CN109497083B - Medicament for removing flying cotton and fly of plants and application thereof - Google Patents

Medicament for removing flying cotton and fly of plants and application thereof Download PDF

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CN109497083B
CN109497083B CN201811464368.8A CN201811464368A CN109497083B CN 109497083 B CN109497083 B CN 109497083B CN 201811464368 A CN201811464368 A CN 201811464368A CN 109497083 B CN109497083 B CN 109497083B
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plant
medicament
mass
flying
plants
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CN109497083A (en
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任桂芳
李广
王建红
车少臣
张国锋
仲丽
邵金丽
仇兰芬
夏菲
任斌斌
刘倩
周江鸿
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BEIJING INSTITUTE OF LANDSCAPE ARCHITECTURE
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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/28Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
    • A01N47/36Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< directly attached to at least one heterocyclic ring; Thio analogues thereof
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01GHORTICULTURE; CULTIVATION OF VEGETABLES, FLOWERS, RICE, FRUIT, VINES, HOPS OR SEAWEED; FORESTRY; WATERING
    • A01G7/00Botany in general
    • A01G7/06Treatment of growing trees or plants, e.g. for preventing decay of wood, for tingeing flowers or wood, for prolonging the life of plants
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N33/00Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds
    • A01N33/02Amines; Quaternary ammonium compounds
    • A01N33/12Quaternary ammonium compounds
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/06Unsaturated carboxylic acids or thio analogues thereof; Derivatives thereof
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/10Aromatic or araliphatic carboxylic acids, or thio analogues thereof; Derivatives thereof
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/40Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/501,3-Diazoles; Hydrogenated 1,3-diazoles
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/561,2-Diazoles; Hydrogenated 1,2-diazoles
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
    • A01N43/647Triazoles; Hydrogenated triazoles
    • A01N43/6531,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/90Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/10Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
    • A01N47/20N-Aryl derivatives thereof
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/28Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
    • A01N47/38Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< where at least one nitrogen atom is part of a heterocyclic ring; Thio analogues thereof

Abstract

The invention relates to a medicament for removing plant flying cotton and fly, which comprises the following raw medicines in parts by weight: plant growth regulator: plant fruit thinning agent: the herbicide is (1-10): (1-10): (5-100), the plant growth regulator comprises one or more of forchlorfenuron, 6-benzyladenine, paclobutrazol, uniconazole, 2, 4-dichlorophenoxyacetic acid, triiodobenzoic acid, 2-chloroethyltrimethylammonium chloride and cycloheximide, the plant thinning agent comprises one or more of indate and chlorpropham, and the herbicide comprises one or more of sulfonylurea herbicide, imidazolinone herbicide and triazolopyrimidine herbicide; can inhibit the growth and development of flower buds of plants such as poplar, willow, plane and the like, thereby having the effect of preventing and treating flying cotton wool. The invention also relates to the application of the medicament in the plant flying-cotton lint removal, which is used for applying medicament to plants in an injection mode or a spraying mode to achieve the purposes of inhibiting the expansion of plant flower buds and preventing and treating flying-cotton lint.

Description

Medicament for removing flying cotton and fly of plants and application thereof
Technical Field
The invention relates to the technical field of plant flying cotton fly removal, in particular to a medicament for removing plant flying cotton fly and application thereof.
Background
The flying catkin of plants such as poplar, willow and the like is an attachment of seeds of plants such as poplar, willow and the like, and the flying catkin can fly with wind to play a role in helping seeds to spread and disperse, so that the flying catkin pollution is caused. The harm is mainly reflected in three aspects: firstly, the flying cotton fibers are easy to wrap harmful substances such as pollutant particles, heavy metals and the like, and are easy to cause discomfort and even inflammation after contacting with the skin of citizens, so that skin allergy of allergic people is caused; meanwhile, the catkins are easy to be inhaled into nostrils, so that respiratory diseases such as asthma, chronic bronchitis and the like are aggravated, and the health of citizens is damaged. Secondly, the flying wadding often blocks the radiator fin of the automobile water tank to cause the boiling pot to extinguish, and can also shield the sight of pedestrians and vehicles, thereby causing influence on traffic safety and public safety. Thirdly, the flying wadding is easy to cause fire when contacting open fire, thereby bringing hidden danger to public safety. Therefore, the flying-floc problem of plants such as salix populi becomes a focus and a hot point of social attention, and concerns the vital interests of people, and the public has high call for the control of the flying-floc of salix populi.
