CN109518302A - A kind of automatically cleaning wig fiber - Google Patents
A kind of automatically cleaning wig fiber Download PDFInfo
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- CN109518302A CN109518302A CN201811415444.6A CN201811415444A CN109518302A CN 109518302 A CN109518302 A CN 109518302A CN 201811415444 A CN201811415444 A CN 201811415444A CN 109518302 A CN109518302 A CN 109518302A
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- wig fiber
- added
- automatically cleaning
- wig
- shell meal
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- 239000000835 fiber Substances 0.000 title claims abstract description 110
- 238000004140 cleaning Methods 0.000 title claims abstract description 56
- 102000002322 Egg Proteins Human genes 0.000 claims abstract description 52
- 108010000912 Egg Proteins Proteins 0.000 claims abstract description 52
- 210000003278 egg shell Anatomy 0.000 claims abstract description 52
- 235000012054 meals Nutrition 0.000 claims abstract description 31
- 229920001343 polytetrafluoroethylene Polymers 0.000 claims abstract description 20
- 239000004810 polytetrafluoroethylene Substances 0.000 claims abstract description 20
- 229920002492 poly(sulfone) Polymers 0.000 claims abstract description 14
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000006185 dispersion Substances 0.000 claims abstract description 13
- 239000007788 liquid Substances 0.000 claims abstract description 13
- 229920002239 polyacrylonitrile Polymers 0.000 claims abstract description 13
- 229920005989 resin Polymers 0.000 claims abstract description 13
- 239000011347 resin Substances 0.000 claims abstract description 13
- -1 polytetrafluoroethylene Polymers 0.000 claims abstract description 9
- 239000002994 raw material Substances 0.000 claims abstract description 9
- IYVLHQRADFNKAU-UHFFFAOYSA-N oxygen(2-);titanium(4+);hydrate Chemical compound O.[O-2].[O-2].[Ti+4] IYVLHQRADFNKAU-UHFFFAOYSA-N 0.000 claims abstract description 7
- 238000000034 method Methods 0.000 claims abstract description 6
- 239000000243 solution Substances 0.000 claims description 36
- 239000000203 mixture Substances 0.000 claims description 30
- 238000009987 spinning Methods 0.000 claims description 28
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 20
- 238000002360 preparation method Methods 0.000 claims description 18
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 15
- 238000003756 stirring Methods 0.000 claims description 14
- 229920001661 Chitosan Polymers 0.000 claims description 11
- 108010022355 Fibroins Proteins 0.000 claims description 11
- 125000002057 carboxymethyl group Chemical group [H]OC(=O)C([H])([H])[*] 0.000 claims description 11
- 230000001476 alcoholic effect Effects 0.000 claims description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 10
- 239000012460 protein solution Substances 0.000 claims description 9
- 238000002166 wet spinning Methods 0.000 claims description 8
- 238000004544 sputter deposition Methods 0.000 claims description 7
- 230000015271 coagulation Effects 0.000 claims description 6
- 238000005345 coagulation Methods 0.000 claims description 6
- 230000001133 acceleration Effects 0.000 claims description 5
- 230000001112 coagulating effect Effects 0.000 claims description 5
- 238000004108 freeze drying Methods 0.000 claims description 5
- 238000000227 grinding Methods 0.000 claims description 5
- 238000012986 modification Methods 0.000 claims description 5
- 230000004048 modification Effects 0.000 claims description 5
- 238000004321 preservation Methods 0.000 claims description 5
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 4
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 4
- 229910052719 titanium Inorganic materials 0.000 claims description 4
- 239000010936 titanium Substances 0.000 claims description 4
- 240000007594 Oryza sativa Species 0.000 claims description 2
- 235000007164 Oryza sativa Nutrition 0.000 claims description 2
- 238000000151 deposition Methods 0.000 claims description 2
- 230000008021 deposition Effects 0.000 claims description 2
- 238000001755 magnetron sputter deposition Methods 0.000 claims description 2
- 235000009566 rice Nutrition 0.000 claims description 2
- 239000004408 titanium dioxide Substances 0.000 claims description 2
- 239000000126 substance Substances 0.000 abstract description 7
- 238000002844 melting Methods 0.000 abstract description 6
- 230000008018 melting Effects 0.000 abstract description 6
- 238000002156 mixing Methods 0.000 abstract description 6
- 238000012545 processing Methods 0.000 abstract description 2
- 230000000052 comparative effect Effects 0.000 description 24
- 230000003115 biocidal effect Effects 0.000 description 13
- 239000003063 flame retardant Substances 0.000 description 7
