CN109575445A - A kind of Flexible toothbrush handle polypropylene material and preparation method thereof - Google Patents
A kind of Flexible toothbrush handle polypropylene material and preparation method thereof Download PDFInfo
- Publication number
- CN109575445A CN109575445A CN201710906540.XA CN201710906540A CN109575445A CN 109575445 A CN109575445 A CN 109575445A CN 201710906540 A CN201710906540 A CN 201710906540A CN 109575445 A CN109575445 A CN 109575445A
- Authority
- CN
- China
- Prior art keywords
- toothbrush handle
- polypropylene material
- calcium carbonate
- flexible
- injection molding
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
Abstract
The invention discloses a kind of Flexible toothbrush handle polypropylene materials and preparation method thereof.The component and weight percent of the toothbrush handle polypropylene material are as follows: atactic copolymerized polypropene 50~90%, calcium carbonate 8~48%, Masterbatch 2%.The calcium carbonate is precipitated calcium carbonate, and diameter dimension is in 200~2000 mesh.Toothbrush handle polypropylene material according to the present invention, use the preferable atactic copolymerized polypropene of toughness for primary raw material, and calcium carbonate is added, its rigidity is improved on the basis of meeting its toughness, so that the inflexible target of product promotes 20% or more, rigid-tough balance is more excellent, and the present invention is suitble to manufacture toothbrush handle product flexible, and manufacturing process is simple.
Description
Technical field
The present invention relates to a kind of polypropylene materials, more particularly to a kind of Flexible toothbrush handle polypropylene material and its preparation side
Method.
Background technique
Currently, toothbrush handle in the market all uses injection molding and is made.Tooth-brush handle be preferably it is long and straight, handle
Middle section will be bent slightly up, and have certain elastic and fixed fulcrum, it is therefore desirable to which camber, selection hold function with anti-skidding fit
The toothbrush of energy is best.Toothbrush handle is usually of a straight line type with head toothbrushes, and tooth stress not only uniformly but also was convenient for erect brush, but some are special
The handle designs of special-shaped toothbrush have certain curvature.Toothbrush handle form is easy to hold.Brush handle is preferably formed with anti-skidding rubber, should hold
It holds comfortably, length is moderate, and has elasticity appropriate, and excessive strength when being brushed teeth with buffering makes toothbrush go to decontaminate with enough
The strength of power and massage gum, and can be to avoid due to strength macrolesion gum of brushing teeth.
Polypropylene is a kind of import plastic material that dosage is huge.About toothbrush handle use in injection molding pp material, make
For the product of modern crafts, polymarization method for prodcing polyacrylates is mature, technically reliable, and toothbrush handle pp material is crowd multiduty one
Kind.Toothbrush handle polypropylene dedicated material is had no currently on the market, and each producer is only screened according to the Performance Evaluation of itself.It utilizes
Toothbrush handle made of general polypropylene material is more crisp, easy fracture.
Summary of the invention
The object of the present invention is to provide a kind of Flexible toothbrush handle polypropylene materials and preparation method thereof, are led by being blended
It to be the atactic copolymerized polypropene containing calcium carbonate.The approach for realizing this purpose is the calcium carbonate that certain mesh number is added, and is passed through
The atactic copolymerized polypropene of suitable melting means is chosen to realize.
The technical solution adopted by the present invention is that:
A kind of Flexible toothbrush handle polypropylene material, the component and weight percent of the toothbrush handle polypropylene material are as follows: nothing
Advise copolymer polypropylene 50~90%, calcium carbonate 8~48%, Masterbatch 2%.
The melt index of the atactic copolymerized polypropene is 0.2~20.
The preferred precipitated calcium carbonate of the calcium carbonate, diameter dimension is in 200~2000 mesh.
A kind of preparation method of Flexible toothbrush handle polypropylene material, its step are as follows:
(1) atactic copolymerized polypropene, calcium carbonate and Masterbatch are put into progress uniform stirring 5~15 in super mixer
Minute, the speed of super mixer is 500~1500 revs/min；
(2) above-mentioned gained mixture is put into injection molding machine, carries out injection molding, injection molding machine temperature is 180~230
DEG C, air-cooled 4~5 hours after taking-up, finally obtain the toothbrush handle polypropylene material.
