CN109504847A - Low-cost plastic die steel and preparation method thereof - Google Patents

Low-cost plastic die steel and preparation method thereof Download PDF

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Publication number
CN109504847A
CN109504847A CN201811480289.6A CN201811480289A CN109504847A CN 109504847 A CN109504847 A CN 109504847A CN 201811480289 A CN201811480289 A CN 201811480289A CN 109504847 A CN109504847 A CN 109504847A
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steel
die steel
plastic die
heating
preparation
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CN109504847B (en
Inventor
冯丹竹
赵坦
范刘群
隋轶
尤晓铭
李文斌
李广龙
金耀辉
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Angang Steel Co Ltd
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Angang Steel Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/02Ferrous alloys, e.g. steel alloys containing silicon
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/0221Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the working steps
    • C21D8/0226Hot rolling
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/002Ferrous alloys, e.g. steel alloys containing In, Mg, or other elements not provided for in one single group C22C38/001 - C22C38/60
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/38Ferrous alloys, e.g. steel alloys containing chromium with more than 1.5% by weight of manganese

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Heat Treatment Of Steel (AREA)

Abstract

The invention provides a low-cost plastic die steel and a preparation method thereof, wherein the die steel comprises the following components in percentage by weight: 0.15% -0.25%, Si: 0.40-0.80%, Mn: 1.60% -2.80%, Cr: 1.50 to 2.00 percent of Fe, less than or equal to 0.015 percent of P, less than or equal to 0.015 percent of S, 4.3 to 5.0 percent of Si + Mn + Cr, 2.3 to 3.5 percent of Si + Mn, and the balance of Fe and inevitable impurities. The full-thickness homogeneity degree of the die steel is within 3HRC, and the transverse and longitudinal impact ratio can reach 0.84-0.87; the preparation method comprises smelting, casting, heating, rolling and heat treatment; the plastic die steel produced by the method has higher hardness which can reach 37-40HRC, and the full-thickness homogeneity degree reaches 3 HRC; has excellent isotropic performance.