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 6
- 238000001514 detection method Methods 0.000 description 4
- 150000001336 alkenes Chemical class 0.000 description 3
- 230000000845 anti-microbial effect Effects 0.000 description 3
- 239000008367 deionised water Substances 0.000 description 3
- 229910021641 deionized water Inorganic materials 0.000 description 3
- 239000000428 dust Substances 0.000 description 3
- 239000000377 silicon dioxide Substances 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- 210000004243 sweat Anatomy 0.000 description 3
- 241000692870 Inachis io Species 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical compound [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 description 2
- 206010019049 Hair texture abnormal Diseases 0.000 description 1
- 206010053615 Thermal burn Diseases 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 238000004026 adhesive bonding Methods 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000002074 melt spinning Methods 0.000 description 1
- 239000002105 nanoparticle Substances 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 210000004761 scalp Anatomy 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
- D01F8/10—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one other macromolecular compound obtained by reactions only involving carbon-to-carbon unsaturated bonds as constituent
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
- D01F1/103—Agents inhibiting growth of microorganisms
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
- D01F8/08—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyacrylonitrile as constituent
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
- D01F8/16—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one other macromolecular compound obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds as constituent
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/46—Oxides or hydroxides of elements of Groups 4 or 14 of the Periodic Table; Titanates; Zirconates; Stannates; Plumbates
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Artificial Filaments (AREA)
Abstract
The invention mainly relates to staple fibre processing technique fields, disclose a kind of automatically cleaning wig fiber, be prepared from the following raw materials: dispersion liquid 13 ~ 15, modified egg-shell meal 2 ~ 3, lac 1.6 ~ 1.8, nano oxygen titanium dioxide 1.1 ~ 1.3, nano silver 0.26 ~ 0.32 is concentrated in polyacrylonitrile 46 ~ 48, polysulfone resin 17 ~ 19, polytetrafluoroethylene (PTFE) 60%；Automatically cleaning wig fiber provided by the invention, submissive silk is sliding, is easy to arrange, heat-resisting quantity is strong, avoids high temperature deformation, can effectively refuse dirt, and self-cleaning ability is strong, enhances the durability of wig；Polytetrafluoroethylene (PTFE) 60% is added in polyacrylonitrile and polysulfone resin to be concentrated in dispersion liquid, the side Bian Jiare is stirred, and makes the abundant melting mixing of substance, improves the intensity and smoothness of wig fiber；Modified egg-shell meal and lac are added, and a small amount of acetum is added and is stirred under vacuum, improves glossiness, smoothness and the heat-resisting quantity of wig fiber.
Description
Technical field
The invention mainly relates to staple fibre processing technique field more particularly to a kind of automatically cleaning wig fibers.
Background technique
Wig can play preferable decoration function, can convert different hair styles at any time, and can be avoided and often scald
Dye is damaged to caused by true hair, while can save a large amount of time and expense；Wig is all that true hair is made after treatment mostly
It is standby to form, but true hair purchase is difficult at present, and purchasing price is high, to limit the production of wig, therefore gradually uses
Staple fibre replaces true hair, but most of staple fibre wig is easily deformed and burns when contacting high temperature, and generates difficulty
The smell of news, and washing can become very short-tempered afterwards several times, be difficult to arrange.
During wearing wig, wig is directly contacted with extraneous and scalp, becomes easily infected by dust and sweat, though therefore
Right wig generally allows cleaning in 1 ~ 2 month primary, but consumer is substantially after wearing wig and just will do it within 3 ~ 5 days clearly
It washes, causes germ to breed to avoid sweat and dust accumulation, but wig can make dry hair short-tempered after frequent clean, matter
Sense be deteriorated, influence the use of wig, thus need in the market one kind can self-cleaning wig, keep away wig fiber itself can
Exempt from the contamination of the substances such as dust and sweat and keeps cleaning.
