CN109576759A - A kind of construction method of titanium building materials for building - Google Patents
A kind of construction method of titanium building materials for building Download PDFInfo
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- CN109576759A CN109576759A CN201811515110.6A CN201811515110A CN109576759A CN 109576759 A CN109576759 A CN 109576759A CN 201811515110 A CN201811515110 A CN 201811515110A CN 109576759 A CN109576759 A CN 109576759A
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- titanium plate
- titanium
- building
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D11/00—Electrolytic coating by surface reaction, i.e. forming conversion layers
- C25D11/02—Anodisation
- C25D11/26—Anodisation of refractory metals or alloys based thereon
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D7/00—Electroplating characterised by the article coated
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
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Abstract
The present invention provides a kind of construction methods of titanium building materials for building, including step 1: cutting titanium plate, and carries out surface mechanical polishing and first time oil removal treatment；Step 2: processing connecting hole or connection structure in titanium plate, and is bent, embossed, acid etching molding；Step 3: titanium plate being placed into electrolytic cell and carries out cell reaction, and titanium plate surface anodization is made to generate sull, takes out the electrolyte of titanium plate and clean the surface；Step 4: titanium plate is placed into boiling water and decocts progress surface-sealing；Wherein, added with fat-soluble pigment in the electrolyte in step 3.The present invention has the characteristics that construction method is simple, the service life is long, use scope is wide.
Description
Technical field
The present invention relates to building material technical fields, more particularly to a kind of construction method of titanium building materials for building.
Background technique
With building, the fast development of architectural decoration, people are to visually the requirement of effect is got on building color
Come higher.
Wherein, historical building is also a kind of need cultural assets to be protected, existing palace, temple, natural science in building
The roof of the buildings such as shop is built using copper material, but with the deterioration of the natural environments such as atmosphere, acid rain, the surface of copper material can be sour
Rain corrosion generates patina, or even copper material surface corrosion can be gone out aperture, reduces the service life of the building.Wherein, with people
Requirement to living environment, tourist district be continuously improved, more and more more tend to build building beautiful, that vision is comfortable.
Meanwhile in recent years since titanium plate has the characteristics that corrosion resistance, heat resistance, lightweight, titanium plate as building materials,
Ornaments raw material is widely used.Moreover, because titanium oxide be it is colorless and transparent, building can be made under the interference of light
Multiple color is presented, there is good decoration function.Under non-illumination, titanium plate is rendered as the color of titanium plate itself, can make to build
Object or ornament are intensely dark.
Accordingly, it is desirable to provide color can be presented under light illumination and also have corresponding color under non-light conditions for one kind
Color building materials.
Summary of the invention
That the purpose of the present invention is to provide a kind of construction methods is simple, the service life is long, use scope is wide, under various circumstances still
The titanium building materials construction method for building of color can be shown.
Realize that the technical solution of goal of the invention is as follows: a kind of construction method of titanium building materials for building, comprising:
Step 1: titanium plate is cut, and carries out surface mechanical polishing and first time oil removal treatment；
Step 2: processing connecting hole or connection structure in titanium plate, and is bent, embossed, acid etching molding；
Step 3: titanium plate being placed into electrolytic cell and carries out cell reaction, and titanium plate surface anodization is made to generate oxide
Film takes out the electrolyte of titanium plate and clean the surface；
Step 4: titanium plate is placed into boiling water and decocts progress surface-sealing；
Wherein, added with fat-soluble pigment in the electrolyte in step 3.
As a further improvement of the present invention, fat-soluble pigment is synthetic dyestuff, and fat-soluble pigment concentration in electrolyte
It is 5~30%, the colorant selection of low concentration, titanium plate surface can adhere to one layer of light colorant, prevent from largely colouring
The case where agent is enriched in the aperture on oxidation film, causes hyperchromatosis.
