CN109534932A - A kind of organic active liquid fertilizer and its production technology method - Google Patents

A kind of organic active liquid fertilizer and its production technology method Download PDF

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Publication number
CN109534932A
CN109534932A CN201910006081.9A CN201910006081A CN109534932A CN 109534932 A CN109534932 A CN 109534932A CN 201910006081 A CN201910006081 A CN 201910006081A CN 109534932 A CN109534932 A CN 109534932A
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China
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fertilizer
soil
organic active
active liquid
accounts
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CN201910006081.9A
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张旺凡
彭巾英
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Individual
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    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G5/00Fertilisers characterised by their form
    • C05G5/20Liquid fertilisers
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05BPHOSPHATIC FERTILISERS
    • C05B7/00Fertilisers based essentially on alkali or ammonium orthophosphates
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • C05G3/80Soil conditioners

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  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Pest Control & Pesticides (AREA)
  • Soil Sciences (AREA)
  • Fertilizers (AREA)

Abstract

The present invention provides a kind of organic active liquid fertilizer and production technology method for heavy metal pollution of soil reparation.Organic active liquid fertilizer is to account for that 3~5%Wt of gross mass, phosphoric acid second ammonium accounts for 10~20%wt, humic acid accounts for 1~3%wt, 1~5%wt of bridging agent, pig manure liquid account for 67~85%wt and formed with soil multiple-microorganism culture solution, and PH is 8~10.Its production technology method includes Spawn incubation, three pig manure liquefaction, fertilizer preparation steps.The organic active liquid fertilizer has the characteristics that safe and non-toxic, wide adaptability, active strong, at low cost, profitable, easy to use, the heavy metals such as cadmium, mercury, lead in the soil that can effectively degrade, can effectively replace chemical fertilizer, and has effect of increasing production.

