CN109503253A - A kind of natural biological medicine fertilizer, preparation method and its application method - Google Patents
A kind of natural biological medicine fertilizer, preparation method and its application method Download PDFInfo
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- CN109503253A CN109503253A CN201811394055.XA CN201811394055A CN109503253A CN 109503253 A CN109503253 A CN 109503253A CN 201811394055 A CN201811394055 A CN 201811394055A CN 109503253 A CN109503253 A CN 109503253A
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05F—ORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
- C05F11/00—Other organic fertilisers
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N31/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic oxygen or sulfur compounds
- A01N31/08—Oxygen or sulfur directly attached to an aromatic ring system
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N31/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic oxygen or sulfur compounds
- A01N31/08—Oxygen or sulfur directly attached to an aromatic ring system
- A01N31/14—Ethers
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/02—Saturated carboxylic acids or thio analogues thereof; Derivatives thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/36—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
- A01N43/42—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings condensed with carbocyclic rings
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G5/00—Fertilisers characterised by their form
- C05G5/20—Liquid fertilisers
Abstract
The present invention relates to a kind of natural biological medicine fertilizer, preparation method and its application methods.A kind of natural biological medicine fertilizer of the invention, it is detected using chromatographic mass spectrometry translocation method, component including following content: acetic acid 8-52%, formic acid 1-4.3%, propionic acid 0.6-3.2%, hydroxypropanone- 0.02-0.1%, isoquinolin 0.4-2%, guaiacol 0.2-0.9%, paracresol 0.8-2.3%, metacresol 0.3-1.8%, surplus are water.The beneficial effect is that: natural biological medicine fertilizer of the invention is soluble easily in water, is easily absorbed by plants, and helps to sterilize expelling parasite, inhibits pest and disease damage, promote plant self immune system, strengthening root promotees seedling, promotes plant absorption, adjusts plant metabolism, soil is improved, crop quality and resistance effect are improved；It can be widely used for the industrial crops such as grain, vegetables, melon and fruit, tealeaves, edible mushroom, ornamental plant, Chinese herbal medicine.Natural biological medicine fertilizer can be applied to vegetable seeds processing, root dipping, spray, trickle irrigation, pour the heart and the prevention and control of plant diseases, pest control.
Description
Technical field
The present invention relates to field of agricultural production technologies, the in particular to preparation technical field of fertilizer, and in particular to Yi Zhongtian
Right biological medicine fertilizer, preparation method and its application method.
Background technique
Due to applying pesticides, chemical fertilizer simple in a large amount of agricultural production processes, hazard residue causes fertilizer to farmland pollution
The decline of the food qualities such as evil, nitrite exceeded, grain and oil.People eat the grain containing heavy metal substances such as pesticide, fertilizer residues
The food such as oil, gourd, fruit and vegetable, the organs such as nervous system, liver, kidney in heavy then direct harmful to human, cause to be poisoned to death；It is light then
It is excessive to make one internal Nitrate Accumulation, becomes nitrite, the illnesss such as cancer is caused largely to occur.Nocuousness in pesticide, chemical fertilizer
The heavy metals objects such as residual directly affect ecological, environmental protective, not only cause massive losses to vast farmers, but also give the people
Health, rural economic development and social harmony cause huge hidden danger.For the residual contamination for solving and controlling pesticide, chemical fertilizer
It is excessively used, country proposes pesticide and Reducing amount of chemical fertilizer applied action plan, and fertilizer application is excessive and the contradiction of soil hardening, pesticide make
It is vied each other with contradiction, the contradiction of national industrial policies and peasant benefit, the means of agricultural production agricultural chemicals enterprise that excess and product quality require
With the contradiction of industry benign development, various contradiction interlockings affect the development of domestic agricultural industry dearly.Agri-scientific research list
Position, the means of agricultural production Corporation R & D various new pesticide and chemical fertilizer, but can improve crop yield, pest and disease damage is reduced, really realizes pesticide
And Reducing amount of chemical fertilizer applied, new technology and the Product Report for improving plant autoimmune ability are less.
Biological medicine fertilizer of the development based on improving plant autoimmunity and be metabolized, on the one hand reducing consumption of chemical agent is symbol
Sustainable agriculture development direction is closed, the blank of China's product is also filled up；On the other hand high security, the ring due to biological medicine fertilizer
Border friendly, microbial inoculum itself fast adaptability and lasting period be long etc. can to overcome phytotoxicity caused by chemical agent, drug resistance and residual
The problems such as staying.But existing biological medicine fertilizer is substantially materials such as existing fertilizer component, farm chemical ingredients and auxin
It mixes, or is formed using the materials mixed fermentation such as pericarp, tree ash, poultry manure, existing biological medicine fertilizer is promoting
It is obviously insufficient into the comprehensive performance in terms of plant growth, sterilization expelling parasite, inhibition pest and disease damage, raising crops quality.
Summary of the invention
It is an object of the invention to overcome the deficiencies of the prior art and provide one kind can promote plant growth, sterilization expelling parasite,
New type natural biological medicine fertilizer, preparation method and its application method for inhibiting pest and disease damage, improving crops quality.It is provided by the invention
New drug fertilizer is used for crop, reaches volume increase, chemical fertilizer and pesticide reduction, pollution-free, non agricultural chemical residuum resultant effect.
A kind of natural biological medicine fertilizer provided by the invention, technical solution are as follows:
A kind of natural biological medicine fertilizer, the component including following content: acetic acid 8-52%, formic acid 1-4.3%, propionic acid 0.6-
3.2%, hydroxypropanone- 0.02-0.1%, isoquinolin 0.4-2%, guaiacol 0.2-0.9%, paracresol 0.8-2.3%, first
Phenol 0.3-1.8%, surplus are water.
It preferably, further include the component of following content: 2,4,6- trimethylpyridine 0.08-1.2%, 2 amino -5- methylbenzenes
Formic acid 0.8-3.9%, butyric acid 0.08-0.6%, crotonic acid 0.05-0.3%.
