CN109526953A - A kind of low temperature resistant resistance to hard water flies anti-auxiliary agent - Google Patents

A kind of low temperature resistant resistance to hard water flies anti-auxiliary agent Download PDF

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Publication number
CN109526953A
CN109526953A CN201811573534.8A CN201811573534A CN109526953A CN 109526953 A CN109526953 A CN 109526953A CN 201811573534 A CN201811573534 A CN 201811573534A CN 109526953 A CN109526953 A CN 109526953A
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Prior art keywords
auxiliary agent
surfactant
low temperature
temperature resistant
hard water
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CN201811573534.8A
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CN109526953B (en
Inventor
张卫
李翠英
何建芬
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SHIJIAZHUANG BOJIATE CHEMICAL INDUSTRY Co Ltd
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SHIJIAZHUANG BOJIATE CHEMICAL INDUSTRY Co Ltd
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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/30Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests characterised by the surfactants
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/02Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
    • A01N25/04Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
    • A01N25/06Aerosols
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/28Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
    • A01N47/30Derivatives containing the group >N—CO—N aryl or >N—CS—N—aryl
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/28Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
    • A01N47/36Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< directly attached to at least one heterocyclic ring; Thio analogues thereof

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  • Life Sciences & Earth Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Agronomy & Crop Science (AREA)
  • Plant Pathology (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Chemical & Material Sciences (AREA)
  • Toxicology (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

Fly anti-auxiliary agent the invention discloses a kind of low temperature resistant resistance to hard water, belongs to insecticides adjuvant field, phosphoric acid esters surface active agent, sulfonate surfactant, Sulfates surfactant, glycine betaine and water;The present invention can be improved the stability for flying anti-medicament, prevent medicament from aggregate and precipitate occurs, and has excellent permeability and dispersibility, is suitably applied that temperature is lower, in the higher environment of the water hardness.

