CN109534802A - A kind of far infrared of usury desert material is from raw glaze china and its preparation process - Google Patents
A kind of far infrared of usury desert material is from raw glaze china and its preparation process Download PDFInfo
- Publication number
- CN109534802A CN109534802A CN201811583049.9A CN201811583049A CN109534802A CN 109534802 A CN109534802 A CN 109534802A CN 201811583049 A CN201811583049 A CN 201811583049A CN 109534802 A CN109534802 A CN 109534802A
- Authority
- CN
- China
- Prior art keywords
- china
- desert
- usury
- pug
- far infrared
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000463 material Substances 0.000 title claims abstract description 29
- 238000002360 preparation method Methods 0.000 title claims abstract description 11
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 51
- 239000004576 sand Substances 0.000 claims abstract description 38
- 229910052742 iron Inorganic materials 0.000 claims abstract description 26
- 241001271907 Baphia racemosa Species 0.000 claims abstract description 24
- 239000011777 magnesium Substances 0.000 claims abstract description 16
- 229910052749 magnesium Inorganic materials 0.000 claims abstract description 14
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims abstract description 13
- CNLWCVNCHLKFHK-UHFFFAOYSA-N aluminum;lithium;dioxido(oxo)silane Chemical compound [Li+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O CNLWCVNCHLKFHK-UHFFFAOYSA-N 0.000 claims abstract description 11
- 229910052642 spodumene Inorganic materials 0.000 claims abstract description 11
- 239000010456 wollastonite Substances 0.000 claims abstract description 11
- 229910052882 wollastonite Inorganic materials 0.000 claims abstract description 11
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 claims abstract description 11
- 238000010304 firing Methods 0.000 claims abstract description 10
- 229910052656 albite Inorganic materials 0.000 claims abstract description 9
- DLHONNLASJQAHX-UHFFFAOYSA-N aluminum;potassium;oxygen(2-);silicon(4+) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Al+3].[Si+4].[Si+4].[Si+4].[K+] DLHONNLASJQAHX-UHFFFAOYSA-N 0.000 claims abstract description 9
- 238000000498 ball milling Methods 0.000 claims abstract description 8
- 239000004615 ingredient Substances 0.000 claims abstract description 8
- 238000003825 pressing Methods 0.000 claims abstract description 8
- 210000000988 bone and bone Anatomy 0.000 claims abstract description 7
- 238000007873 sieving Methods 0.000 claims abstract description 7
- 238000004513 sizing Methods 0.000 claims abstract description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 66
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 38
- 238000000034 method Methods 0.000 claims description 27
- 230000008569 process Effects 0.000 claims description 22
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims description 16
- 238000010438 heat treatment Methods 0.000 claims description 16
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 14
- 239000013078 crystal Substances 0.000 claims description 13
- 239000000377 silicon dioxide Substances 0.000 claims description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 11
- 229910052573 porcelain Inorganic materials 0.000 claims description 10
- 238000005245 sintering Methods 0.000 claims description 10
- 239000000126 substance Substances 0.000 claims description 10
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 8
- 229910052593 corundum Inorganic materials 0.000 claims description 7
- 229910052906 cristobalite Inorganic materials 0.000 claims description 7
- 229910001845 yogo sapphire Inorganic materials 0.000 claims description 7
- KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 claims description 6
- 239000012298 atmosphere Substances 0.000 claims description 6
- 229910052681 coesite Inorganic materials 0.000 claims description 6
- 229910052682 stishovite Inorganic materials 0.000 claims description 6
- 229910052905 tridymite Inorganic materials 0.000 claims description 6
- 238000004061 bleaching Methods 0.000 claims description 5
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims description 5
- 238000007885 magnetic separation Methods 0.000 claims description 5
- 239000002002 slurry Substances 0.000 claims description 5
- 238000004506 ultrasonic cleaning Methods 0.000 claims description 5
- 238000005336 cracking Methods 0.000 claims description 4
- 229910052710 silicon Inorganic materials 0.000 claims description 4
- 239000010703 silicon Substances 0.000 claims description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 3
- 229910052799 carbon Inorganic materials 0.000 claims description 3
- 229910052757 nitrogen Inorganic materials 0.000 claims description 3
- 239000001301 oxygen Substances 0.000 claims description 3
- 229910052760 oxygen Inorganic materials 0.000 claims description 3
- 239000002689 soil Substances 0.000 claims description 2
- 230000006641 stabilisation Effects 0.000 claims description 2
- 238000011105 stabilization Methods 0.000 claims description 2
- 239000012299 nitrogen atmosphere Substances 0.000 claims 1
- 239000002994 raw material Substances 0.000 abstract description 14
- 239000000440 bentonite Substances 0.000 abstract description 12
- 229910000278 bentonite Inorganic materials 0.000 abstract description 12
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 abstract description 11
- 238000004519 manufacturing process Methods 0.000 abstract description 6
- 238000005516 engineering process Methods 0.000 abstract description 4
- 238000001228 spectrum Methods 0.000 abstract description 2
- 239000000919 ceramic Substances 0.000 description 16
- 229910010293 ceramic material Inorganic materials 0.000 description 13
- 239000003864 humus Substances 0.000 description 9
- 229910052500 inorganic mineral Inorganic materials 0.000 description 8
- 239000011707 mineral Substances 0.000 description 8
- 239000004927 clay Substances 0.000 description 7
- 230000000694 effects Effects 0.000 description 7
- 239000000843 powder Substances 0.000 description 7
- 239000010453 quartz Substances 0.000 description 7
- 235000012239 silicon dioxide Nutrition 0.000 description 7
- 229910052761 rare earth metal Inorganic materials 0.000 description 6
- 150000002910 rare earth metals Chemical class 0.000 description 6
- 239000005995 Aluminium silicate Substances 0.000 description 5
- 235000012211 aluminium silicate Nutrition 0.000 description 5
- 230000008859 change Effects 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 5
- 238000011161 development Methods 0.000 description 5
- 230000018109 developmental process Effects 0.000 description 5
- 238000001035 drying Methods 0.000 description 5
- 239000010433 feldspar Substances 0.000 description 5
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 5
- 238000002156 mixing Methods 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 4
- 230000006872 improvement Effects 0.000 description 4
- 238000000465 moulding Methods 0.000 description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Substances [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 4
- 230000008901 benefit Effects 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 239000000084 colloidal system Substances 0.000 description 3
- 238000000227 grinding Methods 0.000 description 3
- 239000010977 jade Substances 0.000 description 3
- 238000001556 precipitation Methods 0.000 description 3
- 230000002035 prolonged effect Effects 0.000 description 3
- 238000001179 sorption measurement Methods 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 238000006467 substitution reaction Methods 0.000 description 3
- 229910021532 Calcite Inorganic materials 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 description 2
- 235000012241 calcium silicate Nutrition 0.000 description 2
- 229910052570 clay Inorganic materials 0.000 description 2
