CN109517669A - 具有除臭功能的厕所用除垢剂及其制备方法 - Google Patents
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- 238000004332 deodorization Methods 0.000 title claims description 14
- 238000002360 preparation method Methods 0.000 title abstract description 11
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims abstract description 39
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims abstract description 25
- 239000002994 raw material Substances 0.000 claims abstract description 8
- 239000003599 detergent Substances 0.000 claims abstract description 6
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims description 36
- 229910002651 NO3 Inorganic materials 0.000 claims description 14
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 claims description 14
- 239000002202 Polyethylene glycol Substances 0.000 claims description 12
- 239000004115 Sodium Silicate Substances 0.000 claims description 12
- 239000010446 mirabilite Substances 0.000 claims description 12
- LNOPIUAQISRISI-UHFFFAOYSA-N n'-hydroxy-2-propan-2-ylsulfonylethanimidamide Chemical compound CC(C)S(=O)(=O)CC(N)=NO LNOPIUAQISRISI-UHFFFAOYSA-N 0.000 claims description 12
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- 229920001223 polyethylene glycol Polymers 0.000 claims description 12
- 229920002545 silicone oil Polymers 0.000 claims description 12
- 239000001488 sodium phosphate Substances 0.000 claims description 12
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 claims description 12
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- 229910052911 sodium silicate Inorganic materials 0.000 claims description 12
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 claims description 12
- 229910000406 trisodium phosphate Inorganic materials 0.000 claims description 12
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- 238000010438 heat treatment Methods 0.000 claims description 9
- 238000001816 cooling Methods 0.000 claims description 5
- 239000000686 essence Substances 0.000 claims description 5
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical group [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 claims description 4
- 239000003795 chemical substances by application Substances 0.000 claims description 2
- 239000004317 sodium nitrate Substances 0.000 claims description 2
- 235000010344 sodium nitrate Nutrition 0.000 claims description 2
- 238000000034 method Methods 0.000 claims 4
- 238000004140 cleaning Methods 0.000 abstract description 3
- 241000894006 Bacteria Species 0.000 abstract description 2
- OCJBOOLMMGQPQU-UHFFFAOYSA-N 1,4-dichlorobenzene Chemical compound ClC1=CC=C(Cl)C=C1 OCJBOOLMMGQPQU-UHFFFAOYSA-N 0.000 abstract 1
- 229910019142 PO4 Inorganic materials 0.000 abstract 1
- 239000004372 Polyvinyl alcohol Substances 0.000 abstract 1
- 235000021355 Stearic acid Nutrition 0.000 abstract 1
- DDXLVDQZPFLQMZ-UHFFFAOYSA-M dodecyl(trimethyl)azanium;chloride Chemical compound [Cl-].CCCCCCCCCCCC[N+](C)(C)C DDXLVDQZPFLQMZ-UHFFFAOYSA-M 0.000 abstract 1
- 150000002191 fatty alcohols Chemical class 0.000 abstract 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 abstract 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 abstract 1
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- 239000010452 phosphate Substances 0.000 abstract 1
- 229920002401 polyacrylamide Polymers 0.000 abstract 1
- 229940051841 polyoxyethylene ether Drugs 0.000 abstract 1
- 229920000056 polyoxyethylene ether Polymers 0.000 abstract 1
- 229920002451 polyvinyl alcohol Polymers 0.000 abstract 1
- 230000002265 prevention Effects 0.000 abstract 1
- 230000001681 protective effect Effects 0.000 abstract 1