Existing 105951211 A of patent document CN discloses a kind of antibiosis and self-cleaning type synthetic wig fiber of hair containing peacock,
The intensity of abundant raw material, wig fiber is higher, but the wig fiber being prepared can only carry out simple hydrophobic effect, anti-pollution
Ability is very unsatisfactory, and self-cleaning effect is poor；202099627 U of patent document CN discloses a kind of antibiosis self-cleaning wig hairline,
Uniformly adhere to nano-titanium dioxide in fiber surface, have preferable self-cleaning ability, but obtained wig fibre strength compared with
Low, smoothness is poor, and short-tempered and fracture is easy to appear during using and arranging, equally also will affect the using effect of wig.
Summary of the invention
In order to make up the defect of prior art, the object of the present invention is to provide a kind of automatically cleaning wig fibers.
A kind of automatically cleaning wig fiber, is made of raw material from the following weight: polyacrylonitrile 46 ~ 48, polysulfone resin 17 ~
19, polytetrafluoroethylene (PTFE) 60% be concentrated dispersion liquid 13 ~ 15, modified egg-shell meal 2 ~ 3, lac 1.6 ~ 1.8, nano oxygen titanium dioxide 1.1 ~
1.3, nano silver 0.26 ~ 0.32.
The modification egg-shell meal, eggshell is cleaned, 30 ~ 35nm is milled to, and Eggshell weight 1.2 ~ 1.6 is added into eggshell
The fibroin albumen of Eggshell weight 17 ~ 19% is added in 70 ~ 80 DEG C of 20 ~ 30min of vacuum stirring in the carboxymethyl chitosan solution of amount again
Solution, continues 30 ~ 40min of insulated and stirred, freeze-drying to no moisture, and grinding obtains modified egg-shell meal.
The carboxymethyl chitosan solution, mass percentage concentration are 0.6 ~ 0.8%.
The silk fibroin protein solution, mass percentage concentration are 1.1 ~ 1.3%.
A kind of preparation method of automatically cleaning wig fiber, comprising the following steps:
(1) polytetrafluoroethylene (PTFE) 60% is added in polyacrylonitrile and polysulfone resin to be concentrated in dispersion liquid, has been slowly heated to while stirring
Full-fusing makes the abundant melting mixing of substance, improves the intensity and smoothness of wig fiber, obtains mixture A；
(2) modified egg-shell meal and lac are added into mixture A, the volume fraction that modified egg-shell meal weight 24 ~ 26% is added is
1.5 ~ 1.7% acetum, heat preservation are stirred under vacuum 30 ~ 40min, improve glossiness, smoothness and the high temperature resistant of wig fiber
Property, obtain mixture B；
(3) nano silver is added in mixture B, stirs evenly, the intensity and antibiotic property of wig can be improved, obtain mixture C；
(4) by mixture C be sent into spinning machine carry out wet spinning, coagulating bath is alkaline ethanol solution, take out spinning after spend from
Sub- water is rinsed to neutrality, is kept wig fiber intensity with higher, is obtained spinning fibre；
(5) spinning fibre is placed in baking oven, it is 4 ~ 8% that water content is dried in 40 ~ 45 DEG C, will be received using magnetically controlled DC sputtering
Rice titanium dioxide deposition improves the intensity and self-cleaning ability of wig fiber in spinning fibre surface, arranges, and derives from cleaning wig
Fiber.
The wet spinning of the step (4), spinneret 6 ~ 7m/min of speed, stretch bath temperature 53 by 16 ~ 20 DEG C of coagulation bath temperature
~ 57 DEG C, 4 ~ 5m/min of draft speed.
Sodium hydroxide is added in 56 ~ 58% alcoholic solution to volume fraction in the alkaline ethanol solution of the step (4)
Solution, the pH for being adjusted to alcoholic solution is 9.1 ~ 9.3.