Description

A kind of low temperature resistant resistance to hard water flies anti-auxiliary agent
Technical field
The present invention relates to one kind to fly anti-auxiliary agent, and especially a kind of low temperature resistant resistance to hard water flies anti-auxiliary agent, belongs to insecticides adjuvant Field.
Background technique
Fly anti-to be the effective ways for forcing down insect density by a kind of large area of airplane spray pesticide, short-term, fly anti- The medicament and auxiliary agent for the profession for needing to be consistent with aircraft.For flying anti-auxiliary agent, study at present more for missible oil, suspension Agent, dry and wet pulvis, but for aqueous suspension agent to fly the research of anti-auxiliary agent less.The anti-auxiliary agent that flies of aqueous suspension agent is flying anti-spray process In be easy to appear that resistance to hard water ability is poor, phenomena such as flocculation, precipitating occurs in low temperature, and when using different formulations of pesticide mixtures It will appear similar problem, especially when flying to prevent requiring concentration high by spraying, this flocculation, deposited phenomenon are more obvious.
Patent document CN201810748423.X discloses a kind of modified vegetable oil and flies anti-auxiliary agent and preparation method thereof and answer It include that the modified rosin oil of 42-56 parts by weight, the surfaces of 14-20 parts by weight are living with the raw material that, the modified vegetable oil flies anti-auxiliary agent Property agent, 10-20 parts by weight wetting spreader-sticker and 10-20 parts by weight anti-drift agent.This flies the raw material kind that anti-auxiliary agent includes Class is more, the effect primarily served be improve medical fluid droplet performance, when low temperature, the water hardness are high using still will appear precipitating, wadding Solidifying problem.
Summary of the invention
Fly anti-auxiliary agent the technical problem to be solved by the invention is to provide a kind of low temperature resistant resistance to hard water, can be improved and fly to prevent The stability of medicament, prevent medicament occur aggregate and precipitate, have excellent permeability and dispersibility, be suitably applied temperature compared with In low, the higher environment of the water hardness.
In order to solve the above technical problems, the technical scheme adopted by the invention is that:
A kind of low temperature resistant resistance to hard water flies anti-auxiliary agent, and phosphoric acid esters surface active agent, Sulfonates surface are living Property agent, Sulfates surfactant, glycine betaine and water.
Technical solution of the present invention further improvement lies in that: further include nonionic surfactant.
Above-mentioned technical proposal of the invention further improvement lies in that: in raw material the mass percent of each ingredient be phosphate Class surfactant 2~12%, sulfonate surfactant 15~30%, Sulfates surfactant 6~20%, beet Alkali 4~15%, water 45~60%.
Technical solution of the present invention further improvement lies in that: phosphate ester surfactant be isooctanol polyethoxylate phosphorus Acid esters;Sulfonate surfactant is alkylbenzene sulfonate, alkyl ethyl sulfonate or aliphatic alcohol polyoxyethylene sulfonate In any one or several combination;Sulfates surfactant is fatty alcohol polyoxyethylene ether sulfate or alkylphenol formaldehyde tree It is any or combinations thereof in rouge polyoxyethylene ether sulfate;Glycine betaine is dodecyl azochlorosulfonate propyl lycine, cocamidopropyl propyl amide Glycine betaine, hexadecyldimethyl benzyl ammonium sulfoethyl glycine betaine, N- lauroyl amido glycine betaine, N- palmityl amido glycine betaine or N- ten Any one or several combination in eight amido betaines.
Technical solution of the present invention further improvement lies in that: in raw material the mass percent of each ingredient be phosphoric acid ester surface Activating agent 1~6%, sulfonate surfactant 9~22%, Sulfates surfactant 3~9%, glycine betaine 2~8%, Nonionic surfactant 17~30%, water 45~60%.
