CN109576072A - A kind of environmental protection leather cleaning frost and preparation method thereof - Google Patents

A kind of environmental protection leather cleaning frost and preparation method thereof Download PDF

Info

Publication number
CN109576072A
CN109576072A CN201811398556.5A CN201811398556A CN109576072A CN 109576072 A CN109576072 A CN 109576072A CN 201811398556 A CN201811398556 A CN 201811398556A CN 109576072 A CN109576072 A CN 109576072A
Authority
CN
China
Prior art keywords
oil
tween
environmentally friendly
leather cleaning
white
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201811398556.5A
Other languages
Chinese (zh)
Inventor
黄荣华
李光贞
黄清华
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Guangzhou City Mstar Technology Ltd Also Effective
Original Assignee
Guangzhou City Mstar Technology Ltd Also Effective
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Guangzhou City Mstar Technology Ltd Also Effective filed Critical Guangzhou City Mstar Technology Ltd Also Effective
Priority to CN201811398556.5A priority Critical patent/CN109576072A/en
Publication of CN109576072A publication Critical patent/CN109576072A/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/825Mixtures of compounds all of which are non-ionic
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005Other compounding ingredients characterised by their effect
    • C11D3/0031Carpet, upholstery, fur or leather cleansers
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02Inorganic compounds ; Elemental compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/18Hydrocarbons
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2093Esters; Carbonates
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/26Organic compounds containing nitrogen
    • C11D3/28Heterocyclic compounds containing nitrogen in the ring
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/26Organic compounds containing nitrogen
    • C11D3/30Amines; Substituted amines ; Quaternized amines
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/667Neutral esters, e.g. sorbitan esters

Abstract

The invention discloses a kind of environmentally friendly leather cleaning frosts and preparation method thereof.Environmentally friendly leather cleaning frost is configured according to a certain mass ratio by card wave, triethanolamine, White Mineral Oil, medical ventolin, sapn, tween, methyl esters, propyl ester, mould inhibitor, cleaning carbon atom.The present invention uses non-industrial raw material, courageously uses cosmetics-stage raw material and is prepared, has good leather cleaning ability, safe and healthy, natural environmental-protective, and can directly contact human skin.