A kind of toothbrush handle flexible prepared by the present invention has preferable rigid-tough balance.Atactic copolymerized polypropene is recognized
To be a kind of preferable material of toughness, but its rigidity is weaker.By be added diameter dimension the calcium carbonate of 200~2000 mesh can
Preferably to solve the problems, such as this.
The utility model has the advantages that toothbrush handle of the invention is due to using the preferable atactic copolymerized polypropene of toughness for primary raw material, and
Addition contains calcium carbonate, so that the rigid-tough balance of product is more excellent.Due to using atactic copolymerized polypropene for primary raw material,
And be added and contain calcium carbonate and Masterbatch, compared with being added without calcium carbonate, the inflexible target of toothbrush handle will promote 20% or more,
And change in toughness is little, and rigid-tough balance is more excellent.This technique is suitble to manufacture toothbrush handle product flexible, and manufacturing process
Simply.
Specific embodiment
Detailed description of the preferred embodiments below, it should be noted however that protection of the invention
Range is not limited to these specific embodiments, but is determined by claims.
Embodiment 1
A kind of toothbrush handle of flexible polypropylene material, the component and weight percent of the toothbrush handle are as follows: random copolymerization is poly-
Propylene 90%, calcium carbonate 8%, Masterbatch 2%, calcium carbonate are 200 mesh.
(1) atactic copolymerized polypropene, calcium carbonate and Masterbatch are put into first and carries out uniform stirring in super mixer
10 minutes, the speed of super mixer was 800 revs/min；
(2) above-mentioned gained mixture is put into injection molding machine, carries out injection molding, injection molding machine temperature is taken out at 210 DEG C
Decaptitating and air-cooled 2 hours are carried out after product, finally obtain product toothbrush handle.
National standard (GB/T9341-2008) batten is made in powder after step (1) mixing, and it is curved to measure its in standard laboratory
Bent modulus 986MPa, room temperature shock resistance 20.8kJ/m2。
Embodiment 2
A kind of toothbrush handle of flexible polypropylene material, the component and weight percent of the toothbrush handle are as follows: random copolymerization is poly-
Propylene 80%, calcium carbonate 18%, Masterbatch 2%, calcium carbonate are 500 mesh.
(1) atactic copolymerized polypropene, calcium carbonate and Masterbatch are put into first and carries out uniform stirring in super mixer
10 minutes, the speed of super mixer was 800 revs/min；
(2) above-mentioned gained mixture is put into injection molding machine, carries out injection molding, injection molding machine temperature is taken out at 210 DEG C
Decaptitating and air-cooled 2 hours are carried out after product, finally obtain product toothbrush handle.
National standard (GB/T9341-2008) batten is made in powder after step (1) mixing, and it is curved to measure its in standard laboratory
Bent modulus 1020MPa, room temperature shock resistance 20.2kJ/m2。
Embodiment 3
A kind of toothbrush handle of flexible polypropylene material, the component and weight percent of the toothbrush handle are as follows: random copolymerization is poly-
Propylene 70%, calcium carbonate 28%, Masterbatch 2%, calcium carbonate are 1000 mesh.
(1) atactic copolymerized polypropene, calcium carbonate and Masterbatch are put into first and carries out uniform stirring in super mixer
10 minutes, the speed of super mixer was 800 revs/min；
(2) above-mentioned gained mixture is put into injection molding machine, carries out injection molding, injection molding machine temperature is taken out at 210 DEG C
Decaptitating and air-cooled 2 hours are carried out after product, finally obtain product toothbrush handle.
National standard (GB/T9341-2008) batten is made in powder after step (1) mixing, and it is curved to measure its in standard laboratory
Bent modulus 1068MPa, room temperature shock resistance 19.8kJ/m2。
Embodiment 4
A kind of toothbrush handle of flexible polypropylene material, the component and weight percent of the toothbrush handle are as follows: random copolymerization is poly-
Propylene 60%, calcium carbonate 38%, Masterbatch 2%, calcium carbonate are 1500 mesh.
