CN109536177A - The soil conditioner and production method produced using sodium glutamate mother liquid and trade waste - Google Patents
The soil conditioner and production method produced using sodium glutamate mother liquid and trade waste Download PDFInfo
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- CN109536177A CN109536177A CN201811586635.9A CN201811586635A CN109536177A CN 109536177 A CN109536177 A CN 109536177A CN 201811586635 A CN201811586635 A CN 201811586635A CN 109536177 A CN109536177 A CN 109536177A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K17/00—Soil-conditioning materials or soil-stabilising materials
- C09K17/40—Soil-conditioning materials or soil-stabilising materials containing mixtures of inorganic and organic compounds
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Abstract
The present invention relates to a kind of soil conditioner produced using sodium glutamate mother liquid and trade waste and production methods, belong to soil conditioner.Raw material including following parts by weight: 50-90 parts of the gourmet powder fermenting tail washings of concentration 50-55%, 5-50 parts of plant ash, 5-20 parts of monosodium glutamate waste active carbon, 1-2 parts of blackstrap.The present invention makes full use of the physicochemical property of gourmet powder fermenting tail washings, monosodium glutamate waste active carbon, blackstrap, plant ash, depth integration, provide a kind of production of comprehensive utilization waste material wide spectrum, multi-functional soil conditioner product, meet the comprehensive nutritional need of crop, activation repairing soil micro-ecosystem system, the harmful substance of absorption retention pedo relict, realizes soil health comprehensively, soil indices significantly improve, and provide quality product to solve the bottleneck problem of current agricultural development.
Description
Technical field
The invention belongs to soil conditioners, more particularly to produce soil conditioner using sodium glutamate mother liquid and trade waste
Method.
Background technique
China has a vast territory, resourceful, fertile soil, is the treasure of the Chinese nation, but with chemical fertilizer in recent years,
Pesticide is gradually introduced, a large amount of to use, and is consumed the original organic matter in soil excessively, is declined year by year, causes soil depletion hardened,
Chronic administration pesticide leads to drug accumulation, and microecological balance is broken, a large amount of harmful substance of pedo relict, for present
Soil status is badly in need of a large amount of, good soil conditioner improved product rehabilitating soil, realizes agricultural sustainable development.
With the development of economy, further processing of grains industry flourishes, and monosodium glutamate annual output reaches more than 200 ten thousand tons, and year generates
More than 1,000 ten thousand tons, organic matter 12-13% of organic waste gourmet powder fermenting liquor, free amino acid 5-8%, sugared 8-10%, nitrogen 6-7%, phosphorus
0.5%, potassium 1-2%, rich in the soluble small organic molecule nutriment such as amino acid, nitrogen, active biological enzyme, polysaccharide.But taste
Smart fermentation tailing liquor has two serious deficiencies, is on the one hand acidity, and pH3.8-4.0, chronic administration will lead to soil and excessively be acidified；
On the other hand precisely due to monosodium glutamate tail washings is sticky, slurry-spraying pelletizing must use superhigh temperature, this will lead to organic matter amino acid and exists
Stewing in shallow water in pyroprocess, organic nutrient are largely destroyed, be manured into soil in be not easy to dissolve, or even the particle having is in the soil
One or two years still exists in the form of granules, cannot dissolve, and by crop utilization, causes the great wasting of resources.
In the industrial production, the plant ash that straw power generation generates, the waste active carbon that glutamate production decoloration generates, due to independent
Using will appear fugitive dust, packed and transported is at high cost, application is difficult to mechanization, it is difficult to really be applied to agricultural production, mostly carry out
Outdoor accumulation, industry landfill, pollutes environment, waste of resource.
The mother liquor blackstrap of sugarcane or beet sugar industry processing, is rich in monosaccharide and disaccharide, biotin, vitamins bioactivity
Substance.
Monosodium glutamate waste active carbon appearance is furvous powder, has good absorption property, chemical stability is good, is resistant to strong acid
Highly basic is amenable to water logging, high temperature.Partial size 1mm belongs to porous hereinafter, specific surface area is up to 1000~1500 meters squared per grams
Hydrophobic adsorbent.
