CN1095395A - Liquid protection agent for leather products and preparation method - Google Patents
Liquid protection agent for leather products and preparation method Download PDFInfo
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- CN1095395A CN1095395A CN 93105084 CN93105084A CN1095395A CN 1095395 A CN1095395 A CN 1095395A CN 93105084 CN93105084 CN 93105084 CN 93105084 A CN93105084 A CN 93105084A CN 1095395 A CN1095395 A CN 1095395A
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- protection agent
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Abstract
The invention provides liquid protection agent for leather products, comprise natural wax, nonionic surface active agent, sheep oil, silicone oil, glycerine, vinylformic acid finishing agent, essence and water.The method for preparing liquid protection agent for leather products comprises mixes natural wax and nonionic surface active agent, heat fused, add hot water, the even postcooling of vigorous stirring is to room temperature, add sheep oil, glycerine silicone oil and pigment, mix the back vigorous stirring, compound is cooled off to room temperature, add vinylformic acid finishing agent and essence again, mix liquid protection agent for leather products.This curing agent has excellent effect to leatherware anti-chap, waterproof, anti-electrostatic and rub resistance, makes leatherware light as new, gloss nature after being coated with, leather hand feeling is soft, plentiful and high resilience.
Description
The present invention relates to liquid protection agent for leather products, relate in particular to protection agent for leather products such as leather shoes, leatherwear.The invention still further relates to the method for preparing liquid protection agent for leather products.
At present, liquid shoe polish and the leather oil sold on the market are of a great variety, and existing home-made has import again.But behind these product life-time service, accumulated thick film on the leatherware surface, and because the film of one deck is incomplete, uneven distribution has seriously influenced the visual appearance of leatherware.
DE3323929 has introduced a kind of leather and leather shoes liquid water-latex type curing agent, contain blended wax such as Carlow and cling to wax, gama wax, montanic acid ester type waxes, lanolin, aliphatic polyurethane resin emulsion, water soluble polycarboxylic acid, nonionic emulsifier, C2-12 water soluble hydroxy amine and essence, sanitas, defoamer and thickening material etc.Owing to adopt resin emulsion as material of main part, make the leatherware surface film of uneven distribution occur, and owing to itself do not contain the guard composition, cause leatherware surface hardening, big and dark crackle occurs, also have, lanolin emulsification need add too much tensio-active agent, particularly must add the close tensio-active agent of hydrophilic and oleophilic value, tensio-active agent adds too much the easy bubble that produces.
Purpose of the present invention just provides and overcomes the liquid protection agent for leather products that has defective in the prior art fully; its adopts film forming as thin as a wafer, replace original resene material of main part from the natural wax of brightness height, protection leather; and, just can obtain the ideal effect in conjunction with sheep oil stuffing guard technology.
Liquid protection agent for leather products of the present invention comprises natural wax, nonionic surface active agent, sheep oil, silicone oil, glycerine, vinylformic acid finishing agent, pigment, essence and water.Wherein, natural wax is meant a kind of or its mixture in Carlow crust wax, montanin wax and the paraffin, and they all are selected from the commercially available prod.Natural wax has filling, glazing, multiple function such as smooth, and the consumption of the leatherware good hand feeling after the wherethrough reason, coating gloss nature, natural wax of the present invention is counted 3-21 part by the weight part of liquid protection agent for leather products.Nonionic surface active agent in the liquid protection agent for leather products of the present invention is that newborn lark A(auxiliary reagent factory produces Tianjin), be the condenses of Fatty Alcohol(C12-C14 and C12-C18) and oxyethane, as wax class emulsifying agent, its consumption is 0.3-5 part.Sheep oil is meant, by the grease that extracts in the lanolin, through depickling, decolouring, deodorization chemical treatment, the mineral oil of adding 10-40% and/or animal oil such as ox, lard mix, its consumption is 0.5-2 part, and it has performances such as the leatherware of making soft surface, plentiful, tough and tensile, fire prevention, wear-resistant and antifatigue.Silicone oil is the commercially available prod, plays a part to replenish the oil content froth breaking in liquid protection agent for leather products of the present invention, and its consumption is 0.01-1 part, and glycerine prevents that as wetting agent leatherware is dry and cracked, selects the commercially available prod for use, and its consumption is 0.3-0.8 part.The vinylformic acid finishing agent is by the emulsion of polynary acrylic resin copolymerization gained, is selected from 21
RiceEmulsion acrylic resin or R2 Emulsion acrylic resin (being produced by Tianjin leather chemical industry factory), its consumption is 0.8-2.0 part.Pigment is black or brown, and a kind of with among acid particle black, Acid Black 10B, the erie black ATT of black pigment is the commercially available prod, and its consumption is 0.1-0.7 part.Essence is by the artificial redeployed mixtures two or more at least and even tens kinds of natural perfumes that contain, and suitable have jasmine, fruital, lemon and osmanthus flower fragrant spices.Its consumption is 0.05-0.3 part.Water is tap water, distilled water or deionized water, and its consumption is 20-40 part.