The magnetically controlled DC sputtering of the step (5), 400 ~ 500V of acceleration voltage, 120 ~ 140G of magnetic field, 5 ~ 7mTorr of air pressure,
33 ~ 35mA/cm of current density, 25 ~ 30W/cm of power density.
The automatically cleaning wig fiber, fiber number are 40 ~ 44dtex.
The invention has the advantages that automatically cleaning wig fiber provided by the invention, submissive silk is sliding, is easy to arrange, heat-resisting quantity
By force, high temperature deformation is avoided, dirt can be effectively refused, self-cleaning ability is strong, enhances the durability of wig；By polyacrylonitrile and polysulfones tree
Rouge is added polytetrafluoroethylene (PTFE) 60% and is concentrated in dispersion liquid, and the side Bian Jiare is stirred, and makes the abundant melting mixing of substance, improves wig
The intensity and smoothness of fiber；Modified egg-shell meal and lac are added, and a small amount of acetum is added and is stirred under vacuum, is improved
Glossiness, smoothness and the heat-resisting quantity of wig fiber；Modified egg-shell meal is by eggshell, carboxymethyl chitosan and fibroin albumen through height
The modified obtained nano particle of temperature, has apparent antibiotic property and high temperature resistance；It is eventually adding nano silver, and is stirred
Uniformly, the intensity and antibiotic property of wig can be improved；Mixed raw material is subjected to wet spinning, keeps wig fiber with higher
Intensity；Low temperature drying is carried out after spinning, and nano-titanium dioxide is passed through into Deposited By Dc Magnetron Sputtering in spinning fibre surface, is mentioned
The intensity and self-cleaning ability of high wig fiber.
Specific embodiment
Illustrate the present invention with specific embodiment below.
Embodiment 1
A kind of automatically cleaning wig fiber, is made of raw material from the following weight: polyacrylonitrile 46, polysulfone resin 17, polytetrafluoroethyl-ne
Dispersion liquid 13, modified egg-shell meal 2, lac 1.6, nano oxygen titanium dioxide 1.1, nano silver 0.26 is concentrated in alkene 60%.
The modification egg-shell meal, eggshell is cleaned, 30 ~ 35nm is milled to, and 1.2 times of Eggshell weight amounts are added into eggshell
Carboxymethyl chitosan solution the silk fibroin protein solution of Eggshell weight 17% is added, continues to keep the temperature in 70 DEG C of vacuum stirring 20min
30min, freeze-drying to no moisture are stirred, grinding obtains modified egg-shell meal.
The carboxymethyl chitosan solution, mass percentage concentration 0.6%.
The silk fibroin protein solution, mass percentage concentration 1.1%.
A kind of preparation method of automatically cleaning wig fiber, comprising the following steps:
(1) polytetrafluoroethylene (PTFE) 60% is added in polyacrylonitrile and polysulfone resin to be concentrated in dispersion liquid, has been slowly heated to while stirring
Full-fusing makes the abundant melting mixing of substance, improves the intensity and smoothness of wig fiber, obtains mixture A；
(2) modified egg-shell meal and lac are added into mixture A, the volume fraction that modified egg-shell meal weight 24% is added is 1.5%
Acetum, heat preservation be stirred under vacuum 30min, improve wig fiber glossiness, smoothness and heat-resisting quantity, obtain mixture B；
(3) nano silver is added in mixture B, stirs evenly, the intensity and antibiotic property of wig can be improved, obtain mixture C；
(4) mixture C is sent into spinning machine and carries out wet spinning, spinneret speed 6m/min, stretches bath temperature by 16 DEG C of coagulation bath temperature
53 DEG C of degree, draft speed 4m/min, coagulating bath is alkaline ethanol solution, is rinsed with deionized water to neutrality, is protected after taking out spinning
Wig fiber intensity with higher is held, fiber number 40dtex obtains spinning fibre；The alkaline ethanol solution, to volume point
For number for sodium hydroxide solution is added in 56% alcoholic solution, the pH for being adjusted to alcoholic solution is 9.1 ~ 9.3；
(5) spinning fibre is placed in baking oven, it is 4% that water content is dried in 40 DEG C, using magnetically controlled DC sputtering by nano-silica
Change titanium and is deposited on spinning fibre surface, acceleration voltage 400V, magnetic field 120G, air pressure 5mTorr, current density 33mA/cm, power
Density 25W/cm improves the intensity and self-cleaning ability of wig fiber, arranges, and derives from cleaning wig fiber.