Description

A kind of environmental protection leather cleaning frost and preparation method thereof
Technical field
This product is related to daily fine chemical fields, and in particular to a kind of environmental protection leather cleaning frost and preparation method thereof.
Background technique
With the high speed development of China's economic, the increasingly raising of living standards of the people, Chinese luxury goods consumption is also continuous It is soaring.Chinese luxury goods consumption total value alreadys exceed the U.S., and Japan becomes the big luxury goods country of consumption of the first in the world.It is expected that extremely 2025, global luxury goods market value will increase by 1,000,000,000,000 yuans, reach 2.7 trillion yuans.Chinese Consumer's will act as Main force, estimation " will buy " 44% world market to 2025 (from the Chinese luxury goods consumption report of Mai Kenxi 2017).It is luxurious Market all shows huge market prospects and consumption after the leathercrafts such as wasteful name of an article Gui Bao packet, handbag, leather shoes and its nursing, maintenance Potentiality.
Leather cleaning product is mostly with Brazil wax, paraffin oil, solvent, dyestuff, acetone, petrobenzene, two currently on the market The petrochemical industry such as butyl glycol ether are at being grouped as, then add some auxiliary agents for having cleaning, glazing etc., and the detergent of similar this formula is long Phase using being easy that leather is made the aging phenomena such as embrittlement, dry and cracked breakage of hardening occur, to the cleaning effect of high-grade luxury goods leathercraft Not satisfactory, long-time service also has a degree of injury to human body.And after cleaning have wax class, grease, petrobenzene etc. other Residual components influence the adhesive force of coating and the maintenance effect of entirety when subsequent renovation colouring.
Summary of the invention
It is an object of the present invention to provide a kind of leather cleaning of environmental protection frost, non-industrial raw material courageously uses cosmetics-stage Raw material is prepared, and has good leather cleaning ability, safe and healthy, natural environmental-protective, and can directly contact human skin.Together When the purpose of the present invention also for meeting luxury goods consumer, high-grade leathercraft user the improvement need strong to leather cleaning It asks.
To achieve the above object, technical solution of the present invention provides a kind of environmentally friendly leather cleaning frost, which is characterized in that described The composition of environmentally friendly leather cleaning frost and the weight percent of component are as follows:
Card wave 3 ~ 8%
Triethanolamine 4 ~ 8%
White Mineral Oil 20 ~ 25%
Medical ventolin 6 ~ 12%
Sapn 5 ~ 15%
Tween 4 ~ 6%
Methyl esters 5 ~ 10%
Propyl ester 4 ~ 10%
Mould inhibitor 1 ~ 2%
Clean carbon atom 15 ~ 27%
The card wave active ingredient: Finasteride, chemical name: -5 α of 17 β-(5- tertiary butyl amine formyl) -4- azepine-hero Steroid -1- alkene -3- ketone.Molecular formula: C23H36N2O2, molecular weight: 372.55, this product is white or class white film or Film coated tablets, Remove whitening color or off-white color after being coated.
The triethanolamine: 1, in cosmetics (including skin washing, eye glue, moisturizing, shampoo etc.) it is used as emulsification Agent, moisturizer, humidizer, thickener, PH poising agent.For being neutralized into soap with fatty acid in cosmetic formulations, with sulphation Fatty acid is neutralized into amine salt.Triethanolamine is that emulsifier is commonly used in cream preparation, is had with the cream products that triethanolamine emulsifies The colloid phase stability that the characteristics of lotion is fine and smooth, lotion brilliant white, another triethanolamine and higher fatty acids or higher aliphatic are formed Good, it is high can to hold additional ingredients specific gravity for stable product quality.Triethanolamine is containing the most normal of the acid high-molecular gel such as carbomer With neutralizer, triethanolamine by with the neutralization of the carboxyl of carbomer, form stable macromolecular structure, reach thickening and moisturizing Application effect;2, triethanolamine is added in liquid detergent, oily dirt, the especially removal of nonpolarity sebum can be improved, Meanwhile detergency ability can be improved by improving alkalinity.And there is its fabulous compatibility.