It preferably, further include the component of following content: quinoline 0.08-2.2%, 2,7- dimethyl quinoline 0.2-2.2%, second
Amide 0.08-0.9%, gamma-butyrolacton 0.06-0.7%.
Preferably, the constituent content of natural biological medicine fertilizer are as follows: acetic acid 45-52%, formic acid 4-4.3%, propionic acid 2.6-
3.2%, hydroxypropanone- 0.07-0.1%, isoquinolin 0.9-2%, guaiacol 0.7-0.9%, paracresol 2-2.3%, metacresol
1.6-1.8%.2,4,6 picoline 0.2-1.2%, 2 amino -5- methyl benzoic acid 3.3-3.9%, butyric acid 0.4-0.6%, bar
Beans acid 0.1-0.3%, quinoline 0.8-2.2%, 2,7- dimethyl quinoline 1-2.2%, acetamide 0.7-0.9%, gamma-butyrolacton
0.5-0.7%.
It preferably, further include the component of following content: microelement 0.06-0.08%, nitrate nitrogen 4-6%.
Preferably, the component and content of the natural biological medicine fertilizer are detected using chromatographic mass spectrometry translocation method.
Preferably, humic acid, amino acid, a great number of elements, moderate-element or micro are added in the natural biological medicine fertilizer
One of element is appointed several.
Preferably, the humic acid content added in the natural biological medicine fertilizer is more than or equal to 3%；Or the natural biological
Free aminoacid content in medicine fertilizer is more than or equal to 10%；Or a great number of elements (N, P in the natural biological medicine fertilizer2O5、
K2O) total amount is more than or equal to 50%；Or moderate-element (the Ca, Mg) total amount in the natural biological medicine fertilizer is more than or equal to 100
Gram/L；Or microelement (Fe, Mn, Zn, Mo, B) total amount (calculating based on the element) in the natural biological medicine fertilizer is more than or equal to
10%.
The application method of natural biological medicine fertilizer of the invention, is diluted to 200~600 times for natural biological medicine fertilizer, will dilute
Liquid impregnates seed, root dipping, trickle irrigation, pours the heart or spray.
A kind of preparation method of natural biological medicine fertilizer of the invention, 500-1400 DEG C of high-temperature flue gas and lignite are led to together
In the space for entering hypoxemia high negative pressure, make brown coal powder drying and dehydrating, shredded tobacco for water pipes gas is drawn, condensed water flue gas obtains natural biological medicine
Fertilizer.
Preferably, humic acid is added in above-mentioned natural biological medicine fertilizer, its humic acid content is made to be more than or equal to 3%；Or
Amino acid is added in above-mentioned natural biological medicine fertilizer, its free aminoacid content is made to be more than or equal to 10%；Or above-mentioned natural
A great number of elements is added in biological medicine fertilizer, its a great number of elements total amount is made to be more than or equal to 50%；Or in above-mentioned natural biological medicine fertilizer
Moderate-element is added, its moderate-element total amount is made to be more than or equal to 100 grams/L；Or it is added in above-mentioned natural biological medicine fertilizer micro
Element, the microelement total amount for calculating it based on the element are more than or equal to 10%.
Preferably, 700-1200 DEG C of high-temperature flue gas and lignite are passed through oxygen content less than 12% together, negative pressure is -100
In the space of~-6000Pa；
The method of condensed water flue gas is directly to pass through condensing plant for water flue gas condensing；Or it perform the following steps in sequence:
Liquefy shredded tobacco for water pipes gas first, then carries out centrifugal treating and filtration treatment, filtrate is finally carried out revolving and handles to obtain natural biological
Medicine fertilizer.
Implementation of the invention includes following technical effect:
Natural biological medicine fertilizer of the invention is soluble easily in water, is easily absorbed by plants, and helps to sterilize expelling parasite, inhibits pest and disease damage,
Promote plant self immune system, strengthening root promotees seedling, promotes plant absorption, adjusts plant metabolism, improves soil, improves crop quality
It is acted on resistance；It can be widely used for the industrial crops such as grain, vegetables, melon and fruit, tealeaves, edible mushroom, ornamental plant, Chinese herbal medicine.
Natural biological medicine fertilizer can be applied to vegetable seeds processing, root dipping, spray, trickle irrigation, pour the heart and the prevention and control of plant diseases, pest control.
Butyric acid, guaiacol during the natural biological medicine that the present invention limits is fertile are the memory substances of plant, can promote root system
Growth and plant growth.Acetic acid, metacresol have sterilization expelling parasite well, inhibit pest and disease damage effect.Guaiacol, which has, to be promoted
Plant absorption adjusts the effect of plant metabolism.Formic acid, hydroxypropanone- have the effect of improving crops quality.Said components are closed
Together, there is synergistic function, so that natural biological medicine fertilizer has more preferable effect.
In addition, gamma-butyrolacton is also the memory substance of plant, root growth and plant growth can be promoted, have and promote to plant
Object absorbs, and adjusts the effect of plant metabolism.2 amino -5- methyl benzoic acids, quinoline, crotonic acid have sterilization expelling parasite, suppression well
Pest and disease damage effect processed.
Lignite is the relatively low pit coal of degree of coalification, is to be dehydrated after peat deposits, be compacted be changed into organic-biological rock
Initial stage product, gain the name because appearance is brown or crineous.Lignite complicated component has available high value ingredient, Shen
Ask someone that there is many-sided research in lignite use aspects, during applicant has found drying and upgrading lignite in the course of the research,
Due to high temperature action, many natural materials are incorporated in the shredded tobacco for water pipes gas after drying, the shredded tobacco for water pipes gas after drying brown coal is after condensing
The component in medicine fertilizer that can be used as natural biological medicine fertilizer, and obtain promote root growth and plant growth, sterilization expelling parasite,
Inhibit pest and disease damage, promote that there is synergistic function in terms of plant absorption, adjusting plant metabolism, raising crops quality.