- 239000008117 stearic acid Substances 0.000 abstract 1
- 239000004094 surface-active agent Substances 0.000 abstract 1
- 230000000694 effects Effects 0.000 description 3
- 239000000126 substance Substances 0.000 description 2
- 241000700605 Viruses Species 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000001877 deodorizing effect Effects 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0068—Deodorant compositions
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/042—Acids
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
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- C11D3/046—Salts
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
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- C11D3/048—Nitrates or nitrites
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- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
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Abstract
本发明涉及一种清洁剂，具体涉及一种厕所用防垢剂及其制备方法。本发明所述的厕所用防垢剂，由以下重量份数的原料制成：聚乙烯醇40‑60份；脂肪醇聚氧乙烯醚5‑10份；十二烷基三甲基氯化铵6‑8份；柠檬酸10‑12份；芒硝16‑20份；硬脂酸3‑5份；聚丙烯酰胺2‑4份；对二氯苯4‑8份；磷酸酯10‑12份；香精10‑20份；表面活性剂0.5‑1.5份。本发明防垢剂能够在马桶表面形成保护膜，有效防止结垢；阻垢能力强，延长马桶的清洗周期，并且能够防止细菌滋生；所述制备方法简单易行。
Description
技术领域
本发明涉及一种除垢剂，具体涉及一种具有除臭功能的厕所用除垢剂及其制备方法。
背景技术
卫生间除垢是人们日常生活中很重要的清洁卫生任务，残留的污垢首先是影响感官，其次会滋生大量有害的微生物、细菌、病毒等，影响人类生活。现市场上常见的厕所类除垢产品，大多都是强酸性物质进行化学腐蚀除垢，这种方式除垢能力强，快速高效。但是，相应带来的问题便是强烈的刺激性气味，并且通常会持续很长一段时间。而刺激性气味不够强的除垢剂往往又效果很差，除垢效果慢。绝大多数除垢剂仅仅只是除垢，没有除臭功能。
发明内容
针对现有技术的不足，本发明的目的是提供一种具有除臭功能的厕所用除垢剂，无刺激性气味，并且能够快速去垢；本发明同时提供其简单易行的制备方法。
本发明所述的具有除臭功能的厕所用除垢剂，由以下重量份数的原料制成：
磷酸三钠2～7份、硅油2～4份、聚丙烯酸钠1～2份、硝酸盐1～3份、芒硝10～15份、草酸1～3份、柠檬酸2～5份、香精1～5份、水10～30份、氨基磺酸5～15份、硅酸钠2～5份、无水硫酸钠20～30份和聚乙二醇10～20份。
优选地，由以下重量份数的原料制成：
磷酸三钠5份、硅油3份、聚丙烯酸钠1.5份、硝酸盐2份、芒硝12份、草酸2份、柠檬酸3份、香精3份、水20份、氨基磺酸10份、硅酸钠4份、无水硫酸钠25份和聚乙二醇15份。
其中：所述的硝酸盐为硝酸钠。
所述的具有除臭功能的厕所用除垢剂的制备方法，包括如下步骤：
(1)将水、磷酸三钠与聚丙烯酸钠在常温下均匀混合，静置10～20分钟；
(2)依次加入硝酸盐、芒硝、硅酸钠和无水硫酸钠，加热至溶解；
(3)降温至20～30℃，加入硅油、草酸、柠檬酸、香精、氨基磺酸和聚乙二醇混合均匀。
其中，
步骤(2)中所述的加热为加热至60～80℃。
本发明具有如下优点：
1、除垢速度快，并且没有强烈的刺激性气味，除垢之后保持清洁效果时间长。
2、除垢能力强，并且还保持有一定香味。
3、制备方法简单易行。
具体实施方式
下面结合实施例对本发明做进一步说明，但不限定本发明。
实施例1
所述的具有除臭功能的厕所用除垢剂，由以下重量份数的原料制成：
磷酸三钠5份、硅油3份、聚丙烯酸钠1.5份、硝酸盐2份、芒硝12份、草酸2份、柠檬酸3份、香精3份、水20份、氨基磺酸10份、硅酸钠4份、无水硫酸钠25份和聚乙二醇15份。
其制备方法如下：
(1)将水、磷酸三钠与聚丙烯酸钠在常温下均匀混合，静置15分钟；
(2)依次加入硝酸盐、芒硝、硅酸钠和无水硫酸钠，加热至溶解；
(3)降温至25℃，加入硅油、草酸、柠檬酸、香精、氨基磺酸和聚乙二醇混合均匀。
实施例2
所述的具有除臭功能的厕所用除垢剂，由以下重量份数的原料制成：
磷酸三钠2份、硅油2份、聚丙烯酸钠1份、硝酸盐1份、芒硝10份、草酸1份、柠檬酸2份、香精1份、水10份、氨基磺酸5份、硅酸钠2份、无水硫酸钠20份和聚乙二醇10份。
其制备方法如下：
(1)将水、磷酸三钠与聚丙烯酸钠在常温下均匀混合，静置10分钟；
(2)依次加入硝酸盐、芒硝、硅酸钠和无水硫酸钠，加热至溶解；
(3)降温至20℃，加入硅油、草酸、柠檬酸、香精、氨基磺酸和聚乙二醇混合均匀。
实施例3
所述的具有除臭功能的厕所用除垢剂，由以下重量份数的原料制成：
磷酸三钠7份、硅油4份、聚丙烯酸钠2份、硝酸盐3份、芒硝15份、草酸3份、柠檬酸5份、香精5份、水30份、氨基磺酸15份、硅酸钠5份、无水硫酸钠30份和聚乙二醇20份。
其制备方法如下：
(1)将水、磷酸三钠与聚丙烯酸钠在常温下均匀混合，静置20分钟；
(2)依次加入硝酸盐、芒硝、硅酸钠和无水硫酸钠，加热至溶解；
(3)降温至30℃，加入硅油、草酸、柠檬酸、香精、氨基磺酸和聚乙二醇混合均匀。
Claims (5)
1.一种具有除臭功能的厕所用除垢剂，其特征在于：由以下重量份数的原料制成：
磷酸三钠2～7份、硅油2～4份、聚丙烯酸钠1～2份、硝酸盐1～3份、芒硝10～15份、草酸1～3份、柠檬酸2～5份、香精1～5份、水10～30份、氨基磺酸5～15份、硅酸钠2～5份、无水硫酸钠20～30份和聚乙二醇10～20份。
2.根据权利要求1所述的具有除臭功能的厕所用除垢剂，其特征在于：由以下重量份数的原料制成：
磷酸三钠5份、硅油3份、聚丙烯酸钠1.5份、硝酸盐2份、芒硝12份、草酸2份、柠檬酸3份、香精3份、水20份、氨基磺酸10份、硅酸钠4份、无水硫酸钠25份和聚乙二醇15份。
3.根据权利要求1所述的具有除臭功能的厕所用除垢剂，其特征在于：所述的硝酸盐为硝酸钠。
4.一种权利要求1-3任一所述的具有除臭功能的厕所用除垢剂的制备方法，其特征在于：包括如下步骤：
(1)将水、磷酸三钠与聚丙烯酸钠在常温下均匀混合，静置10～20分钟；
(2)依次加入硝酸盐、芒硝、硅酸钠和无水硫酸钠，加热至溶解；
(3)降温至20～30℃，加入硅油、草酸、柠檬酸、香精、氨基磺酸和聚乙二醇混合均匀。
5.根据权利要求4所述的具有除臭功能的厕所用除垢剂的制备方法，其特征在于：步骤(2)中所述的加热为加热至60～80℃。
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| CN110484375A (zh) * | 2019-09-07 | 2019-11-22 | 阜阳洁平日化有限公司 | 一种高性能的定量缓释瓶装洁厕剂及其制备方法 |
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| CN110484375A (zh) * | 2019-09-07 | 2019-11-22 | 阜阳洁平日化有限公司 | 一种高性能的定量缓释瓶装洁厕剂及其制备方法 |
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