Description

A kind of organic active liquid fertilizer and its production technology method
Technical field
The invention belongs to agricultural technology fields.More particularly to a kind of organic active liquid of biologically rehabilitating soil heavy metal pollution Body fertilizer and production technology method.
Background technique
While various metals, nonmetallic and coal mining, by the heavy metal element band overlying strata in earth formation Surface diffuses into plough horizon with washing away by the leaching of rainwater, in addition the pollution of urban industry waste water, until making water system With many times exceeded to the heavy metal element of human health such as cadmium, lead, mercury, chromium etc. in soil, by biologies such as crops It absorbs with after enrichment, into human body, makes various neoplastic diseases that blowout outburst be presented, seriously affect the health of people.It is another Aspect causes soil physical and chemical property to change, shows soil since inorganic chemistry element fertilizer and organic agricultural chemicals is used for a long time It is acidified, is hardened, soil beneficial microbe is sharply reduced, and farmland ecological environment is seriously destroyed, and causes soil fertility to decline, agriculture Crop resistance reduction, quality variation, yield decline, in addition stubble robs formula operation more than a year, soil ecology cannot get nature reparation, Have become a big obstacle of agricultural development, more becomes a big hidden danger of health of people.
China is the country having a large population and a few land, and large area, which is lain fallow, does not meet national conditions, physics and chemical remediation, first is that cost Height, second is that effect is poor, using biological prosthetic not only safe and non-toxic, activity is strong, it is wide to adapt to, and with more at low cost, profitable, uses Simple and convenient feature.
Summary of the invention
The present invention provides a kind of organic active liquid fertilizer, the organic active liquid fertilizer microbial culture medium accounts for gross mass 3~5%Wt, phosphoric acid second ammonium accounts for 10~20%wt, humic acid accounts for 1~3%wt, 1~5%wt of bridging agent, pig manure liquid account for 67~85%wt It is formed, PH is 8~10.
The present invention also additionally provides a kind of production technology method of organic active liquid fertilizer, including Spawn incubation, pig manure liquid Change, three steps of fertilizer preparation.First spare with fluid nutrient medium culture soil beneficial microbe, culture medium prescription is every liter of Portugal Grape sugar 10 grams, 1 gram of potassium nitrate, 0.2 gram of magnesium sulfate, 0.5 gram of potassium dihydrogen phosphate, 1~5 gram of urea nitrogen.Microorganism fungus kind is yellow bar Pseudomonas, the bacillus of Rhod, Trichoderma etc., cultivation temperature are that Pig dung and urine is passed through 110 DEG C of high-temperature sterilization liquid again by 28 DEG C of Change processing, after cooling, first by 10~20%wt phosphoric acid second ammonium, 1~3%wt, the addition of humic acid 1~5%wt bridging agent 67~85% In wt pig manure liquid, pH to 8~10 is adjusted, then wherein and sufficiently strand is mixed uniformly by the addition of cultured microorganism fungus kind.Generally Mu dosage 100kg, during wherein half is manured into soil as base manure, half is made top dressing punching and is applied.
The process of Zinc fractions is soil under the action of various microorganisms, by mineralization and humified process, soil Earth forms colloid crumb structure." organic active liquid fertilizer " says it is fertilizer, is because no longer needing to apply other chemistry fertilizer after application Material and organic fertilizer, fully achieve the purpose of higher yield of crops;It says that it is organic, be with decomposed organic fertilizer is carrier culture The certain beneficial microbes of soil are allowed to mass propagation;It says its activity, is inside added with mineralization activity agent, also known as organic mineralising frame Bridge agent makes the good colloidal state of Zinc fractions and shields the harmful substances such as heavy metal in soil, meanwhile, in beneficial microorganism Under effect, the organic matter in soil is decomposed;It says its liquid, is to exist in the form of liquid, is easier to seep than solid state Thoroughly, it is distributed in soil.
Specific embodiment:
The organic active liquid fertilizer that harmful heavy metal pollutes in soil, the organic active liquid can be reduced the present invention provides a kind of Fertile microbial culture medium account for 3~5%Wt of gross mass, phosphoric acid second ammonium accounts for 10~20%wt, humic acid accounts for 1~3%wt, bridging agent 1~ 5%wt, pig manure liquid account for 67~85%wt and are formed, and PH is 8~10.
The present invention also additionally provides the production technology method of organic active liquid fertilizer, including the liquefaction of Spawn incubation, pig manure, fertilizer Material prepares three steps.First spare with fluid nutrient medium culture soil beneficial microbe, culture medium prescription is every liter of glucose 10 grams, 1 gram of potassium nitrate, 0.2 gram of magnesium sulfate, 0.5 gram of potassium dihydrogen phosphate, 1~5 gram of urea nitrogen.Microorganism fungus kind be Flavobacterium, Bacillus, the Trichoderma of Rhod, cultivation temperature are that 28 DEG C of are again handled Pig dung and urine by 110 DEG C of high-temperature sterilization liquefaction, After cooling, first by 10~20%wt phosphoric acid second ammonium, 1~5%wt, the addition of humic acid 1~3%wt bridging agent in 67~85%wt pig manure liquid In, pH to 8~10 is adjusted, then wherein and sufficiently strand is mixed uniformly by the addition of cultured microorganism fungus kind.
Organic active liquid fertilizer of the invention has safe and non-toxic, and activity is strong, it is wide to adapt to, at low cost, profitable, uses letter Folk prescription just the characteristics of, can replace other chemical fertilizer completely, and can make that plant growth is healthy and strong, reaches the increased mesh of economic flow rate 's.