Description

A kind of low cost plastic die steel and preparation method thereof
Technical field
The invention belongs to the plastic die steels and its preparation of metal material production technical field more particularly to a kind of low cost Method.
Background technique
All kinds of molds are as basic technological equipment, the height of production technology level, it has also become measure a national product The one of the important signs that of manufacture level height.China's die industry will to it is large-scale, accurate, complicated, efficiently, long-life and multi-functional Direction is developed.In recent years, China's die & mold development is rapid, and yield has leaped into the front ranks of the world, wherein account for main body be plastics at Shape mold.But the raw material metals price such as Mo, Ni, V rises violently, and causes the price of plastic die steel also constantly soaring therewith.It opens The plastic die steel of hair low-cost and high-performance is of great significance for mold manufacturing enterprise.
Existing patented technology and document about plastic die steel is more.Invention is " at a kind of pre-hardening of plastic die steel Reason method " plastic mould steel chemical composition percentage disclosed in (CN101805820A) are as follows: C 0.36, Si 0.52, Mn 0.86, P 0.014, S 0.003, Cr 1.74, Mo 0.36.Invention " a kind of pre-hardened plastic mold steel and its manufacturing method " (CN102899571A) the pre-hardened plastic mold steel chemical component percentage disclosed in are as follows: C 0.35-0.45, Si 0.25- 0.35, Mn 1.30-1.80, Cr 1.5-2.0, Mo 0.1-0.3, V 0.04-0.12, P≤0.02, S≤0.008.Invention " one The production method of kind of easy cutting plastic mold steel plate " plastic mould steel chemical composition percentage disclosed in (CN103556065A) Are as follows: C 0.35-0.45, Si 0.25-0.35, Mn 1.50-1.60, P≤0.008, S 0.05-0.10, Als 0.010- 0.045, Cr 1.80-2.00, Mo 0.15-0.20.Invention " a kind of high tougness die steel for plastics and its production method " (CN103710625A) pre-hardened plastic mold steel chemical component percentage disclosed in are as follows: C 0.30-0.42, Si 0.20- 0.50, Mn 0.75-1.00, Cr 1.50-2.00, Mo 0.25-0.50, S≤0.015, P≤0.025, Als 0.010- 0.040, remaining is Fe and inevitable impurity.Invention " a kind of economical plastic steel plate for die and its manufacturing method " (CN106811687A) the chemical component percentage of plastic die steel disclosed in are as follows: C 0.40-0.50, Si 0.40-0.70, Mn 1.10-1.50, Cr 0.60-0.80, Mo 010-0.20, B 0.001-0.0012, P < 0.020, S < 0.015, surplus Fe And inevitable impurity.
Containing the valuable of 0.1~0.5% different content in the above chemical component for inventing related plastic die steel Metal Mo and V etc., cost of alloy are high.
" bainite pre-hardened plastic mold steel and its preparation and the heat treatment method " of patent CN102650021A application is adopted With multiway forging hot-working;It is cooling that air-cooled+air-cooled mode is carried out again;Most laggard tempering heat treatment, the production cycle is longer, efficiency It is low, while production cost is greatly improved using forging, normalizing, tempering.
Patent CN104294159A " a kind of novel plastic mould steel and its preparation and heat treatment process " is heated using breaking down, Spheroidizing, the interior preheating of vacuum drying oven, Quench heating, then oily cold or air cooling, the production technology of continuous tempering three times, energy Source consumption is big, high process cost.
Patent CN107587075A " inexpensive plastic die steel and its production method " is although without precious metal Mo, Ni etc. Element, but use normalized treatment and tempering technique to steeply rise cost after rolling.
Document " tissue of economical P20 plastic die steel and hardness research " (Si Songhua etc., heat treatment, 2010,5 (21): Online initial curing process 31-34) is used, but as plate thickness increases, hardness fluctuations are larger.
It can be seen from the above, existing plastic die steel exists, cost of alloy is high or complex process or performance deficiency etc. lack Point.Therefore, researching and developing while having both low cost and high performance plastic die steel has certain challenge for Die Industry.
Summary of the invention
It is an object of the invention to overcome the above problem and plastic die steel that is insufficient and providing a kind of low cost and its life Production method, this kind of plastic die steel have excellent performance and low in cost, shorten the production cycle.
What the object of the invention was realized in:
A kind of plastic die steel of low cost, the ingredient of the mould steel are as follows by weight percentage: C:0.15%~ 0.25%, Si:0.40%~0.80%, Mn:1.60%~2.80%, Cr:1.50%~2.00%, P≤0.015%, S≤ 0.015%, and Si+Mn+Cr=4.3%~5.0%, Si+Mn=2.3%~3.5%, surplus are Fe and inevitable impurity.
Within mould steel through thickness homogeneity 3HRC, transverse and longitudinal impacts ratio up to 0.84-0.87.
It is as follows that present component designs reason:
C: a part participates in solution strengthening, and a part forms carbide with alloying element and participates in precipitation strength.The main shape of carbon At carbide.To reduce the carbon equivalent of steel, reducing the flame gas cutting sensibility of steel, need to reduce carbon content.But carbon content is too low, It will be unfavorable for the acquisition of bainite structure, the hardness of steel will not be able to guarantee, when carbon content is excessively high, can make carbide inhomogeneities Increase, seriously affects its toughness.For the comprehensive performance for guaranteeing this kind of plastic die steel, the present invention select to be added carbon content for 0.15%~0.25%.
Si: carry out that displacement solution strengthening is highly effective, and displacement solution strengthening generally causes the spherical symmetry of iron to ferrite Distortion, it can generate elastic interaction with edge dislocation.The solid solution of Si makes the lattice constant of ferrite matrix become smaller, atom Radius 0.118nm, α-Fe are 0.126nm, it can be seen that, the solid solution alloy element for reducing lattice constant has relatively effective strong Change effect.Si is also the effective element for improving resistance to tempering.Si reduces diffusion velocity of the carbon in ferrite, precipitation when making to be tempered Carbide be not easy to assemble, increase temper resistance.The ε-carbide of tempered martensite and matrix can be made to keep coherence and uniformly divide Cloth makes tempered martensite maintain good combination of strength and toughness.But Si reduces the toughness and plasticity of steel to a certain extent, because This, to obtain good combination of strength and toughness, the present invention selects that Si content is added to be 0.40%~0.80%.
Mn: property and shape that steel is formed by oxide in solidification be can change.It and S have biggish affinity simultaneously Power, can to avoid on crystal boundary formed low melting point sulfide FeS, and with the MnS of certain plasticity exist, to eliminate sulphur Adverse effect, improve the hot-working character of steel.Mn has solution strengthening effect, to improve the intensity of ferrite and austenite And hardness.Manganese is weak carbide formation element, it is solvable enter cementite in formed alloyed cementite (Fe, Mn)3C, formation can The free energy of reduction system tends to more stable state.Manganese dissolves in austenite the harden ability that can strongly increase steel, while strong Lower the Ms point of steel.To obtain good combination of strength and toughness, the present invention uses the alloy design philosophy of low-carbon high-manganese, present invention choosing Selecting and Mn content is added is 1.60%~2.80%.
Cr: chromium can increase the harden ability of steel, improve temper resistance, and generate post-curing phenomenon;Chromium be in strong carbon Compound formation element can form carbide with carbon in steel, also dissolve in solid solution and Fe3In C, chromium is to the wear-resistant of steel Property, elevated temperature strength, hot hardness, toughness have favorable influence, while it dissolves in matrix the corrosion resistance that can significantly improve steel Energy.But when too high levels, microstructure coarsening can be made, therefore, the present invention selects that Cr content is added to be 1.50%~2.00%.
Studies have shown that obtaining structural difference under certain austenitizing condition and certain cooling velocity and mainly depending on The content of Yu Gangzhong carbon and alloying element.The decisive ingredient for influencing martensite hardness is carbon, and alloys producing very little can To say that the hardenability of martensite is mainly to be determined by carbon.But the hardness of bainite be then have with carbon and alloying element content compared with Important Relations.Wherein than more prominent, the effect of carbon is small more than to martensite for the effect of silicon.Therefore, intensity and toughness are equal in order to obtain Excellent final performance need to be controlled being used cooperatively for alloying element.For save cost of alloy, the present invention be not added Mo, The alloying element of the higher costs such as Ni, V gives full play to the mutually matched work of Si, Mn, Cr using the design philosophy of low C high Mn With being similarly obtained the plastic steel plate for die haveing excellent performance, therefore Si+Mn+Cr=4.3%~5.0% in the present invention, Si+Mn= 2.3%~3.5%.
P, S: facilitate the improvement of machinability.If content excessively will lead to macrosegregation, the homogeneous of steel is influenced Property and degree of purity, but consider production cost, the present invention select be added P≤0.015%, S≤0.015%.
The two of technical solution of the present invention are to provide a kind of preparation method of the plastic die steel of low cost, including smelt, pour Casting, heating, rolling, heat treatment;