The preparation method of natural biological medicine fertilizer of the invention is at low cost using the high lignite of natural reserves as raw material, and
And upgrading can also be dehydrated for lignite by the way, moreover it is possible to obtain the fire coal with economic value.It can also be in natural biological medicine fertilizer
Adding a certain amount of amino acid, perhaps ammino acid liquid fertilizer or humic acid liquid fertilizer is made in humic acid.
Detailed description of the invention
Fig. 1 is the flow diagram of the preparation method of natural biological medicine fertilizer.
Specific embodiment
The present invention is described in detail below in conjunction with embodiment and attached drawing, it should be pointed out that described reality
It applies example and is intended merely to facilitate the understanding of the present invention, and do not play any restriction effect to it.
Embodiment 1
It is shown in Figure 1,800 DEG C of high-temperature flue gas and brown coal powder are passed through to the space of hypoxemia (or anaerobic) high negative pressure together
It is interior, make brown coal powder drying and dehydrating, shredded tobacco for water pipes gas is drawn, condensed water flue gas obtains natural biological medicine fertilizer；Using chromatographic mass spectrometry translocation
The component and content of method detection natural biological medicine fertilizer.The component and content of natural biological medicine fertilizer are acetic acid 8%, first in the present embodiment
Acid 4%, propionic acid 3.2%, hydroxypropanone- 0.07%, isoquinolin 1.4%, guaiacol 0.9%, paracresol 2.3%, metacresol
1.6%, surplus is water.
Embodiment 2
It is shown in Figure 1,850 DEG C of high-temperature flue gas and brown coal powder are passed through together in the space of hypoxemia high negative pressure, made brown
Coal dust drying and dehydrating draws shredded tobacco for water pipes gas, and condensed water flue gas obtains natural biological medicine fertilizer；Day is detected using chromatographic mass spectrometry translocation method
The component and content of right biological medicine fertilizer.In the present embodiment the component and content of natural biological medicine fertilizer be acetic acid 23%, formic acid 1%,
Propionic acid 1.4%, hydroxypropanone- 0.05%, isoquinolin 2%, guaiacol 0.7%, paracresol 2%, metacresol 1.8%, surplus are
Water.
Embodiment 3
It is shown in Figure 1,500 DEG C of high-temperature flue gas and brown coal powder are passed through together in the space of hypoxemia high negative pressure, made brown
Coal dust drying and dehydrating draws shredded tobacco for water pipes gas, and condensed water flue gas obtains natural biological medicine fertilizer；Day is detected using chromatographic mass spectrometry translocation method
The component and content of right biological medicine fertilizer.The component and content of natural biological medicine fertilizer are acetic acid 45%, formic acid in the present embodiment
4.3%, propionic acid 0.6%, hydroxypropanone- 0.1%, isoquinolin 0.9%, guaiacol 0.4%, paracresol 0.8%, metacresol
0.7%, surplus is water.
Embodiment 4
It is shown in Figure 1,1400 DEG C of high-temperature flue gas and brown coal powder are passed through together in the space of hypoxemia high negative pressure, made brown
Coal dust drying and dehydrating draws shredded tobacco for water pipes gas, and condensed water flue gas obtains natural biological medicine fertilizer；Day is detected using chromatographic mass spectrometry translocation method
The component and content of right biological medicine fertilizer.The component and content of natural biological medicine fertilizer are acetic acid 52%, formic acid in the present embodiment
2.2%, propionic acid 2.6%, hydroxypropanone- 0.02%, isoquinolin 0.4%, guaiacol 0.2%, paracresol 1.4%, metacresol
0.3%, surplus is water.
Embodiment 5
It is shown in Figure 1,1200 DEG C of high-temperature flue gas and brown coal powder are passed through together in the space of hypoxemia high negative pressure, made brown
Coal dust drying and dehydrating draws shredded tobacco for water pipes gas, and condensed water flue gas obtains natural biological medicine fertilizer；Day is detected using chromatographic mass spectrometry translocation method
The component and content of right biological medicine fertilizer.The component and content of natural biological medicine fertilizer are acetic acid 33%, formic acid in the present embodiment
2.1%, propionic acid 2.9%, hydroxypropanone- 0.08%, isoquinolin 0.8%, guaiacol 0.5%, paracresol 1.7%, metacresol
0.9%, 2,4,6- trimethylpyridines 1.2%, 2 amino -5- methyl benzoic acids 0.8%, butyric acid 0.08%, crotonic acid 0.05%,
Surplus is water.
Embodiment 6
It is shown in Figure 1,1300 DEG C of high-temperature flue gas and brown coal powder are passed through together in the space of hypoxemia high negative pressure, made brown
Coal dust drying and dehydrating draws shredded tobacco for water pipes gas, and condensed water flue gas obtains natural biological medicine fertilizer；Day is detected using chromatographic mass spectrometry translocation method
The component and content of right biological medicine fertilizer.The component and content of natural biological medicine fertilizer are acetic acid 19%, formic acid in the present embodiment
3.8%, propionic acid 3.1%, hydroxypropanone- 0.06%, isoquinolin 1.1%, guaiacol 0.7%, paracresol 2.1%, metacresol
1.1%, 2,4,6- trimethylpyridines 0.2%, 2 amino -5- methyl benzoic acids 3.9%, butyric acid 0.4%, crotonic acid 0.3% is remaining
Amount is water.
Embodiment 7
It is shown in Figure 1,700 DEG C of high-temperature flue gas and brown coal powder are passed through together in the space of hypoxemia high negative pressure, made brown
Coal dust drying and dehydrating draws shredded tobacco for water pipes gas, and condensed water flue gas obtains natural biological medicine fertilizer；Day is detected using chromatographic mass spectrometry translocation method
The component and content of right biological medicine fertilizer.The component and content of natural biological medicine fertilizer are acetic acid 29%, formic acid in the present embodiment
1.8%, propionic acid 1.9%, hydroxypropanone- 0.09%, isoquinolin 1.5%, guaiacol 0.6%, paracresol 2.2%, metacresol
1.2%, 2,4,6- trimethylpyridines 0.08%, 2 amino -5- methyl benzoic acids 3.3%, butyric acid 0.6%, crotonic acid 0.1% is remaining
Amount is water.