The sycamore is an important street tree species in south China, is widely planted in north, is heavily shaded and has a tall plant shape, but a large amount of fruit hairs can be scattered every year in the fruit drop period of the sycamore, and serious influence is caused on the environment and human health. According to statistics, the mean of 200-.
Therefore, the search for a chemical or method capable of preventing flying cotton wool of plants such as poplar, willow and tabebuia avellanedae is a problem to be solved by those skilled in the art.
Disclosure of Invention
Aiming at the defects in the prior art, the first purpose of the invention is to provide a medicament for thinning plant catkin fly hair, which can inhibit the growth and development of flower buds of plants such as poplar, willow, plane.
The first purpose of the invention is realized by the following technical scheme:
a medicament for thinning plant flying cotton and fly comprises the following raw medicines in parts by weight: the plant growth regulator comprises one or more of forchlorfenuron, 6-benzyladenine, paclobutrazol, uniconazole, 2, 4-dichlorophenoxyacetic acid, triiodobenzoic acid, 2-chloroethyltrimethylammonium chloride and cycloheximide, the plant fruit thinning agent comprises one or more of indate and chlorpropham, and the herbicide comprises one or more of sulfonylurea herbicides, imidazolinone herbicides and triazolopyrimidine herbicides.
By adopting the technical scheme, the forchlorfenuron (3-isopropyl chlorocarbamate) is a phenylurea plant growth regulator with cytokinin activity, has the biological activity 10-100 times higher than that of 6-benzylaminopurine, is widely applied to agriculture, horticulture and fruit trees, promotes cell division and promotes cell expansion and elongation. 6-benzyladenine (6-benzzylaminopurine) and forchlorfenuron (1- (2-chloro-4-pyridine) -3-phenylurea) belong to plant growth regulators with the same effect. The naphthylacetic acid (1-naphthylacetic acid) is applied to flower production, can promote flower growth, control plant type, induce flowering and fruiting, prevent flowering diseases and prevent falling, and can also obviously improve planting benefits. Paclobutrazol ((2RS, 3RS) -1- (4-chlorphenyl) -4, 4-dimethyl-2- (1H-1, 2, 4-triazole-1-yl) pentan-3-ol) is a plant growth regulator, and has the effects of delaying plant growth, inhibiting stem elongation, shortening internode, promoting plant tillering and increasing plant stress resistance. Uniconazole ((E) - (RS) -1- (4-chlorphenyl) -4, 4-dimethyl-2- (1H-2, 4-triazole-1-yl) pent-1-en-3-ol) belongs to a broad-spectrum and high-efficiency plant growth regulator, has the effects of controlling vegetative growth, inhibiting cell elongation, shortening internodes, dwarfing plants, promoting lateral bud growth and flower bud formation and enhancing stress resistance, has the activity 6-10 times higher than that of the uniconazole, but has the residue of 1/10 of the paclobutrazol in soil. 2, 4-Dichlorophenoxyacetic acid is a representative synthetic auxin (auxin), an auxin analog, 2, 4-D for short. Triiodobenzoic acid, 2-chloroethyl trimethyl ammonium chloride and cycloheximide (3- [2- (3, 5-dimethyl-2-oxocyclohexyl) -2-hydroxyethyl ] glutarimide) all belong to anti-auxin, prevent the polar transportation of auxin in plants from top to bottom, are easy to be absorbed by plants, can be transported in stems, influence the growth and development of the plants, inhibit the top growth of the plants, dwarf the plants and promote the growth