The molten steel completed will be smelted and be cast into steel billet;Steel billet is put into heating furnace and is heated, heating process was divided into for three stages, First stage: 670 DEG C~730 DEG C, heating rate 60~100 DEG C/h, 1~2.5h of soaking time, second stage: 1170 DEG C~ 1230 DEG C, heating rate 60~100 DEG C/h, 2.5~4.5h of soaking time, the phase III: 1210 DEG C~1250 DEG C, heating rate 60~100 DEG C/h, 5~8h of soaking time;Heating cycle of the invention facilitates alloying element and is sufficiently dissolved, and improves slab center Alloying elements distribution, effectively mitigation degree of segregation.Steel billet after heating obtains the steel plate of 20-120mm specification through multi- pass rolling, 1150~1250 DEG C of start rolling temperature, preceding two percentage pass reduction rolls rate control in 10-20r/min, finish to gauge in 15%-25% 950~1050 DEG C of temperature.It can make this kind of plastic die steel central part that fully deformed occur using the big soft reduction process of low speed, promote Hole diffusion, engagement, are conducive to the abatement of hole, prevent the generation of defect.It is carried out by the way of air-cooled after steel plate is offline cold But to 600 DEG C -650 DEG C, in wrapping up energy-saving heat preserving cotton within the scope of 570 DEG C -620 DEG C on the steel plate, heat-preservation cotton is reusable, protects Warm 5-7h makes steel plate generate " self tempering " effect, and energy conservation and environmental protection, steel plate is made to reach good using the release of steel plate self heat Performance.
The beneficial effects of the present invention are:
1, it is not added with the higher metallic element of the cost of alloy such as Mo, Ni, V, with the alloy design philosophy of low C high Mn, is passed through The interaction of Si, Mn, Cr alloying element, obtains a kind of simple production process, period short plastic die steel;
2, this kind of plastic die steel has higher hardness, and up to 37-40HRC, through thickness homogeneity reaches 3HRC;
3, with excellent equal orientation performance, transverse and longitudinal impact ratio is up to 0.84-0.87.As it can be seen that this kind of plastic die steel Hardness, toughness, equal orientation performance be superior to 3Cr2Mo steel.
Specific embodiment
Below by embodiment, the present invention is further illustrated.
The embodiment of the present invention is smelted, is cast, is heated, is rolled, is heat-treated according to the component proportion of technical solution.It will It smelts the molten steel completed and is cast into steel billet;Steel billet is put into heating furnace and is heated, heating process was divided into for three stages, the first stage: 670 DEG C~730 DEG C, heating rate 60~100 DEG C/h, 1~2.5h of soaking time, second stage: 1170 DEG C~1230 DEG C, heating Speed 60~100 DEG C/h, 2.5~4.5h of soaking time, the phase III: 1210 DEG C~1250 DEG C, 60~100 DEG C of heating rate/ H, 5~8h of soaking time;Steel billet after heating obtains the steel plate of 20-120mm specification through multi- pass rolling, and start rolling temperature 1150~ 1250 DEG C, preceding two percentage pass reduction rolls rate control in 10-20r/min, finishing temperature 950~1050 in 15%-25% ℃;It carries out being cooled to 600 DEG C -650 DEG C by the way of air-cooled after steel plate is offline, in 570 DEG C of -620 DEG C of range inside holding 5-7h. The ingredient of steel of the embodiment of the present invention is shown in Table 1.The heating technique parameter of steel of the embodiment of the present invention is shown in Table 2.Steel of the embodiment of the present invention Rolling and heat treatment main technologic parameters are shown in Table 3.The Rockwell hardness of steel of the embodiment of the present invention is shown in Table 4.Steel of the embodiment of the present invention Equal orientation performance is shown in Table 5.
The ingredient (wt%) of 1 steel of the embodiment of the present invention of table
Embodiment C Si Mn Cr P S Si+Mn+Cr Si+Mn
1 0.15 0.60 2.80 1.60 0.015 0.015 5 3.4
2 0.20 0.50 2.50 2.00 0.013 0.014 5 3
3 0.25 0.80 1.60 1.90 0.010 0.011 4.3 2.4
4 0.18 0.40 1.92 1.98 0.012 0.013 4.3 2.32
5 0.21 0.75 2.40 1.83 0.013 0.010 4.98 3.15
6 0.17 0.73 2.74 1.50 0.014 0.015 4.97 3.47
7 0.22 0.67 2.63 1.70 0.012 0.012 5 3.3
8 0.24 0.70 1.71 1.89 0.009 0.014 4.3 2.41
The heating technique parameter of 2 steel of the embodiment of the present invention of table
The rolling and heat treatment main technologic parameters of 3 steel of the embodiment of the present invention of table
The Rockwell hardness of 4 steel of the embodiment of the present invention of table
The equal orientation performance of 5 steel of the embodiment of the present invention of table
In order to state the present invention, explanation appropriately and is being sufficiently carried out to the present invention by embodiment among the above, it is above Embodiment is merely to illustrate the present invention, and not limitation of the present invention, those of ordinary skill in related technical field, not In the case where being detached from the spirit and scope of the present invention, it can also make a variety of changes and modification, made any modification are equally replaced It changes, improve, should all be included in the protection scope of the present invention, scope of patent protection of the invention should be limited by claim It is fixed.