Summary of the invention
The present invention provides a kind of soil conditioner produced using sodium glutamate mother liquid and trade waste and production method, with solution
The above problem existing for certainly existing sodium glutamate mother liquid soil conditioner.
The technical solution adopted by the present invention is that: the raw material including following parts by weight:
50-90 parts of the gourmet powder fermenting tail washings of concentration 50-55%；
5-50 parts of plant ash；
5-20 parts of monosodium glutamate waste active carbon；
1-2 parts of blackstrap.
A method of soil conditioner is produced using sodium glutamate mother liquid and trade waste, including the following steps:
(1) nutrient solution is prepared
(1) it by 5-50 parts of plant ash, puts into 50-90 parts of gourmet powder fermenting tail washings of concentration 50-55%, 60-80 DEG C, fills
Divide mixing, without reaction end is precipitated as, obtains mixed material；
(2) in upper step mixed material, blackstrap 1-2 parts is put into, continues to be stirred, 70-90 DEG C of temperature, 0.5-1 is small
When, obtain mixed material；
(3) in upper step mixed liquor, then 5-20 parts of monosodium glutamate waste active carbon are put into, 90-100 DEG C of temperature, mixes well steaming
It boils 1-2 hours, nutrient solution preparation is completed；
(2) slurry-spraying pelletizing
Nutrient solution preparation tank persistently stirs boiling, sprays to the particulate material of pelletizer through spray nozzle by dnockout pumps
In curtain, heat drying furnace provides hot-air, and moment and slurry contact, iterative cycles, particle incrementally increase, until reaching standard, transmits
To screening machine；
(3) it sieves, pack
The soil conditioner particle formed through slurry-spraying pelletizing obtains 90% or more granularity of granular fertilizer in 1- through vibrosieve
Between 4.75mm, packing is carried out after cooler is cooling and gets product soil conditioner.
The present invention is further analyzed below as follows:
(1) combined reaction, it is organic chelated
Gourmet powder fermenting tail washings pH3.8-4.0, organic matter 12-13%, free amino acid 5-8%, sugared 8-10% after concentration,
Nitrogen 6-7%, phosphorus 0.5%, potassium 1-2%, rich in the soluble small organic molecule nutrients such as amino acid, nitrogen, active biological enzyme, polysaccharide
Matter.The main component of plant ash is potassium carbonate (K2CO3), so being mineral element contained by all plants, nearly all contain in plant ash
Have.What wherein content was most is potassium element, contains potassium 6~12%, wherein 90% or more is water solubility, is existed with carbonate form；
Followed by phosphorus generally contains 1.5~3%；Also contain the micronutrient elements such as calcium, magnesium, silicon, sulphur and iron, manganese, copper, zinc, boron, molybdenum one
As, pH9-12.It is carried out by carbanion in sulfate radical a large amount of in gourmet powder fermenting tail washings, hydrogen ion and plant ash comprehensive anti-
It answers, one side acid-base integration releases carbon dioxide, then passes through soluble free small organic molecule carboxyl, amino isopolarity group
With it is free in trace element chelated recombination.
(2) edaphon prebiotics are deployed
The mother liquor blackstrap of sugarcane or beet sugar industry processing is added in mixed liquor, is rich in monosaccharide and disaccharide, biotin, dimension
Raw element class bioactive substance, further chelating recombinates, carbohydrate, organic-inorganic nitrogen, amino acid, vitamine class biology in mixed liquor
Active material, middle micro-element nutrition balance, form the nutrient solution of activating soil microorganism demand.
(3) waste active carbon displacement sorption is pelletized
Monosodium glutamate waste active carbon appearance is furvous powder, has good absorption property, chemical stability is good, is resistant to strong acid
Highly basic is amenable to water logging, high temperature, and partial size 1mm belongs to porous hereinafter, specific surface area is up to 1000~1500 meters squared per grams
Hydrophobic adsorbent.After industrial application, it is adsorbed with haloform and precursor substance, carbon tetrachloride, benzene class, phenols chemical substance,
It is reacted, nutrient solution is adsorbed again, the addition of active carbon reduces material by carrying out washing displacement at 80 DEG C with nutrient solution
The viscosity of slurry, while active carbon greatly reduces pelleting temperature, in nutriment not by height as the carrier as granulation
In the case that temperature is destroyed, spraying granulating can be completed.