of lateral buds and tillers. The indole ester (ethyl-5-chloro-1 hydro-3-indolylacetic acid) and the chlorpropham (3-chloroisopropyl carbamate) are vegetable and fruit agents, belong to auxin inhibitory substances and can obtain expected effects by inhibiting the growth of plant organs. Sulfonylurea herbicides, imidazolinone herbicides and triazolopyrimidine herbicides all belong to ALS inhibitors, which disrupt the synthesis of valine, leucine and isoleucine in plants by inhibiting the ALS enzyme (acetolactescence synthase), and are safe to humans and animals since this target is not involved. The ALS enzyme, also known as acetohydroxy acid synthetase (AHAS), is a key enzyme in branched chain amino acid synthesis; catalyzing two molecules of pyruvic acid to generate acetolactate and carbon dioxide in the synthesis of valine and leucine, and catalyzing one molecule of pyruvic acid and one molecule of ketobutyric acid to generate 2-glyoxal-2-hydroxybutyric acid and carbon dioxide in the synthesis of isoleucine; biochemistry, genetics and field practice have proven to be an important herbicide target; if the ALS enzyme activity is inhibited, the synthesis of branched chain amino acid is hindered, and the protein synthesis and the plant growth are further influenced; during the growth of plants, flower organs require more ALS activity than the vegetative organs of plants, i.e. flower organs are more sensitive to low doses of ALS inhibitors, so that this type of agent has an effect on the flower organs of plants only in a certain dosage range and does not cause phytotoxicity to the normal vegetative growth of plants. In conclusion, the components in the raw pesticide are the agents with the effect of removing the flying cotton of the plants, and the agents are compounded with the auxiliary agents to form the agent of the invention, so that the effect of removing the flying cotton of the plants is realized.
Preferably, the sulfonylurea herbicides include 3- (4, 6-dimethoxypyrimidin-2-yl) -1- (2-methoxyformylbenzyl) sulfonylurea, 3- (4-methoxy-6-methyl-1, 3, 5-triazin-2-ylcarbamoylsulfamoyl) thiophene-2-carboxylic acid, methyl 2- [ 4-methoxy-6-methyl-1, 3, 5-triazin-2-yl (methyl) carbamoylsulfamoyl ] benzoate, 2- (4, 6-dimethoxy-2-pyrimidylcarbamoylsulfamoyl) -N, N-dimethylnicotinamide, 5- (4, 6-dimethyloxypyrimidin-2-ylcarbamoylsulfamoyl-1-methylcarbamoylsulfamoyl) -1-methylcarbamoylsulfonyl Pyrazole-4-carboxylic acid ethyl ester, 1- (4, 6-dimethoxypyrimidin-2-yl) -3- (3-trifluoromethyl-2-pyridinesulfonyl) urea, 1- (4, 6-dicarbamimidol-2-yl) -3- (3-ethylthio-2-pyridylthio) urea, 2- (4, 6-dimethoxypyrimidin-2-ylaminocarbonylaminosulfonyl) -a- (methanesulfonamido) p-methylbenzoate.
By adopting the technical scheme, the structural formula of the sulfonylurea herbicide is shown as
Figure BDA0001888224660000031
Wherein R can be Cl, COOH or CO2CH3、SO2CH2CH3、CH2CF3、CF3、OCH2Cl、OCH3、 OCH2CF3、NO2、OCH2CH3、O(CH2)2OCH3、O(CH2)2C1、COOC2H5、CON(CH3)2(ii) a X may be CH3、CL、OCH3、CHOF2、NHCH3、N(CH3)2、CF3、SCH3(ii) a Y may be OCH3、CH3、Cl、 CHOF2、OC2H5、OCH2CF3. This herbicide is safe to humans and animals since it disrupts valine, leucine and isoleucine synthesis in plants by inhibiting the ALS enzyme (acetolactesynthase), and this target is not involved in humans and animals. The research on the application of the plant fly-away feather removing agent to the plant fly-away feather is not found.
Preferably, the imidazolinone herbicide is 2- [4, 5-dihydro-4-methyl-4- (1-methylethyl) -5-oxo-1H-imidazol-2-yl ] -5-ethyl-3-pyridinecarboxylic acid.