The White Mineral Oil is cosmetics-stage white oil, is obtained after deep refining using hydrogenating materials.Suitable for changing Adornment industry, can make the base of the ointment and softening agent such as hair-cream, hair oil, lipstick, face oil, skin care oil, sunblock lotion, baby oil, toilet cream Plinth oil.It can be used as antistatic agent, emollients, solvent, solvent, hydrocarbon can increase moist feeling, be usually used in white poultice In object or skin care products.
The medical ventolin is the uniform soft pasty masses for having certain stringiness, wire drawing very short, odorless, In be divided into medical albolene and medical yellow petroleum jelly again by refining depth, respectively white, faint yellow to light yellow;It is applicable in In medical ointment, the raw material and facial ointment of emulsifiable paste;With naphthadil and mineral oil or with the white of spice oil and fusing Paraffin or ceresine mix obtained, can be used to manufacture medical ointment, to manufacture emulsion in textile industry, also can be used as survey Measuring device tool and the anticorrosive lubricating grease of surgical instruments are used.By it is highly purified reach pharmaceutical grade when can be used as ointment, for medicine Vaseline jelly may be furnished with other substances.
The sapn alias sorbitan fatty acid ester.This product is wax white or yellowish, plates, powder Shape (>=100 mesh).It is dissolved in ethyl alcohol, ether, methanol and the carbon tetrachloride of heat, ether is slightly soluble in, petroleum ether, hot water can be scattered in In, it is w/o type emulsifier, there is very strong emulsification, dispersion, lubricating action.Can be mixed with various surfactants, especially adapt to With Tween-60 (T-60), it is used in compounding better effect.HLB (hydrophile-lipophile balance) value 4.7,52-57 DEG C of fusing point.
The tween: 1, alias polysorbate, pH value: about 6-8 [5%(W/V) aqueous solution] flash-point: 149 DEG C of are non- Ionic surfactant has foreign odor, and warm and slight bitter, is a series of partial fatty acid ester of polyoxyethylene sorbitans. Amber thick liquid nano generally is arrived in faint yellow, but different because of molecular weight difference.Due to having in polysorbate molecule More one polyoxyethylene groups of hydrophilic radical, therefore hydrophily is strong, is a kind of nonionic surface active agent.Frequently as oil-in-water (O/W) type emulsifier disperses other substances uniformly in the solution, is mainly used for food, cosmetics.With other emulsifiers such as moon Lauryl sulfate or spans share, and can increase the stability of emulsion.Tween can be used to be dissolved in water liquid after emulsifying essential oil In, it plays a role completely.Comparatively, polysorbas20 milder is some, and the emulsibility of Tween 80 is more stronger;2, polysorbate by Sorb (sugar) alcohol is made by three-step reaction.Firstly, sorb dehydration of alcohols forms sorbitan;Sorbitan with fatty acid such as Oleic acid, stearic acid generate hexose ester;Finally polysorbate is generated with reacting ethylene oxide under the action of catalyst;3, due to tween It is formed by ester from different higher fatty acids for sorbierite, therefore tween is actually the series of products of same type, general fine Chemical industry shop or chemical reagents corporation point 20, select according to different needs by 40,60,80 a lot of kinds.Tween-60 is stearic acid Ester;Tween-80 is oleate;Tween-20 is laurate;Used in the present invention be exactly Tween-20 be laurate, be The mixture of polyoxyethylene sorbitan monolaurate and the double Span 20s of a part of polyoxyethylene.
The methyl esters is also known as fatty acid methyl ester, adipic acid monomethyl ester, and adipic acid hydrogen methyl esters is that widely used surface is living The raw material of property agent (SAA), can produce two major classes surfactant from fatty acid methyl ester.One kind is by sulfonation and raw It produces fatty acid methyl ester sulfonate (MES), another kind of is by adding hydrogen to produce fatty alcohol.
The propyl ester also known as propyl acetate, molecular formula: CH3COOCH2CH2CH3, colorless clear liquid have pears sample fragrant Gas, -92 DEG C of fusing point, 101.6 DEG C of boiling point, relative density 0.836, refractive index 1.3844, puts 450 DEG C, explosion naturally by 12 DEG C of flash-point The limit 2% ~ 8%, steam relative density 3.52 can be miscible with alcohol, ether, the solubility about 1.6% in 16 DEG C of water.