- 229910001873 dinitrogen Inorganic materials 0.000 description 2
- 238000005265 energy consumption Methods 0.000 description 2
- SZVJSHCCFOBDDC-UHFFFAOYSA-N ferrosoferric oxide Chemical compound O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 description 2
- 238000003837 high-temperature calcination Methods 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 238000011065 in-situ storage Methods 0.000 description 2
- 150000002484 inorganic compounds Chemical class 0.000 description 2
- 229910010272 inorganic material Inorganic materials 0.000 description 2
- 229910052748 manganese Inorganic materials 0.000 description 2
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 239000002243 precursor Substances 0.000 description 2
- 230000005855 radiation Effects 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 238000002834 transmittance Methods 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 208000005156 Dehydration Diseases 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000005282 brightening Methods 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000002734 clay mineral Substances 0.000 description 1
- 230000003749 cleanliness Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000000748 compression moulding Methods 0.000 description 1
- 238000007596 consolidation process Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 235000019628 coolness Nutrition 0.000 description 1
- 230000009193 crawling Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 229910052588 hydroxylapatite Inorganic materials 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- FYDKNKUEBJQCCN-UHFFFAOYSA-N lanthanum(3+);trinitrate Chemical compound [La+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O FYDKNKUEBJQCCN-UHFFFAOYSA-N 0.000 description 1
- 238000005065 mining Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 1
- XYJRXVWERLGGKC-UHFFFAOYSA-D pentacalcium;hydroxide;triphosphate Chemical compound [OH-].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O XYJRXVWERLGGKC-UHFFFAOYSA-D 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 229910052903 pyrophyllite Inorganic materials 0.000 description 1
- 238000012797 qualification Methods 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 239000012744 reinforcing agent Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 229910052594 sapphire Inorganic materials 0.000 description 1
- 230000035040 seed growth Effects 0.000 description 1
- IMNMWKFKHDPTSB-UHFFFAOYSA-N silicic acid zirconium Chemical compound [Zr].[Si](O)(O)(O)O IMNMWKFKHDPTSB-UHFFFAOYSA-N 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 239000006104 solid solution Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000002352 surface water Substances 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 229910000314 transition metal oxide Inorganic materials 0.000 description 1
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 230000002087 whitening effect Effects 0.000 description 1
- 238000004383 yellowing Methods 0.000 description 1
- 229910052727 yttrium Inorganic materials 0.000 description 1
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 229910001928 zirconium oxide Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
- C04B35/14—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on silica
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/626—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
- C04B35/63—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B using additives specially adapted for forming the products, e.g.. binder binders
- C04B35/6303—Inorganic additives
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3201—Alkali metal oxides or oxide-forming salts thereof
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3201—Alkali metal oxides or oxide-forming salts thereof
- C04B2235/3203—Lithium oxide or oxide-forming salts thereof
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3205—Alkaline earth oxides or oxide forming salts thereof, e.g. beryllium oxide
- C04B2235/3206—Magnesium oxides or oxide-forming salts thereof
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3205—Alkaline earth oxides or oxide forming salts thereof, e.g. beryllium oxide
- C04B2235/3208—Calcium oxide or oxide-forming salts thereof, e.g. lime
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3217—Aluminum oxide or oxide forming salts thereof, e.g. bauxite, alpha-alumina
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3231—Refractory metal oxides, their mixed metal oxides, or oxide-forming salts thereof
- C04B2235/3232—Titanium oxides or titanates, e.g. rutile or anatase
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3231—Refractory metal oxides, their mixed metal oxides, or oxide-forming salts thereof
- C04B2235/3244—Zirconium oxides, zirconates, hafnium oxides, hafnates, or oxide-forming salts thereof
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/327—Iron group oxides, their mixed metal oxides, or oxide-forming salts thereof
- C04B2235/3272—Iron oxides or oxide forming salts thereof, e.g. hematite, magnetite
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/44—Metal salt constituents or additives chosen for the nature of the anions, e.g. hydrides or acetylacetonate
- C04B2235/447—Phosphates or phosphites, e.g. orthophosphate or hypophosphite
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/65—Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes
- C04B2235/656—Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes characterised by specific heating conditions during heat treatment
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/65—Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes
- C04B2235/656—Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes characterised by specific heating conditions during heat treatment
- C04B2235/6562—Heating rate
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/65—Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes
- C04B2235/656—Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes characterised by specific heating conditions during heat treatment
- C04B2235/6565—Cooling rate
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/65—Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes
- C04B2235/656—Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes characterised by specific heating conditions during heat treatment
- C04B2235/6567—Treatment time
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/70—Aspects relating to sintered or melt-casted ceramic products
- C04B2235/96—Properties of ceramic products, e.g. mechanical properties such as strength, toughness, wear resistance
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/70—Aspects relating to sintered or melt-casted ceramic products
- C04B2235/96—Properties of ceramic products, e.g. mechanical properties such as strength, toughness, wear resistance
- C04B2235/9646—Optical properties
- C04B2235/9661—Colour
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Compositions Of Oxide Ceramics (AREA)
Abstract
The present invention relates to a kind of far infrareds of usury desert material from raw glaze china and its preparation process, including the following raw material by weight percentage: being derived from the grains of sand in desert: 50% ~ 60%;Pyrophillite: 10% ~ 20%;Camwood knag: 8% ~ 15%;Gangue: 10% ~ 18%;Magnesium-based bentonite: 2% ~ 4%;Potassium feldspar: 4% ~ 8%;Albite: 4% ~ 8%;Spodumene: 2% ~ 5%;Zirconium silicate: 3% ~ 5%;Wollastonite: 4% ~ 6%;The production technology of the Bone China includes the following steps: to be formulated ingredient, ball milling, sieving, removes iron, filters pressing, first time pugging, second of pugging and sizing firing;Produced by the present invention to have preferable toughness and higher intensity from raw glaze china, good thermal stability suitable for the environment of rapid heat cycle, while having preferable radiance and wide spectrum.