Embodiment 8
It is shown in Figure 1,1000 DEG C of high-temperature flue gas and brown coal powder are passed through together in the space of hypoxemia high negative pressure, made brown
Coal dust drying and dehydrating draws shredded tobacco for water pipes gas, and condensed water flue gas obtains natural biological medicine fertilizer；Day is detected using chromatographic mass spectrometry translocation method
The component and content of right biological medicine fertilizer.The component and content of natural biological medicine fertilizer are acetic acid 48%, formic acid in the present embodiment
4.1%, propionic acid 0.6%, hydroxypropanone- 0.1%, isoquinolin 1.9%, guaiacol 0.4%, paracresol 0.8%, metacresol
0.9%, 2,4,6- trimethylpyridines 0.09%, 2 amino -5- methyl benzoic acids 2.3%, butyric acid 0.3%, crotonic acid 0.09%,
Quinoline 2.2%, 2,7- dimethyl quinoline 0.2%, acetamide 0.7%, gamma-butyrolacton 0.06%, surplus are water.
Embodiment 9
It is shown in Figure 1,1150 DEG C of high-temperature flue gas and brown coal powder are passed through together in the space of hypoxemia high negative pressure, made brown
Coal dust drying and dehydrating draws shredded tobacco for water pipes gas, and condensed water flue gas obtains natural biological medicine fertilizer；Day is detected using chromatographic mass spectrometry translocation method
The component and content of right biological medicine fertilizer.The component and content of natural biological medicine fertilizer are acetic acid 51%, formic acid in the present embodiment
2.5%, propionic acid 2.9%, hydroxypropanone- 0.08%, isoquinolin 0.8%, guaiacol 0.4%, paracresol 1.6%, metacresol
0.4%, 2,4,6- trimethylpyridines 0.8%, 2 amino -5- methyl benzoic acids 1.4%, butyric acid 0.2%, crotonic acid 0.15%, quinoline
Quinoline 0.08%, 2,7- dimethyl quinoline 2.2%, acetamide 0.08%, gamma-butyrolacton 0.5%, surplus are water.
Embodiment 10
It is shown in Figure 1,800 DEG C of high-temperature flue gas and brown coal powder are passed through together in the space of hypoxemia high negative pressure, made brown
Coal dust drying and dehydrating draws shredded tobacco for water pipes gas, and condensed water flue gas obtains natural biological medicine fertilizer；Day is detected using chromatographic mass spectrometry translocation method
The component and content of right biological medicine fertilizer.The component and content of natural biological medicine fertilizer are acetic acid 43%, formic acid in the present embodiment
4.1%, propionic acid 0.7%, hydroxypropanone- 0.08%, isoquinolin 1.9%, guaiacol 0.4%, paracresol 1.8%, metacresol
0.9%, 2,4,6- trimethylpyridines 0.6%, 2 amino -5- methyl benzoic acids 3.1%, butyric acid 0.1%, crotonic acid 0.2%, quinoline
Quinoline 0.8%, 2,7- dimethyl quinoline 1%, acetamide 0.9%, gamma-butyrolacton 0.7%, surplus are water.
Embodiment 11
It is shown in Figure 1,1400 DEG C of high-temperature flue gas and brown coal powder are passed through together in the space of hypoxemia high negative pressure, made brown
Coal dust drying and dehydrating draws shredded tobacco for water pipes gas, and condensed water flue gas obtains natural biological medicine fertilizer；Day is detected using chromatographic mass spectrometry translocation method
The component and content of right biological medicine fertilizer.In the present embodiment the component and content of natural biological medicine fertilizer be acetic acid 31%, formic acid 2%,
Propionic acid 2.4%, hydroxypropanone- 0.08%, isoquinolin 1.2%, guaiacol 0.7%, paracresol 2%, metacresol 1.6%, 2,4,
6- trimethylpyridine 0.09%, 2 amino -5- methyl benzoic acids 1.1%, butyric acid 0.6%, crotonic acid 0.2%, quinoline 1.1%, 2,
7- dimethyl quinoline 0.9%, acetamide 0.2%, gamma-butyrolacton 0.3%, microelement 0.07%, surplus are water.
Embodiment 12
It is shown in Figure 1,500 DEG C of high-temperature flue gas and brown coal powder are passed through together in the space of hypoxemia high negative pressure, made brown
Coal dust drying and dehydrating draws shredded tobacco for water pipes gas, and condensed water flue gas obtains natural biological medicine fertilizer；Day is detected using chromatographic mass spectrometry translocation method
The component and content of right biological medicine fertilizer.The component and content of natural biological medicine fertilizer are acetic acid 49%, formic acid in the present embodiment
2.1%, propionic acid 2.6%, hydroxypropanone- 0.09%, isoquinolin 0.8%, guaiacol 0.5%, paracresol 1.6%, metacresol
0.9%, 2,4,6- trimethylpyridines 0.08%, 2 amino -5- methyl benzoic acids 2.3%, butyric acid 0.5%, crotonic acid 0.2%, quinoline
Quinoline 1.8%, 2,7- dimethyl quinoline 1.6%, acetamide 0.4%, gamma-butyrolacton 0.5%, microelement 0.08%, nitrate nitrogen
5%, surplus is water.
Embodiment 13
It is shown in Figure 1,900 DEG C of high-temperature flue gas and brown coal powder are passed through together in the space of hypoxemia high negative pressure, made brown
Coal dust drying and dehydrating draws shredded tobacco for water pipes gas, and condensed water flue gas obtains natural biological medicine fertilizer；Day is detected using chromatographic mass spectrometry translocation method
The component and content of right biological medicine fertilizer.The component and content of natural biological medicine fertilizer are acetic acid 48%, formic acid in the present embodiment
2.1%, propionic acid 2.9%, hydroxypropanone- 0.09%, isoquinolin 0.8%, guaiacol 0.5%, paracresol 1.6%, metacresol
0.9%, 2,4,6- trimethylpyridines 0.08%, 2 amino -5- methyl benzoic acids 2.3%, butyric acid 0.5%, crotonic acid 0.2%, quinoline
Quinoline 1.8%, 2,7- dimethyl quinoline 1.6%, acetamide 0.4%, gamma-butyrolacton 0.6%, microelement 0.06%, nitrate nitrogen
4%, surplus is water.
