Summary of the invention
The objective of the invention is to the deficiency to prior art, and a kind of anodic oxidation aluminium sheet and preparation technology thereof are provided, it has corrosion-resistant, wear resistance, the non-fading characteristics of rich color.
For reaching above-mentioned functions, technical scheme provided by the invention is:
A kind of anodic oxidation aluminium sheet comprises aluminium alloy panel, and the outside surface of said aluminium alloy panel is provided with oxidation film layer.Described oxidation film layer is double-deck sull, is the blocking layer near one deck of alloy matrix aluminum, and one deck of outside is a porous layer.The thickness on said blocking layer is 0.03-0.05um, and the thickness of said porous layer is 10-15um.
Aforesaid a kind of anodic oxidation aluminium sheet, its preparation technology may further comprise the steps:
A, can manufacturing: choose the thick aluminum or aluminum alloy panel of 1-6mm and carry out can manufacturing, thereby reach the dimensional precision of design code and the workpiece of form accuracy;
B, the last extension:, guarantee current flowing with the said workpiece of rubber-like clamp;
C, anodic oxidation:
C1, electrochemical deoiling: the workpiece of steps A gained, with alkaline wash at 50-80 ℃ of following alkali cleaning 1-10 minute, in order to remove organic grease of said workpiece surface and inorganic carbide;
C2, hot water clean;
C3, sulfuric acid neutralization: at room temperature carry out pickling 2-10 second with pickle solution;
C4, clear water clean;
C5, chemical rightenning: under 90-110 ℃, chemical rightenning is handled the 3-7 branch and is planted, and makes said workpiece surface smooth, bright with polishing fluid;
C6, clear water clean;
C7, bright dipping: oxide debris or insolubles 5-10 second with nitric acid liquid is at room temperature removed said workpiece surface, make said workpiece surface expose crystallizing layer;
C8, anodic oxidation: using anodic oxidation electrolyte, is 13-26 ℃ in temperature, and voltage is 12-24V, and electric current is 0.8-2.5A/dm
2Condition under, carried out anodize 30-50 minute;
C9, cleaning: at room temperature, in three rinse baths, carry out three times respectively and clean, the time of cleaning for the third time is 1-2 minute;
C10, dyeing: will pass through workpiece after the anodic oxidation of said step C9, be immersed in temperature immediately is that 20-80 ℃, pH value are that 1-30 divides kind in the solution that contains dyestuff of 4.5-5.5, makes sull hole absorbing dye and catches shades of colour;
C11, sealing of hole handle: being immersed in PH4.5-5.5, temperature to said workpiece is 10~20min in 80~85 ℃ the nickel salt solution;
C12, cleaning: clean with ionized water or pure water.
C13, drying: under 60-70 ℃ temperature, dried 15 minutes, to reach the effect of baking and curing.
Preferably, every liter of alkaline wash of said step C1 comprises the raw material of following content:
Sodium hydroxide 50~70g
Tensio-active agent 1~3g
Preferably, every liter of pickle solution of said step C3 comprises the raw material of following content:
Sulfuric acid 100~200ml
Preferably, every liter of polishing fluid of said step C5 comprises the raw material of following content:
Sulfuric acid 100~150ml
Phosphoric acid 700~800ml
Nitric acid 50~60m1
Preferably, every liter of nitric acid liquid of said step C7 comprises the raw material of following content:
Nitric acid 200~300ml
Preferably, said step C9 cleans for the third time, and the rinse water requirements in water quality is that pH value is pure water or the deionized water of 7-8.
Preferably, every liter of nickel salt solution of said step C11 comprises the raw material of following content:
Single nickel salt (NiSO
46H
2O) 4~5g
Sodium-acetate (NaAc) 5~6g
Boric acid (H
3BO
3) 5~6g
Beneficial effect of the present invention is: a kind of anodic oxidation aluminium sheet of the present invention, comprise aluminium alloy panel, and the outside surface of said aluminium alloy panel is provided with oxidation film layer.Oxidation film layer even compact, its thickness are 10-15um, thereby can improve the wearability and the erosion resistance of Al alloy parts significantly.In addition, the porous surface of oxidation film layer forms versicolor outward appearance behind the absorbing dye in these holes, satisfy people to the multifarious requirement of appearance color; The manufacture craft of anodic oxidation aluminium sheet of the present invention, technology reliably are prone to row, make sticking power, acid resistance, solvent resistance, wear resistance, shock-resistance and the good mechanical properties of the finished product anodic oxidation aluminium sheet.
Embodiment
1 couple of the present invention does further elaboration below in conjunction with accompanying drawing:
A kind of anodic oxidation aluminium sheet as shown in Figure 1 comprises aluminium alloy panel 1, and the outside surface of aluminium alloy panel 1 is provided with oxidation film layer.Oxidation film layer is double-deck sull, is blocking layer 2 near one deck of alloy matrix aluminum, and one deck of outside is a porous layer 3.The thickness on blocking layer 2 is 0.03-0.05um, and the thickness of porous layer 3 is 10-15um.Oxidation film layer even compact, its thickness are 10-15um, thereby can improve the wearability and the erosion resistance of Al alloy parts significantly.In addition, the porous surface of oxidation film layer forms versicolor outward appearance behind the absorbing dye in these holes, satisfy people to the multifarious requirement of appearance color.