Description
Technical field
The present invention relates to ceramic technology fields, and in particular to a kind of usury with desert material far infrared from raw glaze china and its
Preparation process.
Background technique
With the continuous development of ceramic technology, people make ceramics using different raw materials and different technique, and ceramics go out
Many new types are showed, china and far-infrared ceramic are exactly two wherein more popular types.China is a kind of generally acknowledged
High-grade porcelain, Dehua jade porcelain, which is exactly that one kind in china is significant, to be represented, and raw material is mainly wanted based on animal bone ash, is added a certain amount of
Soft porcelain made of kaolin, quartz, feldspar etc. has fine and smooth porcelain, whiteness height, transparency height, glaze smooth, mechanical strong
Spend the advantages that high, but a large amount of developments and utilizations of mineral resources, ore is increasingly poor, Longyan kaolin ore reserves substantially under
Drop, exploitation receive stringent limitation, to maintain the quality and yield of china, using the new original for capableing of alternative ore resource
Material is the research direction of the following china development.The eighties in last century, high radiated infrared ceramic material was flourished in foreign countries,
The wide husband in the high island of Japan, high fields great one et al. use Fe3O4、MnO2, the transition metal oxides such as CuO, CoO be raw material, normal direction is made
All band radiance is greater than 0.90 high radiated infrared ceramic material;Patent of the ParkerHolding company, the U.S. in its application
Claim in document, uses AB2O4Type inorganic compound is formed as infrared radiant material, and wherein A is mainly by Mg, Zn, Mn, Ni, Co
Deng composition, B is mainly Al, Cr, Mn, Fe etc..Far-infrared ceramic is through more than 20 kinds of inorganic compounds and trace meter or specific day
Right ore is sintered in different proportions respectively, is produced larger to the dependence of nonrenewable resources.To high-quality resource
It excessively utilizes, accelerates the too fast exhaustion of resource, increase the production cost of far-infrared ceramic.
Desert occupies the 10% of land area, and 1,720,000 square kilometres of China's sandy land area accounts for nearly the 1/ of national territorial area
5.Currently, being to develop recovery industry and modern agriculture using the most important approach in desert, and the grains of sand in desert are introduced into
It is a kind of completely new thinking and developing direction in traditional ceramics industry, mining mineral resource amount can be reduced, reduce ceramic industry
Energy consumption promotes the development and reform of ceramics while meeting the megatrend of energy-saving and emission-reduction, ecological protection.The desert grains of sand
Middle light mineral content is very high, and generally 90% or more, light mineral main component is quartz, feldspar and calcite, alternative ceramics
Quartz and the materials such as feldspar in raw materials for production, can by using the scheme of the sand grains alternative ore resource in desert with being introduced into desert
Area provides a new sand control sand prevention road.
Application No. is 201410210975.7 Chinese patents to disclose a kind of iron tailings far-infrared ceramic material and its system
Preparation Method, specifically disclosed ceramic material is mainly by iron tailings 35~75%, clay 1~9%, silica 1 1~25%, carbon
Sour calcium 11~25% and aluminium oxide 2~6% are constituted, and the sum of each component is 100%, at the same with iron tailings, clay, silica,
Calcium silicates and aluminium oxide are raw material, and iron is made after ball milling, sieving, ingredient, stirring, drying, mixing, dry-pressing formed and sintering
Tailing far-infrared ceramic material.The invention takes full advantage of iron tailings, reduces production cost, but far-infrared ceramic material is made
Expect brittle, poor toughness and radiation wave band is relatively narrow.Application No. is 201410211126.3 Chinese patents to disclose one kind containing dilute
The iron tailings far-infrared ceramic material and preparation method thereof of soil, specifically disclosed ceramic material mainly by iron tailings 35~75%,
Clay 1~7%, silica 6~25%, calcium carbonate 6~25%, aluminium oxide 2~7% and rare earth 1~9% are constituted, each component
The sum of be 100%, while using iron tailings, clay, silica, calcium silicates and aluminium oxide as primary raw material, and be to add with rare earth
Add agent, the iron tail containing rare earth is mainly made after ball milling, sieving, ingredient, stirring, drying, mixing, dry-pressing formed and sintering process
Mine far-infrared ceramic material.The invention not only takes full advantage of iron tailings while can be improved the far infrared transmission ability of ceramics,
The far infrared of high emissivity is radiated, but far-infrared ceramic material ductile strength obtained is poor, thermostable type is poor, Wu Fashi
Environment for rapid heat cycle.
Summary of the invention
To solve the above problem in the prior art, the present invention provides a kind usury with desert material far infrared from raw glaze
China and its preparation process introduce desert grains of sand substitution kaolin ore and quartz mine in china pug, can be made have compared with
Good toughness and higher intensity from raw glaze china, thermostable type is good, suitable for the environment of rapid heat cycle, while have compared with
Good wide spectrum and radiance.