By adopting the technical scheme, the imidazolinone herbicide has the structural formula:
Figure BDA0001888224660000032
wherein A is-COOH, X is N, and R1 and R2 are methyl and isopropyl, respectively. 2- [4, 5-dihydro-4-methyl-4- (1-methylethyl) -5-oxo-1H-imidazol-2-yl ] -5-ethyl-3-pyridinecarboxylic acid, also known as Imazethapyr, is a highly effective herbicide of the imidazoiinone class, acting by inhibiting the ALS enzyme, being absorbed by the roots and leaves of weeds, conducted in the plant, causing weeds to stop growing and then die. The research and the application of the plant flying cotton and fly wool in the aspect of thinning and removing are not found.
Preferably, the triazolopyrimidine herbicide is 2 ', 6' -difluoro-5-methoxy-8-fluoro [1, 2, 4] triazolo [1, 5-c ] pyrimidine-2-sulfonanilide.
By adopting the technical scheme, the 2 ', 6' -difluoro-5-methoxy-8-fluoro [1, 2, 4] triazolo [1, 5-c ] pyrimidine-2-sulfonanilide, also known as florasulam (florasulam), is a systemic conduction type herbicide and can be conducted to the whole weed, so that the weed is thoroughly killed without relapse. The florasulam has a wide herbicidal spectrum, can prevent and kill most broad-leaved weeds in wheat fields, including cleavers (Rubiaceae), mai-jia (Boraginaceae) and other difficult-to-prevent weeds, and has a very good inhibiting effect on euphorbia helioscopia (Euphorbiaceae) which is the most difficult-to-prevent weeds in the wheat fields. The research and the application of the plant flying cotton and fly wool in the aspect of thinning and removing are not found.
Preferably, the dosage form of the medicament is: wettable powder, water dispersible granules, suspending agents, micro-emulsions, micro-capsule suspending agents, aqueous solutions, aqueous emulsions or missible oils.
By adopting the technical scheme, the medicament is prepared into various dosage forms, different dosage forms can be selected according to different application occasions and environments, the application range is wider, and the applicability is stronger.
The second purpose of the invention is to provide the application of the medicament for thinning plant flying cotton and fly in the thinning of plant flying cotton and fly, so that the flying cotton of willow, poplar, sycamore and other plants can be thinned, the fruits of the plants can not normally grow and fall off, and the effect of thinning, preventing and controlling is achieved.
The second purpose of the invention is realized by the following technical scheme:
the application of a medicament for removing plant flying cotton and fly is to spray the medicament on leaves of a plant in a spraying way, wherein the spraying time is from the beginning of the bud period or inflorescence expanding period of the plant to the beginning of the flowering period or the beginning of the elongation of the inflorescence, the pesticide application is stopped, 0.2g/L-20g/L of the medicament is sprayed on the leaves for 1-2 times, and the pesticide application interval is less than 15 days; wherein, 0.2g/L-20g/L is the concentration of the spray solution after the medicament is diluted.
Preferably, the medicament is injected into the trunk of the plant by an injection mode according to the injection concentration of 0.1g/cm-5g/cm breast diameter, the application time is from the beginning of the bud period or the inflorescence expanding period of the plant to the beginning of the flowering period or the beginning of the elongation of the inflorescence, the application is carried out for 1-2 times, and the application interval is less than 15 days.
By adopting the technical scheme, the plant to be thinned and removed of the flying cotton and the flying hair enters the budding period or the inflorescence expanding period in a spraying or injection mode until the plant enters the initial flowering period or the inflorescence begins to extend, so that the plant fruits can not normally develop and fall off, the control effect is good, and the plant self-growth is safe and harmless. The pesticide application operation is simple, and is convenient for basic greening workers to master and implement, thereby facilitating large-scale popularization and use.
The medicament for thinning out plant flying cotton and fly has the action mechanism of inhibiting the growth of plant flower buds to inhibit the formation of flying cotton and fly or fruit hairs, so the medicament is applied to the poplar and willow at the beginning of the flowering bud expansion period when the flower buds enter the inflorescence expansion period and the plant begins to elongate after entering the inflorescence, and the aim is achieved. When the plants such as the poplar, the sycamore and the like enter an inflorescence expanding period or a bud period, the pesticide is injected into a trunk or sprayed onto leaves, the pesticide is diffused to each part of the tree along with plant transpiration and leaf absorption, the flower bud development of the tree is inhibited, fruits are aborted or cannot grow normally and fall flowers and fruits, and the pollution and harm caused by flying cotton wool or fruit wool are reduced.