Product of the present invention is with the following functions:
(a) containing nutriment needed for plant, pH5-8, organic matter 10%, free amino acid 5-8%, sugared 8-10%,
Nitrogen 6-7%, phosphorus 1-2%, potassium 2-5% are rich in bioactive substance, containing all necessary mineral elements of plant, and with
Organic chelated form exists, it can be achieved that sustained-release and controlled release.It can promote the photosynthesis of plant；Rich in micro member needed for plant
Element promotes crop vigor, Accelerate bloom result；Crop can be improved to the resistance of pest and disease damage.
(b) particle prebiotics are formed, by the way that gradually dissolution discharges in the soil, bacillus in activating soil, saccharomycete,
The beneficial microbes such as lactic acid bacteria, photosynthetic bacteria, mould are realized the quick breeding of indigenous probiotic bacterium, are aoxidized in the soil, nitre
The processes such as change, ammonification, fixed nitrogen, vulcanization promote the decomposition of the soil organism and the conversion of nutrient, and act on root of the crop table, root
Border, promotes the secondary metabolites controlling diseases such as the plant sustained release basic element of cell division, gibberellin, heteroauxin, and hestening rooting promotees
Into plant growth, enhance disease resistance.Long-time service can increase substantially utilization rate of fertilizer, improve soil fertilizer, water retention property,
Culture fertility optimizes crop nutritional condition, increasing both production and income.
(c) active carbon by nutrient be gradually absorbed release after, to herbicide, insecticide, pesticide, synthetic detergent,
Synthetic dyestuffs, amine chemicals etc. have preferable removal effect；Soil a variety of inorganic pollutions (arsenic, cadmium, cobalt, chromium, copper, fluorine,
Mercury, manganese, nickel, lead, selenium, vanadium, zinc) and organic pollutant (six six six, DDT, polycyclic aromatic hydrocarbon) have it is very strong absorption, retention,
Carrying capacity, can effectively reduce pollutant in soil concentration, reduce contaminant component participate in crops physiology circulation and
Precipitating in grain, vegetables achievees the purpose that administer soil pollution.Active carbon is stablized due to chemical property also has loose soil
Earth increases permeability, improves soil texture, improves soil vitality.
The present invention makes full use of the physicochemical property of gourmet powder fermenting tail washings, monosodium glutamate waste active carbon, blackstrap, plant ash, depth
Fusion provides a kind of production of comprehensive utilization waste material wide spectrum, multi-functional soil conditioner product, meets the comprehensive battalion of crop
The demand of supporting, activation repairing soil micro-ecosystem system, the harmful substance of absorption retention pedo relict realize soil health, soil comprehensively
Earth indices significantly improve, and provide quality product to solve the bottleneck problem of current agricultural development.
Specific embodiment
Embodiment 1
(1) nutrient solution is prepared
(1) it by 5 parts of plant ash, puts into 50 parts of gourmet powder fermenting tail washings of concentration 50%, 60 DEG C, is sufficiently mixed, without heavy
Forming sediment is reaction end, obtains mixed material；
(2) in upper step mixed material, 1 part of blackstrap is put into, continues to be stirred, temperature 70 C, 0.5 hour, obtain mixed
Close material；
(3) in upper step mixed liquor, then 5 parts of monosodium glutamate waste active carbon are put into, 90 DEG C of temperature, mix well boiling 1 hour,
Nutrient solution preparation is completed；
(2) slurry-spraying pelletizing
Nutrient solution preparation tank persistently stirs boiling, sprays to the particulate material of pelletizer through spray nozzle by dnockout pumps
In curtain, heat drying furnace provides hot-air, and moment and slurry contact, iterative cycles, particle incrementally increase, until reaching standard, transmits
To screening machine；
(3) it sieves, pack
The soil conditioner particle formed through slurry-spraying pelletizing obtains 90% or more granularity of granular fertilizer in 1- through vibrosieve
Between 4.75mm, packing is carried out after cooler is cooling and gets product soil conditioner.