Technical solution of the present invention:
A kind of far infrared of usury desert material is from raw glaze china, china pug component and weight percent are as follows: is derived from
The grains of sand in desert: 45%~55%;Pyrophillite: 8%~10%;Camwood knag: 6%~8%;Gangue: 10%~13%;Magnesium
Base bentonite: 2%~4%;Potassium feldspar: 4%~8%;Albite: 3%~6%;Micron order spodumene: 1%~3%;Silicic acid
Zirconium: 2%~4%;Wollastonite: 4%~6%.
Wherein, chemical composition is by weight percentage in the china pug are as follows: SiO2: 60%~70%;Al2O3: 15%
~20%;CaO:2.0%~4.5%;ZrO2: 3.5%~5.0%;Na2O+K2O:2.6%~4.6%;Fe2O3: 1.2%~
2.0%;MgO:2.8%~3.8%;LiO2: 0.8%~1.5%;TiO2: 0.5%~1.0%;P2O5: 0.05%~
0.2%.
Wherein, the desert grains of sand are deposited in by ultrasonic cleaning removal after the grains of sand needs for being derived from desert are mixed with water
The siliceous scale and siliceous film on surface.
Wherein, the camwood knag needs successively to be pre-processed by smashing slurry, magnetic separation and the process flow of bleaching.
From the preparation process of raw glaze china, process flow is followed successively by is matched by formula for a kind of far infrared of usury desert material
Material, sieving, removes iron, filters pressing, first time pugging, second of pugging, sizing firing at ball milling;The china pug 1200 DEG C~
It is once sintered into 1300 DEG C of high temperature from raw glaze china, the sintering procedure of once-firing is as follows:
(1) room temperature~200 DEG C are heated up 2~3h to 300 DEG C at a slow speed, are fired in oxygen atmosphere, heating rate 1
~1.5 DEG C/min;
(2) 200 DEG C~900 DEG C, heating rate is improved, holding heating rate is 8~10 DEG C/min;
(3) 900 DEG C~1200 DEG C, reducing heating rate prevents china from cracking, and heating rate is 3~5 DEG C/min;
(4) in 1200 DEG C~1300 DEG C range 3~6h of inside holding, it is passed through nitrogen in this temperature range, builds nitrogen gas
Atmosphere promotes china crystal phase stabilization to be formed;
(5) 1300 DEG C~600 DEG C, high temperature is quickly cooled down the stage, and rate of temperature fall is 16~18 DEG C/min;
(6) 100 DEG C or less are naturally cooled to.
Wherein, the pH of pug is adjusted as 7~8 in alkalescent in the first time pugging and second of pugging;Because of pug
In contain camwood knag, camwood knag contains more carbonaceous humus, and humus and lye effect can hydrolyze to form protective glue
Body facilitates mud material forming performance improvement.
The invention has the following beneficial effects:
1, clay, quartz and the feldspar being introduced into bone china paste in the present invention in grains of sand substitution part Dehua jade porcelain billet material
Equal raw materials, wherein grains of sand proportion is up to the use of 50%~60% alternative clay mineral;The grains of sand contain 90% or more
The light minerals such as quartz, feldspar and calcite, can be with SiO in bone china paste2、CaO、 Al2O3、Na2O、K2The ingredients such as O are substituted,
Wherein, the clay raw material of Dehua jade porcelain is reduced from Longyan kaolin using the grains of sand instead of whole quartz mines mostly
The use of kaolin ore and hydroxyapatite saves the cost of winning of mineral resources, has been greatly reduced mineral resources utilization,
The exploitation and waste for reducing mineral resources, reduce production cost.It realizes simultaneously and desert is made full use of, be a kind of complete
New sand control thinking and scheme meet the development trend of ecological protection and circular economy.
2, far infrared produced by the present invention from raw glaze china there is preferable toughness and higher intensity, fracture toughness to be greater than
12MPa·m1/2, glaze surface intensity is greater than 580kg, f/mm2, flexural strength is all satisfied ceramic high-ductility between 450-460MPa
High-strength requirement, and good thermal stability, it is not cracked to exchange multiple china in -20 DEG C~180 DEG C of section, is suitable for
In the environment of rapid heat cycle, while higher infrared emittance is able to maintain at 5-20 μm.
2, bone china paste and glaze are mixed in the present invention and is integrated, realized in sintering procedure from raw glaze, without " applying
Glaze " process guarantees that glaze is uniform, prevents finished product china surface from thin glaze, glaze line, crawling and the dirty defect of glaze occur.Meanwhile it adopting
About half is reduced than process used in traditional china technological process of production with single firing process, " polishing " process is not necessarily to, reduces
Dust emission;Without " washing " process, reduce water resources consumption;Without a large amount of heating, coolings and drying process, energy is saved
Source reduces energy consumption and " three wastes " discharge.
3, the main component in the present invention in pyrophillite, camwood knag and gangue is silica and aluminium oxide, still
The crystal phase and structure of aluminium oxide are different in three kinds of raw materials, pass through between the aluminium oxide of different crystal phases under conditions of high-temperature calcination
In-situ compound technology is equivalent to as mutual additional toughening crystal phase, without introducing other reinforcing agent or crystal seed, three kinds of oxidations
Aluminium crystal seed, which can interpenetrate, grows into that grain aspect ratio is big, the equally distributed chip reinforcement of whisker, and three kinds of aluminium oxide crystalline substances
Although grain is different, compatibility is preferable, interlaced with each other to be connected to form three-dimensional netted distribution, and then enhances the toughness of china
And intensity, while three kinds of raw material itself toughenings eliminate matrix phase and toughening mutually physically or chemically not to a certain extent
Compatibility, ensure that the thermodynamic stability of matrix phase and toughening phase, and then improve the thermal stability of china.
4, it joined magnesium-based bentonite in china pug in the present invention, contain Mg in magnesium-based bentonite2+, can and Fe2+Instead
The solid solution that MgFeO should be generated, with TiO2Reaction generates MgOTiO2, Fe2+And TiO2It can precipitate, can weaken
The adverse effect of iron, titanium to china whiteness, while the Mg that magnesium-based bentonite introduces2+With milkiness effect, it is also beneficial to improve bone
Porcelain billet body whiteness;The degree of purity that can be improved color when colored china is made in different pigment is added simultaneously.