Embodiment 2
A kind of automatically cleaning wig fiber, is made of raw material from the following weight: polyacrylonitrile 47, polysulfone resin 18, polytetrafluoroethyl-ne
Dispersion liquid 14, modified egg-shell meal 2.5, lac 1.7, nano oxygen titanium dioxide 1.2, nano silver 0.29 is concentrated in alkene 60%.
The modification egg-shell meal, eggshell is cleaned, 30 ~ 35nm is milled to, and 1.4 times of Eggshell weight amounts are added into eggshell
Carboxymethyl chitosan solution the silk fibroin protein solution of Eggshell weight 18% is added, continues to keep the temperature in 75 DEG C of vacuum stirring 25min
35min, freeze-drying to no moisture are stirred, grinding obtains modified egg-shell meal.
The carboxymethyl chitosan solution, mass percentage concentration 0.7%.
The silk fibroin protein solution, mass percentage concentration 1.2%.
A kind of preparation method of automatically cleaning wig fiber, comprising the following steps:
(1) polytetrafluoroethylene (PTFE) 60% is added in polyacrylonitrile and polysulfone resin to be concentrated in dispersion liquid, has been slowly heated to while stirring
Full-fusing makes the abundant melting mixing of substance, improves the intensity and smoothness of wig fiber, obtains mixture A；
(2) modified egg-shell meal and lac are added into mixture A, the volume fraction that modified egg-shell meal weight 25% is added is 1.6%
Acetum, heat preservation be stirred under vacuum 35min, improve wig fiber glossiness, smoothness and heat-resisting quantity, obtain mixture B；
(3) nano silver is added in mixture B, stirs evenly, the intensity and antibiotic property of wig can be improved, obtain mixture C；
(4) mixture C is sent into spinning machine and carries out wet spinning, spinneret speed 7m/min, stretches bath temperature by 18 DEG C of coagulation bath temperature
55 DEG C of degree, draft speed 4.5m/min, coagulating bath is alkaline ethanol solution, is rinsed with deionized water to neutrality after taking out spinning,
Wig fiber intensity with higher is kept, fiber number 42dtex obtains spinning fibre；The alkaline ethanol solution, Xiang Tiji
Sodium hydroxide solution is added in the alcoholic solution that score is 57%, the pH for being adjusted to alcoholic solution is 9.1 ~ 9.3；
(5) spinning fibre is placed in baking oven, it is 6% that water content is dried in 43 DEG C, using magnetically controlled DC sputtering by nano-silica
Change titanium and is deposited on spinning fibre surface, acceleration voltage 450V, magnetic field 130G, air pressure 6mTorr, current density 34mA/cm, power
Density 28W/cm improves the intensity and self-cleaning ability of wig fiber, arranges, and derives from cleaning wig fiber.
Embodiment 3
A kind of automatically cleaning wig fiber, is made of raw material from the following weight: polyacrylonitrile 48, polysulfone resin 19, polytetrafluoroethyl-ne
Dispersion liquid 15, modified egg-shell meal 3, lac 1.8, nano oxygen titanium dioxide 1.3, nano silver 0.32 is concentrated in alkene 60%.
The modification egg-shell meal, eggshell is cleaned, 30 ~ 35nm is milled to, and 1.6 times of Eggshell weight amounts are added into eggshell
Carboxymethyl chitosan solution the silk fibroin protein solution of Eggshell weight 19% is added, continues to keep the temperature in 80 DEG C of vacuum stirring 30min
40min, freeze-drying to no moisture are stirred, grinding obtains modified egg-shell meal.
The carboxymethyl chitosan solution, mass percentage concentration 0.8%.
The silk fibroin protein solution, mass percentage concentration 1.3%.