The mould inhibitor is methyl p-hydroxybenzoate, 1,2- benzo Yi Sai Lin -3- ketone, nano phase ag_2 o leather are anti- One or more of mould dose.
The cleaning carbon atom is a kind of transparency liquid of colorless and odorless, is had excellent performance and very economical, is had excellent Physical chemistry and toxicological security, be practically free of aromatic hydrocarbons and sulphur.It is non-stimulated to eyes and skin, no sensitization.To various originals Material active matter and grease have dissolution and compatibility well.Excellent powder dispersibility, surface tension bottom, easily sprawl and by Emulsification.It can be widely used for various products, in sun-proof, color make-up, makeup removing, hair care and basic skin-protection product, also can be used as both effectiveness The oil-soluble carrier of substance.Limpid, colourless, tasteless, height is branched, harmless, easily biological-degradable, noresidue sense, skin Sense is salubrious.Evaporation rate is very fast, waterproof, anti-sweat, is suitable for dry-ness skin care, treatment.Density, viscosity are small, and oil sense is extremely light, Skin sense and oil-soluble can be improved, promote the auxiliary malleability of product and smear sense.Good hand touch, salubrious gas permeability is strong, moistens non-greasy, protects It is wet to slide, substantially reduce the greasy feeling of cream and product emulsion, safety and environmental protection.
A method of producing aforementioned environmentally friendly leather cleaning frost, it is characterised in that include the following steps.
S1: card taking wave, triethanolamine, White Mineral Oil are in container, 15 ~ 20 points of dispersion stirring under the action of high speed disperser Clock, revolving speed are controlled in 1000RPM, are uniformly mixing to obtain the first mixed liquor.
S2: adding medical ventolin, sapn, tween later, and revolving speed control continues dispersion stirring 10 ~ 15 in 1200RPM Minute, after mixing evenly up to second of mixed liquor.
S3: second of mixed liquor is added in the first mixed liquor, and it is mixed that the third is obtained after continuing stirring 5-10 minutes Close liquid.
S4: then taking methyl esters, propyl ester, mould inhibitor to be added in the third mixed liquor, and dissolution stirs evenly, and revolving speed control exists 1000RPM is stirred 5 minutes.
S5: it will finally clean carbon atom and be added in the solution of S4, stirred, mixing time 5-15 minutes, turned using mulser Speed is in 800RPM.
S6: standing is examined after five minutes, is filled in packing container.
Specific embodiment
Environmentally friendly leather cleaning frost of the invention is described in further detail below.Following instance is only used for clearly saying Bright technical solution of the present invention, and not intended to limit the protection scope of the present invention.
Example 1
The composition of environmentally friendly leather cleaning frost and the weight percent of component in example 1 are as follows:
Card wave 4%
Triethanolamine 6%
White Mineral Oil 21%
Medical ventolin 11%
Sapn 14%
Tween 6%
Methyl esters 8%
Propyl ester 5%
Methyl p-hydroxybenzoate 1%
Clean carbon atom 24%
Example 2
The composition of environmentally friendly leather cleaning frost and the weight percent of component in example 2 are as follows:
Card wave 5%
Triethanolamine 7%
White Mineral Oil 24%
Medical ventolin 10%
Sapn 12%
Tween 5%
Methyl esters 9%
Propyl ester 7%
Methyl p-hydroxybenzoate 1%
Clean carbon atom 20%
Example 3
The composition of environmentally friendly leather cleaning frost and the weight percent of component in example 3 are as follows:
Card wave 6%
Triethanolamine 5%
White Mineral Oil 22%
Medical ventolin 7%
Sapn 13%
Tween 5%
Methyl esters 6%
Propyl ester 9%
1,2- benzo Yi Sai Lin -3- ketone 1.5%
Clean carbon atom 25.5%
Example 4
The composition of environmentally friendly leather cleaning frost and the weight percent of component in example 4 are as follows:
Card wave 8%
Triethanolamine 7%
White Mineral Oil 24%
Medical ventolin 7%
Sapn 13.5%
Tween 5.2%
Methyl esters 7%
Propyl ester 8%
Nano phase ag_2 o leather fungicide 1%
Clean carbon atom 19.3%
Example 5
The composition of environmentally friendly leather cleaning frost and the weight percent of component in example 5 are as follows:
Card wave 4.2%
Triethanolamine 8%
White Mineral Oil 22%
Medical ventolin 10.3%
Sapn 12%
Tween 5.6%
Methyl esters 8%
Propyl ester 7%
Nano phase ag_2 o leather fungicide 1.6%
Clean carbon atom 21.3%.