5, the present invention in joined wollastonite in powder, zirconium silicate and spodumene, wherein zirconium silicate chemical stability is good, not by
The influence of china firing atmosphere, and the base glaze separating property of china can be significantly improved, improve china hardness of glaze surface;Zirconium silicate simultaneously
Baddeleyite is formed after china high-temperature calcination, is because it is after ceramic firing so that whitening effect can be played in ceramic glaze
Baddeleyite etc. is constituted, incident light wave is constituted and is scattered, the effect for reaching milkiness, brightening;Spodumene can enable china to be subjected to
The environmental change of rapid heat cycle guarantees good thermal stability;Firing temperature can be greatly lowered in wollastonite in powder, shorten firing
Time largely saves fuel, hence it is evident that reduces product cost;The mechanical performance of product is improved simultaneously, is reduced the crack of product and is stuck up
Bent, increase glaze gloss improves idiosome intensity, and then improves the qualification rate of product.
Specific embodiment
Below with reference to preferred embodiment, the present invention is further illustrated.
Embodiment 1
A kind of far infrared of usury desert material is from raw glaze china, china pug component and weight percent are as follows: is derived from
The grains of sand 50% in desert;Pyrophillite 10%;Camwood knag 8%;Gangue 10%;Magnesium-based bentonite 2%;Potassium feldspar 6%;Albite
3%;Micron order spodumene 3%;Zirconium silicate 2%;Wollastonite 6%.
Preferably, chemical composition is by weight percentage in the china pug are as follows: SiO2: 60%;Al2O3: 20%;CaO:
4.5%;ZrO2: 5.0%;Na2O+K2O:4.6%;Fe2O3: 1.2%;MgO:2.8%; LiO2: 0.8%;TiO2: 1.0%;
P2O5: 0.1%.
Preferably, the process flow that above-mentioned china pug prepares china is followed successively by by formula ingredient, is derived from desert for 50%
The grains of sand, 10% pyrophillite, 8% camwood knag, 10% gangue, 2% magnesium-based bentonite, 6% potassium feldspar, 3%
Albite, 3% micron order spodumene, 2% zirconium silicate and 6% nanometer wollastonite be put into ball mill and mixed
Grinding, wherein material: ball: uniformly mixed pug is made in water 1:1.5:0.5;Then, uniformly mixed pug be successively sieved,
Except iron, filters pressing, first time pugging, second of pugging and sizing sintering process, final pug can cross 350 meshes.
Preferably, sand is deposited in by ultrasonic cleaning removal after the grains of sand needs for being derived from desert are mixed with aqueous solution
The sand of the siliceous scale and siliceous film on unconcerned grains of sand surface, desert passes through prolonged weathering, siliceous scale and siliceous film
It is widely present etc. the siliceous beds of precipitation on grains of sand surface, substance adsorption energy Europe and the charge-carrying capability of the grains of sand can be changed.
Preferably, the camwood knag needs successively to be pre-processed by smashing slurry, magnetic separation and the process flow of bleaching.
Wherein, the pH of pug is adjusted as 7 in alkalescent in the first time pugging and second of pugging;Because containing in pug
There is camwood knag, camwood knag contains more carbonaceous humus, and humus and lye effect can hydrolyze to form protecting colloid, have
Help mud material forming performance improvement.
Embodiment 2
A kind of far infrared of usury desert material is from raw glaze china, china pug component and weight percent are as follows: is derived from
The grains of sand 55% in desert;Pyrophillite 8%;Camwood knag 6%;Gangue 11%;Magnesium-based bentonite 3%;Potassium feldspar 4%;Albite
4%;Micron order spodumene 1%;Zirconium silicate 4%;Wollastonite 4%.
Preferably, chemical composition is by weight percentage in the china pug are as follows: SiO2: 65%;Al2O3: 18%;CaO:
3%;ZrO2: 4%;Na2O+K2O:3.2%;Fe2O3: 1.8%;MgO:3.2%; LiO2: 1%;TiO2: 0.75%;P2O5:
0.05%.
Preferably, the process flow that above-mentioned china pug prepares china is followed successively by by formula ingredient, is derived from desert for 55%
The grains of sand, 8% pyrophillite, 6% camwood knag, 11% gangue, 3% magnesium-based bentonite, 4% potassium feldspar, 4%
Albite, 1% micron order spodumene, 4% zirconium silicate and 4% nanometer wollastonite ball mill in carry out mixed grinding,
Wherein expect: ball: uniformly mixed pug is made in water 1:1.5:0.5;Then, uniformly mixed pug by sieving, except iron,
Filters pressing, first time pugging, second of pugging and sizing sintering process, final pug can cross 350 meshes.
Preferably, Desert Sand is deposited in by ultrasonic cleaning removal after the grains of sand needs for being derived from desert are mixed with water
The sand of the siliceous scale and siliceous film on grain surface, desert passes through prolonged weathering, the silicon such as siliceous scale and siliceous film
The matter beds of precipitation are widely present on grains of sand surface, can change substance adsorption energy Europe and the charge-carrying capability of the grains of sand.
Preferably, the camwood knag needs successively to be pre-processed by smashing slurry, magnetic separation and the process flow of bleaching.
Preferably, the pH of pug is adjusted as 8 in alkalescent in the first time pugging and second of pugging;Because in pug
Containing camwood knag, camwood knag contains more carbonaceous humus, and humus and lye effect can hydrolyze to form protecting colloid,
Facilitate mud material forming performance improvement.
Embodiment 3
A kind of far infrared of usury desert material is from raw glaze china, china pug component and weight percent are as follows: is derived from
The grains of sand 45% in desert;Pyrophillite 9%;Camwood knag 7%;Gangue 13%;Magnesium-based bentonite 4%;Potassium feldspar 8%;Albite
4%;Micron order spodumene 2%;Zirconium silicate 3%;Wollastonite 5%.