(1) atactic copolymerized polypropene, calcium carbonate and Masterbatch are put into first and carries out uniform stirring in super mixer
10 minutes, the speed of super mixer was 800 revs/min；
(2) above-mentioned gained mixture is put into injection molding machine, carries out injection molding, injection molding machine temperature is taken out at 210 DEG C
Decaptitating and air-cooled 2 hours are carried out after product, finally obtain product toothbrush handle.
National standard (GB/T9341-2008) batten is made in powder after step (1) mixing, and it is curved to measure its in standard laboratory
Bent modulus 1111MPa, room temperature shock resistance 19.3kJ/m2。
Embodiment 5
A kind of toothbrush handle of flexible polypropylene material, the component and weight percent of the toothbrush handle are as follows: random copolymerization is poly-
Propylene 50%, calcium carbonate 48%, Masterbatch 2%, calcium carbonate are 2000 mesh.
(1) atactic copolymerized polypropene, calcium carbonate and Masterbatch are put into first and carries out uniform stirring in super mixer
10 minutes, the speed of super mixer was 800 revs/min；
(2) above-mentioned gained mixture is put into injection molding machine, carries out injection molding, injection molding machine temperature is taken out at 210 DEG C
Decaptitating and air-cooled 2 hours are carried out after product, finally obtain product toothbrush handle.
National standard (GB/T9341-2008) batten is made in powder after step (1) mixing, and it is curved to measure its in standard laboratory
Bent modulus 1156MPa, room temperature shock resistance 18.9kJ/m2。
Comparative examples 6
A kind of toothbrush handle of polypropylene material, the component and weight percent of the toothbrush handle are as follows: atactic copolymerized polypropene
98%, Masterbatch 2%.
(1) atactic copolymerized polypropene and Masterbatch are put into super mixer first and are carried out uniform stirring 10 minutes,
The speed of super mixer is 800 revs/min；
(2) above-mentioned gained mixture is put into injection molding machine, carries out injection molding, injection molding machine temperature is taken out at 210 DEG C
Decaptitating and air-cooled 2 hours are carried out after product, finally obtain product toothbrush handle.
National standard (GB/T9341-2008) batten is made in powder after step (1) mixing, and it is curved to measure its in standard laboratory
Bent modulus 812MPa, room temperature shock resistance 21.8kJ/m2。
Although a specific embodiment of the invention is described in detail above in conjunction with the embodiments, need to refer to
Out, the scope of protection of the present invention is not limited by these specific embodiments, but is determined by claims.This
Field technical staff can carry out these embodiments in the range of not departing from technical idea and purport of the invention appropriate
Change, and the embodiment after these changes is also included within protection scope of the present invention.
Claims (6)
1. a kind of Flexible toothbrush handle polypropylene material, which is characterized in that the component and weight hundred of the toothbrush handle polypropylene material
Divide ratio are as follows: atactic copolymerized polypropene 50~90%, calcium carbonate 8~48%, Masterbatch 2%.
2. Flexible toothbrush handle polypropylene material according to claim 1, which is characterized in that the atactic copolymerized polypropene
Melt index be 0.2~20.
3. Flexible toothbrush handle polypropylene material according to claim 1, which is characterized in that the calcium carbonate is lightweight carbon
Sour calcium, diameter dimension is in 200~2000 mesh.
4. a kind of preparation method of Flexible toothbrush handle polypropylene material described in claim 1, which is characterized in that including following step
It is rapid:
(1) atactic copolymerized polypropene, calcium carbonate and Masterbatch are put into and carries out 5~15 points of uniform stirring in super mixer
Clock, the speed of super mixer are 500~1500 revs/min；
(2) above-mentioned gained mixture is put into injection molding machine, carries out injection molding, injection molding machine temperature takes at 180~230 DEG C
Air-cooled 4~5 hours after out, the toothbrush handle polypropylene material is finally obtained.