Claims (3)

1. a kind of plastic die steel of low cost, which is characterized in that the ingredient of the mould steel is as follows by weight percentage: C: 0.15%~0.25%, Si:0.40%~0.80%, Mn:1.60%~2.80%, Cr:1.50%~2.00%, P≤ 0.015%, S≤0.015%, and Si+Mn+Cr=4.3%~5.0%, Si+Mn=2.3%~3.5%, surplus is for Fe and not It can avoid impurity.
2. a kind of plastic die steel of low cost according to claim 1, which is characterized in that the mould steel through thickness homogeneity Within 3HRC, transverse and longitudinal impacts ratio up to 0.84-0.87.
3. a kind of a kind of preparation method of the plastic die steel of low cost of any of claims 1 or 2, including smelting, casting, add Heat, rolling, heat treatment;It is characterized by:
The molten steel completed will be smelted and be cast into steel billet;Steel billet is put into heating furnace and is heated, heating process was divided into for three stages, and first Stage: 670 DEG C~730 DEG C, heating rate 60~100 DEG C/h, 1~2.5h of soaking time, second stage: 1170 DEG C~1230 DEG C, heating rate 60~100 DEG C/h, 2.5~4.5h of soaking time, the phase III: 1210 DEG C~1250 DEG C, heating rate 60~ 100 DEG C/h, 5~8h of soaking time;Steel billet after heating obtains the steel plate of 20-120mm specification, start rolling temperature through multi- pass rolling 1150~1250 DEG C, preceding two percentage pass reduction rolls rate control in 10-20r/min in 15%-25%, and finishing temperature 950~ 1050℃;It carries out being cooled to 600 DEG C -650 DEG C by the way of air-cooled after steel plate is offline, in 570 DEG C of -620 DEG C of range inside holdings 5-7h。
CN201811480289.6A 2018-12-05 2018-12-05 Low-cost plastic die steel and preparation method thereof Active CN109504847B (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113481357A (en) * 2021-06-30 2021-10-08 江苏省沙钢钢铁研究院有限公司 Plastic die steel plate and production method thereof
CN113512681A (en) * 2021-06-30 2021-10-19 江苏省沙钢钢铁研究院有限公司 Plastic die steel plate and production method thereof
CN114892094A (en) * 2022-05-31 2022-08-12 宝武集团鄂城钢铁有限公司 Pre-hardened mirror plastic die steel and production method thereof

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Publication number Priority date Publication date Assignee Title
CN101476086A (en) * 2008-01-02 2009-07-08 宝山钢铁股份有限公司 Economic steel for plastic cavity die and manufacturing method thereof
CN105112794A (en) * 2015-08-25 2015-12-02 石家庄钢铁有限责任公司 Low-cost plastic mold steel and production method thereof
CN107587075A (en) * 2017-08-30 2018-01-16 武汉钢铁有限公司 Inexpensive plastic die steel and its production method

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101476086A (en) * 2008-01-02 2009-07-08 宝山钢铁股份有限公司 Economic steel for plastic cavity die and manufacturing method thereof
CN105112794A (en) * 2015-08-25 2015-12-02 石家庄钢铁有限责任公司 Low-cost plastic mold steel and production method thereof
CN107587075A (en) * 2017-08-30 2018-01-16 武汉钢铁有限公司 Inexpensive plastic die steel and its production method

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113481357A (en) * 2021-06-30 2021-10-08 江苏省沙钢钢铁研究院有限公司 Plastic die steel plate and production method thereof
CN113512681A (en) * 2021-06-30 2021-10-19 江苏省沙钢钢铁研究院有限公司 Plastic die steel plate and production method thereof
WO2023272873A1 (en) * 2021-06-30 2023-01-05 江苏省沙钢钢铁研究院有限公司 Plastic mold steel plate and production method therefor
EP4365317A4 (en) * 2021-06-30 2024-10-16 Institute Of Res Of Iron And Steel Jiangsu Province/Sha Steel Co Ltd Cn Plastic mold steel plate and production method therefor
CN114892094A (en) * 2022-05-31 2022-08-12 宝武集团鄂城钢铁有限公司 Pre-hardened mirror plastic die steel and production method thereof
CN114892094B (en) * 2022-05-31 2023-03-03 宝武集团鄂城钢铁有限公司 Pre-hardened mirror plastic die steel and production method thereof

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