In conclusion, the invention has the following beneficial effects:
(1) the flying-cotton-like hair or fruit hair treatment period is controlled to be in the flower bud development period by inhibiting the development of plant flower buds to cause fruit abortion or the fruit falling due to abnormal growth and development, so that the flying-cotton-like hair or fruit hair treatment period is fundamentally solved;
(2) all the components of the medicament are beneficial and harmless to plant growth, and only have an inhibiting effect on flower bud development; while inhibiting the flower bud development, the nutrient consumption of the plant in the aspect of reproductive organ growth can be relatively reduced, so that more nutrients are used for plant growth, and the plant growth vigor is better;
(3) the preparation is prepared into different dosage forms, the application method is simple, and the greening personnel can conveniently master and implement the application method;
(4) the pesticide has obvious effect of preventing flying cotton and flying wool, and the prevention and control rate is over 90 percent when the spraying concentration is more than 2 g/L.
Detailed Description
The medicament of the invention can be prepared into dosage forms such as wettable powder, water dispersible granules, suspending agents, micro-emulsion, microcapsule suspending agents, aqueous solutions, aqueous emulsions or missible oils and the like by assisting with an auxiliary agent according to the weight percentage of 5-25% of a raw medicament, 10-30% of a solvent, 1-15% of an emulsifier, 1-15% of a dispersant and 1-8% of a wetting agent and supplementing the carrier to 100%, wherein the solvent is selected from ethanol, methanol, toluene, xylene, acetone, acetonitrile, ethyl acetate, cyclohexanone and the like; the emulsifier is selected from agricultural emulsion series (calcium dodecyl benzene sulfonate), NP series (nonylphenol polyoxyethylene ether phosphate), EL series (castor oil polyoxyethylene ether), AEO series (fatty alcohol polyoxyethylene ether), sodium polyacrylate, styrene-maleic anhydride, etc.; the dispersant is selected from sodium tripolyphosphate, sodium hexametaphosphate, sodium lignosulfonate, naphthalene sulfonate formaldehyde condensate and the like; the wetting agent is selected from benzene cumic powder, fructus Gleditsiae Abnormalis powder, SOPA (alkylphenol formaldehyde resin polyoxyethylene ether) (230, 235, 270), washing powder, and sodium dodecyl benzene sulfonate; the carrier is selected from diatomite, pottery clay, attapulgite, kaolin, activated clay, light calcium carbonate, white carbon black, etc. The method for preparing different dosage forms by using different auxiliary agents and solvents in an auxiliary manner is a conventional technical means, is not in the protection range of the invention, and is not repeated herein. The following description will be given only by taking a representative wettable powder of the present invention as an example.
Example 1
6-benzyladenine, indrical ester, 2- (4, 6-dimethoxy-2-pyrimidyl carbamoylamino sulfonyl) -N, N-dimethyl nicotinamide are mixed and stirred evenly according to the proportion of 1: 2: 3, and 75 percent of ethanol, 80 percent of castor oil polyoxyethylene ether, 130 percent of diatomite, 70 percent of sodium hexametaphosphate and 35 percent of sodium dodecyl benzene sulfonate which are equal in mass to the total amount of the raw medicaments, are used as auxiliary materials, and then the mixture is crushed to obtain the wettable powder A.
Example 2
Forchlorfenuron, chlorpropham, 2- [ 4-methoxy-6-methyl-1, 3, 5-triazine-2-yl (methyl) carbamic acid sulfamoyl ] methyl benzoate are mixed and stirred uniformly according to the proportion of 1: 5, and 75% of ethanol, 80% of castor oil polyoxyethylene ether, 130% of diatomite, 70% of sodium hexametaphosphate and 35% of sodium dodecyl benzene sulfonate are added in an auxiliary manner, wherein the mass of the ethanol is equal to that of the total amount of raw medicaments, and the sodium dodecyl benzene sulfonate is crushed to obtain the medicament B of wettable powder.