Technical solution of the present invention further improvement lies in that: nonionic surfactant be fatty alcohol polyoxyethylene ether, have Machine silicon polyoxyethylene ether, tallow amine polyoxyethylene ether, alkyl phenol formaldehyde resin polyoxyethylene ether, castor oil polyoxyethylene ether, benzene Ethyl -phenol polyoxyethylene ether, triphenoethyl benzene phenol polyoxyethylene polyoxypropylene ether, lauric acid amide of ethanol, amine oxide, alkane Any one or a few group in base glucosides, sorbitan fatty acid ester or polyoxyethylene sorbitan pears alcohol monolaurate It closes.
Technical solution of the present invention further improvement lies in that: amine oxide be octadecyl dimethyl amine oxide, myristyl The combination of any one or more of dihydroxy ethyl amine oxide or cocodimethyl amine oxide;Alkyl glycosides is alkyl sugar It is any or combinations thereof in glycosides 0810 or alkyl glycosides 1214.
The present invention also proposes a kind of preparation method for flying anti-auxiliary agent of low temperature resistant resistance to hard water, comprising the following steps: by it is each at Divide mass percentage to carry out ingredient, stirs evenly at 40~60 DEG C to get anti-auxiliary agent is flown.
The present invention also proposes a kind of application for flying anti-auxiliary agent of low temperature resistant resistance to hard water, i.e., will fly anti-auxiliary agent and Thidiazuron opposes It is anti-spraying for flying after careless precititation suspension mixing.
By adopting the above-described technical solution, the technological progress achieved by the present invention is:
The low temperature resistant resistance to hard water of one kind provided by the invention flies anti-auxiliary agent, can be improved the stability for flying anti-medicament, prevents Aggregate and precipitate occurs for medicament, has excellent permeability and dispersibility, is suitably applied that temperature is lower, the higher environment of the water hardness In.
The present invention uses phosphate ester surfactant, sulfonate surfactant, Sulfates surfactant, sweet tea Dish alkali and water are as raw material.Phosphate ester surfactant can solubilising, wetting, sulfonate surfactant has preferable Wetting power and oil removing power, Sulfates surfactant can reduce surface tension, and glycine betaine has in the higher water of hardness Good stability, when being used cooperatively with other surfactants, available ideal viscosity.When phosphoric acid ester surface-active Agent 2~12%, sulfonate surfactant 15~30%, Sulfates surfactant 6~20%, glycine betaine 4~15%, When water 45~60%, above-mentioned each substance cooperation, which is formed by, to be flown anti-auxiliary agent and avoids using and store process to occur being layered or sink The problem of shallow lake, and can reduce surface tension, improve wettability can be with it when nonionic surfactant is added Its surfactant is compatible well, further enhances the stability of auxiliary agent.Medicament is enhanced after mixing with pesticidal chemical Stability and homogeneity, prevent medicament when flying anti-spraying temperature is lower, in the higher environment of the water hardness using being easy precipitating The phenomenon that.
It is prepared by the present invention fly anti-auxiliary agent with good permeability, wetability and dispersibility can after being mixed with medicament Increase medicament and fall on the later adhesive rate of crop surface, enhances medical fluid in the plate-out ability and permeability of crop surface, can make to make Object preferably absorbs medical fluid.When being especially used cooperatively with Thidiazuron diuron aqueous suspension, it can guarantee the uniform steady of medical fluid It is fixed, prevent medical fluid from aggregation or layering occurs and causes liquor strength uneven, drug effect can be significantly improved by flying anti-auxiliary agent using this, Pesticide dosage can be saved simultaneously, greatly reduces drug cost, the pollution to environment is reduced, while flying anti-auxiliary agent itself and is used Material toxicity is small, is a kind of environmentally protective to fly anti-auxiliary agent.