Claims (11)

1. a kind of environmental protection leather cleaning frost, which is characterized in that the composition of the environmental protection leather cleaning frost and the weight percent of component Than are as follows:
Card wave 3 ~ 8%
Triethanolamine 4 ~ 8%
White Mineral Oil 20 ~ 25%
Medical ventolin 6 ~ 12%
Sapn 5 ~ 15%
Tween 4 ~ 6%
Methyl esters 5 ~ 10%
Propyl ester 4 ~ 10%
Mould inhibitor 1 ~ 2%
Clean carbon atom 15 ~ 27%
The environmentally friendly leather cleaning frost according to right 1, which is characterized in that the card wave active ingredient: Finasteride, chemistry Title: 17 β-(5- tertiary butyl amine formyl) -4- aza-5 alpha-androstane -1- alkene -3- ketone, molecular formula: C23H36N2O2, molecule Amount: 372.55, this product is white or class white film or Film coated tablets, removes whitening color or off-white color after coating.
2. the frost of the environmentally friendly leather cleaning according to right 1, which is characterized in that the triethanolamine: 1, cosmetics (including Skin washing, eye glue, moisturizing, shampoo etc.) in be used as emulsifier, moisturizer, humidizer, thickener, PH poising agent,
For being neutralized into soap with fatty acid in cosmetic formulations, it is neutralized into amine salt with sulfated fatty acid, triethanolamine is cream Emulsifier is commonly used in paste formulation, and there is the characteristics of lotion is fine and smooth, lotion brilliant white, another three second with the cream products that triethanolamine emulsifies Hydramine and the colloid phase stability that higher fatty acids or higher aliphatic are formed are good, and stable product quality can hold additional ingredients ratio Weight is high,
Triethanolamine is the most frequently used neutralizer containing the acid high-molecular gel such as carbomer, triethanolamine by with carbomer Carboxyl neutralizes, and forms stable macromolecular structure, reaches the application effect of thickening and moisturizing;2, three are added in liquid detergent Ethanol amine can improve oily dirt, the especially removal of nonpolarity sebum, meanwhile, detergency ability can be improved by improving alkalinity,
And there is its fabulous compatibility.
3. the environmentally friendly leather cleaning frost according to right 1, which is characterized in that the White Mineral Oil is cosmetics-stage white oil, is Obtained after deep refining using hydrogenating materials, be suitable for cosmetic industry, can make hair-cream, hair oil, lipstick, face oil, skin care oil, The base oil of the ointment such as sunblock lotion, baby oil, toilet cream and softening agent can be used as antistatic agent, emollients, solvent, solvent, carbon Hydrogen compound can increase moist feeling, be usually used in white cream drug or skin care products.
4. the environmentally friendly leather cleaning frost according to right 1, which is characterized in that the medical ventolin is that have certain drawing The very short uniform soft pasty masses of silk property, wire drawing, odorless, wherein being divided into medical albolene and medicine Huang again by refining depth Vaseline is respectively white, faint yellow to light yellow;Suitable for medical ointment, the raw material and facial ointment of emulsifiable paste;Use paraffin Rouge mixes obtained with mineral oil or with the white paraffin wax or ceresine of spice oil and fusing, can be used to manufacture medical oil Cream also can be used as measuring apparatus and the anticorrosive lubricating grease of surgical instruments used, through excessively high to manufacture emulsion in textile industry Degree purification can be used as ointment when reaching pharmaceutical grade, and the vaseline jelly for medicine may be furnished with other substances.
5. the environmentally friendly leather cleaning frost according to right 1, which is characterized in that the sapn alias sorbitan fatty acid Ester,
This product be wax white or yellowish, plates, powder shape (>=100 mesh), be dissolved in heat ethyl alcohol, ether, methanol and Carbon tetrachloride is slightly soluble in ether, petroleum ether, can be scattered in hot water, is w/o type emulsifier, have it is very strong emulsification, dispersion, Lubricating action, can be mixed with various surfactants, and especially adaptation and Tween-60 (T-60) is used in compounding better effect, HLB (hydrophile-lipophile balance) value 4.7,52-57 DEG C of fusing point.
6. the environmentally friendly leather cleaning frost according to right 1, which is characterized in that the tween: 1, alias polysorbate, soda acid Degree: about 6-8 [5%(W/V) aqueous solution] flash-point: 149 DEG C of are nonionic surface active agent, there is a foreign odor, warm and slight bitter, are A series of partial fatty acid ester of polyoxyethylene sorbitans generally arrives amber thick liquid nano in faint yellow, but because dividing Son amount difference and it is different, due to there is more one polyoxyethylene groups of hydrophilic radical in polysorbate molecule, therefore hydrophily By force, it is a kind of nonionic surface active agent, frequently as oil-in-water (O/W) type emulsifier, makes other substances uniformly in the solution Dispersion, is mainly used for food, cosmetics, shares with other emulsifiers such as sldium lauryl sulfate or spans, can increase emulsion Stability, tween can be used to be dissolved in water liquid after emulsifying essential oil, play a role completely, comparatively, polysorbas20 is warmer With it is some, the emulsibility of Tween 80 is more stronger;2, polysorbate is made by sorb (sugar) alcohol by three-step reaction,