The preparation method of liquid protection agent for leather products of the present invention comprises natural wax and nonionic surface active agent is dropped in the reactor, and its intensification is heated to 60-100 ℃, melts until natural wax; 80-100 ℃ hot water is dropped in the fused wax liquid, and the even postcooling of vigorous stirring is to room temperature; In reactor, add sheep oil, glycerine, silicone oil and pigment, carried out after mixing vigorous stirring 5-20 minute; Compound is cooled off to room temperature, add vinylformic acid finishing agent and essence again, mix and promptly get liquid protection agent for leather products.
Below with embodiment the present invention is described in detail.
Embodiment 1
7 parts in wax is clung in the Carlow, and 7 parts of montanin waxes, 1 part in paraffin and newborn lark A4 part are dropped in the reactor, after the heat fused, pour 20 parts of 85 ℃ of hot water into, be chilled to room temperature after vigorous stirring is even, to wherein adding 0.4 part of glycerine, 0.5 part of silicone oil, 1 part of sheep oil, 0.2 part of Acid Black 10B, stirred 5 minutes, after being chilled to room temperature, add 1 part of R2 Emulsion acrylic resin, 0.1 part of fruital and osmanthus flower fragrant spices, mix, get the black liquor protection agent for leather products.
Embodiment 2
4 parts in wax, 4 parts of montanin waxes are clung in the Carlow, 2 parts in paraffin and newborn lark A2 part are dropped in the reactor, after the heat fused, pour 25 parts of 90 ℃ of hot water into, be chilled to room temperature after vigorous stirring is even, to wherein adding 0.5 part of 0.6 part of glycerine, 1 part of silicone oil, 0.5 part of sheep oil and acid particle black, stirred 10 minutes, and be chilled to room temperature, add 1.5 parts of R2 Emulsion acrylic resins, 0.15 part of jasmine and osmanthus flower fragrant spices, mix the black liquor protection agent for leather products.
Embodiment 3
The Carlow is clung in 6 parts in wax, 3 parts of montanin waxes, the newborn lark A1 part input reactor, after the heat fused, pour 30 parts of 80 ℃ of hot water into, be chilled to room temperature after vigorous stirring is even,, stirred 10 minutes to wherein adding 0.4 part of glycerine, 0.5 part of silicone oil, sheep oil 0.7 part and reddish brown RN0.4 part, after being chilled to room temperature, add 2 parts of R2 Emulsion acrylic resins, 0.2 part of citric acid and jasmine fragrance, mix the brown liquid protection agent for leather products.
Liquid protection agent for leather products of the present invention especially has excellent effect to leather shoes anti-chap, waterproof, anti-electrostatic and rub resistance to leather.After this liquid curing agent applies leather shoes, make leather shoes shining such as new, gloss nature, leather hand feeling is soft, plentiful and high resilience.
Claims (7)
1, liquid protection agent for leather products, comprise by heavy per-cent natural wax 3-21 part, nonionic surface active agent 0.3-5 part, sheep oil 0.5-2 part, silicone oil 0.01-1 part, glycerine 0.3-0.8 part, vinylformic acid finishing agent 0.8-2.0 part, pigment 0.1-0.7 part, essence 0.05-0.3 part and water 20-40 part.
2, according to the liquid protection agent for leather products of claim 1, wherein said natural wax is a kind of or its mixture in Carlow crust wax, montanin wax and the paraffin.
3, according to the liquid protection agent for leather products of claim 1, wherein said nonionic surface active agent is newborn lark A.
4, according to the liquid protection agent for leather products of claim 1, wherein said sheep oil is meant by the grease that extracts in the lanolin and handles through depickling, decolouring and deodorization, adds 10-40% mineral oil and/or animal oil and mix.