It is prepared by the present invention to fly anti-auxiliary agent and be suitable for using in the environment that temperature is low, the water hardness is high.When water hardness compared with When big, more calcium and magnesium ion can be contained in water, when preparing pesticide, if environment temperature reduces, calcium and magnesium ion meeting and agriculture Ingredient in medicine reacts and forms precipitating, not only influences the drug effect of pesticide but also influences to use, when flying anti-spraying, due to It forms precipitating and causes liquor strength uneven, the cleaning of bottom precipitation difficulty.When preparing pesticide, with the use of prepared by the present invention Low temperature resistant resistance to hard water flies anti-auxiliary agent, is 0~4 DEG C in use environment temperature, the water hardness is that the water hardness is that 18~20 times of standards are hard It when water, still ensures that the stable homogeneous of medical fluid, no precipitating generate, is suitble to fly to prevent spraying use.
Specific embodiment
Here is certain specific embodiments of the invention, to be described in further detail.
A kind of low temperature resistant resistance to hard water flies anti-auxiliary agent, and phosphoric acid esters surface active agent, Sulfonates surface are living Property agent, Sulfates surfactant, glycine betaine and water, the mass percent of each ingredient is phosphoric acid ester surface-active in raw material Agent 2~12%, sulfonate surfactant 15~30%, Sulfates surfactant 6~20%, glycine betaine 4~15%, Water 45~60%.Preferably, phosphoric acid esters surface active agent, sulfonate surfactant, Sulfates surface Activating agent, glycine betaine, water and nonionic surfactant, the mass percent of each ingredient is phosphoric acid ester surface-active in raw material Agent 1~6%, sulfonate surfactant 9~22%, Sulfates surfactant 3~9%, glycine betaine 2~8%, it is non-from Sub- surfactant 17~30%, water 45~60%.
Phosphate ester surfactant is Phosphate of Polyoxyethylene Isooctyl Ether.
Sulfonate surfactant is alkylbenzene sulfonate, alkyl ethyl sulfonate or fatty alcohol polyoxyethylene ether sulfonic acid Any one or several combination in salt.
Sulfates surfactant is fatty alcohol polyoxyethylene ether sulfate or alkyl phenol formaldehyde resin polyoxyethylene ether It is any or combinations thereof in sulfate.
Glycine betaine is dodecyl azochlorosulfonate propyl lycine, Cocoamidopropyl betaine, hexadecyldimethyl benzyl ammonium sulfoethyl It is any or several in glycine betaine, N- lauroyl amido glycine betaine, N- palmityl amido glycine betaine or N- stearamide base glycine betaine The combination of kind.
Nonionic surfactant be fatty alcohol polyoxyethylene ether, organosilicone polyoxyethylene ether, tallow amine polyoxyethylene ether, Alkyl phenol formaldehyde resin polyoxyethylene ether, castor oil polyoxyethylene ether, phenethyl phenol polyoxyethylene ether, triphenoethyl benzene phenol are poly- Oxypropylene polyoxyethylene ether, lauric acid amide of ethanol, amine oxide, alkyl glycosides, sorbitan fatty acid ester or polyoxy second Any one or the combination of several of them in alkene dehydration pears alcohol monolaurate.Preferably, amine oxide is octadecyldimethyl oxygen Change the combination of any one or more of amine, myristyl dihydroxy ethyl amine oxide or cocodimethyl amine oxide;Alkane Base glucosides is any or combinations thereof in alkyl glycosides 0810 or alkyl glycosides 1214.
Preparation method includes the following steps: to carry out ingredient by each composition quality percentage composition, stir evenly at 40~60 DEG C, Fly anti-auxiliary agent to obtain the final product.
In use, flying anti-spraying for flying after anti-auxiliary agent is mixed with Thidiazuron diuron aqueous suspension.
Embodiment 1
Under conditions of temperature is 55 DEG C, by 4 parts of fatty alcohol polyoxyethylene ether, 2 parts of organosilicone polyoxyethylene ether, phenethyl 5 parts of phenol polyoxyethylene ether, 2 parts of alkyl benzene calcium sulfonate, 2 parts of N- palmityl amido glycine betaine, myristyl dihydroxy ethyl oxygen Change 1 part of amine, 1,214 5 parts of alkyl glycosides, 6 parts of neopelex, 5 parts of alkyl ethyl sulfonate, aliphatic alcohol polyethenoxy 4 parts of ether sodium sulfate, 2 parts of aliphatic alcohol polyoxyethylene sulfonate, 2 parts of Phosphate of Polyoxyethylene Isooctyl Ether and 60 parts of water, mixing And stir evenly, it obtains flying anti-auxiliary agent.It is faint yellow or yellow transparent liquid that this, which flies anti-auxiliary agent,.