Preferably, chemical composition is by weight percentage in the china pug are as follows: SiO2: 70%;Al2O3: 15%;CaO:
2.0%;ZrO2: 3.5%;Na2O+K2O:2.6%;Fe2O3: 2.0%;MgO:3.5%; LiO2: 0.8%;TiO2: 0.5%;
P2O5: 0.1%.
Preferably, the process flow that above-mentioned china pug prepares china is followed successively by by formula ingredient, is derived from desert for 45%
The grains of sand, 9% pyrophillite, 7% camwood knag, 13% gangue, 4% magnesium-based bentonite, 8% potassium feldspar, 4%
Albite, 2% micron order spodumene, 3% zirconium silicate and 5% nanometer wollastonite be put into ball mill and mixed
Grinding, wherein material: ball: uniformly mixed pug is made in water 1:1.5:0.5;Then, uniformly mixed pug by sieving,
Except iron, filters pressing, first time pugging, second of pugging and sizing sintering process, final pug can cross 350 meshes.
Preferably, Desert Sand is deposited in by ultrasonic cleaning removal after the grains of sand needs for being derived from desert are mixed with water
The sand of the siliceous scale and siliceous film on grain surface, desert passes through prolonged weathering, the silicon such as siliceous scale and siliceous film
The matter beds of precipitation are widely present on grains of sand surface, can change substance adsorption energy Europe and the charge-carrying capability of the grains of sand.
Preferably, the camwood knag needs successively to be pre-processed by smashing slurry, magnetic separation and the process flow of bleaching.
Preferably, the pH of pug is adjusted as 8 in alkalescent in the first time pugging and second of pugging;Because in pug
Containing camwood knag, camwood knag contains more carbonaceous humus, and humus and lye effect can hydrolyze to form protecting colloid,
Facilitate mud material forming performance improvement.
China pug made of raw material proportioning according to above-mentioned implementation 1-3 is once calcined in 1200 DEG C~1300 DEG C high temperature
At from raw glaze china, the process of once-firing is as follows:
(1) room temperature~200 DEG C are heated up 2~3h to 300 DEG C at a slow speed, are fired in oxygen atmosphere, heating rate 1
~1.5 DEG C/min;It heats up at a slow speed to prevent molding blank from cracking, sloughs the free water in molding blank and the combination on pug surface
Water, pug enter the stage of dehydration and drying and consolidation steadily;
(2) 200 DEG C~800 DEG C, heating rate is improved, holding heating rate is 8~10 DEG C/min;The bone during this temperature
Hydroxyl in porcelain pug in pyrophillite is constantly sloughed, camwood knag, gangue and organic impurities and humus in magnesium-based bentonite
It gradually decomposes at high operating temperatures, china pug is fired in this temperature range and consolidated;Simultaneously in this temperature range, with temperature
It constantly increases, the occurrence status of iron is also constantly changing in pyrophillite, under conditions of high-temperature oxydation, because of the oxygen atom in environment
It is spread along vacancy into the crystal of pyrophillite, and impurity iron ionic valence condition in lattice is caused to change with energy level, pyrophyllite powder
Body is gradually converted into snowy white, increases the whiteness of pug, while pyrophillite crystal form takes place and is changed into inclined pyrophillite, unsetting
SiO2And cristobalite;
(3) 800 DEG C~1200 DEG C, heating rate is 3~5 DEG C/min, carries out the sintering shrinkage forming process of china pug;
Anyway crystal transition and crystal seed growth gradually occur for pyrophillite, camwood knag and gangue in this temperature range china pug,
In-situ reaction reaction occurs in three kinds of raw materials between the aluminium oxide of different crystal phases, is the critical period of transformation toughening, reduces at this time
Heating rate can prevent china from cracking;
(4) in 1200 DEG C~1300 DEG C range 3~6h of inside holding, it is passed through nitrogen in this temperature range, builds nitrogen gas
Atmosphere, avoids the interference of ambient atmos, while extending soaking time, collectively promotes the three-dimensional netted crystal phase of china inside pug formation
Structure gradually tends towards stability, and then improves china toughness after molding;
(5) 1300 DEG C~600 DEG C, high temperature is quickly cooled down the stage, and rate of temperature fall is 16~18 DEG C/min;In this temperature range
Chilling is needed, prevents the low price ferro element contained in molding china to be oxidized to high price iron again and makes china yellowing, quality
It is impermeable;
(6) 100 DEG C or less are naturally cooled to.
Comparative example 1:
A kind of High-tenacity high-strength far-infrared ceramic material, ceramic components are calculated by mass percentage are as follows: SiC toughening whisker 5%;
Nanometer ZrO2(2Y) precursor 15%;And the MgO proportion as framework material is 15%;Surplus is nanometer α-Al2O3;
The nanometer ZrO2(2Y) is the zirconium oxide precursor for being mixed with 2% rare-earth yttrium;The MgO is submicron order powder, granularity
It is 0.1-1 μm;α-the Al2O3Purity is 99% or more nano alumina powder jointed, granularity 50-200nm;The SiC whisker
Length is 200-500 μm.
Comparative example 2
A kind of iron tailings far-infrared ceramic material and preparation method thereof containing rare earth:
A, iron tailings is put into ball milling 30min in ball mill, after ball milling, crosses 350 meshes, obtains iron tailings powder;
B, the iron tailings powder for taking the step A of weight 35% to obtain, then add the titanium dioxide of the clay of weight 7%, 25%
Silicon, 25% calcium carbonate, 7% aluminium oxide and 1% lanthanum nitrate and above-mentioned raw materials weight 15% water, mix simultaneously continue
Stir 30min;
C, by the mixture in step B under the conditions of 100 DEG C, 1h is dried;
D, the mixing after drying in step C is crossed into 120 meshes after ball milling mixing 60min;
It E, is 30MPa in briquetting pressure by the mixing in step D, under conditions of pressure maintaining 1.5min, pottery is made in compression moulding
Green body, is then put into sintering furnace and is sintered by porcelain billet body, finally the obtained iron tailings far-infrared ceramic material containing rare earth.