A kind of preparation method of automatically cleaning wig fiber, comprising the following steps:
(1) polytetrafluoroethylene (PTFE) 60% is added in polyacrylonitrile and polysulfone resin to be concentrated in dispersion liquid, has been slowly heated to while stirring
Full-fusing makes the abundant melting mixing of substance, improves the intensity and smoothness of wig fiber, obtains mixture A；
(2) modified egg-shell meal and lac are added into mixture A, the volume fraction that modified egg-shell meal weight 26% is added is 1.7%
Acetum, heat preservation be stirred under vacuum 40min, improve wig fiber glossiness, smoothness and heat-resisting quantity, obtain mixture B；
(3) nano silver is added in mixture B, stirs evenly, the intensity and antibiotic property of wig can be improved, obtain mixture C；
(4) mixture C is sent into spinning machine and carries out wet spinning, spinneret speed 7m/min, stretches bath temperature by 20 DEG C of coagulation bath temperature
57 DEG C of degree, draft speed 5m/min, coagulating bath is alkaline ethanol solution, is rinsed with deionized water to neutrality, is protected after taking out spinning
Wig fiber intensity with higher is held, fiber number 44dtex obtains spinning fibre；The alkaline ethanol solution, to volume point
For number for sodium hydroxide solution is added in 58% alcoholic solution, the pH for being adjusted to alcoholic solution is 9.1 ~ 9.3；
(5) spinning fibre is placed in baking oven, it is 8% that water content is dried in 45 DEG C, using magnetically controlled DC sputtering by nano-silica
Change titanium and is deposited on spinning fibre surface, acceleration voltage 500V, magnetic field 140G, air pressure 7mTorr, current density 35mA/cm, power
Density 30W/cm improves the intensity and self-cleaning ability of wig fiber, arranges, and derives from cleaning wig fiber.
Comparative example 1
Remove polysulfone resin, remaining preparation method, with embodiment 1.
Comparative example 2
Modified egg-shell meal is changed to egg-shell meal, remaining preparation method, with embodiment 1.
Comparative example 3
Remove lac, remaining preparation method, with embodiment 1.
Comparative example 4
Remove nano oxygen titanium dioxide, remaining preparation method, with embodiment 1.
Comparative example 5
Remove nano silver, remaining preparation method, with embodiment 1.
Comparative example 6
It removes step (2) and (3), raw material is added in step (1), remaining preparation method, with embodiment 1.
Comparative example 7
Wet spinning in step (4) is changed to melt spinning, remaining preparation method, with embodiment 1.
Comparative example 8
Coagulation bath temperature in step (4) is changed to 35 DEG C, remaining preparation method, with embodiment 1.
Comparative example 9
Temperature in step (5) is changed to 60 DEG C, remaining preparation method, with embodiment 1.
Comparative example 10
Magnetically controlled DC sputtering in step (5) is changed to gluing, remaining preparation method, with embodiment 1.
Comparative example 11
A kind of antibiosis and self-cleaning type synthetic wig fiber of the hair containing peacock disclosed in existing 105951211 A of patent document CN.
Comparative example 12
Existing 202099627 U of patent document CN discloses a kind of antibiosis self-cleaning wig hairline.
The mechanical property of embodiment and comparative example wig fiber:
Example and the wig fiber of comparative example are appropriate respectively, according to " fibre strength detection technique and instrument, Zhu Genfeng etc. "
Method, using dry strong (CN/dtex) of YG029-I full automatic single yarn tester detection wig fiber, wet strong (CN/dtex) and
Dry to stretch (%), every group repeats detection 3 times, and results are averaged, and the mechanical property of embodiment and comparative example wig fiber is shown in Table 1.
Table 1: the mechanical property of embodiment and comparative example wig fiber
From table 1 the result shows that, the automatically cleaning wig fiber of embodiment is done strong, wet strong and dry mechanical property of stretching and is substantially better than pair
Ratio illustrates that automatically cleaning wig fiber provided by the invention has good mechanical property and service performance, and intensity is high, and does not lose
Very, higher with the similarity really sent out.