Example 3
Mixing and stirring naphthylacetic acid, Indocusate and 2- [4, 5-dihydro-4-methyl-4- (1-methylethyl) -5-oxo-1H-imidazole-2-yl ] -5-ethyl-3-pyridine carboxylic acid according to the proportion of 1: 10, and adding 75% of ethanol, 80% of castor oil polyoxyethylene ether, 130% of diatomite, 70% of sodium hexametaphosphate and 35% of sodium dodecyl benzene sulfonate into the mixture, wherein the ethanol, the castor oil polyoxyethylene ether, the diatomite, the sodium hexametaphosphate and the sodium dodecyl benzene sulfonate are uniformly mixed, and then crushing to obtain a medicament C of wettable powder.
Example 4
Uniconazole, indrilate, 3- (4, 6-dimethoxypyrimidine-2-yl) -1- (2-methoxy formyl benzyl) sulfonylurea are mixed fully and stirred uniformly according to the proportion of 2: 1: 5, and 75 percent of ethanol, 80 percent of castor oil polyoxyethylene ether, 130 percent of diatomite, 70 percent of sodium hexametaphosphate and 35 percent of sodium dodecyl benzene sulfonate which are equal in mass and total amount of raw materials are added in an auxiliary manner, and then the mixture is crushed to obtain a medicament D of wettable powder.
Example 5
The preparation method comprises the following steps of fully mixing and uniformly stirring paclobutrazol, chlorpropham, 3- (4-methoxy-6-methyl-1, 3, 5-triazine-2-yl carbamoylsulfamoyl) thiophene-2-carboxylic acid according to the proportion of 10: 1: 5, and adding 75% of ethanol, 80% of castor oil polyoxyethylene ether, 130% of diatomite, 70% of sodium hexametaphosphate and 35% of sodium dodecyl benzene sulfonate which are equal in mass to the total amount of a raw material, wherein the ethanol, the castor oil polyoxyethylene ether, the diatomite and the sodium dodecyl benzene sulfonate are equal in mass to the total amount of the raw material, and then crushing to obtain a medicament E of wettable powder.
Example 6
2, 4-dichlorophenoxyacetic acid, 2 ', 6' -difluoro-5-methoxy-8-fluoro [1, 2, 4] triazolo [1, 5-c ] pyrimidine-2-sulfonanilide are mixed and stirred evenly according to the proportion of 1: 15, and 75 percent of ethanol, 80 percent of castor oil polyoxyethylene ether, 130 percent of diatomite, 70 percent of sodium hexametaphosphate and 35 percent of sodium dodecyl benzene sulfonate which are equal in mass to the total amount of the raw medicament are added as auxiliary materials, and then the mixture is crushed to obtain the medicament F of wettable powder.
Example 7
Triiodobenzoic acid, indate, 1- (4, 6-dimethoxypyrimidin-2-yl) -3- (3-trifluoromethyl-2-pyridinesulfonyl) urea, 1- (4, 6-dicaroxopyrimidin-2-yl) -3- (3-ethylthio-2-pyridylthio) urea are mixed and stirred uniformly in a sufficient way, and then crushed to obtain a medicament G of wettable powder, wherein the ratio of the triiodobenzoic acid to the indate to the 1: 50 is assisted by 75% of ethanol, 80% of castor oil polyoxyethylene ether, 130% of kieselguhr, 70% of sodium hexametaphosphate and 35% of sodium dodecyl benzene sulfonate which are equal to the total amount (mass) of the raw medicaments in a ratio of 1: 50.
Example 8
Fully mixing and stirring 2-chloroethyltrimethylammonium chloride, indole ester, 2- (4, 6-dimethoxypyrimidine-2-ylcarbamoyl-a- (methylsulfonamido) p-methyl benzoate, 75% of ethanol, 80% of castor oil polyoxyethylene ether, 130% of diatomite, 70% of sodium hexametaphosphate and 35% of sodium dodecyl benzene sulfonate according to the mass ratio of 3: 1: 10, wherein the mass ratio of the ethanol to the total amount of the raw materials is equal to that of the raw materials, and then crushing to obtain the medicament H of wettable powder.