Embodiment 14
It is prepared in natural biological medicine fertilizer in embodiment 1 and adds humic acid, its humic acid content is made to be more than or equal to 3%,
The medicine fertilizer rich in humic acid is obtained, the content of humic acid is equal to 3% in the present embodiment.
Embodiment 15
It is prepared in natural biological medicine fertilizer in embodiment 5 and adds humic acid, its humic acid content is made to be more than or equal to 3%,
The medicine fertilizer rich in humic acid is obtained, the content of humic acid is equal to 5% in the present embodiment.
Embodiment 16
It is prepared in natural biological medicine fertilizer in embodiment 8 and adds humic acid, its humic acid content is made to be more than or equal to 3%,
The medicine fertilizer rich in humic acid is obtained, the content of humic acid is equal to 10% in the present embodiment.
Embodiment 17
It is prepared in natural biological medicine fertilizer in embodiment 12 and adds humic acid, its humic acid content is made to be more than or equal to 3%,
The medicine fertilizer rich in humic acid is obtained, the content of humic acid is equal to 13% in the present embodiment.
Embodiment 18
It is prepared in natural biological medicine fertilizer in embodiment 2 and adds amino acid, be more than or equal to its free aminoacid content
10%, the medicine fertilizer rich in amino acid is obtained, the content of amino acid is equal to 10% in the present embodiment.
Embodiment 19
It is prepared in natural biological medicine fertilizer in embodiment 6 and adds amino acid, be more than or equal to its free aminoacid content
10%, the medicine fertilizer rich in amino acid is obtained, the content of amino acid is equal to 15% in the present embodiment.
Embodiment 20
It is prepared in natural biological medicine fertilizer in embodiment 9 and adds amino acid, be more than or equal to its free aminoacid content
10%, the medicine fertilizer rich in amino acid is obtained, the content of amino acid is equal to 18% in the present embodiment.
Embodiment 21
It is prepared in natural biological medicine fertilizer in embodiment 12 and adds amino acid, be more than or equal to its free aminoacid content
10%, the medicine fertilizer rich in amino acid is obtained, the content of amino acid is equal to 10% in the present embodiment.
Embodiment 22
It is prepared in natural biological medicine fertilizer in embodiment 13 and adds a great number of elements, moderate-element or microelement, make it
A great number of elements (the present embodiment N, P2O5、K2O) total amount is more than or equal to 50%, keeps its moderate-element (the present embodiment Ca, Mg) total
Amount is more than or equal to 100 grams/L, make its microelement (the present embodiment Fe, Mn, Zn, Mo, B) total amount (calculating based on the element) greater than etc.
In 10%.
In natural biological medicine fertilizer of the invention, it can be added as needed in a great number of elements, moderate-element or microelement
A kind of or appoint several, the present invention no longer enumerates.A great number of elements refers to that plant normal growth development requirement or content are biggish
Essential nutrient element refers generally to 6 kinds of carbon, hydrogen, oxygen, nitrogen, phosphorus and potassium elements.Moderate-element refers to requirement in process of crop growth
It is higher than the nutrient of microelement inferior to a great number of elements, moderate-element typically constitutes from the 0.1%~1% of crop body dry matter,
It is often referred to three kinds of calcium, magnesium, sulphur elements.Microelement refers to the few element of plant normal growth development requirement, refer generally to iron,
The elements such as manganese, zinc, copper, boron, molybdenum, chlorine, sodium, nickel.
Lignite is the relatively low pit coal of degree of coalification, is to be dehydrated after peat deposits, be compacted be changed into organic-biological rock
Initial stage product, brown coal powder high temperature, hypoxemia, high negative pressure space in dispersed by high speed depolymerization, and directly connect with high-temperature flue gas
Touching carries out efficient mass heat transfer, and many natural materials have been incorporated in the shredded tobacco for water pipes gas after brown coal drying, by can after water flue gas condensing
To obtain new type natural biological medicine fertilizer, the effective component of the natural biological medicine fertilizer has effects that following:
1, the butyric acid in the present invention, guaiacol, gamma-butyrolacton are the memory substances of plant, can promote root growth and
Plant growth.
2, acetic acid, methyl benzoic acid, quinoline, metacresol, crotonic acid have sterilization expelling parasite well, inhibit disease in the present invention
Insect pest effect.
3, the guaiacol in the present invention, gamma-butyrolacton, which have, promotes plant absorption, adjusts the effect of plant metabolism.
4, the formic acid in the present invention, hydroxypropanone- have the effect of improving crops quality.
Due to the ingredient of the lignite of different batches have it is fraction of not identical, after testing the study found that the group detected
Divide and content has certain difference, but the lignite of all batches contains specific effective component, resulting natural biological
Medicine fertilizer is soluble easily in water, is easily absorbed by plants, and helps to sterilize expelling parasite, inhibits pest and disease damage, promotes plant self immune system, strengthen
Root promotees seedling, promotes plant absorption, adjusts plant metabolism, improves soil, improves crop quality and resistance effect；It can be widely used for
The industrial crops such as grain, vegetables, melon and fruit, tealeaves, edible mushroom, ornamental plant, Chinese herbal medicine.Due to the natural attribute of lignite, use
Have the function of synergy between the component for the natural biological medicine fertilizer that lignite obtains, there is high security, environment friendly, bacterium
The feature of agent fast adaptability itself and lasting period length.