As a further improvement of the present invention, cell reaction specific steps in step 3 are as follows:
A, power on, be electrochemically reacted；Power supply is closed, chemical reaction and titanium plate coloring are carried out.When power supply is connected,
It is electrochemically reacted, in the film of titanium plate Surface Creation titanium dioxide and titanium monoxide, while a small amount of two on titanium plate surface
Titanium oxide is by the acid dissolution in electrolyte；When power supply disconnects, is chemically reacted, further make the titanium dioxide quilt on titanium plate surface
The molten multiple apertures of generation of acid in electrolyte；
B, it repeats to power on and disconnect power supply in step a, titanium plate surface is made to carry out cell reaction and chemical reaction circulation
It is generated to oxidation film.In electrochemical reaction and chemical reaction process, the colorant in electrolyte can be in the oxygen on titanium plate surface
Change deposition in the aperture in film to colour titanium plate.
As a further improvement of the present invention, 10~110V of voltage of power supply, and the switched on and off time ratio of power supply is
3:2.In order to colour titanium plate uniformly, increase the thickness of oxidation film constantly, colorant attachment area is deepened, coloring
Uniformly；Power supply is chemically reacted when disconnecting, and is dissolved the titanium dioxide in the oxide layer on titanium plate surface and is formed aperture, makes
Toner deposition coloring.
As a further improvement of the present invention, in step a, cooling device is connected while closing power supply, cooling device is used
Cool down in electrolyte, reduce the formation of aperture on sull and promote deposition of the fat-soluble pigment on aperture,
The concentration for preventing aperture inner coloring agent from adhering to is excessive.
As a further improvement of the present invention, cooling device is cold water cooling device, and cold water temperature is 0~10 DEG C, is passed through
The cooling of cooling device, the chemical reaction that can inhibit and slow down titanium plate surface film oxide generates aperture, and makes to be deposited in aperture
Pigment be not easy to be discharged outside aperture, making to colour pigment in titanium plate in oxidation film reduces, titanium plate surface generate one layer it is light
Color.
As a further improvement of the present invention, the face of design is presented to guarantee the building built using titanium plate in illumination
Color needs to be sufficiently formed oxidation film in cell reaction, in step a, the switched on and off circulation of power supply 3~4 times.
Compared with prior art, the invention has the advantage that:
1. select construction of the titanium plate as building, can avoid because being contacted for a long time with atmosphere, corroded by acid rain, dust storm etc. and
It destroys, increases the service life of Historical Buildings, reduce the Maintenance and Repair cost of Historical Buildings, reduce the work of operating personnel
Intensity and security risk.
2. building is for visit of travelling, living uses, the house that the titanium plate after colorant colours is built will not be because outer
The variation of boundary's environment and generate huge variation, even if night, rainy days anomalous weather under, the color of building surface
It can be not much different with the color of building under daytime or fair weather.
Specific embodiment
Invention is described in detail in following each embodiment, but it should be stated that, these embodiments are not pair
Limitation of the invention, those of ordinary skill in the art according to these embodiments made by function, method or structure etc.
Effect transformation or substitution, all belong to the scope of protection of the present invention within.
Embodiment 1:
In the present embodiment, a kind of construction method of titanium building materials for building, comprising the following steps:
Step 1: cutting the titanium plate with a thickness of 1.5cm, and carry out surface mechanical polishing and with acetone and alcohol to titanium plate into
Row oil removal treatment；
Step 2: processing connecting hole in titanium plate, and titanium plate is bent into circular open and close type domed shape, and with acid etching or
Person carves out shape；
Electrolytic cell is put into 4 DEG C of cold water by step 3, then by titanium plate be put into added with 10.0% it is light blue fat-soluble
In the electrolyte of color liquid, electrolyte be 1.0% hydrofluoric acid, 3.0% phosphoric acid, 0.5% hydrogen peroxide mixed solution, connect 40 ±
The power supply of 1v, is first electrochemically reacted 15min, in titanium plate Surface Creation titanium dioxide and titanium monoxide, while titanium plate surface
A small amount of titanium dioxide by the acid dissolution in electrolyte；When power supply disconnects, chemical reaction 10min is carried out, titanium plate surface is made
For titanium dioxide by the molten multiple apertures of generation of acid in electrolyte, being formed makes the oxidation film on titanium plate surface form porous layer, and makes electricity
Pale blue fat-soluble pigment in solution liquid is deposited in aperture, and power supply is opened and disconnection is electrochemically reacted and chemically reacts circulation
3 times, the generation of titanium plate surface oxide layer and the coloring of oxide layer are completed, then titanium plate is taken out to rapidly the electrolysis of simultaneously clean the surface
Liquid；
Step 4: titanium plate surface coloring liquid is cleaned with deionized water, and titanium plate is placed into decoct in boiling water and carries out surface
Sealing of hole, naturally dry must colour after titanium plate building materials.
