CN109517471A - MMA two-component protrusion-type road paint and the preparation method and application thereof - Google Patents
MMA two-component protrusion-type road paint and the preparation method and application thereof Download PDFInfo
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- CN109517471A CN109517471A CN201811266797.4A CN201811266797A CN109517471A CN 109517471 A CN109517471 A CN 109517471A CN 201811266797 A CN201811266797 A CN 201811266797A CN 109517471 A CN109517471 A CN 109517471A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
- C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09D133/10—Homopolymers or copolymers of methacrylic acid esters
- C09D133/12—Homopolymers or copolymers of methyl methacrylate
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
- Road Paving Structures (AREA)
Abstract
The invention belongs to road paint technical fields, in particular to a kind of MMA two-component protrusion-type road paint and the preparation method and application thereof, it is made of in mass ratio for 50:50:2 first component, second component and initiator, wherein the first component prepares gained: 1#20-30 parts of MMA resin, 3-8 parts of pigment, 20-40 parts of natural siliceous sand, 20-40 parts of bead, 5-12 parts of auxiliary agent by the raw material of following parts by weight；Wherein the second component prepares gained: 2#20-30 parts of MMA resin, 3-8 parts of pigment, 20-40 parts of natural siliceous sand, 20-40 parts of bead, 5-12 parts of auxiliary agent by the raw material of following parts by weight.Initiator is added into second component by weight in use, component A, component B are stirred evenly respectively in road paint of the present invention；Then it is mixed with first component, pen machine hopper is added, coating protrusion forming and hardening can be used.Road paint non-volatility solvent of the present invention, it is environmentally protective, and solidification process needs to heat, and it is environmentally protective, there is not easy to crack, firm, shock resistance, anti-pressure ability, the good advantage of durable weatherability.
Description
Technical field
The invention belongs to road paint technical field, in particular to a kind of MMA two-component protrusion-type road paint and its system
Preparation Method and application.
Background technique
Pavement marker coating plays prompt and warning function, transport is gone on smoothly and people and vehicle safety be must can not
Few.Current existing protrusion-type road paint, most of for heat molten type, when use, which needs to heat, is melted to flow regime
It can be used, and durability and weatherability are limited, need to be to add with liquefied gas or oil plant when there is the disadvantages of easily-deformable of being heated, and heating
Heat source consumes energy, and waste of resource increases cost, therefore there are disadvantages in terms of energy-saving and environmental protection for traditional road paint, no
Meet demand of the present market to energy saving, environmentally protective novel product.Therefore, it is necessary to research and develop novel protrusion-type coating
Change these deficiencies, accomplishes energy-saving and environment-friendly and durable.
Summary of the invention
The technical problem to be solved by the present invention is to overcome drawbacks described above, provide a kind of MMA two-component protrusion-type road paint
And the preparation method and application thereof.
In order to solve the above-mentioned technical problem, the technical solution of the present invention is as follows:
A kind of MMA two-component protrusion-type road paint, is 50:50:2 by first component, second component and initiator in mass ratio
Composition, wherein the first component by following parts by weight raw material prepare gained: 1#20-30 part of MMA resin, 3-8 parts of pigment, naturally
20-40 parts of quartz sand, 20-40 parts of bead, 5-12 parts of auxiliary agent；Wherein the second component prepares institute by the raw material of following parts by weight
: 2#20-30 parts of MMA resin, 3-8 parts of pigment, 20-40 parts of natural siliceous sand, 20-40 parts of bead, 5-12 parts of auxiliary agent.
Preferably, the auxiliary agent includes dispersing agent, forming agent, helps type agent, wherein the preferred gas phase SiO of forming agent2, help type agent
It is preferred that polyurea compound.
Preferably, the first component prepares gained: 1#26 parts of MMA resin, pigment 5 part, day by the raw material of following parts by weight
Right 30 parts of quartz sand, 30 parts of bead, 9 parts of auxiliary agent.
Preferably, the mass percentage of active component methyl methacrylate is 50-60% in the MMA resin 1#.