Firstly, sorb dehydration of alcohols forms sorbitan;Sorbitan generates hexose ester with fatty acid such as oleic acid, stearic acid; Finally polysorbate is generated with reacting ethylene oxide under the action of catalyst;3, since tween is sorbierite and different higher aliphatics Acid is formed by ester, therefore tween is actually the series of products of same type, in general fine chemistry industry shop or chemical reagents corporation point It 20,40,60,80 a lot of kinds, is selected according to different needs, Tween-60 is stearate;Tween-80 is oleate;It spits Temperature -20 is laurate;Used in the present invention be exactly Tween-20 be laurate, be polyoxyethylene sorbitan list The mixture of laurate and the double Span 20s of a part of polyoxyethylene.
7. the environmentally friendly leather cleaning frost according to right 1, which is characterized in that the methyl esters is also known as fatty acid methyl ester, oneself two Sour mono-methyl, adipic acid hydrogen methyl esters are the raw materials of widely used surfactant (SAA), can be with from fatty acid methyl ester Two major classes surfactant is produced, one kind is by the way that, with production fatty acid methyl ester sulfonate (MES), another kind of is to pass through in sulfonation Hydrogen is added to produce fatty alcohol.
8. the environmentally friendly leather cleaning frost according to right 1, which is characterized in that the propyl ester also known as propyl acetate, molecular formula: CH3COOCH2CH2CH3, colorless clear liquid have pears sample fragrance, and -92 DEG C of fusing point, 101.6 DEG C of boiling point, relative density 0.836, Refractive index 1.3844, puts 450 DEG C, explosion limit 2% ~ 8%, steam relative density 3.52 can be mixed with alcohol, ether naturally by 12 DEG C of flash-point It is molten, the solubility about 1.6% in 16 DEG C of water.
9. the environmentally friendly leather cleaning frost according to right 1, which is characterized in that the mould inhibitor is P-hydroxybenzoic acid first One or more of ester, 1,2- benzo Yi Sai Lin -3- ketone, nano phase ag_2 o leather fungicide.
10. the environmentally friendly leather cleaning frost according to right 1, which is characterized in that the cleaning carbon atom is a kind of colourless nothing The transparency liquid of taste is had excellent performance and very economical, have excellent physical chemistry and toxicological security, be practically free of aromatic hydrocarbons and Sulphur,
Non-stimulated to eyes and skin, no sensitization has dissolution and compatibility well to various raw material active matters and grease, excellent Different powder dispersibility, surface tension bottom are easily sprawled and are emulsified, can be widely used for various products, such as sun-proof, color make-up, In makeup removing, hair care and basic skin-protection product, the oil-soluble carrier of both effectiveness substance also can be used as, limpid, colourless, tasteless, height Collateralization, harmless, easily biological-degradable, noresidue sense, skin sense is salubrious, and evaporation rate is very fast, waterproof, anti-sweat, is applicable in In dry-ness skin care, treatment, density, viscosity are small, and oil sense is extremely light, can improve skin sense and oil-soluble, promote the auxiliary malleability of product And sense is smeared, good hand touch, salubrious gas permeability is strong, moistens non-greasy, and moisturizing lubrication substantially reduces the greasy of cream and product emulsion Sense, safety and environmental protection.
11. a kind of method for producing aforementioned environmentally friendly leather cleaning frost, which is characterized in that the preparation method includes the following steps:
S1: card taking wave, triethanolamine, White Mineral Oil are in container, dispersion stirring 15 ~ 20 minutes under the action of high speed disperser, Revolving speed is controlled in 1000RPM, is uniformly mixing to obtain the first mixed liquor;
S2: adding medical ventolin, sapn, tween later, and revolving speed control continues 10 ~ 15 points of dispersion stirring in 1200RPM Clock, after mixing evenly up to second of mixed liquor;
S3: second of mixed liquor is added in the first mixed liquor, obtains the third mixed liquor after continuing stirring 5-10 minutes;
S4: then taking methyl esters, propyl ester, mould inhibitor to be added in the third mixed liquor, and dissolution stirs evenly, and revolving speed control exists 1000RPM is stirred 5 minutes;
S5: it will finally clean carbon atom and be added in the solution of S4, stirred using mulser, mixing time 5-15 minutes, revolving speed existed 800RPM;
S6: standing is examined after five minutes, is filled in packing container.
CN201811398556.5A 2018-11-22 2018-11-22 A kind of environmental protection leather cleaning frost and preparation method thereof Pending CN109576072A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201811398556.5A CN109576072A (en) 2018-11-22 2018-11-22 A kind of environmental protection leather cleaning frost and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201811398556.5A CN109576072A (en) 2018-11-22 2018-11-22 A kind of environmental protection leather cleaning frost and preparation method thereof