Embodiment 2:
In the present embodiment, a kind of construction method for the titanium building materials that gymnasium is for building, comprising the following steps:
Step 1: the titanium plate with a thickness of 3.5cm is cut, and carries out surface mechanical polishing and first is carried out to titanium plate with alcohol
Secondary oil removal treatment；
Step 2: processing connecting hole in titanium plate, and titanium plate is bent into the flower pattern domed shape in gymnasium；
Step 3: the step of second of oil removal treatment is carried out to titanium plate with alcohol before cell reaction.
Electrolytic cell is put into 8 DEG C of cold water by step 4, then titanium plate is put into the fat-soluble coloring of hyacinthine added with 16%
In the electrolyte of liquid, electrolyte is the mixed solution of 0.5% hydrochloric acid, 3.0% oxalic acid, 0.5 hydrogen peroxide, connects the electricity of 70 ± 1v
Source is first electrochemically reacted 27min, and in titanium plate Surface Creation titanium dioxide and titanium monoxide, while titanium plate surface is a small amount of
Titanium dioxide by the acid dissolution in electrolyte；When power supply disconnects, chemical reaction 18min is carried out, the titanium dioxide on titanium plate surface is made
For titanium by the molten multiple apertures of generation of acid in electrolyte, being formed makes the oxidation film on titanium plate surface form porous layer, and makes in electrolyte
Hyacinthine fat-soluble pigment be deposited in aperture, power supply is opened and disconnection be electrochemically reacted and chemically react circulation 3 times,
The generation of titanium plate surface oxide layer and the coloring of oxide layer are completed, then titanium plate is taken out to rapidly the electrolyte of simultaneously clean the surface；
Step 5: titanium plate surface coloring liquid is cleaned with deionized water, and titanium plate is placed into decoct in boiling water and carries out surface
Sealing of hole, naturally dry must colour after titanium plate building materials.
Embodiment 3:
In the present embodiment, a kind of construction method for the titanium building materials that palace is for building, comprising the following steps:
Step 1: the titanium plate with a thickness of 2.0cm is cut, and carries out surface mechanical polishing and first is carried out to titanium plate with alcohol
Secondary oil removal treatment；
Step 2: processing connecting hole in titanium plate, and titanium plate is bent into the flower pattern domed shape in palace；
Step 3: the step of second of oil removal treatment is carried out to titanium plate with alcohol before cell reaction.
Titanium plate is put into the electrolyte added with the 18% fat-soluble coloring liquid of green by step 4, and electrolyte is 0.5% phosphorus
The mixed solution of acid, 3.0% oxalic acid, 0.5% hydrogen peroxide, 0.15% sulfuric acid connects the power supply of 90 ± 1v, first carries out electrochemistry
20min is reacted, is electrolysed in a small amount of titanium dioxide of titanium plate Surface Creation titanium dioxide and titanium monoxide, while titanium plate surface
Acid dissolution in liquid；When power supply disconnects, chemical reaction 30min is carried out, makes the titanium dioxide on titanium plate surface by the acid in electrolyte
Molten to generate multiple apertures, being formed makes the oxidation film on titanium plate surface form porous layer, and makes the green fat-soluble pigment in electrolyte
It is deposited in aperture, power supply is opened and disconnection is electrochemically reacted and chemically reacts circulation 3 times, completes titanium plate surface oxide layer
Generation and oxide layer coloring, then rapidly by titanium plate take out and clean the surface electrolyte；
Step 5: titanium plate surface coloring liquid is cleaned with deionized water, and titanium plate is placed into decoct in boiling water and carries out surface
Sealing of hole, naturally dry must colour after titanium plate building materials.
