CN109504545A - 一种膏状除垢剂及制备方法 - Google Patents

一种膏状除垢剂及制备方法 Download PDF

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CN109504545A
CN109504545A CN201811383350.5A CN201811383350A CN109504545A CN 109504545 A CN109504545 A CN 109504545A CN 201811383350 A CN201811383350 A CN 201811383350A CN 109504545 A CN109504545 A CN 109504545A
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paste
scale remover
poly
sodium carboxymethylcellulose
propionamide
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桂芳成
廉振强
李景吾
王红霞
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Henan Zong Yuan Environmental Protection & Technology Co Ltd
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Henan Zong Yuan Environmental Protection & Technology Co Ltd
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    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/825—Mixtures of compounds all of which are non-ionic
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/042—Acids
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/046—Salts
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2075—Carboxylic acids-salts thereof
    • C11D3/2082—Polycarboxylic acids-salts thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/22—Carbohydrates or derivatives thereof
    • C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
    • C11D3/225—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin etherified, e.g. CMC
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3769—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/50—Perfumes
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/008—Polymeric surface-active agents
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/72—Ethers of polyoxyalkylene glycols

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Inorganic Chemistry (AREA)
  • Molecular Biology (AREA)
  • Detergent Compositions (AREA)
  • Cosmetics (AREA)

Abstract

本发明属于日用化工品领域，涉及去污除垢剂，具体是一种膏状除垢剂及其制备方法，膏状除垢剂由一定重量份的水，TX‑10，OP‑10，聚丙酰胺，羧甲基纤维素钠，硫酸，草酸，氟氢化铵和香精，经过一定的方法制备而成。与现有技术相比，能将液体或粉剂去污剂变为膏状，以涂抹方式附着在墙壁表面，不流坠，作用充分均匀，去污除垢消痕效果好，还能加香，改善污浊空间气味。

Description

一种膏状除垢剂及制备方法
技术领域
本发明属于日用化工品领域，涉及生活设施表面除污用品，具体是一种膏状除垢剂及制备方法。
背景技术
家庭、宾馆、饭店、洗浴间等生活设施，在使用时间长了之后会在瓷砖、玻璃墙壁表面形成污垢，特别是经常使用洗涤剂、清洁剂、洗发用品、沐浴露等用品后，容易形成含硅污垢，难以用清水冲洗。
现有的去污除垢方法，有的用“去污粉”擦拭，虽然效果较好，但是对瓷砖或玻璃壁面会造成划伤，失去光泽；有的用“洁厕灵”喷洒，但是由于是液体，容易流坠，与污垢接触作用不均匀、时间短,需要重复喷施，用量较多，还会对环境造成一定酸污染。对于严重的积垢，除污后还会遗留污垢的痕迹。
发明内容
针对现有的去污粉或洁厕灵，无论是粉状或液体的除污品存在的缺陷，本发明目的在于提供一种膏状除垢剂，并总结出制备方法，能够以涂抹方式使用，不流淌，作用时间延长，除污去垢能力增强，除垢效果进一步提高，减轻环境污染。
本发明采取的技术方案是：一种膏状除垢剂，由以下百分比重量份：水60－80％，TX-10 1－5％，OP-10 5－10％，聚丙酰胺1－5％，羧甲基纤维素钠1－5％，硫酸（98％）5－10％，草酸1－5％，氟氢化铵5－10％，香精0－1％制成膏状剂型。
本发明一种膏状除垢剂的制备方法，把硫酸倒入搅拌器内适量的水中，边倒边搅拌，冷却至室温后，加入草酸搅拌溶解完全，继续搅拌再依次加入TX-10，OP-10；另用适量的水溶化聚丙酰胺；另用适量的水发胀羧甲基纤维素钠；将聚丙酰胺溶液和发胀的羧甲基纤维素钠加入搅拌器搅拌均匀后，再加入氟氢化铵，最后加入香精，搅拌均匀，终呈粘稠状膏剂，稀稠度可用加碱水调节，检验、包装，成为膏状除垢剂。
本发明选择上述组分，其中，水作为溶剂，起到溶解、稀释、均质其它原料的作用；TX-10、OP-10作为乳化剂，起到乳化、渗透作用，能使污垢中的油污溶解脱离墙壁表面；硫酸、草酸、氟氢化铵为酸性物质，硫酸能除去污垢中的碱性物质，草酸缓释，有还原性能除去灰垢和铁锈污垢，氟氢化铵尤其是对含硅污垢能溶解脱离，还能去除污垢痕迹；聚丙酰胺、羧甲基纤维素钠为增稠剂，聚丙酰胺在增稠中还具有粘性和生膜作用，羧甲基纤维素钠还具有稳定作用，两者协同，能将除垢剂液体形态变为粘稠的膏状，能使除垢剂以涂抹方式附着在墙壁表面，不流坠，挂墙持久，复盖均匀，作用充分；香精，作为香味剂，能够在去污过程中，利用香精挥发出的芳香改善场所空间的气味。与现有技术相比，具有使用方便，去污除垢能力增强，去污除垢消痕效果明显提高，减少环境污染，改善空间气味等显著优点。
具体实施方式
本发明一种膏状除垢剂，由以下百分比重量份原料：水60－80％，TX-10 1－5％，OP-10 5－10％，聚丙酰胺1－5％，羧甲基纤维素钠1－5％，硫酸（98％）5－10%，草酸1－5％，氟氢化铵5－10％，香精0－1％，制成膏状剂型。
本发明一种膏状除垢剂实施例1，由以下百分比重量份原料制成膏剂：水60％，TX-10 5％，OP-10 5％，聚丙酰胺5％，羧甲基纤维素钠5％，硫酸8％，草酸5％，氟氢化铵7％，香精1％。
本发明一种膏状除垢剂实施例2，由以下百分比重量份原料制成膏剂：水80％，TX-10 1％，OP-10 5％，聚丙酰胺1％，羧甲基纤维素钠4％，硫酸（98％）5％，草酸1.9％，氟氢化铵5％，香精0.1％。
本发明一种膏状除垢剂实施例3，由以下百分比重量份原料制成膏剂：水70％，TX-10 3％，OP-10 6％，聚丙酰胺3％，羧甲基纤维素钠2％，硫酸7％，草酸2.5％，氟氢化铵6％，香精0.5％。
使用时，视污垢墙壁表面大小，污垢轻重，将适量的本产品挤涂在墙面上，用毛刷（或细布）均匀刷抹，遍及边缝，不留空白，等待一定时间（约10分钟），在局部擦拭检查去污除垢效果，达到去污除垢目的后，用抹布擦去，最后用清水冲洗干净。不使用时，密封保存，防止干燥，本品有腐蚀性，防止与人体接触，安全保管。