Preferably, the second component prepares gained: 2#26 parts of MMA resin, pigment 5 part, day by the raw material of following parts by weight
Right 30 parts of quartz sand, 30 parts of bead, 9 parts of auxiliary agent.
Preferably, the mass percentage of active component methyl methacrylate is 30-40% in the MMA resin 2#.
Preferably, the initiator is benzoyl peroxide, benzoyl peroxide, appointing in methyl ethyl ketone peroxide
It anticipates one kind.
It is a further object of the present invention to provide a kind of preparation method of MMA two-component protrusion-type road paint, including it is as follows
Step:
(1) preparation of first component: MMA resin 1# is put into modulation tank, controlled at 15 DEG C -20 DEG C, by weight
Pigment is added, natural siliceous sand, bead are stirred at low speed to being uniformly dispersed；Auxiliary agent is added to continue to stir at low speed to mixing state；
Sampling and testing, detection viscosity are up to qualified first component, weight calculation packaging；
(2) preparation of second component: MMA resin 2# is put into modulation tank, controlled at 15 DEG C -20 DEG C, by weight
Pigment is added, natural siliceous sand, bead are stirred at low speed to being uniformly dispersed；Auxiliary agent is added to continue to stir at low speed to mixing state；
Sampling and testing, detection viscosity are up to qualified second component, weight calculation packaging；
(3) initiator prepares: weighing initiator, weight calculation packaging by weight.
Preferably, step (1), the mixing speed stirred at low speed described in step (2) are 50-300r/min.
The present invention also provides a kind of applications of MMA two-component protrusion-type road paint, include the following steps:
(1) good dedicated blade coating protrusion-type pen machine is debugged, opens component A, component B stirs evenly respectively；By weight
Initiator is added into second component；
(2) component B of component A and addition initiator is mixed by usage amount, pen machine hopper is added, pen machine starts
Work, coating protrusion forming and hardening can be delivered for use after solidification is completed in sizing.
Compared with prior art the beneficial effects of the present invention are:
(1) initiator is added in two-component protrusion-type road paint of the present invention when in use, can complete within a short period of time
Coating by liquid to solid variation and sizing and solidifying, whole process do not need to heat, therefore do not need the consumption energy, be a kind of
Energy-saving and environment-friendly road paint；And in coating each component ingredient be all it is solvent-free, the solidification process and production process of coating are equal
Without using solvent, it is the solidification occurred after cross-linking reaction and completes, non-volatility solvent non-hazardous to human body, meet green
The requirement of environmental protection, belongs to the product of non-hazardous human body.
(2) density of two-component protrusion-type road paint of the present invention is 1.8g/m3, loss of weight after wearability C200r/1000g
18mg complies fully with the industry to road paint hardness, wear-resisting, water-fast, alkali resistance standard requirements.
(3) two-component protrusion-type road paint of the present invention is without heating, and use process can be completed in charging on pen machine,
It does not need to purchase large scale equipment, reduces the energy consumption that equipment generates, reduce the influence of environmental pollution, and heat molten type protrusion road applies
Material can use when heating furnace being needed to be heated to 180-220 DEG C.
(4) after two-component protrusion-type road paint molding of the present invention, not easy to crack, firm, shock resistance, anti-pressure ability are resistance to
Long weatherability is good, and through overtesting, when sizzler gas pavement temperature is up to 70 DEG C, the label done using road paint of the present invention is not
It can soften, will not deform；And cold snap not embrittlement when using, it is not easy to crack.
Specific embodiment
Specific embodiments of the present invention will be further explained below.It should be noted that for these implementations
The explanation of mode is used to help understand the present invention, but and does not constitute a limitation of the invention.In addition, invention described below
Technical characteristic involved in each embodiment can be combined with each other as long as they do not conflict with each other.