Embodiment 2
(1) nutrient solution is prepared
(1) it by 27 parts of plant ash, puts into 70 parts of gourmet powder fermenting tail washings of concentration 53%, 70 DEG C, is sufficiently mixed, without heavy
Forming sediment is reaction end, obtains mixed material；
(2) in upper step mixed material, 1.5 parts of blackstrap is put into, continues to be stirred, 80 DEG C of temperature, 0.8 hour, obtain
Mixed material；
(3) in upper step mixed liquor, then 12 parts of monosodium glutamate waste active carbon are put into, 95 DEG C of temperature, it is small mixes well boiling 1.5
When, nutrient solution preparation is completed；
(2) slurry-spraying pelletizing
Nutrient solution preparation tank persistently stirs boiling, sprays to the particulate material of pelletizer through spray nozzle by dnockout pumps
In curtain, heat drying furnace provides hot-air, and moment and slurry contact, iterative cycles, particle incrementally increase, until reaching standard, transmits
To screening machine；
(3) it sieves, pack
The soil conditioner particle formed through slurry-spraying pelletizing obtains 90% or more granularity of granular fertilizer in 1- through vibrosieve
Between 4.75mm, packing is carried out after cooler is cooling and gets product soil conditioner.
Embodiment 3
(1) nutrient solution is prepared
(1) it by 50 parts of plant ash, puts into 90 parts of gourmet powder fermenting tail washings of concentration 55%, 80 DEG C, is sufficiently mixed, without heavy
Forming sediment is reaction end, obtains mixed material；
(2) in upper step mixed material, 2 parts of blackstrap is put into, continues to be stirred, 90 DEG C of temperature, 1 hour, must mix
Material；
(3) in upper step mixed liquor, then 20 parts of monosodium glutamate waste active carbon are put into, 100 DEG C of temperature, it is small mixes well boiling 2
When, nutrient solution preparation is completed；
(2) slurry-spraying pelletizing
Nutrient solution preparation tank persistently stirs boiling, sprays to the particulate material of pelletizer through spray nozzle by dnockout pumps
In curtain, heat drying furnace provides hot-air, and moment and slurry contact, iterative cycles, particle incrementally increase, until reaching standard, transmits
To screening machine；
(3) it sieves, pack
The soil conditioner particle formed through slurry-spraying pelletizing obtains 90% or more granularity of granular fertilizer in 1- through vibrosieve
Between 4.75mm, packing is carried out after cooler is cooling and gets product soil conditioner.
Too large or too small particle is returned to by pulverizer, is recycled again as carrier by screening.
Effect of the invention is illustrated come a step by experimental data below.
By adding plant ash, apparent variation (fixed monosodium glutamate waste active carbon addition is had occurred in the pH value of soil conditioner
Amount is the 5%) table 1 of plant ash adding proportion and final soil conditioner product pH of the present invention:
1 plant ash of table and soil conditioner pH change
(fixing plant ash additive amount is for the variation of the soil conditioner solution rate of the present invention of waste active carbon adding proportion
20%) 2, are shown in Table:
The variation of 2 waste active carbon of table and soil conditioner solution rate of the present invention
The soil conditioner of the method for the present invention production, has been achieved for apparent effect by Field information, table 3 is trimly
One group of data of Ha Er Soils In The Region improvement:
Table 3 applies the variation of soil physical and chemical property after soil conditioner
In summary: the present invention solves the problems, such as to use sodium glutamate mother liquid merely originally；And form completely new soil tune
Agent product is managed, the comprehensive nutritional need of crop, activation repairing soil micro-ecosystem system are met, absorption retention pedo relict has
Evil substance, realizes that soil health, soil indices significantly improve comprehensively.
Claims (2)
1. a kind of soil conditioner produced using sodium glutamate mother liquid and trade waste, which is characterized in that including following parts by weight
Raw material:
50-90 parts of the gourmet powder fermenting tail washings of concentration 50-55%；
5-50 parts of plant ash；
5-20 parts of monosodium glutamate waste active carbon；
1-2 parts of blackstrap.