Example 9
The method comprises the following steps of fully mixing and uniformly stirring cycloheximide, forchlorfenuron, 5- (4, 6-dimethyloxypyrimidine-2-yl carbamoyl sulfamoyl-1-methylpyrazole-4-ethyl formate, 75% of ethanol, 80% of castor oil polyoxyethylene ether, 130% of diatomite, 70% of sodium hexametaphosphate and 35% of sodium dodecyl benzene sulfonate according to the mass ratio of 5: 10: 100, wherein the mass ratio of the ethanol to the total amount of a raw medicament is equal to that of the raw medicament, and the sodium dodecyl benzene sulfonate is 35% of the total amount of the raw medicament, and then crushing to obtain the medicament H of wettable powder.
Example 10
The method comprises the following steps of fully mixing and uniformly stirring cycloheximide, forchlorfenuron and 1- (4, 6-dimethoxypyrimidin-2-yl) -3- (3-ethylthio-2-pyridylthio) urea in a ratio of 5: 3: 10, and adding 75% by mass of ethanol, 80% by mass of castor oil polyoxyethylene ether, 130% by mass of diatomite, 70% by mass of sodium hexametaphosphate and 35% by mass of sodium dodecyl benzene sulfonate into the mixture, and then crushing the mixture to obtain the wettable powder medicament I.
Test example 1
The test tree is the populus tomentosa in the north-Xiaohe park in Beijing, the medicament A prepared in the example 1 is diluted into the spray dosage with the concentration of the spray liquid of 0.2g/L-20g/L in a daily spray mode of 3 months and 23 months in 2017, and is sprayed on the leaves of female plants of the populus tomentosa, and the medicament is uniformly sprayed on the front and back surfaces of the leaves until the leaves are wet. The application is carried out once again when the populus tomentosa is in the full bloom stage in 12 months in 2017. Three groups of 12 branches with the length of about 30cm are randomly selected from the control (i.e. the Chinese white poplar without pesticide application) and the test Chinese white poplar in the four directions of the upper part, the middle part, the lower part, the south east and the north west of the Chinese white poplar, the number of buds on each branch and the number of fruit abortion and non-abortion on inflorescence of the control and test Chinese white poplar are investigated, the number of fruit abortion and non-abortion on inflorescence of each branch is calculated, the control rate of the medicament on the fruit abortion on the inflorescence of a female plant of the Chinese white poplar is used as the flying-floc control rate, and the test results are shown in table 1.
The flying catkin prevention and control rate is (average number of fruitless abortion per branch of control tree/total number of fruits-average number of fruitless abortion per branch of test tree/total number of fruits)/average number of fruitless abortion per branch of control tree/total number of fruits 100%
TABLE 1 control results of drug A on flying-catkin of Populus tomentosa
Figure BDA0001888224660000071
Figure BDA0001888224660000081
As can be seen from the control result data in the table 1, the control effect of the medicament A on the flying-feather of the populus tomentosa is good, and the inhibition rate of the medicament A on the flying-feather of the populus tomentosa can reach 57.32-98.25% when the medicament A is applied to the leaves of the populus tomentosa according to the spray concentration of 0.2-20 g/L. Meanwhile, the inhibition rate of the medicament A on the flying-floc of the Chinese white poplar is obviously improved along with the increase of the spray concentration.
Test example 2
The test tree is populus tomentosa in the north-Xiaohe park in Beijing, and the trunk of the steamed bread willow is injected once by the dose of the chest diameter shown in the table 2 through a high-pressure injector (can also be a bottle insert or a hanging bottle) of 0.11-0.55MPa in an injection mode in 3 and 20 days in 2017. The application of the medicine is carried out once when the steamed bread willow is in the full-bloom stage in last 4 months of 2017, and the interval between the two application of the medicine is less than 15 days. Repeating three times in the four directions of the upper, middle, lower, southeast, northwest of a control (steamed bread willow without injection operation) and a test plant, randomly taking 12 branches with the length of about 30cm to obtain three groups, investigating the number of buds on each branch of the control and the test Chinese white poplar and the number of abortive and non-abortive fruits on inflorescence, calculating the number of abortive and non-abortive fruits on inflorescence of each branch, and aborting the fruits on inflorescence of a female plant of the Chinese white poplar by using a medicament.