Claims (5)

1.一种膏状除垢剂，其特征是由以下百分比重量份原料：水60－80％，TX-10 1－5％，OP-10 5－10％，聚丙酰胺1－5％，羧甲基纤维素钠1－5％，硫酸（98％）5－10%，草酸1－5％，氟氢化铵5－10％，香精0－1％，制成膏状剂型。
2.根据权利要求1所述一种膏状除垢剂，其特征是由以下百分比重量份原料制成膏剂：水60％，TX-10 5％，OP-10 5％，聚丙酰胺5％，羧甲基纤维素钠5％，硫酸7％，草酸5％，氟氢化铵7％，香精1％。
3.根据权利要求1所述一种膏状除垢剂，其特征是由以下百分比重量份原料制成膏剂：水80％，TX-10 1％，OP-10 5％，聚丙酰胺1％，羧甲基纤维素钠1％，硫酸（98％）5％，草酸1.9％，氟氢化铵5％，香精0.1％。
4.根据权利要求1所述一种膏状除垢剂，其特征是由以下百分比重量份原料制成膏剂：水70％，TX-10 3％，OP-10 6％，聚丙酰胺3％，羧甲基纤维素钠2％，硫酸7％，草酸2.5％，氟氢化铵6％，香精0.5％。
5.根据权利要求1－4所述的任一种膏状除垢剂，其特征是制备方法为：把硫酸倒入搅拌器内适量的水中，边倒边搅拌，冷却至室温后，加入草酸搅拌溶解完全，再依次搅拌加入TX-10，OP-10；另用适量的水溶化聚丙酰胺；另用适量的水发胀羧甲基纤维素钠；将聚丙酰胺溶液和发胀的羧甲基纤维素钠加入搅拌器搅拌均匀后，再加入氟氢化铵，最后加入香精，搅拌均匀，终呈粘稠状膏剂，检验、包装，成为膏状除垢剂。
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Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101280245A (zh) * 2008-05-21 2008-10-08 张光 洁厕膏

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101280245A (zh) * 2008-05-21 2008-10-08 张光 洁厕膏

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
刘智安: "《工业循环冷却水处理》", 30 September 2017, 北京：中国轻工业出版社 *
梁治齐: "《实用清洗技术手册》", 31 January 2000, 北京：化学工业出版社 *

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