Embodiment 1
A kind of MMA two-component protrusion-type road paint, is 50:50:2 by first component, second component and initiator in mass ratio
Composition, wherein the first component prepares gained: 1#20 parts of MMA resin, 3 parts of pigment, natural quartz by the raw material of following parts by weight
20 parts of sand, 20 parts of bead, 5 parts of auxiliary agent, the mass percentage of active component methyl methacrylate is in MMA resin 1#
50%；Wherein the second component prepares gained: 2#20 parts of MMA resin, 3 parts of pigment, natural quartz by the raw material of following parts by weight
20 parts of sand, 20 parts of bead, 5 parts of auxiliary agent, the mass percentage of active component methyl methacrylate is in MMA resin 2#
30%.
A kind of preparation method of MMA two-component protrusion-type road paint, includes the following steps:
(1) preparation of first component: MMA resin 1# is put into modulation tank, and controlled at 15 DEG C, face is added by weight
Material, natural siliceous sand, bead are stirred under 50r/min speed to being uniformly dispersed；Auxiliary agent is added to continue to stir at low speed to mixing
State；Sampling and testing, detection viscosity are up to qualified first component, weight calculation packaging；
(2) preparation of second component: MMA resin 2# is put into modulation tank, and controlled at 15 DEG C, face is added by weight
Material, natural siliceous sand, bead are stirred under 50r/min speed to being uniformly dispersed；Auxiliary agent is added to continue to stir at low speed to mixing
State；Sampling and testing, detection viscosity are up to qualified second component, weight calculation packaging；
(3) initiator prepares: weighing initiator, weight calculation packaging by weight.
A kind of application of MMA two-component protrusion-type road paint, includes the following steps:
(1) good dedicated blade coating protrusion-type pen machine is debugged, opens component A, component B stirs evenly respectively；By weight
Initiator is added into second component；
(2) component B of component A and addition initiator is mixed by usage amount, pen machine hopper is added, pen machine starts
Work, coating protrusion forming and hardening can be delivered for use after solidification is completed in sizing.
Embodiment 2
A kind of MMA two-component protrusion-type road paint, is 50:50:2 by first component, second component and initiator in mass ratio
Composition, wherein the first component prepares gained: 1#26 parts of MMA resin, 5 parts of pigment, natural quartz by the raw material of following parts by weight
30 parts of sand, 30 parts of bead, 9 parts of auxiliary agent, the mass percentage of active component methyl methacrylate is in MMA resin 1#
55%；Wherein the second component prepares gained: 2#26 parts of MMA resin, 5 parts of pigment, natural quartz by the raw material of following parts by weight
30 parts of sand, 30 parts of bead, 9 parts of auxiliary agent, the mass percentage of active component methyl methacrylate is in MMA resin 2#
35%.
A kind of preparation method of MMA two-component protrusion-type road paint, includes the following steps:
(1) preparation of first component: MMA resin 1# is put into modulation tank, and controlled at 18 DEG C, face is added by weight
Material, natural siliceous sand, bead are stirred under 100r/min speed to being uniformly dispersed；Auxiliary agent is added to continue to stir at low speed to mixed
Even state；Sampling and testing, detection viscosity are up to qualified first component, weight calculation packaging；
(2) preparation of second component: MMA resin 2# is put into modulation tank, and controlled at 18 DEG C, face is added by weight
Material, natural siliceous sand, bead are stirred under 100r/min speed to being uniformly dispersed；Auxiliary agent is added to continue to stir at low speed to mixed
Even state；Sampling and testing, detection viscosity are up to qualified second component, weight calculation packaging；
(3) initiator prepares: weighing initiator, weight calculation packaging by weight.
A kind of application of MMA two-component protrusion-type road paint, includes the following steps:
(1) good dedicated blade coating protrusion-type pen machine is debugged, opens component A, component B stirs evenly respectively；By weight
Initiator is added into second component；
(2) component B of component A and addition initiator is mixed by usage amount, pen machine hopper is added, pen machine starts
Work, coating protrusion forming and hardening can be delivered for use after solidification is completed in sizing.