The dosage of the medicine is determined according to the diameter at breast height when the medicine is injected and used, and for the willow trees with different diameter at breast height, the effect is relatively consistent as long as the unit dosage (namely the dosage per cm diameter at breast height) is determined, so that the medicine effect of the willow trees with different diameter at breast height does not need to be distinguished. The steamed bread willow with the diameter at breast height of 25cm is taken as an example for medicine application detection, and specific prevention and control results are shown in table 2.
TABLE 2 preventive and therapeutic effects of the agent B on flying wool of steamed bread willow
Figure BDA0001888224660000091
As can be seen from the data in Table 2, the medicament B has good control effect on the flying floc of the steamed bread willow. The medicament B is injected into the steamed bread willow according to the injection dosage of 0.1g/cm-5g/cm, and the inhibition rate of flying cotton and flying wool of the steamed bread willow reaches 59.38% -95.67%. Meanwhile, the inhibition rate of the medicament B on the flying catkin of the steamed bun is obviously improved along with the increase of the injection dosage.
The present embodiment is only for explaining the present invention, and it is not limited to the present invention, and those skilled in the art can make modifications of the present embodiment without inventive contribution as needed after reading the present specification, but all of them are protected by patent law within the scope of the claims of the present invention.

Claims (5)

1. The medicament for thinning plant flying cotton and fly is characterized by comprising the following raw medicaments in part by weight: 6-benzyladenine, indole ripester, 2- (4, 6-dimethoxy-2-pyrimidylaminocarbamoyl sulfamoyl) -N, N-dimethylnicotinamide at a ratio of 1: 2: 3, 75% ethanol by mass of the total amount of raw medicines (mass), 80% castor oil polyoxyethylene ether by mass of the total amount of raw medicines, 130% diatomite by mass of the total amount of raw medicines, 70% sodium hexametaphosphate by mass of the total amount of raw medicines, and 35% sodium dodecyl benzene sulfonate by mass of the total amount of raw medicines;
or comprises forchlorfenuron, chlorpropham, methyl 2- [ 4-methoxy-6-methyl-1, 3, 5-triazine-2-yl (methyl) carbamate sulfamoyl ] benzoate in a ratio of 1: 5, 75% of ethanol in mass, 80% of castor oil polyoxyethylene ether in mass, 130% of diatomite in mass, 70% of sodium hexametaphosphate in mass and 35% of sodium dodecyl benzene sulfonate in mass.
2. The agent for thinning plant flying feathers according to claim 1, wherein the agent is in the form of: wettable powder, water dispersible granules, suspending agents, micro-emulsions, micro-capsule suspending agents, aqueous solutions, aqueous emulsions or missible oils.
3. Use of an agent for repelling plant lint according to any one of claims 1 to 2 for repelling plant lint.
4. Use according to claim 3, characterized in that: spraying the medicament on leaves of the plants in a spraying manner, wherein the spraying time is from the bud stage or the inflorescence expanding stage of the plants to the initial flowering stage or the inflorescence elongation stage, the pesticide application is stopped, and 0.2g/L-20g/L of the medicament is sprayed on the leaves for 1-2 times, and the pesticide application interval is less than 15 days; wherein, 0.2g/L-20g/L is the concentration of the spray solution after the medicament is diluted.
5. Use according to claim 3, characterized in that: injecting the medicament into the trunk of the plant by an injection mode according to the injection concentration of 0.1g/cm-5g/cm, wherein the application time is 1-2 times from the bud stage or the inflorescence expanding stage of the plant to the initial flowering stage or the inflorescence elongation stage of the plant, and the interval is less than 15 days.
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