The invention still further relates to a kind of preparation technology who prepares anodic oxidation aluminium sheet of the present invention, below several then embodiment describe in detail:
Embodiment 1: a kind of anodic oxidation aluminium sheet, and its preparation technology may further comprise the steps:
A, can manufacturing: choose the thick aluminum or aluminum alloy panel of 1mm and carry out can manufacturing, thereby reach the dimensional precision of design code and the workpiece of form accuracy;
B, the last extension: with the said workpiece of rubber-like clamp; Guarantee current flowing; Because anchor clamps and workpiece surface all can generate sull very soon during anodic oxidation; Anchor clamps and workpiece have slightly and loosening promptly can change contacting points position in this process, hinder current flowing, so must avoid burning workpiece because of loose contact produces heat with the said workpiece of rubber-like clamp;
C, anodic oxidation:
C1, electrochemical deoiling: the workpiece of steps A gained, with alkaline wash 50 ℃ of following alkali cleanings 1 minute, in order to remove organic grease of said workpiece surface and inorganic carbide; Wherein every liter of alkaline wash comprises the raw material of following content:
Sodium hydroxide 50g
Tensio-active agent 1g
C2, hot water clean;
C3, sulfuric acid neutralization: at room temperature carry out 2 seconds of pickling with pickle solution; Wherein every liter of pickle solution comprises the raw material of following content:
Sulfuric acid 100ml
C4, clear water clean;
C5, chemical rightenning: under 90 ℃, 3 fens kinds are handled in chemical rightenning, make said workpiece surface smooth, bright with polishing fluid; Wherein every liter of polishing fluid comprises the raw material of following content:
Sulfuric acid 100ml
Phosphoric acid 800ml
Nitric acid 50ml
C6, clear water clean;
C7, bright dipping: oxide debris or 5 seconds of insolubles with nitric acid liquid is at room temperature removed said workpiece surface, make said workpiece surface expose crystallizing layer; Wherein every liter of nitric acid liquid comprises the raw material of following content:
Nitric acid 200ml
C8, anodic oxidation: using anodic oxidation electrolyte, is 13 ℃ in temperature, and voltage is 12V, and electric current is 0.8A/dm
2Condition under, carried out anodize 50 minutes;
C9, cleaning: at room temperature, in three rinse baths, carry out three times respectively and clean, the time of cleaning for the third time is 1 minute, and the rinse water requirements in water quality is that pH value is 7 pure water or deionized water.
C10, dyeing: will pass through workpiece after the anodic oxidation of said step C9, be immersed in temperature immediately is that 20 ℃, pH value are 30 fens kinds in 4.5 the solution that contains dyestuff, makes sull hole absorbing dye and catches shades of colour;
C11, sealing of hole handle: being immersed in PH4.5, temperature to said workpiece is 20min in 80 ℃ the nickel salt solution; Wherein every liter of nickel salt solution comprises the raw material of following content:
Single nickel salt (NiSO
46H
2O) 4g
Sodium-acetate (NaAc) 5g
Boric acid (H
3BO
3) 5g
C12, cleaning: clean with ionized water or pure water.
C13, drying: under 60 ℃ temperature, dried 15 minutes, to reach the effect of baking and curing.
Embodiment 2: a kind of anodic oxidation aluminium sheet, and its preparation technology may further comprise the steps:
A, can manufacturing: choose the thick aluminum or aluminum alloy panel of 4mm and carry out can manufacturing, thereby reach the dimensional precision of design code and the workpiece of form accuracy;
B, the last extension: with the said workpiece of rubber-like clamp; Guarantee current flowing; Because anchor clamps and workpiece surface all can generate sull very soon during anodic oxidation; Anchor clamps and workpiece have slightly and loosening promptly can change contacting points position in this process, hinder current flowing, so must avoid burning workpiece because of loose contact produces heat with the said workpiece of rubber-like clamp;
C, anodic oxidation:
C1, electrochemical deoiling: the workpiece of steps A gained, with alkaline wash 65 ℃ of following alkali cleanings 5 minutes, in order to remove organic grease of said workpiece surface and inorganic carbide; Wherein every liter of alkaline wash comprises the raw material of following content:
Sodium hydroxide 60g
Tensio-active agent 2g
C2, hot water clean;
C3, sulfuric acid neutralization: at room temperature carry out 6 seconds of pickling with pickle solution; Wherein every liter of pickle solution comprises the raw material of following content:
Sulfuric acid 150ml
C4, clear water clean;
C5, chemical rightenning: under 100 ℃, 5 fens kinds are handled in chemical rightenning, make said workpiece surface smooth, bright with polishing fluid; Wherein every liter of polishing fluid comprises the raw material of following content:
Sulfuric acid 125ml
Phosphoric acid 750ml
Nitric acid 55ml
C6, clear water clean;
C7, bright dipping: oxide debris or 7 seconds of insolubles with nitric acid liquid is at room temperature removed said workpiece surface, make said workpiece surface expose crystallizing layer; Wherein every liter of nitric acid liquid comprises the raw material of following content:
Nitric acid 250ml
C8, anodic oxidation: using anodic oxidation electrolyte, is 20 ℃ in temperature, and voltage is 18V, and electric current is 1.7A/dm
2Condition under, carried out anodize 40 minutes;
C9, cleaning: at room temperature, in three rinse baths, carry out three times respectively and clean, the time of cleaning for the third time is 1.5 minutes, and the rinse water requirements in water quality is that pH value is 7.5 pure water or deionized water.