Embodiment 3
A kind of MMA two-component protrusion-type road paint, is 50:50:2 by first component, second component and initiator in mass ratio
Composition, wherein the first component prepares gained: 1#30 parts of MMA resin, 8 parts of pigment, natural quartz by the raw material of following parts by weight
40 parts of sand, 40 parts of bead, 12 parts of auxiliary agent, the mass percentage of active component methyl methacrylate is in MMA resin 1#
60%；Wherein the second component prepares gained: 2#30 parts of MMA resin, 8 parts of pigment, natural quartz by the raw material of following parts by weight
40 parts of sand, 40 parts of bead, 12 parts of auxiliary agent, the mass percentage of active component methyl methacrylate is in MMA resin 2#
40%.
A kind of preparation method of MMA two-component protrusion-type road paint, includes the following steps:
(1) preparation of first component: MMA resin 1# is put into modulation tank, and controlled at 20 DEG C, face is added by weight
Material, natural siliceous sand, bead are stirred under 300r/min speed to being uniformly dispersed；Auxiliary agent is added to continue to stir at low speed to mixed
Even state；Sampling and testing, detection viscosity are up to qualified first component, weight calculation packaging；
(2) preparation of second component: MMA resin 2# is put into modulation tank, and controlled at 20 DEG C, face is added by weight
Material, natural siliceous sand, bead are stirred under 300r/min speed to being uniformly dispersed；Auxiliary agent is added to continue to stir at low speed to mixed
Even state；Sampling and testing, detection viscosity are up to qualified second component, weight calculation packaging；
(3) initiator prepares: weighing initiator, weight calculation packaging by weight.
A kind of application of MMA two-component protrusion-type road paint, includes the following steps:
(1) good dedicated blade coating protrusion-type pen machine is debugged, opens component A, component B stirs evenly respectively；By weight
Initiator is added into second component；
(2) component B of component A and addition initiator is mixed by usage amount, pen machine hopper is added, pen machine starts
Work, coating protrusion forming and hardening can be delivered for use after solidification is completed in sizing.
The above are present pre-ferred embodiments, it is only applicable to the principle for helping to understand the embodiment of the present invention；Meanwhile for this
The those skilled in the art in field, according to the present embodiment, there will be changes in terms of specific embodiments and scope of application, comprehensive
Upper described, the contents of this specification are not to be construed as limiting the invention.
Claims (9)
1. a kind of MMA two-component protrusion-type road paint, it is characterised in that: in mass ratio by first component, second component and initiator
It is formed for 50:50:2, wherein the first component prepares gained: 1#20-30 parts of MMA resin, pigment by the raw material of following parts by weight
3-8 parts, 20-40 parts of natural siliceous sand, 20-40 parts of bead, 5-12 parts of auxiliary agent；Wherein the second component is by following parts by weight
Raw material preparation gained: 2#20-30 parts of MMA resin, 3-8 parts of pigment, 20-40 parts of natural siliceous sand, 20-40 parts of bead, auxiliary agent
5-12 parts.
2. MMA two-component protrusion-type road paint according to claim 1, it is characterised in that: the first component is by as follows
The raw material of parts by weight prepares gained: 1#26 parts of MMA resin, 5 parts of pigment, 30 parts of natural siliceous sand, 30 parts of bead, 9 parts of auxiliary agent.
3. MMA two-component protrusion-type road paint according to claim 1 or 2, it is characterised in that: the MMA resin 1#
The mass percentage of middle active component methyl methacrylate is 50-60%.
4. MMA two-component protrusion-type road paint according to claim 1, it is characterised in that: the second component is by as follows
The raw material of parts by weight prepares gained: 2#26 parts of MMA resin, 5 parts of pigment, 30 parts of natural siliceous sand, 30 parts of bead, 9 parts of auxiliary agent.
5. MMA two-component protrusion-type road paint according to claim 1 or 4, it is characterised in that: the MMA resin 2#
The mass percentage of middle active component methyl methacrylate is 30-40%.
6. MMA two-component protrusion-type road paint according to claim 1, it is characterised in that: the initiator is peroxide
Change benzoyl, benzoyl peroxide, any one in methyl ethyl ketone peroxide.