Publications (1)

Publication Number Publication Date
CN109576072A true CN109576072A (en) 2019-04-05

Family

ID=65923670

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201811398556.5A Pending CN109576072A (en) 2018-11-22 2018-11-22 A kind of environmental protection leather cleaning frost and preparation method thereof

Country Status (1)

Country Link
CN (1) CN109576072A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113717587A (en) * 2021-09-02 2021-11-30 李超 Decolorizing gel for TPE and silica gel products and preparation method thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1928042A (en) * 2005-09-08 2007-03-14 天津市世雄科技发展有限公司 Decontamination mildew-resistant paste for leather
CN101921668A (en) * 2009-06-12 2010-12-22 孙文国 Light-colored leather cleaning agent
CN102516883A (en) * 2011-11-22 2012-06-27 唐兴旺 Leather cleaning, nourishing and care cream and production method thereof
CN103666786A (en) * 2013-11-22 2014-03-26 南通信一服饰有限公司 Leather cleaning and polishing agent
CN106434040A (en) * 2016-09-27 2017-02-22 枣阳市华威硅氟材料有限公司 Flexible leather detergent containing hydroxyl silicone oil

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1928042A (en) * 2005-09-08 2007-03-14 天津市世雄科技发展有限公司 Decontamination mildew-resistant paste for leather
CN101921668A (en) * 2009-06-12 2010-12-22 孙文国 Light-colored leather cleaning agent
CN102516883A (en) * 2011-11-22 2012-06-27 唐兴旺 Leather cleaning, nourishing and care cream and production method thereof
CN103666786A (en) * 2013-11-22 2014-03-26 南通信一服饰有限公司 Leather cleaning and polishing agent
CN106434040A (en) * 2016-09-27 2017-02-22 枣阳市华威硅氟材料有限公司 Flexible leather detergent containing hydroxyl silicone oil

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113717587A (en) * 2021-09-02 2021-11-30 李超 Decolorizing gel for TPE and silica gel products and preparation method thereof

Similar Documents

Publication Publication Date Title
US5342611A (en) Hair cleansing composition
US3829563A (en) Emollient cleansing compositions
CN100581527C (en) Composition containing polyglycerol/medium-chain fatty acid ester
US11904039B2 (en) Cosmetic composition for makeup removal comprising water-soluble surfactant and oil-soluble surfactant
JP2001520175A (en) Emollient composition
CN1291883A (en) Liquid personal cleansing emulsion compositions with containing weighting oil
US4130497A (en) Detergent composition
US4960592A (en) Lanolin and lanolin oil skin treatment composition
Kelm et al. The role of fatty acids in cosmetic technology
CN109106621A (en) Cleansing composition and its preparation method and application
JP2007518678A (en) Highly unsaponifiable matter and method using the same
KR102410538B1 (en) Non-petrochemically derived cationic emulsifiers and related compositions and methods
JPS6127094B2 (en)
CN109153788A (en) Novel organopolysiloxane or its acid neutralize salt and their purposes
CN109414391A (en) Emulsification composition and the cosmetics for using it
JPH06107521A (en) Skin cleansing agent
CN109576072A (en) A kind of environmental protection leather cleaning frost and preparation method thereof
CN102482424B (en) Silicone modified fatty acids, method of preparation and usage thereof
EP2794549B1 (en) Fatty acid ester compositions for use as emollients
JP2002020623A (en) Water-in-oil emulsion in polar solvent
CN102655840A (en) Personal care emulsions comprising waxy materials and organopolysiloxanes
CN104784061B (en) Lecithin emulsification thickened systems are preparing the application in sprayable cream
JP2003055128A (en) Transparent cosmetic composition
JPS6026086B2 (en) cosmetics
CN109662909A (en) A kind of makeup removing oleogel essence dew and preparation method thereof with self-emulsifying moisturizing effect

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
WD01 Invention patent application deemed withdrawn after publication
WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20190405