CN105295284A - Special material with high resilience for grass of artificial turf and preparation method thereof - Google Patents
Special material with high resilience for grass of artificial turf and preparation method thereof Download PDFInfo
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- CN105295284A CN105295284A CN201510822612.3A CN201510822612A CN105295284A CN 105295284 A CN105295284 A CN 105295284A CN 201510822612 A CN201510822612 A CN 201510822612A CN 105295284 A CN105295284 A CN 105295284A
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Abstract
The invention discloses a special material with high resilience for grass of artificial turf and a preparation method thereof. The special material comprises the following raw materials: SEBS rubber resin, a softening plasticizer, polyolefin elastomer, ethylene propylene terpolymer rubber, polypropylene resin, activated nanometer calcium carbonate, anti-oxidant, a light stabilizing agent and a processing aid, wherein the SEBS rubber resin is styrene-ethylene-butadiene-styrol copolymer, the activated nanometer calcium carbonate is at least one selected from the group consisting of stearic acid activated nanometer calcium carbonate and silane coupling agent activated nanometer calcium carbonate, and the polyolefin elastomer is at least one selected from the group consisting of ethylene-octylene copolymer, ethylene-butylene copolymer and propylene-ethylene copolymer. The special material has the advantages of no halogen, good aging resistance, soft texture, easiness in machine shaping, etc. The preparation method is simple and easily implementable and can rapidly prepare a special material product with high resilience for the grass of artificial turf; and the prepared product can be widely applied to a variety of football courts, tennis courts, golf courses and the like and has a wide application scope.
Description
Technical field
The present invention relates to artificial turf, be specifically related to a kind of high resilience artificial turf blade of grass PP Pipe Compound and preparation method thereof, belong to wire forming field of material technology.
Background technology
Along with improving constantly of people's living standard, the mode of life also more and more diversification of people, nowadays, people more and more pay attention to strengthening physical culture motion exercise.Therefore, artificial turf is gathered around and is held out broad prospects.Compared to true turf, the advantages such as artificial turf is easy to arrange, and maintenance cost is low.Artificial turf comprises blade of grass above, blade of grass damping material spaced intermediate and basic unit three part composition.Now commercially general blade of grass is made up of PP, PE or PA, but the turf that above three kinds of materials are made all also has a lot of deficiencies.PP turf is widely used, and is generally used for tennis court, basketball court, playground etc.; But due to some reasons of its material itself; Material is comparatively hard, light fastness aging is poor; Comparatively PP is strong for the soft light aging resisting of PE turf performance; PA turf pulling force is strong, fire-retardant good with wear resisting property, is generally used for golf percussion pad and hockey field, but its price.In addition, above three-type-person makes flexible inadequate and large to the skin injury shortcoming of turf.
Summary of the invention
The object of the invention is to overcome the deficiencies in the prior art, provide one to have resilience good, anti-aging, tensile strength is high and quality soft, high resilience artificial turf blade of grass PP Pipe Compound of very easily machine-shaping and preparation method thereof.
Contriver finds, SEBS rubber resin, terpolymer EP rubber, polyolefin elastomer, acrylic resin are composite contributes to the tensile strength and the ageing resistance that improve material under softening softening agent is assisted, and the material proportion obtained is moderate, quality is soft, is suitable as very much artificial turf blade of grass material.
Contriver is found by test, and appropriate active nano-calcium carbonate is conducive to the wear resisting property improving the artificial turf blade of grass that the present invention is prepared for main raw material with SEBS rubber resin, terpolymer EP rubber, polyolefin elastomer, acrylic resin; But active nano-calcium carbonate is easily reunited usually, the present invention is by softening softening agent and the raw material mixture such as SEBS rubber resin and terpolymer EP rubber, efficiently solve the agglomeration traits of active nano-calcium carbonate, make active nano-calcium carbonate improve the wear resistance of PP Pipe Compound of the present invention.
For achieving the above object, the present invention adopts following technical scheme:
A kind of high resilience artificial turf blade of grass PP Pipe Compound, is made up of the raw material of following mass percent:
Described SEBS rubber resin is SIS/SEBS;
Described polyolefin elastomer is at least one in ethylene-octene copolymer, ethylene-butene copolymer, propylene-ethylene copolymers;
Described nano active charcoal acid calcium is at least one in stearic acid activation nano-calcium carbonate, silane coupling agent activation nano-calcium carbonate;
Described processing aid is at least one in low molecule ester class, polysiloxane-based, metal soap, stearic acid complex ester class, amides.
For realizing the object of the invention further, preferably, described softening softening agent is at least one in saturated straight chain naphthenic oil and white mineral oil.