Preferably, it is big to remove first to carry out separation of air from dust after extraction shredded tobacco for water pipes gas to prepare the preparation method of natural biological medicine fertilizer
Particulate matter, separation of air from dust step are that will be introduced into separator to be dusted processing with the water flue gas stream of dust.It
The preparation method of right biological medicine fertilizer further includes lignite pre-treatment step, and lignite pre-treatment step is lignite raw material through broken crusher machine
After through scrapper conveyor be transported to vibrating screen, Vibration Screen selects the powdery brown coal of setting partial size, the high-temperature flue gas that hot-blast stove generates
It is synchronous with pretreated powdery brown coal under the action of induced air negative-pressure to enter drying machine；Oxygen content less than 12%, negative pressure be-
The thermal current of 100~-6000Pa introduces in dry place from air inlet, it is preferable that oxygen content < 3%, negative pressure in dry place
For -500~-800Pa.
Specifically, shredded tobacco for water pipes gas can directly pass through condensing plant for water flue gas condensing；Preferably, purer high-quality in order to prepare
Natural biological medicine fertilizer, natural biological medicine fertilizer can also be obtained using following methods:
(1), the shredded tobacco for water pipes gas after lignite high temperature fast dewatering is collected, collection liquid is obtained；In the present embodiment, lignite high temperature is quick
Dewatered shredded tobacco for water pipes gas, which drenches technology by shelves, to be collected, and shredded tobacco for water pipes air-flow is condensed into the technology of water after shelves drench plate, scrap build at
This is low, and liquefaction effect is good.
(2), collection liquid is introduced into centrifugal device progress centrifugal treating and obtains supernatant；In the present embodiment, collection liquid exists
5~15min is centrifuged under the conditions of 5000~16000r/min, the restriction of above-mentioned condition can quickly separate supernatant.
(3), supernatant is filtered with filter, obtains filtrate；In the present embodiment, supernatant is filtered true
It is carried out under empty condition, the filter is sand core filter, sand core filter preferably 8 microns of sand core filters, by largely trying
It tests and shows to be filtered under vacuum conditions, there is better filter effect, the selection of 8 microns of sand core filters can obtain
Filtrate more evenly.
(4), filtrate is subjected to revolving processing, collects evaporation condensate and obtains natural biological medicine fertilizer, in the present embodiment, will filtered
Liquid carries out revolving processing under the conditions of 50~60 DEG C.The new type natural biological medicine fertilizer prepared by the above method is used in crops
On, test result shows to improve potentiality of seed to percentage of seedgermination is improved, seed is promoted to take root, and promotes plant growth hair
It educates, increases crop yield, improve crop quality and have obvious effects on.
The system for preparing natural biological medicine fertilizer includes for conveying the conveying equipment of lignite raw material, connecting with the conveying equipment
The broken screening plant connect and the drying machine connecting with the broken screening installation, the system also includes sequentially connected powder gas
Separator, water smoke condensation device, the separation of air from dust device is for separating the brown coal powder in shredded tobacco for water pipes gas, the cigarette
Gas condensing unit is used to obtain shredded tobacco for water pipes gas liquefaction natural biological medicine fertilizer.
Specifically, the separation of air from dust device is multiple-stage separator either bag filter, preferably multiple-stage separator.Institute
Stating multiple-stage separator is sequentially connected one cyclonic deduster, second cyclone dust extractor, bag filter.Because rich in organic
The shredded tobacco for water pipes gas of matter can be taken away under certain condition of negative pressure by hot wind, and phosphorus content is high, than great, water content is high, particle is big
Particle sink to the bottom separation, therefore the shredded tobacco for water pipes gas rich in organic matter can be obtained.
It is as follows that the natural biological medicine fertilizer that embodiment 1- embodiment 22 is obtained carries out specific Result of service trial.
1, breeding: the natural biological medicine fertilizer that embodiment 1- embodiment 22 is obtained dilutes 200 times, in Qujing Triratna town vegetable
Dish base impregnates summer yellowish-white seed and sows seeds for 24 hours, impregnates summer yellowish-white seed to more solito phreatic water and sows seeds for 24 hours, imitates
Fruit see the table below (statistical result is averaged):
The natural biological medicine fattening kind test effect statistical form of the invention of table 1
As seen from the above table, the natural biological medicine fertilizer that the present invention obtains can growth-promoting root strong sprout, promote plant growth, effective insect prevention
Sterilization, integrates desinsection, diseases prevention, growth promoting.It is not only able to inhibit pest and disease damage, improves soil, but also have and improve crops
The effect of quality and yield.
2, root dipping: the natural biological medicine fertilizer that embodiment 1- embodiment 22 is obtained dilutes 500 times, in Qujing Triratna town vegetable
Dish base is to summer yellowish-white root dipping, and root dipping, effect not see the table below (statistical result is averaged) for control:
The natural biological medicine fertilizer root dipping test effect statistical form of the invention of table 2
As seen from the above table, natural biological medicine fertilizer of the invention can growth-promoting root strong sprout, promote Effects on Plant Growth.
3, it sprays
3.1, Chinese cabbage: the invention that embodiment 1- embodiment 22 is obtained dilutes 400 times, in Qujing Triratna town Vegetable Base
Spray within 5 days every to yellowish-white growth period in summer it is primary, volume increase dose rate be according to test plot Chinese cabbage total output with compare the white of plot
What dish total output calculated, counting its effect see the table below (statistical result is averaged):
The natural biological medicine fertilizer of the invention of table 3 is to Chinese cabbage spraying test effect statistical form
As seen from the above table, natural biological medicine fertilizer of the invention can promote plant growth, improve fertilizer efficiency, collect desinsection, diseases prevention, rush
Length is integrated, and is not only able to inhibit pest and disease damage, is improved soil, but also has the function of improving crops quality and yield.
3.2, rose: the natural biological medicine fertilizer that embodiment 1- embodiment 22 is obtained dilutes 300 times, in Kunming rich people rose
Planting base sprays three times large area downy mildew rose seedling, and effect see the table below:
The natural biological medicine fertilizer of the invention of table 4 is to rose spraying test effect statistical form
As seen from the above table, natural biological medicine fertilizer energy diseases prevention of the invention has the function of improving economic plants quality.