5. the preparation method of Flexible toothbrush handle polypropylene material according to claim 4, which is characterized in that described is random
The melt index of copolymer polypropylene is 0.2~20.
6. the preparation method of Flexible toothbrush handle polypropylene material according to claim 4, which is characterized in that the carbonic acid
Calcium is precipitated calcium carbonate, and diameter dimension is in 200~2000 mesh.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710906540.XA CN109575445A (en) | 2017-09-29 | 2017-09-29 | A kind of Flexible toothbrush handle polypropylene material and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710906540.XA CN109575445A (en) | 2017-09-29 | 2017-09-29 | A kind of Flexible toothbrush handle polypropylene material and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109575445A true CN109575445A (en) | 2019-04-05 |
Family
ID=65914383
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710906540.XA Pending CN109575445A (en) | 2017-09-29 | 2017-09-29 | A kind of Flexible toothbrush handle polypropylene material and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109575445A (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102863671A (en) * | 2012-08-03 | 2013-01-09 | 扬州辰逸旅游用品有限公司 | Toothbrush handle and production method thereof |
| CN105086160A (en) * | 2015-08-27 | 2015-11-25 | 武汉清源管业科技有限公司 | Material special for toothbrush handle and preparation method thereof |
| CN106366455A (en) * | 2016-08-26 | 2017-02-01 | 安徽永高塑业发展有限公司 | Low-temperature and high-impact resistance polypropylene random material |
-
2017
- 2017-09-29 CN CN201710906540.XA patent/CN109575445A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102863671A (en) * | 2012-08-03 | 2013-01-09 | 扬州辰逸旅游用品有限公司 | Toothbrush handle and production method thereof |
| CN105086160A (en) * | 2015-08-27 | 2015-11-25 | 武汉清源管业科技有限公司 | Material special for toothbrush handle and preparation method thereof |
| CN106366455A (en) * | 2016-08-26 | 2017-02-01 | 安徽永高塑业发展有限公司 | Low-temperature and high-impact resistance polypropylene random material |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| MX353401B (en) | Polypropylene yarn having increased young's modulus and method of making same. | |
| JP2008095094A5 (en) | ||
| CN110384616B (en) | Antibacterial complete denture and manufacturing method thereof | |
| CN109575445A (en) | A kind of Flexible toothbrush handle polypropylene material and preparation method thereof | |
| CN110872401A (en) | Carbon nanotube reinforced glove and preparation method thereof | |
| CN105017634A (en) | Flexible, abrasion-resisting artificial ribbed lawn filaments and preparing method thereof | |
| CN105295284A (en) | Special material with high resilience for grass of artificial turf and preparation method thereof | |
| CN109575451A (en) | A kind of toothbrush handle polypropylene material and preparation method thereof | |
| CN109575426A (en) | A kind of toothbrush handle polypropylene material and preparation method thereof | |
| CN109206612A (en) | Bionical spider silk polyaminoacid bioelastomer material and preparation method thereof | |
| CN104497377B (en) | A kind of disc fills glue formula and production technology thereof | |
| CN105064169B (en) | A kind of submissive rhombus monofilament chinampa and preparation method thereof | |
| CN205053199U (en) | Injecting glue toothbrush brush head | |
| CN205143897U (en) | Tumbler formula music toothbrush | |
| CN102153797B (en) | Injection rubber foamed sole and manufacturing method thereof | |
| CN206879793U (en) | A kind of wire rope handling dumbbell toy | |
| CN105390180A (en) | Novel insulating material | |
| CN105124815A (en) | Magnetic jacket fabric | |
| KR20120029114A (en) | String for sports racket | |
| CN203169951U (en) | Table tennis bat grab handle | |
| CN108635789A (en) | A kind of table tennis bat being convenient for changing rubber | |
| CN103554874A (en) | Novel composite polycarbonate material for shell body of water cup and preparation method of novel composite polycarbonate material | |
| CN206902334U (en) | A kind of elastic filament of property | |
| CN217794431U (en) | Knee joint patella ring | |
| CN201759028U (en) | Novel toothbrush head |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20190405 |
|
| WD01 | Invention patent application deemed withdrawn after publication |