服装的抗菌染料，其特征在于：由以下重量份数的原料组成：聚酰胺树脂35份、甲壳素11份、二苯甲酮20份、吖啶稠环烃16份、微晶纤维素12份、有机羧酸化合物15份、聚二甲基硅氧烷16份、脂肪醇聚氧乙烯醚8份、荧光剂6份、光稳定剂7份、去离子水50份。
4.根据权利要求1所述的一种用于户外服装的抗菌染料，其特征在于：由以下重量份数的原料组成：聚酰胺树脂30份、甲壳素8份、二苯甲酮16份、吖啶稠环烃13份、微晶纤维素10份、有机羧酸化合物13份、聚二甲基硅氧烷14份、脂肪醇聚氧乙烯醚7份、荧光剂4份、光稳定剂5份、去离子水45份。
5.根据权利要求1至4中任一项所述的一种用于户外服装的抗菌染料，其特征在于：所述光稳定剂选自酞菁蓝、酞菁绿中的至少一种。
6.根据权利要求1至4中任一项所述的一种用于户外服装的抗菌染料，其特征在于：所述荧光剂为荧光增白剂JD-3 。
7.根据权利要求1至4中任一项所述的一种用于户外服装的抗菌染料，其特征在于：上述户外服装抗菌染料制备方法为：将上述重量份数的原料在常温下经过充分混合40～50min既得上述户外服装抗菌染料。
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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106120383A (zh) * 2016-07-18 2016-11-16 南通富之岛寝具发展有限公司 一种耐高温抗菌染料
CN107724126A (zh) * 2017-10-23 2018-02-23 南通海高纺织品有限公司 纺织染料
CN108589328A (zh) * 2018-05-29 2018-09-28 安徽英士博纺织发展有限公司 一种户外服装生产用新型染料
CN108914653A (zh) * 2018-06-17 2018-11-30 安徽找宝纺织科技有限公司 一种酸性阳离子交换纤维的染色方法

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106120383A (zh) * 2016-07-18 2016-11-16 南通富之岛寝具发展有限公司 一种耐高温抗菌染料
CN107724126A (zh) * 2017-10-23 2018-02-23 南通海高纺织品有限公司 纺织染料
CN108589328A (zh) * 2018-05-29 2018-09-28 安徽英士博纺织发展有限公司 一种户外服装生产用新型染料
CN108914653A (zh) * 2018-06-17 2018-11-30 安徽找宝纺织科技有限公司 一种酸性阳离子交换纤维的染色方法

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