3.3, tealeaves: the natural biological medicine fertilizer that embodiment 1- embodiment 22 is obtained dilutes 500 times, plants in Pu'er tableland tea
Base sprays once every four days, and effect see the table below:
The natural biological medicine fertilizer of the invention of table 5 is to tealeaves spraying test effect statistical form
As seen from the above table, natural biological medicine fertilizer of the invention, which has, improves the effect of economic plants quality.
3.4, strawberry: the natural biological medicine fertilizer that embodiment 1- embodiment 22 is obtained dilutes 400 times, and in Qujing, thatch seeks strawberry
Planting base is to one mu of powdery mildew and the poor strawberry of growing way sprays three times, and effect see the table below:
The natural biological medicine fertilizer of the invention of table 6 is to strawberry spraying test effect statistical form
| Processing | Disease | Malformed fruit rate % | |
| Reference examples | It does not deal with | Dead seedling 10% | 21 |
| Embodiment 1 | Natural biological medicine fertilizer dilutes 400 times and sprays | It eliminates | Nothing |
| Embodiment 2 | Natural biological medicine fertilizer dilutes 400 times and sprays | It eliminates | Nothing |
| Embodiment 3 | Natural biological medicine fertilizer dilutes 400 times and sprays | It eliminates | Nothing |
| Embodiment 4 | Natural biological medicine fertilizer dilutes 400 times and sprays | It eliminates | Nothing |
| Embodiment 5 | Natural biological medicine fertilizer dilutes 400 times and sprays | It eliminates | Nothing |
| Embodiment 6 | Natural biological medicine fertilizer dilutes 400 times and sprays | It eliminates | Nothing |
| Embodiment 7 | Natural biological medicine fertilizer dilutes 400 times and sprays | It eliminates | Nothing |
| Embodiment 8 | Natural biological medicine fertilizer dilutes 400 times and sprays | It eliminates | Nothing |
| Embodiment 9 | Natural biological medicine fertilizer dilutes 400 times and sprays | It eliminates | Nothing |
| Embodiment 10 | Natural biological medicine fertilizer dilutes 400 times and sprays | It eliminates | Nothing |
| Embodiment 11 | Natural biological medicine fertilizer dilutes 400 times and sprays | It eliminates | Nothing |
| Embodiment 12 | Natural biological medicine fertilizer dilutes 400 times and sprays | It eliminates | Nothing |
| Embodiment 13 | Natural biological medicine fertilizer dilutes 400 times and sprays | It eliminates | Nothing |
| Embodiment 14 | Natural biological medicine fertilizer dilutes 400 times and sprays | It eliminates | Nothing |
| Embodiment 15 | Natural biological medicine fertilizer dilutes 400 times and sprays | It eliminates | Nothing |
| Embodiment 16 | Natural biological medicine fertilizer dilutes 400 times and sprays | It eliminates | Nothing |
| Embodiment 17 | Natural biological medicine fertilizer dilutes 400 times and sprays | It eliminates | Nothing |
| Embodiment 18 | Natural biological medicine fertilizer dilutes 400 times and sprays | It eliminates | Nothing |
| Embodiment 19 | Natural biological medicine fertilizer dilutes 400 times and sprays | It eliminates | Nothing |
| Embodiment 20 | Natural biological medicine fertilizer dilutes 400 times and sprays | It eliminates | Nothing |
| Embodiment 21 | Natural biological medicine fertilizer dilutes 400 times and sprays | It eliminates | Nothing |
| Embodiment 22 | Natural biological medicine fertilizer dilutes 400 times and sprays | It eliminates | Nothing |
As seen from the above table, natural biological medicine fertilizer energy diseases prevention of the invention has and improves the effect of economic plants quality.
3.5, Dictyophora rubrovalvata: the natural biological medicine fertilizer that embodiment 1- embodiment 22 is obtained dilutes 500 times, in natural resources dictyophora phalloidea
Planting base sprays three times large area green mould dictyophora phalloidea, and effect see the table below:
The natural biological medicine fertilizer of the invention of table 7 is to Dictyophora rubrovalvata spraying test effect statistical form
As seen from the above table, the mycosis that natural biological medicine fertilizer of the invention generates mushroom has inhibitory effect, has and promotes
The effect of mushroom yield.
3.6, peppermint: the natural biological medicine fertilizer that embodiment 1- embodiment 22 is obtained dilutes 500 times, in Simao vegetable seed
Phytyl peppermint kind spray twice, effect see the table below:
The natural biological medicine fertilizer of the invention of table 8 is to peppermint spraying test effect statistical form
| Processing | Per mu yield (ton) | Rate of growth % | |
| Reference examples | It does not deal with | 0.48 | |
| Embodiment 1 | Natural biological medicine fertilizer dilutes 500 times and sprays 2 times | 0.71 | 47.2 |
| Embodiment 2 | Natural biological medicine fertilizer dilutes 500 times and sprays 2 times | 0.69 | 44.4 |
| Embodiment 3 | Natural biological medicine fertilizer dilutes 500 times and sprays 2 times | 0.70 | 45.8 |
| Embodiment 4 | Natural biological medicine fertilizer dilutes 500 times and sprays 2 times | 0.69 | 44.4 |
| Embodiment 5 | Natural biological medicine fertilizer dilutes 500 times and sprays 2 times | 0.71 | 47.2 |
| Embodiment 6 | Natural biological medicine fertilizer dilutes 500 times and sprays 2 times | 0.69 | 44.4 |
| Embodiment 7 | Natural biological medicine fertilizer dilutes 500 times and sprays 2 times | 0.70 | 45.8 |
| Embodiment 8 | Natural biological medicine fertilizer dilutes 500 times and sprays 2 times | 0.70 | 45.8 |
| Embodiment 9 | Natural biological medicine fertilizer dilutes 500 times and sprays 2 times | 0.69 | 44.4 |
| Embodiment 10 | Natural biological medicine fertilizer dilutes 500 times and sprays 2 times | 0.70 | 45.8 |
| Embodiment 11 | Natural biological medicine fertilizer dilutes 500 times and sprays 2 times | 0.69 | 44.4 |
| Embodiment 12 | Natural biological medicine fertilizer dilutes 500 times and sprays 2 times | 0.71 | 48.6 |
| Embodiment 13 | Natural biological medicine fertilizer dilutes 500 times and sprays 2 times | 0.71 | 47.2 |
| Embodiment 14 | Natural biological medicine fertilizer dilutes 500 times and sprays 2 times | 0.69 | 44.4 |
| Embodiment 15 | Natural biological medicine fertilizer dilutes 500 times and sprays 2 times | 0.70 | 45.8 |
| Embodiment 16 | Natural biological medicine fertilizer dilutes 500 times and sprays 2 times | 0.71 | 47.2 |
| Embodiment 17 | Natural biological medicine fertilizer dilutes 500 times and sprays 2 times | 0.71 | 48.6 |
| Embodiment 18 | Natural biological medicine fertilizer dilutes 500 times and sprays 2 times | 0.69 | 44.4 |
| Embodiment 19 | Natural biological medicine fertilizer dilutes 500 times and sprays 2 times | 0.71 | 47.2 |
| Embodiment 20 | Natural biological medicine fertilizer dilutes 500 times and sprays 2 times | 0.69 | 44.4 |
| Embodiment 21 | Natural biological medicine fertilizer dilutes 500 times and sprays 2 times | 0.70 | 45.8 |
| Embodiment 22 | Natural biological medicine fertilizer dilutes 500 times and sprays 2 times | 0.71 | 47.2 |
Seen by upper table, natural biological medicine fertilizer of the invention can promote plant growth, effect of increasing production.