Embodiment 2~8
Embodiment 2~8 is same as Example 1, except that the selection of raw material composition and technological parameter, such as following table 1 Shown in.
Table 1
Comparative example 1~6
Comparative example 1~4 is same as Example 1, except that the selection of material composition and proportion, such as institute in following table 2 Show.
Comparative example 5~6 is same as Example 2, except that the selection of material composition and proportion, such as institute in following table 2 Show.
Table 2
Test example
What is be prepared in Example 1~8, comparative example 1~6 flies anti-auxiliary agent, detects its viscosity, pH.Viscosity is according to GB/ Rotary process in T 10247-2008 is detected;PH is detected according to the method in GB/T 6368-2008.As a result such as table 3 It is shown.
Table 3
Viscosity (mPas) pH
Embodiment 1 400 6.7
Embodiment 2 370 6.8
Embodiment 3 360 6.7
Embodiment 4 380 6.8
Embodiment 5 430 6.7
Embodiment 6 420 6.9
Embodiment 7 430 6.8
Embodiment 8 400 6.8
Comparative example 1 520 6.6
Comparative example 2 480 6.5
Comparative example 3 460 6.6
Comparative example 4 450 6.6
Comparative example 5 460 6.7
Comparative example 6 480 6.5
It can be seen that the anti-auxiliary agent viscosity that flies being prepared in the embodiment of the present invention 1 according to the testing result in table 3 to compare The viscosity of ratio 1~4 is low, be prepared in embodiment 2 to fly anti-auxiliary agent viscosity lower than comparative example 5~6, therefore, system of the present invention The standby obtained mobility for flying anti-auxiliary agent and stability are better than comparative example.It is prepared by the present invention to fly to prevent compared with comparative example 12 The pH of auxiliary agent will not have an impact the drug effect of pesticide when preparing pesticidal chemical close to neutrality, and pesticide carries out flying blowout prevention After mist, acidic materials residual is not had in the soil, not will cause soil acidification.
By in Examples 1 to 8, comparative example 1~6 fly anti-auxiliary agent and pestsides synthesis and dilution prepares pesticidal chemical, prepare Method is as follows: having in plug graduated cylinder in 100ml and 100g18 times of standard hard water is added, sequentially add 2g Thidiazuron diuron, 5g flies Anti- auxiliary agent, 8g ethephon (CEPHA),2-(chloroethyl) phosphonic acid, turns upside down, and shakes up, and obtains pesticidal chemical.
The ordinary temperature stability and low-temperature stability of pesticidal chemical are evaluated.Ordinary temperature stability evaluation method are as follows: will Above-mentioned pesticidal chemical is placed in 30min in 30 ± 2 DEG C of water-baths.It is not stratified, there is a little precipitating, is considered as qualification;Layering, there have to be more heavy It forms sediment, is considered as unqualified.Low-temperature stability evaluation method are as follows: be placed in above-mentioned pesticidal chemical in 0~4 DEG C of low-temperature test chamber. Placing 30min has a little precipitating, is considered as qualification;There are a large amount of precipitatings when placing 30min, is considered as unqualified.It the results are shown in Table 4.
Table 4
It can be seen that according to the testing result in table 4 and prepared by the present invention fly anti-auxiliary agent and Thidiazuron diuron aqueous suspension It is diluted after mixing with 18 times of standard hard waters, room temperature is not stratified, no precipitating, and precipitating will not be generated in low temperature.And Comparative example is layered after being diluted with 18 times of standard hard waters, partially there is a precipitating, and precipitating increases when low temperature.The present invention can low temperature, It is used in the higher environment of the water hardness, and comparative example is not able to satisfy the requirement used in low temperature, the higher environment of the water hardness then.