2. a kind of production method of the soil conditioner produced using sodium glutamate mother liquid and trade waste, which is characterized in that including
The following steps:
(1) nutrient solution is prepared
(1) it by 5-50 parts of plant ash, puts into 50-90 parts of gourmet powder fermenting tail washings of concentration 50-55%, 60-80 DEG C, it is sufficiently mixed
It closes, without reaction end is precipitated as, obtains mixed material；
(2) in upper step mixed material, blackstrap 1-2 parts is put into, continues to be stirred, 70-90 DEG C of temperature, 0.5-1 hours, obtain
Mixed material；
(3) in upper step mixed liquor, then 5-20 parts of monosodium glutamate waste active carbon are put into, 90-100 DEG C of temperature, mixes well boiling 1-2
Hour, nutrient solution preparation is completed；
(2) slurry-spraying pelletizing
Nutrient solution preparation tank persistently stirs boiling, sprays to the particulate material curtain of pelletizer through spray nozzle by dnockout pumps
In, heat drying furnace provides hot-air, and moment and slurry contact, iterative cycles, particle incrementally increase, until reaching standard, is transmitted to
Screening machine；
(3) it sieves, pack
The soil conditioner particle formed through slurry-spraying pelletizing obtains 90% or more granularity of granular fertilizer in 1-4.75mm through vibrosieve
Between, packing, which is carried out, after cooler is cooling gets product soil conditioner.
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| CN201811586635.9A CN109536177A (en) | 2018-12-24 | 2018-12-24 | The soil conditioner and production method produced using sodium glutamate mother liquid and trade waste |
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| KR100222637B1 (en) * | 1997-04-12 | 1999-10-01 | 김재인 | Fertilizer using water waste sludge and fly-ash and the process thereof |
| CN1451639A (en) * | 2002-04-19 | 2003-10-29 | 邵建华 | Pesticide slow-release nutrient and producing method thereof |
| CN102851032A (en) * | 2012-09-11 | 2013-01-02 | 中国科学院沈阳应用生态研究所 | Alkaline earth improving agent prepared by using monosodium glutamate production waste liquid, and preparation method thereof |
| CN103772013A (en) * | 2013-12-31 | 2014-05-07 | 吉林中粮生化有限公司 | Controlled-release fertilizer special for rice and produced by monosodium glutamate mother solution |
| CN105884449A (en) * | 2015-11-04 | 2016-08-24 | 北京嘉博文生物科技有限公司 | Method for producing organic fertilizer by means of monosodium glutamate wastewater and straw fermentation |
| CN106732237A (en) * | 2017-02-21 | 2017-05-31 | 南京元道环保科技有限公司 | A kind of solidification processing method of waste gourmet powder fermenting liquor |
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2018
- 2018-12-24 CN CN201811586635.9A patent/CN109536177A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100222637B1 (en) * | 1997-04-12 | 1999-10-01 | 김재인 | Fertilizer using water waste sludge and fly-ash and the process thereof |
| CN1451639A (en) * | 2002-04-19 | 2003-10-29 | 邵建华 | Pesticide slow-release nutrient and producing method thereof |
| CN102851032A (en) * | 2012-09-11 | 2013-01-02 | 中国科学院沈阳应用生态研究所 | Alkaline earth improving agent prepared by using monosodium glutamate production waste liquid, and preparation method thereof |
| CN103772013A (en) * | 2013-12-31 | 2014-05-07 | 吉林中粮生化有限公司 | Controlled-release fertilizer special for rice and produced by monosodium glutamate mother solution |
| CN105884449A (en) * | 2015-11-04 | 2016-08-24 | 北京嘉博文生物科技有限公司 | Method for producing organic fertilizer by means of monosodium glutamate wastewater and straw fermentation |
| CN106732237A (en) * | 2017-02-21 | 2017-05-31 | 南京元道环保科技有限公司 | A kind of solidification processing method of waste gourmet powder fermenting liquor |
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Application publication date: 20190329 |