The microorganism remediation of heavy metal-polluted soil is affine absorption or conversion using the bioactivity of microorganism to heavy metal For less toxic product, to reduce the pollution level of heavy metal.Its main technical principle is: (1) dissolving and precipitate: in soil environment In, microorganism can utilize effective nutrition and the energy, and secretion organic acid is complexed and dissolves heavy metal;(2) microorganism is to a huge sum of money Belong to the redox of ion: some heavy metal elements in soil can exist in the form of a variety of prices, they are with high price chemical combination Solubility is usually smaller in the presence of object ion, is not susceptible to migrate, and with low price ionic compound in the presence of, solubility is larger, It is easier to migrate, the oxidation of microorganism can be such that the activity of these heavy metal elements reduces;(3) microorganism to heavy metal from The biological adsorption of son and enrichment: edaphon can adsorb heavy metal ion by electrically charged cell surface, or by taking the photograph Necessary nutrient active absorption heavy metal ion is taken, and by heavy metal ion enrichment in cell surface or inside;(4) mycorhiza The biological effectiveness of fungi and heavy metal-polluted soil: homobium-mycorhiza, mycorrhizal fungi and plant are formed after fungi invaded plants root system Root Symbiont can promote the absorption of Plant To Nutrient nutrient, and mycorrhizal fungi can not only be by the secretion of organic acid to certain in soil Heavy metal ion is activated, and can such as ion exchange, secretion organic ligand, hormone indirectly-acting be influenced in other forms Absorption of the plant to heavy metal.
Bridging agent in organic active liquid fertilizer of the present invention is that zeolite powder and illiteracy open up mountain flour.Zeolite is a kind of silicate Class mineral, by sharing the oxygen-octahedron and aluminum-oxygen tetrahedron three-dimensional screen work composition that oxygen links together, trivalent aluminium substitution four The superfluous negative electrical charge that valence silicon generates is by the metal cation of monovalence or divalent, and usually alkali or alkaline earth metal cation is put down Weighing apparatus has absorption and ion exchanging function, and since every kind of zeolite has its specific uniform aperture, can only be by correspondingly sized Molecule, be widely used as catalyst, soil conditioner, purifying agent for polluted water.It can improve the chemical property of acid soil, reduce soil The content of earth acidity and iron, aluminium mitigates the murder by poisoning of iron aluminium, improves nutrient availability, while the alkali that can also improve soil is full With degree and soil to the holding capacity of nutrient, improve the nutritional condition of crop.It can be added according to the physicochemical property difference of soil Different amounts.
Soil fertility is medium, viscosity is moderate, the content of organic matter is medium, under the conditions of advanced optimizing, organic active liquid Fertile microbial culture medium accounts for that the 4%Wt of gross mass, phosphoric acid second ammonium accounts for 15%wt, humic acid accounts for 2%wt, bridging agent 3%wt, pig manure liquid account for 76%wt is formed, and PH8 is advisable.
In order to which the technical problems, technical solutions and beneficial effects solved by the present invention is more clearly understood, below in conjunction with Embodiment, the present invention will be described in further detail.It should be appreciated that specific embodiment described herein is only used to explain The present invention is not intended to limit the present invention.
Embodiment 1.
It is public first 15 kilograms of phosphoric acid second ammonium, humic acid 2 will to be added in 76 kilograms of pig manure liquid by the disinfection treatment of 110 DEG C of High-temperature Liquefactions Jin, 3 kilograms of zeolite powder, 4 kilograms of microbial inoculum, adjust PH to 8, and sufficiently twisting dress after mixing uniformly in a reservoir, will be above organic Make base manure for 50 kilograms of active liquid fertilizer to apply in paddy soil and turn over, it is when the seedlings of cereal crops divide Xue's phase to intertill that another 50 kilograms of liquid fertilizers is dilute After releasing, make top dressing punching and apply, and blocked up intake-outlet, do not allow Tanaka's Inlet and outlet water, wait water fall naturally it is dry after irrigate again.
Embodiment 2
By Pig dung and urine by 110 DEG C of high-temperature sterilization liquefaction processing, after cooling, first by 10~20%wt phosphoric acid second ammonium, 1~5%wt, corruption The addition of acid 1~3%wt bridging agent is grown in 67~85%wt pig manure liquid, pH to 8~10 is adjusted, then by cultured microbial bacteria Wherein and sufficiently strand is mixed uniformly for kind addition.Mu applies 50 kilograms and makees base manure, Yi Hougen before above-mentioned organic active liquid fertilizer is turned over It is applied according to the production top dressing punching of plant growth situation appropriate adjustment formula rate.
It is tested by multiple large area, embodiment 1 and the prepared organic active liquid fertilizer of embodiment 2 show following spy Point
1. fertilizer efficiency is good, seedlings of cereal crops robust growth, paddy yellow leaf is green when mature, and setting percentage is high, and sterile grain rate is low, and application chemical fertilizer ratio, Increase production 10~15% per acre.
2. content of beary metal reduces by 50% or more in soil and rice.Cadmium content is somebody's turn to do in 0.6mg/kg, application in paddy soil After fertilizer, cadmium content is down to 0.2mg/kg or less in rice.
3. cost is relatively low, with application chemical fertilizer ratio, although cost per mu increases by 150 yuan or so, 15% meter of mu volume increase It calculates, increases paddy over 80 kg per acre, the increased part of fertilizer cost can be offset completely.
4. convenient using simple.Base manure can be used hydraulic pump and spray, top dressing can irrigate when by fertilizer from water inlet from Right purling, it is time saving, laborsaving.