Claims (9)

1. a kind of low temperature resistant resistance to hard water flies anti-auxiliary agent, it is characterised in that: phosphoric acid esters surface active agent, sulfonate Class surfactant, Sulfates surfactant, glycine betaine and water.
2. the low temperature resistant resistance to hard water of one kind according to claim 1 flies anti-auxiliary agent, it is characterised in that: further include nonionic table Face activating agent.
3. the low temperature resistant resistance to hard water of one kind according to claim 1 flies anti-auxiliary agent, it is characterised in that: each ingredient in raw material Mass percent is phosphate ester surfactant 2 ~ 12%, sulfonate surfactant 15 ~ 30%, Sulfates surface-active Agent 6 ~ 20%, glycine betaine 4 ~ 15%, water 45 ~ 60%.
4. the low temperature resistant resistance to hard water of one kind according to claim 3 flies anti-auxiliary agent, it is characterised in that: phosphoric acid ester surface is living Property agent be Phosphate of Polyoxyethylene Isooctyl Ether;Sulfonate surfactant is alkylbenzene sulfonate, alkyl ethyl sulfonate Or any one or several combination in aliphatic alcohol polyoxyethylene sulfonate;Sulfates surfactant is fatty alcohol polyoxy second It is any or combinations thereof in alkene ether sulphate or alkyl phenol formaldehyde resin polyoxyethylene ether sulfate;Glycine betaine is dodecyl sulphur Propyl betaine, Cocoamidopropyl betaine, hexadecyldimethyl benzyl ammonium sulfoethyl glycine betaine, N- lauroyl amido glycine betaine, Any one or several combination in N- palmityl amido glycine betaine or N- stearamide base glycine betaine.
5. the low temperature resistant resistance to hard water of one kind according to claim 2 flies anti-auxiliary agent, it is characterised in that: each ingredient in raw material Mass percent is phosphate ester surfactant 1 ~ 6%, sulfonate surfactant 9 ~ 22%, Sulfates surfactant 3 ~ 9%, glycine betaine 2 ~ 8%, nonionic surfactant 17 ~ 30%, water 45 ~ 60%.
6. the low temperature resistant resistance to hard water of one kind according to claim 5 flies anti-auxiliary agent, it is characterised in that: non-ionic surface active Agent is fatty alcohol polyoxyethylene ether, organosilicone polyoxyethylene ether, tallow amine polyoxyethylene ether, alkylphenol-formaldehyde resin polyoxyethylene Ether, castor oil polyoxyethylene ether, phenethyl phenol polyoxyethylene ether, triphenoethyl benzene phenol polyoxyethylene polyoxypropylene ether, cocounut oil In sour diglycollic amide, amine oxide, alkyl glycosides, sorbitan fatty acid ester or polyoxyethylene sorbitan pears alcohol monolaurate Any one or the combination of several of them.
7. the low temperature resistant resistance to hard water of one kind according to claim 6 flies anti-auxiliary agent, it is characterised in that: amine oxide is octadecane Any one or more of base dimethyl amine, myristyl dihydroxy ethyl amine oxide or cocodimethyl amine oxide Combination;Alkyl glycosides is any or combinations thereof in alkyl glycosides 0810 or alkyl glycosides 1214.
8. a kind of preparation method for flying anti-auxiliary agent of such as described in any item low temperature resistant resistance to hard water of claim 3 ~ 7, feature exist In the following steps are included: stirring evenly by each composition quality percentage composition progress ingredient at 40 ~ 60 DEG C to get anti-auxiliary agent is flown.
9. a kind of application for flying anti-auxiliary agent of low temperature resistant resistance to hard water as claimed in any one of claims 1 to 7, it is characterised in that: fly Anti- auxiliary agent is anti-spraying for flying after mixing with Thidiazuron diuron aqueous suspension.
CN201811573534.8A 2018-12-21 2018-12-21 Low-temperature-resistant and hard-water-resistant flight control aid Active CN109526953B (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111631224A (en) * 2020-06-18 2020-09-08 江苏徐淮地区淮阴农业科学研究所 Rice seed dressing agent and preparation method and application thereof
CN114557340A (en) * 2022-03-15 2022-05-31 浙江新安化工集团股份有限公司 Low-foam anti-crystallization pesticide aqueous solution and preparation process thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102326536A (en) * 2011-07-20 2012-01-25 深圳市长园嘉彩环境材料有限公司 Glyphosate synergist
CN103084119A (en) * 2013-02-06 2013-05-08 中化化工科学技术研究总院 Phosphorylated polymerization polymer dispersant and its preparation method
US20130336916A1 (en) * 2012-06-18 2013-12-19 Tao Zhong Botanical insecticides
CN103858921A (en) * 2014-02-14 2014-06-18 南京善为生物科技有限公司 Environmental-friendly thiamethoxam aqua and preparation method thereof
CN108770843A (en) * 2018-05-25 2018-11-09 浙江新安化工集团股份有限公司 A kind of spray adjuvants and preparation method thereof and include its spray liquid

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102326536A (en) * 2011-07-20 2012-01-25 深圳市长园嘉彩环境材料有限公司 Glyphosate synergist
US20130336916A1 (en) * 2012-06-18 2013-12-19 Tao Zhong Botanical insecticides
CN103084119A (en) * 2013-02-06 2013-05-08 中化化工科学技术研究总院 Phosphorylated polymerization polymer dispersant and its preparation method
CN103858921A (en) * 2014-02-14 2014-06-18 南京善为生物科技有限公司 Environmental-friendly thiamethoxam aqua and preparation method thereof
CN108770843A (en) * 2018-05-25 2018-11-09 浙江新安化工集团股份有限公司 A kind of spray adjuvants and preparation method thereof and include its spray liquid

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
赵洪波等: "《胶体与表面化学理论及应用研究》", 31 March 2016, 黑龙江大学出版社 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111631224A (en) * 2020-06-18 2020-09-08 江苏徐淮地区淮阴农业科学研究所 Rice seed dressing agent and preparation method and application thereof
CN114557340A (en) * 2022-03-15 2022-05-31 浙江新安化工集团股份有限公司 Low-foam anti-crystallization pesticide aqueous solution and preparation process thereof

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