The flame retardant property and anti-microbial property of embodiment and comparative example wig fiber:
Its limit oxygen index LOI(% is measured by GB/T5455-1997 " textile combustion performance test normal beam technique "), and use UL94
The flame retardant rating of standard detection each group wig fiber, and each group wig fiber 25g is taken, 80 ~ 100 mesh are crushed to, to each group wig
Fiber is inoculated with mould, is cultivated according to the optimum condition of mould, and the antibiotic rate of each group wig fiber is detected, and each test repeats
3 times, results are averaged, and the flame retardant property and anti-microbial property of embodiment and comparative example wig fiber are shown in Table 2.
Table 2: the flame retardant property and anti-microbial property of embodiment and comparative example wig fiber
Note: "-" indicates not fire-retardant.
From table 2 the result shows that, the automatically cleaning wig fiber of embodiment, limit oxygen index and antibiotic rate are substantially better than comparison
Example, flame retardant rating is significantly higher, illustrates that automatically cleaning wig fiber provided by the invention has good flame retardant property and antibiotic property
Energy.
The self-cleaning ability of embodiment and comparative example wig fiber:
The wig fiber of selection example and comparative example respectively, being placed in 50 DEG C, drying to constant weight, and each group accurately weighs dry vacation
Fiber 100g is sent out, each group wig fiber is placed in ambient humidity is 90%, temperature is 25 DEG C, PM10 concentration is 300 μ g/m3、
PM2.5 concentration is 200 μ g/m3Natural lighting environment in, stand 60d after take out, weigh the weight of each group wig fiber, implement
Example and the self-cleaning ability of comparative example wig fiber are shown in Table 3.
Table 3: the self-cleaning ability of embodiment and comparative example wig fiber
From table 3 the result shows that, the automatically cleaning wig fiber of embodiment, weight increase is significantly less than comparative example, illustrates this hair
The automatically cleaning wig fiber of bright offer has good self-cleaning ability.
Claims (9)
1. a kind of automatically cleaning wig fiber, which is characterized in that be made of raw material from the following weight: polyacrylonitrile 46 ~ 48, polysulfones
Dispersion liquid 13 ~ 15, modified egg-shell meal 2 ~ 3, lac 1.6 ~ 1.8, nano oxygen titanium dioxide is concentrated in resin 17 ~ 19, polytetrafluoroethylene (PTFE) 60%
Titanium 1.1 ~ 1.3, nano silver 0.26 ~ 0.32.
2. automatically cleaning wig fiber according to claim 1, which is characterized in that the modification egg-shell meal cleans eggshell,
It is milled to 30 ~ 35nm, the carboxymethyl chitosan solution of 1.2 ~ 1.6 times of Eggshell weight amounts is added into eggshell, in 70 ~ 80 DEG C of vacuum
20 ~ 30min is stirred, the silk fibroin protein solution of Eggshell weight 17 ~ 19% is added, continues 30 ~ 40min of insulated and stirred, freeze-drying is extremely
No moisture, grinding, obtains modified egg-shell meal.
3. automatically cleaning wig fiber according to claim 2, which is characterized in that the carboxymethyl chitosan solution, quality
Percentage concentration is 0.6 ~ 0.8%.
4. automatically cleaning wig fiber according to claim 2, which is characterized in that the silk fibroin protein solution, quality percentage
Concentration is 1.1 ~ 1.3%.
5. a kind of preparation method of automatically cleaning wig fiber according to claim 1, which comprises the following steps:
(1) polytetrafluoroethylene (PTFE) 60% is added in polyacrylonitrile and polysulfone resin to be concentrated in dispersion liquid, has been slowly heated to while stirring
Full-fusing obtains mixture A；
(2) modified egg-shell meal and lac are added into mixture A, the volume fraction that modified egg-shell meal weight 24 ~ 26% is added is
1.5 ~ 1.7% acetum, heat preservation are stirred under vacuum 30 ~ 40min, obtain mixture B；
(3) nano silver is added in mixture B, stirs evenly, obtains mixture C；
(4) by mixture C be sent into spinning machine carry out wet spinning, coagulating bath is alkaline ethanol solution, take out spinning after spend from
Sub- water is rinsed to neutrality, obtains spinning fibre；
(5) spinning fibre is placed in baking oven, it is 4 ~ 8% that water content is dried in 40 ~ 45 DEG C, will be received using magnetically controlled DC sputtering
Rice titanium dioxide deposition is arranged in spinning fibre surface, derives from cleaning wig fiber.