5, according to the liquid protection agent for leather products of claim 1, wherein said vinylformic acid finishing agent is meant 21
RiceEmulsion acrylic resin or R2 Emulsion acrylic resin.
6, according to the liquid protection agent for leather products of claim 1, wherein said pigment is meant acid particle black, Acid Black 10B or erie black ATT.
7, prepare the method for liquid protection agent for leather products, comprising:
(a) natural wax and nonionic surface active agent are dropped in the reactor, be heated to 60-100 ℃, the fusing natural wax;
(b) add 80-100 ℃ of hot water in fusing wax, the even postcooling of vigorous stirring is to room temperature;
(c) add sheep oil, silicone oil, glycerine and pigment, mixed the back vigorous stirring 5-20 minute, be cooled to room temperature;
(d) add vinylformic acid finishing agent and essence, mix and make liquid protection agent for leather products.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 93105084 CN1095395A (en) | 1993-05-20 | 1993-05-20 | Liquid protection agent for leather products and preparation method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 93105084 CN1095395A (en) | 1993-05-20 | 1993-05-20 | Liquid protection agent for leather products and preparation method |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1095395A true CN1095395A (en) | 1994-11-23 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 93105084 Pending CN1095395A (en) | 1993-05-20 | 1993-05-20 | Liquid protection agent for leather products and preparation method |
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| CN (1) | CN1095395A (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1331971C (en) * | 2000-06-09 | 2007-08-15 | 赵志刚 | Leather dry cleaning finishing cream |
| CN102775918A (en) * | 2012-07-06 | 2012-11-14 | 南通帝星化工有限公司 | Fragrant shoe polish |
| CN102965921A (en) * | 2012-12-14 | 2013-03-13 | 吴江市利达上光制品有限公司 | Softener for artificial leather |
| CN104152055A (en) * | 2012-10-17 | 2014-11-19 | 北京桑普生物化学技术有限公司 | Concentrated liquid used for preparing leather polishing nursing products, and use thereof |
| CN105113235A (en) * | 2015-09-06 | 2015-12-02 | 上海应用技术学院 | Slow-release aromatic for leather and preparation method of slow-release aromatic |
| CN105219529A (en) * | 2015-09-02 | 2016-01-06 | 上海应用技术学院 | A kind of fragrant leather lavender oil and its preparation method and application |
| CN106928787A (en) * | 2017-03-13 | 2017-07-07 | 广州市佐力新材料科技有限公司 | A kind of leather colouring, complementary color maintaining agent and preparation method thereof |
| CN107099626A (en) * | 2017-05-26 | 2017-08-29 | 上海皇宇科技发展有限公司 | A kind of vamp filling glazing dressing agent and preparation method thereof |
-
1993
- 1993-05-20 CN CN 93105084 patent/CN1095395A/en active Pending
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1331971C (en) * | 2000-06-09 | 2007-08-15 | 赵志刚 | Leather dry cleaning finishing cream |
| CN102775918A (en) * | 2012-07-06 | 2012-11-14 | 南通帝星化工有限公司 | Fragrant shoe polish |
| CN104152055A (en) * | 2012-10-17 | 2014-11-19 | 北京桑普生物化学技术有限公司 | Concentrated liquid used for preparing leather polishing nursing products, and use thereof |
| CN102965921A (en) * | 2012-12-14 | 2013-03-13 | 吴江市利达上光制品有限公司 | Softener for artificial leather |
| CN105219529A (en) * | 2015-09-02 | 2016-01-06 | 上海应用技术学院 | A kind of fragrant leather lavender oil and its preparation method and application |
| CN105113235A (en) * | 2015-09-06 | 2015-12-02 | 上海应用技术学院 | Slow-release aromatic for leather and preparation method of slow-release aromatic |
| CN106928787A (en) * | 2017-03-13 | 2017-07-07 | 广州市佐力新材料科技有限公司 | A kind of leather colouring, complementary color maintaining agent and preparation method thereof |
| CN106928787B (en) * | 2017-03-13 | 2019-04-02 | 广州市佐力新材料科技有限公司 | A kind of colouring of leather, complementary color maintaining agent and preparation method thereof |
| CN107099626A (en) * | 2017-05-26 | 2017-08-29 | 上海皇宇科技发展有限公司 | A kind of vamp filling glazing dressing agent and preparation method thereof |
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Addressee: Anglo fine chemical Beijing Co., Ltd. Document name: payment instructions |