Preferably, described terpolymer EP rubber is at least one in E type EPDM, D type EPDM and H type EPDM.
Preferably, described acrylic resin is at least one in homo-polypropylene, Co-polypropylene and atactic copolymerized polypropene.
Preferably, described oxidation inhibitor is Hinered phenols antioxidant, phosphite ester kind antioxidant and at least one containing oxidation inhibitor in thioesters class.
Preferably, described photostabilizer is at least one in hydroxy benzophenone ketone photostabilizer, hydroxybenzotriazole class photostabilizer, hindered amines stabilizer, Hinered phenols photostabilizer, activation nano-calcium carbonate, mineral-type photostabilizer and composite efficient photostabilizer.
The preparation method of described high resilience artificial turf blade of grass PP Pipe Compound, comprises the following steps:
(1) first softening softening agent is fully absorbed with SEBS rubber resin, then good absorption is softened the SEBS rubber resin of softening agent, polyolefin elastomer, terpolymer EP rubber, acrylic resin, oxidation inhibitor, photostabilizer and processing aid component fully to mix in proportion, obtain mixture;
(2) described mixture is added, extrusion temperature is 160 ~ 200 DEG C, rotating speed is melting mixing in the Strong shear twin screw extruder of 350 ~ 480rpm, then successively through extruding, tie rod, obtain high resilience artificial turf blade of grass PP Pipe Compound goods after air-cooled, pelletizing and drying process.
Preferably, described twin screw extruder length-to-diameter ratio is 40:1 ~ 48:1.
Relative to prior art, beneficial effect of the present invention is:
1) SEBS rubber resin of the present invention, terpolymer EP rubber, polyolefin elastomer, composite tensile strength and the ageing resistance contributing to raising material under softening softening agent is assisted of acrylic resin, and the material proportion obtained is moderate, quality is soft, is suitable as very much artificial turf blade of grass material.
2) the present invention adds the wear resisting property that appropriate active nano-calcium carbonate is conducive to improving the artificial turf blade of grass that the present invention is prepared for main raw material with SEBS rubber resin, terpolymer EP rubber, polyolefin elastomer, acrylic resin.
3) active nano-calcium carbonate is easily reunited usually, the present invention is by softening softening agent and the raw material mixture such as SEBS rubber resin and terpolymer EP rubber, efficiently solve the agglomeration traits of active nano-calcium carbonate, make active nano-calcium carbonate improve the wear resistance of PP Pipe Compound of the present invention.
4) wire forming PP Pipe Compound provided by the invention has Halogen, ageing resistance is good, the advantage of quality softness, due to Halogen, effectively stops discharge objectionable impurities in burning with heat-processed, threatens the health of human body and the phenomenon of environment.
5) processing step of preparation method provided by the invention is succinct, and be easy to realize, can make high resilience artificial turf blade of grass PP Pipe Compound goods fast, these goods can be widely used in various football pitch, tennis court, and golf course etc. are applied widely.
Embodiment
For understanding the present invention better, below in conjunction with embodiment, the invention will be further described, but embodiments of the present invention are not limit so.
Embodiment 1
A kind of high resilience artificial turf blade of grass PP Pipe Compound, it is made up of the raw material of following mass percent: SEBS rubber resin 28 ﹪, softening softening agent 30 ﹪, polyolefin elastomer 8 ﹪, terpolymer EP rubber 12 ﹪, acrylic resin 10 ﹪, activation nano-calcium carbonate 10%, oxidation inhibitor 0.3 ﹪, photostabilizer 0.7 ﹪, processing aid 1 ﹪.
SEBS rubber resin is SIS/SEBS.This SEBS rubber resin selects Ba Ling petrochemical industry SEBSYH-503T (high hydrogenation degree, desalination product).Softening softening agent is saturated straight chain naphthenic oil; Specifically select the naphthene base crude oil KN4006 of Karamay, Xinjiang petro-chemical corporation.Polyolefin elastomer is ethylene-octene copolymer, ethylene-butene copolymer, propylene-ethylene copolymers; Specifically select Vistamaxx3980FL (MI:18, Exxon Mobil).Terpolymer EP rubber (EPDM) selects E type EPDM (Mitsui chemistry 3092PM).Acrylic resin selects the 1100NK (MI:13) of Pu Lima company.Active nano-calcium carbonate is the 625C of the full powder company in Dongguan five.Irganox1076 and Irgafos126 (German BASF) selected by oxidation inhibitor, and wherein Irganox1076 accounts for raw material total mass per-cent is that to account for raw material total mass per-cent be 0.15 ﹪ for 0.15 ﹪, Irgafos126.Composite efficient photostabilizer TU-8288 selected by photostabilizer, this composite efficient photostabilizer TU-8288 is produced by Dongguan City Tong Jin novel material Science and Technology Ltd., have strong band UV absorption function, to metal ion, insensitive and anti-copper evil function, improves material thermostability function etc.Processing aid selects the silicone master batch MB50-002 of DOW CORNING, and lubricant is done in its effect.