7. a kind of preparation method of MMA two-component protrusion-type road paint described in claim 1, it is characterised in that: including such as
Lower step:
(1) preparation of first component: MMA resin 1# is put into modulation tank, controlled at 15 DEG C -20 DEG C, is added by weight
Pigment, natural siliceous sand, bead are stirred at low speed to being uniformly dispersed；Auxiliary agent is added to continue to stir at low speed to mixing state；Sampling
Test, detection viscosity are up to qualified first component, weight calculation packaging；
(2) preparation of second component: MMA resin 2# is put into modulation tank, controlled at 15 DEG C -20 DEG C, is added by weight
Pigment, natural siliceous sand, bead are stirred at low speed to being uniformly dispersed；Auxiliary agent is added to continue to stir at low speed to mixing state；Sampling
Test, detection viscosity are up to qualified second component, weight calculation packaging；
(3) initiator prepares: weighing initiator, weight calculation packaging by weight.
8. the preparation method of MMA two-component protrusion-type road paint according to claim 7, it is characterised in that: step
(1), the mixing speed stirred at low speed described in step (2) is 50-300r/min.
9. a kind of application of MMA two-component protrusion-type road paint, characterized by the following steps:
(1) good dedicated blade coating protrusion-type pen machine is debugged, opens component A, component B stirs evenly respectively；By weight to second
Initiator is added in component；
(2) component B of component A and addition initiator is mixed by usage amount, pen machine hopper is added, pen machine starts work
Make, coating protrusion forming and hardening, after solidification is completed in sizing, can be delivered for use.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811266797.4A CN109517471A (en) | 2018-10-29 | 2018-10-29 | MMA two-component protrusion-type road paint and the preparation method and application thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811266797.4A CN109517471A (en) | 2018-10-29 | 2018-10-29 | MMA two-component protrusion-type road paint and the preparation method and application thereof |
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| Publication Number | Publication Date |
|---|---|
| CN109517471A true CN109517471A (en) | 2019-03-26 |
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ID=65773185
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811266797.4A Pending CN109517471A (en) | 2018-10-29 | 2018-10-29 | MMA two-component protrusion-type road paint and the preparation method and application thereof |
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| CN (1) | CN109517471A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111909585A (en) * | 2020-08-14 | 2020-11-10 | 广州市北二环交通科技有限公司 | PMMA type two-component marking paint, environment-friendly durable two-component marking material using same and construction method thereof |
| CN112175472A (en) * | 2020-09-24 | 2021-01-05 | 安徽省沥美道路新型材料有限公司 | MMA (methyl methacrylate) colored anti-slip floor floating sand coating and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1465635A (en) * | 2002-06-19 | 2004-01-07 | 黄维荃 | Method for preparing convex hot melt type road sign paint |
| CN102634258A (en) * | 2012-03-28 | 2012-08-15 | 山西长达交通设施有限公司 | Road marking coating for preventing destroying by snow shovels as well as preparation method and use method thereof |
| CN106243890A (en) * | 2016-08-23 | 2016-12-21 | 陕西世纪交通工程股份有限公司 | A kind of nanoscale MMA double-component superbright type reflexed light ring friendly coating and preparation method thereof and using method |
-
2018
- 2018-10-29 CN CN201811266797.4A patent/CN109517471A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1465635A (en) * | 2002-06-19 | 2004-01-07 | 黄维荃 | Method for preparing convex hot melt type road sign paint |
| CN102634258A (en) * | 2012-03-28 | 2012-08-15 | 山西长达交通设施有限公司 | Road marking coating for preventing destroying by snow shovels as well as preparation method and use method thereof |
| CN106243890A (en) * | 2016-08-23 | 2016-12-21 | 陕西世纪交通工程股份有限公司 | A kind of nanoscale MMA double-component superbright type reflexed light ring friendly coating and preparation method thereof and using method |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111909585A (en) * | 2020-08-14 | 2020-11-10 | 广州市北二环交通科技有限公司 | PMMA type two-component marking paint, environment-friendly durable two-component marking material using same and construction method thereof |
| CN112175472A (en) * | 2020-09-24 | 2021-01-05 | 安徽省沥美道路新型材料有限公司 | MMA (methyl methacrylate) colored anti-slip floor floating sand coating and preparation method thereof |
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Application publication date: 20190326 |