The principle of the present invention is:
1. titanium plate cutting, deformation, engraving etc. now to be formed to the design shape of building before titanium plate coloring first；Secondly, again
It is electrolysed to form titanium oxide film on titanium plate surface in the electrolytic solution, and so that fat-soluble pigment is adhered to and is sealed in during electrolysis
In the aperture of oxidation film.
Voltage and oxidation film corresponding color when 2. titanium plate is electrolysed:
| Voltage | 10 | 20 | 30 | 40 | 50 | 60 |
| Color | Brown | Hyacinthine | Navy blue | It is light blue | Reddish yellow | Rose-red |
| Voltage | 70 | 80 | 90 | 100 | 110 | |
| Color | Bluish violet | Yellow green | Green | Light green | Celadon |
3. the reaction equation of titanium plate cell reaction are as follows:
H2O-2e→O2-+2H+
Ti+2e→Ti2++Ti4+
Ti4++2O2-→TiO2
Ti2++O2-→TiO
The series of detailed descriptions listed above only for feasible embodiment of the invention specifically
Protection scope bright, that they are not intended to limit the invention, it is all without departing from equivalent implementations made by technical spirit of the present invention
Or change should all be included in the protection scope of the present invention.
It is obvious to a person skilled in the art that invention is not limited to the details of the above exemplary embodiments, Er Qie
In the case where without departing substantially from spirit or essential attributes of the invention, the present invention can be realized in other specific forms.Therefore, no matter
From the point of view of which point, the present embodiments are to be considered as illustrative and not restrictive, and the scope of the present invention is by appended power
Benefit requires rather than above description limits, it is intended that all by what is fallen within the meaning and scope of the equivalent elements of the claims
Variation is included within the present invention.
In addition, it should be understood that although this specification is described in terms of embodiments, but not each embodiment is only wrapped
Containing an independent technical solution, this description of the specification is merely for the sake of clarity, and those skilled in the art should
It considers the specification as a whole, the technical solutions in the various embodiments may also be suitably combined, forms those skilled in the art
The other embodiments being understood that.
Claims (7)
1. a kind of construction method of titanium building materials for building, it is characterised in that: include the following steps,
Step 1: titanium plate is cut, and carries out surface mechanical polishing and first time oil removal treatment；
Step 2: processing connecting hole or connection structure in titanium plate, and is bent, embossed, acid etching molding；
Step 3: titanium plate being placed into electrolytic cell and carries out cell reaction, and titanium plate surface anodization is made to generate sull,
Take out the electrolyte of titanium plate and clean the surface；
Step 4: titanium plate is placed into boiling water and decocts progress surface-sealing；
Wherein, added with fat-soluble pigment in the electrolyte in the step 3.
2. the construction method of one kind according to claim 1 titanium building materials for building, it is characterised in that: the fat-soluble color
Element is synthetic dyestuff, and fat-soluble pigment concentration is 5 ~ 30% in the electrolyte.
3. the construction method of one kind according to claim 2 titanium building materials for building, it is characterised in that: in step 3, institute
State cell reaction specific steps are as follows:
A, power on, be electrochemically reacted；Power supply is closed, chemical reaction and titanium plate coloring are carried out；
B, it repeats to power on and disconnect power supply in step a, the progress cell reaction of titanium plate surface and chemical reaction is made to be recycled to oxygen
Change film to generate.
4. the construction method of one kind according to claim 3 titanium building materials for building, it is characterised in that: the electricity of the power supply
10 ~ 110V is pressed, and the switched on and off time ratio of power supply is 2:3.
5. the construction method of one kind according to claim 3 titanium building materials for building, it is characterised in that: in step a, close
Cooling device is connected while power supply, cooling device reduces the shape of aperture on sull for cooling down to electrolyte
At and promote deposition of the fat-soluble pigment on aperture.