C10, dyeing: will pass through workpiece after the anodic oxidation of said step C9, be immersed in temperature immediately is that 50 ℃, pH value are 15 fens kinds in 5 the solution that contains dyestuff, makes sull hole absorbing dye and catches shades of colour;
C11, sealing of hole handle: being immersed in PH5, temperature to said workpiece is 15min in 82 ℃ the nickel salt solution; Wherein every liter of nickel salt solution comprises the raw material of following content:
Single nickel salt (NiSO
46H
2O) 4.5g
Sodium-acetate (NaAc) 5.5g
Boric acid (H
3BO
3) 5.5g
C12, cleaning: clean with ionized water or pure water.
C13, drying: under 65 ℃ temperature, dried 15 minutes, to reach the effect of baking and curing.
Embodiment 3: a kind of anodic oxidation aluminium sheet, and its preparation technology may further comprise the steps:
A, can manufacturing: choose the thick aluminum or aluminum alloy panel of 6mm and carry out can manufacturing, thereby reach the dimensional precision of design code and the workpiece of form accuracy;
B, the last extension: with the said workpiece of rubber-like clamp; Guarantee current flowing; Because anchor clamps and workpiece surface all can generate sull very soon during anodic oxidation; Anchor clamps and workpiece have slightly and loosening promptly can change contacting points position in this process, hinder current flowing, so must avoid burning workpiece because of loose contact produces heat with the said workpiece of rubber-like clamp;
C, anodic oxidation:
C1, electrochemical deoiling: the workpiece of steps A gained, with alkaline wash 80 ℃ of following alkali cleanings 10 minutes, in order to remove organic grease of said workpiece surface and inorganic carbide; Wherein every liter of alkaline wash comprises the raw material of following content:
Sodium hydroxide 70g
Tensio-active agent 3g
C2, hot water clean;
C3, sulfuric acid neutralization: at room temperature carry out 10 seconds of pickling with pickle solution; Wherein every liter of pickle solution comprises the raw material of following content:
Sulfuric acid 200ml
C4, clear water clean;
C5, chemical rightenning: under 110 ℃, 7 fens kinds are handled in chemical rightenning, make said workpiece surface smooth, bright with polishing fluid; Wherein every liter of polishing fluid comprises the raw material of following content:
Sulfuric acid 150ml
Phosphoric acid 700ml
Nitric acid 60ml
C6, clear water clean;
C7, bright dipping: oxide debris or 10 seconds of insolubles with nitric acid liquid is at room temperature removed said workpiece surface, make said workpiece surface expose crystallizing layer; Wherein every liter of nitric acid liquid comprises the raw material of following content:
Nitric acid 300ml
C8, anodic oxidation: using anodic oxidation electrolyte, is 26 ℃ in temperature, and voltage is 24V, and electric current is 2.5A/dm
2Condition under, carried out anodize 30 minutes;
C9, cleaning: at room temperature, in three rinse baths, carry out three times respectively and clean, the time of cleaning for the third time is 2 minutes, and the rinse water requirements in water quality is that pH value is 8 pure water or deionized water.
C10, dyeing: will pass through workpiece after the anodic oxidation of said step C9, be immersed in temperature immediately is that 80 ℃, pH value are 1 fen kind in 5.5 the solution that contains dyestuff, makes sull hole absorbing dye and catches shades of colour;
C11, sealing of hole handle: being immersed in PH5.5, temperature to said workpiece is 20min in 85 ℃ the nickel salt solution; Wherein every liter of nickel salt solution comprises the raw material of following content:
Single nickel salt (NiSO
46H
2O) 5g
Sodium-acetate (NaAc) 6g
Boric acid (H
3BO
3) 6g
C12, cleaning: clean with ionized water or pure water.
C13, drying: under 70 ℃ temperature, dried 15 minutes, to reach the effect of baking and curing.
The above embodiment; It is preferred embodiments of the present invention; Be not to limit practical range of the present invention,, all should be included in the patent claim of the present invention so all equivalences of doing according to the described structure of claim of the present invention, characteristic and principle change or modify.