Effect corresponding to the concentration of natural biological medicine fertilizer of the invention when in use are as follows: high concentration: it is diluted to 200~
It 400 times, is used when sterilizing expelling parasite, inhibiting pest and disease damage, effect becomes apparent from；Middle concentration: it is diluted to 400-500 times, often
Warm conventional use；Low concentration: 500~600 times are diluted to, is used when growth-promoting root, germination, effect becomes apparent from.
Natural biological medicine of the invention is fertile, has synergistic function between component, is that one kind can be improved plant certainly
Body immune function promotes plant absorption, adjusts plant metabolism, keep soil activation, improve crop quality and resistance, do not generate
Agriculture is residual, ensures the new type natural biological medicine fertilizer of agricultural product quality.
Finally it should be noted that the above embodiments are merely illustrative of the technical solutions of the present invention, rather than the present invention is protected
The limitation of range is protected, although explaining in detail referring to preferred embodiment to the present invention, those skilled in the art are answered
Work as understanding, it can be with modification or equivalent replacement of the technical solution of the present invention are made, without departing from the reality of technical solution of the present invention
Matter and range.
Claims (10)
1. a kind of natural biological medicine fertilizer, which is characterized in that the component including following content: acetic acid 8-52%, formic acid 1-4.3%,
Propionic acid 0.6-3.2%, hydroxypropanone- 0.02-0.1%, isoquinolin 0.4-2%, guaiacol 0.2-0.9%, paracresol 0.8-
2.3%, metacresol 0.3-1.8%, surplus is water.
2. natural biological medicine fertilizer according to claim 1, which is characterized in that further include the component of following content: 2,4,6-
Trimethylpyridine 0.08-1.2%, 2 amino -5- methyl benzoic acid 0.8-3.9%, butyric acid 0.08-0.6%, crotonic acid 0.05-
0.3%.
3. natural biological medicine fertilizer according to claim 1, which is characterized in that further include the component of following content: quinoline
0.08-2.2%, 2,7- dimethyl quinoline 0.2-2.2%, acetamide 0.08-0.9%, gamma-butyrolacton 0.06-0.7%.
4. natural biological medicine fertilizer according to claim 3, which is characterized in that further include the component of following content: micro member
Plain 0.06-0.08%, nitrate nitrogen 4-6%.
5. natural biological medicine fertilizer according to claim 1 to 4, which is characterized in that the component of the natural biological medicine fertilizer
It is detected with content using chromatographic mass spectrometry translocation method.
6. -5 any natural biological medicine fertilizer according to claim 1, which is characterized in that added in the natural biological medicine fertilizer
There are one of humic acid, amino acid, a great number of elements, moderate-element or microelement or appoints several.
7. the application method of -6 any natural biological medicine fertilizer according to claim 1, which is characterized in that by natural biological medicine
Fertilizer is diluted to 200~600 times, and dilution is impregnated seed, root dipping, trickle irrigation, the heart is poured or sprays.
8. a kind of preparation method of natural biological medicine fertilizer, which is characterized in that together by 500-1400 DEG C of high-temperature flue gas and lignite
It is passed through in the space of hypoxemia high negative pressure, makes brown coal powder drying and dehydrating, shredded tobacco for water pipes gas is drawn, condensed water flue gas obtains natural biological medicine
Fertilizer.
9. the preparation method of natural biological medicine fertilizer according to claim 8, which is characterized in that in above-mentioned natural biological medicine fertilizer
Middle addition humic acid makes its humic acid content be more than or equal to 3%；
Or amino acid is added in above-mentioned natural biological medicine fertilizer, so that its free aminoacid content is more than or equal to 10%；
Or a great number of elements is added in above-mentioned natural biological medicine fertilizer, so that its a great number of elements total amount is more than or equal to 50%；
Or moderate-element is added in above-mentioned natural biological medicine fertilizer, so that its moderate-element total amount is more than or equal to 100 grams/L；
Or microelement is added in above-mentioned natural biological medicine fertilizer, the microelement total amount for calculating it based on the element is more than or equal to
10%.
10. the preparation method of natural biological medicine fertilizer according to claim 8, which is characterized in that by 700-1200 DEG C of height
Warm flue gas and lignite are passed through oxygen content less than 12% together, and negative pressure is in the space of -100~-6000Pa；
The method of condensed water flue gas is that water flue gas condensing is directly obtained natural biological medicine fertilizer by condensing plant；Or it successively holds
Row following steps: then liquefaction shredded tobacco for water pipes gas first carries out centrifugal treating and filtration treatment, filtrate is finally carried out revolving and is handled
To natural biological medicine fertilizer.
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