A preparation method for high resilience artificial turf blade of grass PP Pipe Compound, comprises the following steps:
(1) first softening softening agent is fully absorbed with SEBS rubber resin, then good absorption is softened the SEBS rubber resin of softening agent, polyolefin elastomer, acrylic resin, active nano-calcium carbonate, oxidation inhibitor, photostabilizer and processing aid component fully to mix in proportion, obtain mixture.
(2) by feeder, described mixture is sent into Strong shear twin screw extruder, wherein, the length-to-diameter ratio of this Strong shear twin screw extruder is 48:1, screw zones temperature is respectively: 160 DEG C, 170 DEG C, 180 DEG C, 190 DEG C, 190 DEG C, 190 DEG C, 190 DEG C, 190 DEG C, 180 DEG C, 180 DEG C, 180 DEG C, head temperature 180 DEG C, rotating speed is 420rpm.Then successively through extruding, tie rod, obtain high resilience artificial turf blade of grass PP Pipe Compound goods after air-cooled, pelletizing and drying process.
Embodiment 2
A kind of high resilience artificial turf blade of grass PP Pipe Compound, it is made up of the raw material of following mass percent: SEBS rubber resin 35 ﹪, softening softening agent 20 ﹪, polyolefin elastomer 11 ﹪, terpolymer EP rubber 8 ﹪, acrylic resin 14 ﹪, activation nano-calcium carbonate 10%, oxidation inhibitor 0.3 ﹪, photostabilizer 0.7 ﹪, processing aid 1 ﹪.SEBS rubber resin is SIS/SEBS.
This SEBS rubber resin selects Ba Ling petrochemical industry SEBSYH-503T (high hydrogenation degree, desalination product).Softening softening agent is saturated straight chain naphthenic oil; Specifically select the naphthene base crude oil KN4006 of Karamay, Xinjiang petro-chemical corporation.Polyolefin elastomer is ethylene-octene copolymer, ethylene-butene copolymer, propylene-ethylene copolymers; Specifically select Vistamaxx3980FL (MI:18, Exxon Mobil).Terpolymer EP rubber (EPDM) selects E type EPDM (Mitsui chemistry 3092PM).Acrylic resin selects the 1100NK (MI:13) of Pu Lima company.Active nano-calcium carbonate is the 625C of the full powder company in Dongguan five.Irganox1076 and Irgafos126 (German BASF) selected by oxidation inhibitor, and wherein Irganox1076 accounts for raw material total mass per-cent is that to account for raw material total mass per-cent be 0.15 ﹪ for 0.15 ﹪, Irgafos126.Composite efficient photostabilizer TU-8288 selected by photostabilizer, this composite efficient photostabilizer TU-8288 is produced by Dongguan City Tong Jin novel material Science and Technology Ltd., have strong band UV absorption function, to metal ion, insensitive and anti-copper evil function, improves material thermostability function etc.Processing aid selects the silicone master batch MB50-002 of DOW CORNING, and lubricant is done in its effect.
A preparation method for high resilience artificial turf blade of grass PP Pipe Compound, comprises the following steps:
(1) first softening softening agent is fully absorbed with SEBS rubber resin, then good absorption is softened the SEBS rubber resin of softening agent, polyolefin elastomer, acrylic resin, active nano-calcium carbonate, oxidation inhibitor, photostabilizer and processing aid component fully to mix in proportion, obtain mixture.
(2) by feeder, described mixture is sent into Strong shear twin screw extruder, wherein, the length-to-diameter ratio of this Strong shear twin screw extruder is 40:1, screw zones temperature is respectively: 160 DEG C, 175 DEG C, 180 DEG C, 195 DEG C, 190 DEG C, 195 DEG C, 190 DEG C, 200 DEG C, 185 DEG C, 180 DEG C, 180 DEG C, head temperature 180 DEG C, rotating speed is 350rpm.Then successively through extruding, tie rod, obtain high resilience artificial turf blade of grass PP Pipe Compound goods after air-cooled, pelletizing and drying process.
Embodiment 3
A kind of high resilience artificial turf blade of grass PP Pipe Compound, it is made up of the raw material of following mass percent: SEBS rubber resin 20 ﹪, softening softening agent 36 ﹪, polyolefin elastomer 5 ﹪, terpolymer EP rubber 5 ﹪, acrylic resin 15 ﹪, activation nano-calcium carbonate 15%, oxidation inhibitor 1.5 ﹪, photostabilizer 1 ﹪, processing aid 1.5 ﹪.