6. the construction method of one kind according to claim 5 titanium building materials for building, it is characterised in that: the cooling device
For cold water cooling device, cold water temperature is 0 ~ 10 DEG C.
7. the construction method of one kind according to claim 3 titanium building materials for building, it is characterised in that: described in step a
The switched on and off circulation of power supply 3 ~ 4 times.
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| CN201811515110.6A CN109576759A (en) | 2018-12-12 | 2018-12-12 | A kind of construction method of titanium building materials for building |
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| CN201811515110.6A CN109576759A (en) | 2018-12-12 | 2018-12-12 | A kind of construction method of titanium building materials for building |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110158146A (en) * | 2019-06-21 | 2019-08-23 | 浙江厚岸科技发展有限公司 | The color production method of titanium metal containment surface oxide layer is presented in a kind of electropolishing |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1844483A (en) * | 2006-03-15 | 2006-10-11 | 厦门大学 | Process for anode oxidation coloration of titanium and titanium alloy surface |
| CN101096772A (en) * | 2006-06-30 | 2008-01-02 | 佛山市顺德区汉达精密电子科技有限公司 | Process for producing titanium alloy anodic oxidation colorful |
| CN102747402A (en) * | 2012-03-08 | 2012-10-24 | 北京服装学院 | Discharging oxidation coloring method for titanium or titanium alloy |
| CN103540989A (en) * | 2013-09-12 | 2014-01-29 | 云南钛业股份有限公司 | Method of simultaneously oxidizing and coloring two alternating-current electrodes of titanium and titanium alloy |
| CN105965211A (en) * | 2016-06-22 | 2016-09-28 | 宝鸡钛产业研究院有限公司 | Preparation method of colorful titanium punching board for architectural ornament |
| CN106350853A (en) * | 2016-11-03 | 2017-01-25 | 安阳工学院 | Method for electrochemical coloring of metallic titanium and titanium-based alloys |
| CN108705820A (en) * | 2018-06-12 | 2018-10-26 | 福建优净星环境科技有限公司 | A kind of antibacterial aluminium foil composite material and its manufacturing method |
-
2018
- 2018-12-12 CN CN201811515110.6A patent/CN109576759A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1844483A (en) * | 2006-03-15 | 2006-10-11 | 厦门大学 | Process for anode oxidation coloration of titanium and titanium alloy surface |
| CN101096772A (en) * | 2006-06-30 | 2008-01-02 | 佛山市顺德区汉达精密电子科技有限公司 | Process for producing titanium alloy anodic oxidation colorful |
| CN102747402A (en) * | 2012-03-08 | 2012-10-24 | 北京服装学院 | Discharging oxidation coloring method for titanium or titanium alloy |
| CN103540989A (en) * | 2013-09-12 | 2014-01-29 | 云南钛业股份有限公司 | Method of simultaneously oxidizing and coloring two alternating-current electrodes of titanium and titanium alloy |
| CN105965211A (en) * | 2016-06-22 | 2016-09-28 | 宝鸡钛产业研究院有限公司 | Preparation method of colorful titanium punching board for architectural ornament |
| CN106350853A (en) * | 2016-11-03 | 2017-01-25 | 安阳工学院 | Method for electrochemical coloring of metallic titanium and titanium-based alloys |
| CN108705820A (en) * | 2018-06-12 | 2018-10-26 | 福建优净星环境科技有限公司 | A kind of antibacterial aluminium foil composite material and its manufacturing method |
Non-Patent Citations (2)
| Title |
|---|
| 邱望标等: ""钛及钛合金着色工艺及色膜性能研究"", 《腐蚀科学与防护技术》 * |
| 陈亚: "《现代实用电镀技术》", 31 January 2003, 国防工业出版社 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110158146A (en) * | 2019-06-21 | 2019-08-23 | 浙江厚岸科技发展有限公司 | The color production method of titanium metal containment surface oxide layer is presented in a kind of electropolishing |
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