CN109467491A - A kind of flame retardant of pyrotechnic composition - Google Patents

A kind of flame retardant of pyrotechnic composition Download PDF

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Publication number
CN109467491A
CN109467491A CN201811508313.2A CN201811508313A CN109467491A CN 109467491 A CN109467491 A CN 109467491A CN 201811508313 A CN201811508313 A CN 201811508313A CN 109467491 A CN109467491 A CN 109467491A
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CN
China
Prior art keywords
powder
flame retardant
pyrotechnic composition
mesh
bamboo
Prior art date
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Pending
Application number
CN201811508313.2A
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Chinese (zh)
Inventor
王贤凤
郭建彪
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Individual
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Individual
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Publication date
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Priority to CN201811508313.2A priority Critical patent/CN109467491A/en
Publication of CN109467491A publication Critical patent/CN109467491A/en
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    • CCHEMISTRY; METALLURGY
    • C06EXPLOSIVES; MATCHES
    • C06BEXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
    • C06B23/00Compositions characterised by non-explosive or non-thermic constituents
    • C06B23/009Wetting agents, hydrophobing agents, dehydrating agents, antistatic additives, viscosity improvers, antiagglomerating agents, grinding agents and other additives for working up
    • CCHEMISTRY; METALLURGY
    • C06EXPLOSIVES; MATCHES
    • C06BEXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
    • C06B23/00Compositions characterised by non-explosive or non-thermic constituents
    • C06B23/007Ballistic modifiers, burning rate catalysts, burning rate depressing agents, e.g. for gas generating

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Medicinal Preparation (AREA)

Abstract

The present invention discloses a kind of flame retardant of pyrotechnic composition, it includes the component of following ratio by weight: shellac powder: 15%-25%, glutinous rice flour: 5%-15%, charcoal powder: 3%-10%, and surplus is bamboo powder, wood powder or the bamboo powder of -200 mesh of 120 mesh and the mixture of wood powder.Using flame retardant of the invention, delay the combustion efficiency of pyrotechnic composition more preferable, while there is preferable stability and be also possible that pyrotechnic composition light for issuing in burning is more bright-coloured.