6. the preparation method of automatically cleaning wig fiber according to claim 5, which is characterized in that the wet process of the step (4)
Spinning, spinneret 6 ~ 7m/min of speed, stretch 53 ~ 57 DEG C of bath temperature, 4 ~ 5m/min of draft speed by 16 ~ 20 DEG C of coagulation bath temperature.
7. the preparation method of automatically cleaning wig fiber according to claim 5, which is characterized in that the alkalinity of the step (4)
Ethanol solution, to volume fraction for sodium hydroxide solution is added in 56 ~ 58% alcoholic solution, the pH for being adjusted to alcoholic solution is
9.1~9.3。
8. the preparation method of automatically cleaning wig fiber according to claim 5, which is characterized in that the direct current of the step (5)
Magnetron sputtering, 400 ~ 500V of acceleration voltage, 120 ~ 140G of magnetic field, 5 ~ 7mTorr of air pressure, 33 ~ 35mA/cm of current density, power are close
Spend 25 ~ 30W/cm.
9. any one automatically cleaning wig fiber according to claim 1 ~ 8, which is characterized in that fiber number is 40 ~ 44dtex.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201811415444.6A CN109518302A (en) | 2018-11-26 | 2018-11-26 | A kind of automatically cleaning wig fiber |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201811415444.6A CN109518302A (en) | 2018-11-26 | 2018-11-26 | A kind of automatically cleaning wig fiber |
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| CN109518302A true CN109518302A (en) | 2019-03-26 |
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| CN201811415444.6A Withdrawn CN109518302A (en) | 2018-11-26 | 2018-11-26 | A kind of automatically cleaning wig fiber |
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN202099617U (en) * | 2011-03-30 | 2012-01-04 | 东华大学 | Antibiosis self-cleaning wig hairline |
| CN104379010A (en) * | 2013-03-20 | 2015-02-25 | Nom涂料有限公司 | Composition of artificial hair and production method thereof |
| CN105951211A (en) * | 2016-05-23 | 2016-09-21 | 安徽孔雀公主工艺品有限公司 | Antibacterial self-cleaned artificial wig fiber containing peacock feather |
| CN107497307A (en) * | 2017-10-09 | 2017-12-22 | 常州美帛纺织品有限公司 | A kind of preparation method of the special infiltrating and vaporizing membrane of perfume industry |
| CN108823675A (en) * | 2018-07-23 | 2018-11-16 | 合肥旭亚新材料科技有限公司 | A kind of antibacterial ventilative wig fiber |
-
2018
- 2018-11-26 CN CN201811415444.6A patent/CN109518302A/en not_active Withdrawn
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN202099617U (en) * | 2011-03-30 | 2012-01-04 | 东华大学 | Antibiosis self-cleaning wig hairline |
| CN104379010A (en) * | 2013-03-20 | 2015-02-25 | Nom涂料有限公司 | Composition of artificial hair and production method thereof |
| CN105951211A (en) * | 2016-05-23 | 2016-09-21 | 安徽孔雀公主工艺品有限公司 | Antibacterial self-cleaned artificial wig fiber containing peacock feather |
| CN107497307A (en) * | 2017-10-09 | 2017-12-22 | 常州美帛纺织品有限公司 | A kind of preparation method of the special infiltrating and vaporizing membrane of perfume industry |
| CN108823675A (en) * | 2018-07-23 | 2018-11-16 | 合肥旭亚新材料科技有限公司 | A kind of antibacterial ventilative wig fiber |
Non-Patent Citations (1)
| Title |
|---|
| 纺织工业标准化研究所: "《中国纺织标准汇编 基础标准与方法标准卷（一）》", 30 June 2000, 中国标准出版社 * |
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