The performance test from raw glaze china of usury desert material:
Table 1 is normal direction total emissivity test result
Inspection project | Embodiment 1 | Embodiment 2 | Embodiment 3 | Comparative example 1 | Comparative example 2 |
Normal direction whole radiation rate | 0.88 | 0.90 | 0.91 | 0.80 | 0.85 |
As seen from the above table, it is produced by the present invention from raw glaze china even across higher than 800 DEG C condition processing after, infrared spoke
It penetrates rate and is still maintained at higher level, the infrared emittance draw at 5-20 μm can reach 0.90 or more.
2 comprehensive mechanical property test result of table
As seen from the above table, the present invention, which is made from the intensity and toughness of raw glaze china, can reach height made from comparative example 1
The standard of strength high toughness, while water absorption rate is small, good transmittance, improves the thermal stability and rapid heat cycle state change of china
Under stability, if desired add pigment and colored china be made, whiteness higher position can be improved the pure of the color of colored china
Cleanliness.
In conclusion the present invention, which is made, from raw glaze china infrared emittance averagely can reach 0.90 or more, at the same have compared with
Good mechanical property, preferable thermostable type, higher whiteness and light transmittance.
The above embodiment is a preferred embodiment of the present invention, but embodiments of the present invention are not by above-described embodiment
Limitation, other any changes, modifications, substitutions, combinations, simplifications made without departing from the spirit and principles of the present invention,
It should be equivalent substitute mode, be included in protection scope of the present invention.
Claims (6)
1. a kind of far infrared of usury desert material is from raw glaze china, it is characterised in that: china pug component and weight percent
Than are as follows: it is derived from the grains of sand in desert: 45% ~ 55%;Pyrophillite: 8% ~ 10%;Camwood knag: 6% ~ 8%;Gangue: 10% ~ 13%;Magnesium-based is swollen
Profit soil: 2% ~ 4%;Potassium feldspar: 4% ~ 8%;Albite: 3% ~ 6%;Micron order spodumene: 1% ~ 3%;Zirconium silicate: 2% ~ 4%;Wollastonite:
4%~6%。
2. a kind of far infrared of usury desert material as described in claim 1 is from raw glaze china, it is characterised in that: the bone
Chemical composition is by weight percentage in porcelain pug are as follows: SiO2: 60% ~ 70%;Al2O3: 16% ~ 20%;CaO:2.5% ~ 4.5%;ZrO2:
3.5%~5.0%;Na2O+K2O:2.6% ~ 4.6%;Fe2O3: 1.2% ~ 2.5%;MgO:2.8% ~ 3.8%;LiO2: 0.8% ~ 1.5%;TiO2:
0.5%~1.0%;P2O5: 0.1% ~ 0.2%.
3. a kind of far infrared of usury desert material as described in claim 1 is from raw glaze china, it is characterised in that: described to take
The siliceous scale and silicon for being deposited in desert grains of sand surface are removed after needing to mix with water from the grains of sand in desert by ultrasonic cleaning
Matter film.
4. a kind of far infrared of usury desert material as described in claim 1 is from raw glaze china, it is characterised in that: the purple
Knaur needs successively to be pre-processed by smashing slurry, magnetic separation and the process flow of bleaching.
5. a kind of far infrared of usury according to any one of claims 1 to 4 desert material is from the preparation work of raw glaze china
Skill, process flow are followed successively by by formula ingredient, ball milling, sieving, remove iron, filters pressing, first time pugging, second of pugging, sizing burning
At, it is characterised in that: china pug is once sintered into 1200 DEG C ~ 1300 DEG C high temperature from raw glaze china, once-firing
Sintering procedure is as follows:
(1) room temperature ~ 200 DEG C, at a slow speed heat up 2 ~ 3h to 300 DEG C, be fired in oxygen atmosphere, heating rate be 1 ~ 1.5 DEG C/
min;
(2) 200 DEG C ~ 900 DEG C, heating rate is improved, holding heating rate is 8 ~ 10 DEG C/min;
(3) 900 DEG C ~ 1200 DEG C, reducing heating rate prevents china from cracking, and heating rate is 3 ~ 5 DEG C/min;
(4) in 1200 DEG C ~ 1300 DEG C range 3 ~ 6h of inside holding, it is passed through nitrogen in this temperature range, builds nitrogen atmosphere, promotes
China crystal phase stabilization is formed;
(5) 1300 DEG C ~ 600 DEG C, high temperature is quickly cooled down the stage, and rate of temperature fall is 16 ~ 18 DEG C/min;
(6) 100 DEG C or less are naturally cooled to.