Claims (6)

1. a kind of organic active liquid fertilizer, it is characterised in that microbial culture medium accounts for 3~5%wt, phosphoric acid second ammonium accounts for 10~20%wt, Humic acid accounts for 1~3%wt, 1~5%wt of bridging agent, pig manure liquid and accounts for 67~85%wt and formed, and PH is 8~10, production technology side Method includes Spawn incubation, three pig manure liquefaction, fertilizer preparation steps.
2. its culture medium prescription of microbial culture medium is every liter of 10 grams of glucose, 1 gram of potassium nitrate, sulphur according to claim 1 0.2 gram of sour magnesium, 0.5 gram of potassium dihydrogen phosphate, 1~5 gram of urea nitrogen, microorganism fungus kind is the gemma bar of Flavobacterium, Rhod Bacterium, Trichoderma, cultivation temperature are 28 DEG C.
3. pig manure liquefies according to claim 1, liquefied using 110 DEG C of high-temperature sterilizations.
4. fertilizer preparation according to claim 1 builds bridge 10~20%wt phosphoric acid second ammonium, 1~3wt humic acid, 1~5%wt Agent, 3~5%wt bacterium solution are added sufficiently to twist in the pig manure after cooling that liquefies in order and mix uniformly and adjust pH to 8~10.
5. bridging agent is that zeolite powder and illiteracy open up mountain flour according to claim 1.
6. organic active liquid fertilizer according to claim 1, is prepared by Claims 1 to 5.
CN201910006081.9A 2019-01-04 2019-01-04 A kind of organic active liquid fertilizer and its production technology method Pending CN109534932A (en)

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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2005074288A (en) * 2003-08-29 2005-03-24 Sumikon Serutekku Kk Method for cleaning soil polluted with organic matter and cyanide
CN103951532A (en) * 2014-05-21 2014-07-30 安徽飞天农用生物科技股份有限公司 Compound soil remediation agent containing microorganism bacteria and preparation method thereof
CN103964951A (en) * 2014-04-25 2014-08-06 湖南泰谷生物肥料有限公司 Magnetization compound microorganism organic water solution fertilizer as well as preparation method and application thereof
CN107244999A (en) * 2017-05-24 2017-10-13 攀枝花市绿态美生物科技有限公司 It is a kind of to remove microbial bacterial agent of removing heavy metals and its preparation method and application
CN107641049A (en) * 2017-09-22 2018-01-30 济南润丰伟业生物科技有限公司 A kind of microbiological fermented organic fertilizer of repairing heavy metal in soil pollution
CN108975992A (en) * 2017-06-01 2018-12-11 高鲁江 A kind of water conservation absorption conversion heavy metal bacterial manure for improveing soil

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2005074288A (en) * 2003-08-29 2005-03-24 Sumikon Serutekku Kk Method for cleaning soil polluted with organic matter and cyanide
CN103964951A (en) * 2014-04-25 2014-08-06 湖南泰谷生物肥料有限公司 Magnetization compound microorganism organic water solution fertilizer as well as preparation method and application thereof
CN103951532A (en) * 2014-05-21 2014-07-30 安徽飞天农用生物科技股份有限公司 Compound soil remediation agent containing microorganism bacteria and preparation method thereof
CN107244999A (en) * 2017-05-24 2017-10-13 攀枝花市绿态美生物科技有限公司 It is a kind of to remove microbial bacterial agent of removing heavy metals and its preparation method and application
CN108975992A (en) * 2017-06-01 2018-12-11 高鲁江 A kind of water conservation absorption conversion heavy metal bacterial manure for improveing soil
CN107641049A (en) * 2017-09-22 2018-01-30 济南润丰伟业生物科技有限公司 A kind of microbiological fermented organic fertilizer of repairing heavy metal in soil pollution

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Application publication date: 20190329