SEBS rubber resin is SIS/SEBS.This SEBS rubber resin selects the YH-503 of Ba Ling petrochemical industry SEBS.Softening softening agent is paraffin oil (150N of the two dragon of Germany).Polyolefin elastomer is ethylene-octene copolymer, ethylene-butene copolymer, propylene-ethylene copolymers; Specifically select Engage8480 (Dupont Tao Shi).Terpolymer EP rubber (EPDM) selects E type EPDM (Mitsui chemistry 3092PM).Acrylic resin selects the 1100NK (MI:13) of Pu Lima company.Active nano-calcium carbonate is the 625C of the full powder company in Dongguan five.Irganox1076 and Irgafos126 (German BASF) selected by oxidation inhibitor, and wherein Irganox1076 accounts for raw material total mass per-cent is that to account for raw material total mass per-cent be 0.5 ﹪ for 0.1 ﹪, Irgafos126.Composite efficient photostabilizer TU-8288 selected by photostabilizer, this composite efficient photostabilizer TU-8288 is produced by Dongguan City Tong Jin novel material Science and Technology Ltd., have strong band UV absorption function, to metal ion, insensitive and anti-copper evil function, improves material thermostability function etc.Processing aid selects the silicone master batch MB50-002 of DOW CORNING, and lubricant is done in its effect.
A preparation method for high resilience artificial turf blade of grass PP Pipe Compound, comprises the following steps:
(1) first softening softening agent is fully absorbed with SEBS rubber resin, then good absorption is softened the SEBS rubber resin of softening agent, polyolefin elastomer, acrylic resin, active nano-calcium carbonate, oxidation inhibitor, photostabilizer and processing aid component fully to mix in proportion, obtain mixture.
(2) by feeder, described mixture is sent into Strong shear twin screw extruder, wherein, the length-to-diameter ratio of this Strong shear twin screw extruder is 45:1, screw zones temperature is respectively: 160 DEG C, 170 DEG C, 185 DEG C, 190 DEG C, 190 DEG C, 190 DEG C, 195 DEG C, 200 DEG C, 189 DEG C, 185 DEG C, 185 DEG C, head temperature 185 DEG C, rotating speed is 480rpm.Then successively through extruding, tie rod, obtain high resilience artificial turf blade of grass PP Pipe Compound goods after air-cooled, pelletizing and drying process.
Below to carry out quantitative measurement, specifically see table 1 to the high resilience artificial turf blade of grass PP Pipe Compound goods of embodiment 1, embodiment 2 and embodiment 3.
Table 1
Can be learnt by table 1, SEBS rubber resin of the present invention, terpolymer EP rubber, polyolefin elastomer, acrylic resin are composite contributes to the tensile strength and the ageing resistance that improve material, tensile strength 6.5Mpa under softening softening agent is assisted; And the material proportion obtained is moderate, density is 0.9g/cm
3, quality is soft, shore hardness be 70 ?80, be suitable as very much artificial turf blade of grass material.
The present invention adds the wear resisting property that appropriate active nano-calcium carbonate is conducive to improving the artificial turf blade of grass that the present invention is prepared for main raw material with SEBS rubber resin, terpolymer EP rubber, polyolefin elastomer, acrylic resin.
Wire forming PP Pipe Compound provided by the invention has Halogen, ageing resistance is good, quality is soft advantage, due to Halogen, effectively stops discharge objectionable impurities in burning with heat-processed, threatens the health of human body and the phenomenon of environment.
In general, high resilience artificial turf blade of grass PP Pipe Compound of the present invention have ageing-resistant, tensile strength is high, feel is splendid, good and the high flowing of flexibility, the very easily advantage such as machine-shaping, can be widely used in artificial turf monofilament product, its hardness can carry out regulating with practical requirement very easily.And processing step is succinct, be easy to realize.Experienced by actual production, clearly can feel that can improve now artificial turf on the market easily injures the shortcoming of skin.
The announcement of book and instruction according to the above description, those skilled in the art in the invention can also change above-mentioned embodiment and revise.Therefore, the present invention is not limited to embodiment disclosed and described above, also should fall in the protection domain of claim of the present invention modifications and changes more of the present invention.