6. a kind of preparation process of the far infrared of usury desert material as claimed in claim 5 from raw glaze china, feature
Be: the pH that pug is adjusted in the first time pugging and second of pugging is 7 ~ 8 in alkalescent.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201811583049.9A CN109534802B (en) | 2018-12-24 | 2018-12-24 | Far infrared autogenous glaze porcelain with high utilization of desert materials and preparation process thereof |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201811583049.9A CN109534802B (en) | 2018-12-24 | 2018-12-24 | Far infrared autogenous glaze porcelain with high utilization of desert materials and preparation process thereof |
Publications (2)
Publication Number | Publication Date |
---|---|
CN109534802A true CN109534802A (en) | 2019-03-29 |
CN109534802B CN109534802B (en) | 2021-08-24 |
Family
ID=65856978
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201811583049.9A Active CN109534802B (en) | 2018-12-24 | 2018-12-24 | Far infrared autogenous glaze porcelain with high utilization of desert materials and preparation process thereof |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN109534802B (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108484146A (en) * | 2018-04-02 | 2018-09-04 | 肇庆益晟商贸有限公司 | A kind of far-infrared ceramic material and preparation method thereof |
CN111995372A (en) * | 2020-08-13 | 2020-11-27 | 福建省德化县零度创意有限公司 | Dehuajian white porcelain and preparation method thereof |
CN118005027A (en) * | 2024-04-10 | 2024-05-10 | 内蒙古工业大学 | Method for preparing calcium silicate powder by using desert sand |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101121612A (en) * | 2007-07-17 | 2008-02-13 | 桂林工学院 | Method for preparing self-releasing glaze ceramic material by utilizing red mud and red sandstone |
CN101671179A (en) * | 2009-10-15 | 2010-03-17 | 湖南泰鑫瓷业有限公司 | High strength and high wear-resistance zirconium-aluminum-silicon composite self-release glazed ceramic material and manufacture method thereof |
CN105859266A (en) * | 2016-03-31 | 2016-08-17 | 谢敬裕 | Kiln transmutation autogenous glaze Shandong celadon, mud material and method |
CN105906326A (en) * | 2016-04-21 | 2016-08-31 | 福建省德化县晖龙陶瓷有限公司 | High-whiteness autogenous glaze creamy porcelain, preparation method and production process thereof |
CN108706963A (en) * | 2018-06-28 | 2018-10-26 | 温克仁 | A kind of usury is with desert material system from the production technology of raw glaze china |
CN108793983A (en) * | 2018-06-28 | 2018-11-13 | 温克仁 | Spontaneous enamel cement ceramic material and the intelligent production technology of spontaneous enamel cement ceramics |
-
2018
- 2018-12-24 CN CN201811583049.9A patent/CN109534802B/en active Active
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101121612A (en) * | 2007-07-17 | 2008-02-13 | 桂林工学院 | Method for preparing self-releasing glaze ceramic material by utilizing red mud and red sandstone |
CN101671179A (en) * | 2009-10-15 | 2010-03-17 | 湖南泰鑫瓷业有限公司 | High strength and high wear-resistance zirconium-aluminum-silicon composite self-release glazed ceramic material and manufacture method thereof |
CN105859266A (en) * | 2016-03-31 | 2016-08-17 | 谢敬裕 | Kiln transmutation autogenous glaze Shandong celadon, mud material and method |
CN105906326A (en) * | 2016-04-21 | 2016-08-31 | 福建省德化县晖龙陶瓷有限公司 | High-whiteness autogenous glaze creamy porcelain, preparation method and production process thereof |
CN108706963A (en) * | 2018-06-28 | 2018-10-26 | 温克仁 | A kind of usury is with desert material system from the production technology of raw glaze china |
CN108793983A (en) * | 2018-06-28 | 2018-11-13 | 温克仁 | Spontaneous enamel cement ceramic material and the intelligent production technology of spontaneous enamel cement ceramics |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108484146A (en) * | 2018-04-02 | 2018-09-04 | 肇庆益晟商贸有限公司 | A kind of far-infrared ceramic material and preparation method thereof |
CN111995372A (en) * | 2020-08-13 | 2020-11-27 | 福建省德化县零度创意有限公司 | Dehuajian white porcelain and preparation method thereof |
CN118005027A (en) * | 2024-04-10 | 2024-05-10 | 内蒙古工业大学 | Method for preparing calcium silicate powder by using desert sand |
Also Published As
Publication number | Publication date |
---|---|
CN109534802B (en) | 2021-08-24 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN103013442B (en) | Alpha-alumina-based abrasive and preparation method thereof | |
CN103013443B (en) | Alpha-alumina-based abrasive containing sheet-shaped structures, and preparation method thereof | |
CN102363286B (en) | Steel blank grinding abrasion wheel adopting microcrystal ceramic bonding agents | |
CN111533530B (en) | Sanitary ceramic formula and preparation method | |
KR101175999B1 (en) | Manufacturing process of a colour stone using basalt powder | |
CN109534802A (en) | A kind of far infrared of usury desert material is from raw glaze china and its preparation process | |
CN111423124B (en) | Wear-resistant transparent glaze, wear-resistant polished glazed brick and preparation method thereof | |
CN109279615B (en) | A kind of preparation method of the high whiteness calcination of talc of low cost | |
CN1264777C (en) | Reinforced daily ceramic manufacturing process | |
CN109650848A (en) | It is a kind of from raw glaze enamel porcelain pug and use its technique for preparing enamel porcelain | |
CN114735999A (en) | Super-white light-transmitting jade ceramic tile and processing method thereof | |
CN108675657A (en) | A method of preparing silicate-aluminium sulfate compound system clinker using waste residue | |
CN106007685A (en) | Zirconium containing alpha-alumina-based grinding material with submicron grain structure and preparation method | |
CN105060717B (en) | It is a kind of using molybdic tailing as building decorative glass ceramics of main material and preparation method thereof | |
CN110452020A (en) | It is a kind of to introduce black matrix flash glaze ceramics and its manufacture craft prepared by quartz mine tailings | |
CN111995416A (en) | Boron nitride and silicon micro powder compounded ceramic nozzle and manufacturing method thereof | |
CN106866008A (en) | A kind of preparation method of magnesium low-heat cement clinker high | |
CN104961363B (en) | A kind of method of the active ground-slag of use shaft kiln factory and office reason discarded concrete system and aggregate | |
CN114873988A (en) | New daily-use porcelain prepared from waste ceramics and preparation method thereof | |
CN101219911A (en) | Process for producing coloured polished brick | |
CN100591636C (en) | Portland cement used to produce high-grade siliceous refractories and its production process | |
CN108569888A (en) | A kind of Buddha jumping over the wall container formulations and manufacture craft | |
CN103787341A (en) | Method for producing white carbon black from obsidian | |
CN102173430B (en) | Technique for preparing wollastonite ultrafine powder from calcium silicate hydrate | |
CN111807702A (en) | Method for manufacturing glazed tile with glazed three-dimensional effect |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
GR01 | Patent grant | ||
GR01 | Patent grant |