Claims (8)
1. a high resilience artificial turf blade of grass PP Pipe Compound, it is characterized in that, it is made up of the raw material of following mass percent:
Described SEBS rubber resin is SIS/SEBS;
Described polyolefin elastomer is at least one in ethylene-octene copolymer, ethylene-butene copolymer, propylene-ethylene copolymers;
Described nano active charcoal acid calcium is at least one in stearic acid activation nano-calcium carbonate, silane coupling agent activation nano-calcium carbonate;
Described processing aid is at least one in low molecule ester class, polysiloxane-based, metal soap, stearic acid complex ester class, amides.
2. high resilience artificial turf blade of grass PP Pipe Compound according to claim 1, is characterized in that: described softening softening agent is at least one in saturated straight chain naphthenic oil and white mineral oil.
3. high resilience artificial turf blade of grass PP Pipe Compound according to claim 1, is characterized in that: described terpolymer EP rubber is at least one in E type EPDM, D type EPDM and H type EPDM.
4. high resilience artificial turf blade of grass PP Pipe Compound according to claim 1, is characterized in that: described acrylic resin is at least one in homo-polypropylene, Co-polypropylene and atactic copolymerized polypropene.
5. high resilience artificial turf blade of grass PP Pipe Compound according to claim 1, is characterized in that: described oxidation inhibitor is Hinered phenols antioxidant, phosphite ester kind antioxidant and at least one containing oxidation inhibitor in thioesters class.
6. high resilience artificial turf blade of grass PP Pipe Compound according to claim 1, is characterized in that: described photostabilizer is at least one in hydroxy benzophenone ketone photostabilizer, hydroxybenzotriazole class photostabilizer, hindered amines stabilizer, Hinered phenols photostabilizer, mineral-type photostabilizer and composite efficient photostabilizer.
7. the preparation method of high resilience artificial turf blade of grass PP Pipe Compound according to any one of claim 1 ~ 6, is characterized in that comprising the following steps:
(1) first softening softening agent is fully absorbed with SEBS rubber resin, then good absorption is softened the SEBS rubber resin of softening agent, polyolefin elastomer, terpolymer EP rubber, activation nano-calcium carbonate, acrylic resin, oxidation inhibitor, photostabilizer and processing aid component fully to mix in proportion, obtain mixture;
(2) described mixture is added, extrusion temperature is 160 ~ 200 DEG C, rotating speed is melting mixing in the Strong shear twin screw extruder of 350 ~ 480rpm, then successively through extruding, tie rod, obtain high resilience artificial turf blade of grass PP Pipe Compound goods after air-cooled, pelletizing and drying process.
8. the preparation method of high resilience artificial turf blade of grass PP Pipe Compound according to claim 7, it is characterized in that, described twin screw extruder length-to-diameter ratio is 40:1 ~ 48:1.
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Cited By (6)
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| CN106496917A (en) * | 2016-11-09 | 2017-03-15 | 深圳市普特美橡塑原料有限公司 | A kind of modified form of resistance to toluene TPE plastic cement |
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| WO2020142232A1 (en) | 2019-01-03 | 2020-07-09 | Dow Global Technologies Llc | Artificial turf having siloxane polymer containing turf infill and compositions for making such turf infill |
| CN111607237A (en) * | 2020-06-15 | 2020-09-01 | 浦江羽洋塑胶有限公司 | Preparation method of silica gel-like product material |
| CN115094540A (en) * | 2022-07-18 | 2022-09-23 | 江苏赛斯人造草坪有限公司 | Manufacturing method of high-strength wear-resistant artificial lawn grass filaments |
| CN117965009A (en) * | 2024-01-19 | 2024-05-03 | 广州傲群刷业科技有限公司 | Carbon fiber composite material and wire drawing process and application thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN106496917A (en) * | 2016-11-09 | 2017-03-15 | 深圳市普特美橡塑原料有限公司 | A kind of modified form of resistance to toluene TPE plastic cement |
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| CN107974024B (en) * | 2017-12-20 | 2020-03-17 | 石家庄英利体育用品有限公司 | Thermoplastic elastomer composition, and preparation method and application thereof |
| WO2020142232A1 (en) | 2019-01-03 | 2020-07-09 | Dow Global Technologies Llc | Artificial turf having siloxane polymer containing turf infill and compositions for making such turf infill |
| CN111607237A (en) * | 2020-06-15 | 2020-09-01 | 浦江羽洋塑胶有限公司 | Preparation method of silica gel-like product material |
| CN115094540A (en) * | 2022-07-18 | 2022-09-23 | 江苏赛斯人造草坪有限公司 | Manufacturing method of high-strength wear-resistant artificial lawn grass filaments |
| CN117965009A (en) * | 2024-01-19 | 2024-05-03 | 广州傲群刷业科技有限公司 | Carbon fiber composite material and wire drawing process and application thereof |
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