Description

A kind of flame retardant of pyrotechnic composition
Technical field
The present invention relates to fireworks pharmaceutical techniques field more particularly to a kind of flame retardants of pyrotechnic composition.
Background technique
Fireworks medicine is usually made of propellant powder, fire-retardant medicine and colored-light composition.Wherein propellant powder is predominantly so that combustible Burning, is usually made of all kinds of oxidants and combustible.The effect of fire-retardant medicine be reduce propellant powder burning velocity, delay it is coloured The fluorescent lifetime of photo etching.
The Chinese patent of Publication No. CN1763470A discloses a kind of " application of the dicyandiamide in fireworks medicament ", uses Dicyandiamides more than 100 mesh is added in fireworks medicament as fire retardant, and playing reduces burning velocity, extends the colorful light-emitting time Effect.But the prior art, only with the medicament of single dicyandiamide, retarding action is not obvious, while it also can not be with The other components of fireworks medicament generate synergistic effect, are only capable of being purely by way of fire retardant use.In addition dicyandiamide is as chemical agent, Its use cost is also higher.
Summary of the invention
Technical problem to be solved by the present invention lies in, for the above-mentioned deficiency of the prior art, propose it is a kind of cost is relatively low, The flame retardant of good flame retardation effect and the more bright-coloured pyrotechnic composition of color when can make firework display.
The technical solution used to solve the technical problems of the present invention is that proposing a kind of flame retardant of pyrotechnic composition, by weight Part includes the component of following ratio:
Shellac powder: 15%-25%, glutinous rice flour: 5%-15%, charcoal powder: 3%-10%, surplus are -200 purpose of 120 mesh The mixture of bamboo powder, wood powder or bamboo powder and wood powder.
Bamboo powder and wood powder are oxidizers under normal particle sizes, but when bamboo powder, the granularity of wood powder reach 120 mesh with After upper, extremely difficult burning, becomes flame retardant.The present invention using the higher bamboo powder of granularity, wood powder as major ingredient, have it is lower at Sheet and preferable flame retardant effect, while being also possible to be that color is more bright-coloured to lure so that fireworks burn after using bamboo powder and wood powder Cause.
Shellac powder and glutinous rice flour are all preferable flame retardants.Find during the experiment, if only using bamboo powder and wood powder as Flame-proof material flame retardant effect is unsatisfactory.Flame retardant effect is very ideal after adding shellac powder and glutinous rice flour.
Glutinous rice flour also acts as the effect of adhesive simultaneously, and this product is enabled to make this in practical application to pyrotechnic composition The other components of product and pyrotechnic composition are preferably bonded together.Glutinous rice powder content must be suitable, if glutinous rice flour too high levels It may be that pyrotechnic composition sticks into one, pyrotechnic composition too disperses if content is too low, and pyrotechnic composition both cannot form desired Fountain or bright pearl effect.
Charcoal powder primarily serves toning effect in the present invention, so that entire product is in grey black.The product of grey black can It is mixed well with the other compositions with pyrotechnic composition.
It further, further include the fragrance powder of parts by weight 1%-3%.
Fragrance powder primarily serves the effect for improving product odour in the present invention.Product process and with other groups of pyrotechnic composition The working environment of workers can be improved when dividing mixing.
Further, the parts by weight of the flame retardant of the fireworks medicine are as follows: shellac powder: 15%, glutinous rice flour: 5%, charcoal powder: 6%, surplus is the bamboo powder of 120 mesh and the mixture of wood powder.
Further, the parts by weight of the flame retardant of the fireworks medicine are as follows: shellac powder: 20%, glutinous rice flour: 8%, charcoal powder: 3%, surplus is the bamboo powder of 150 mesh.
Further, the parts by weight of the flame retardant of the fireworks medicine are as follows: shellac powder: 25%, glutinous rice flour: 15%, charcoal powder: 10%, surplus is the bamboo powder of 200 mesh and the mixture of wood powder.
The present invention has the following beneficial effects: compared with prior art
1, the virtuous phoenix chemical industry in Liuyang City manages Co., Ltd for this product commission Hunan Entry-Exit Inspection and Quarantine Bureau fireworks explosion Inspection center detection show that the burn rate of this product is 0.0042mm/S, has very outstanding flame retardant effect, while this The ignition temperature of product is 309.3 DEG C, may not catching fire under normal storage, traffic condition.
2, after this product being added to arbitrary fountain or bright pearl class fireworks medicament, it can not only play and delay fireworks burning Effect, while the light color that while also fireworks being burnt issues is more bright-coloured.This product that should be used as flame retardant is The more bright-coloured concrete principle of the light color issued when what can make fireworks burn is still not clear, and inventor's conjecture may be Due to the mixture of the thinner bamboo powder of granularity, wood powder or bamboo powder and wood powder make the combustible of pyrotechnic composition burning when smog compared with It is few, so the color that pyrotechnic composition burns as viewed from visually is more bright-coloured, it is also possible to which this product makes the colored light in pyrotechnic composition Agent burning is more abundant.
Specific embodiment
The following is specific embodiments of the present invention, and technical scheme of the present invention will be further described, but the present invention is simultaneously It is not limited to these embodiments.
Embodiment 1:
With ball mill be made 120 mesh bamboo powder and wood powder it is spare.
By weight score weigh 15% shellac powder, 5% glutinous rice flour, 6% charcoal powder;1% fragrance;Surplus is with bamboo Powder and wood powder polishing.
Above-mentioned powder is obtained into this product after mixing.
Embodiment 2:
The bamboo powder that 150 mesh are made with ball mill is spare.
By weight score weigh 20% shellac powder, 8% glutinous rice flour, 3% charcoal powder;3% fragrance;Surplus is with bamboo Powder polishing.
Above-mentioned powder is obtained into this product after mixing.
Embodiment 3:
With ball mill be made 200 mesh bamboo powder and wood powder it is spare.
By weight score weigh 25% shellac powder, 15% glutinous rice flour, 10% charcoal powder;Surplus is with bamboo powder and wood powder Polishing.
Above-mentioned powder is obtained into this product after mixing.
Specific embodiment described herein is only an example for the spirit of the invention.The neck of technology belonging to the present invention The technical staff in domain can make various modifications or additions to the described embodiments or replace by a similar method In generation, however, it does not deviate from the spirit of the invention or beyond the scope of the appended claims.

Claims (5)

1. a kind of flame retardant of pyrotechnic composition, includes the component of following ratio by weight:
Shellac powder: 15%-25%, glutinous rice flour: 5%-15%, charcoal powder: 3%-10%, surplus be -200 mesh of 120 mesh bamboo powder, The mixture of wood powder or bamboo powder and wood powder.
2. the flame retardant of pyrotechnic composition according to claim 1, it is characterised in that: further include the fragrance of parts by weight 1%-3% Powder.
3. the flame retardant of pyrotechnic composition according to claim 1 or 2, it is characterised in that: the weight of the flame retardant of the fireworks medicine Measure part are as follows: shellac powder: 15%, glutinous rice flour: 5%, charcoal powder: 6%, surplus is the bamboo powder of 120 mesh and the mixture of wood powder.
4. the flame retardant of pyrotechnic composition according to claim 1 or 2, it is characterised in that: the weight of the flame retardant of the fireworks medicine Measure part are as follows: the parts by weight of the flame retardant of the fireworks medicine are as follows: shellac powder: 20%, glutinous rice flour: 8%, charcoal powder: 3%, surplus is The bamboo powder of 150 mesh.
5. the flame retardant of pyrotechnic composition according to claim 1, it is characterised in that: the parts by weight of the flame retardant of the fireworks medicine Are as follows: shellac powder: 25%, glutinous rice flour: 15%, charcoal powder: 10%, surplus is the bamboo powder of 200 mesh and the mixture of wood powder.
CN201811508313.2A 2018-12-11 2018-12-11 A kind of flame retardant of pyrotechnic composition Pending CN109467491A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201811508313.2A CN109467491A (en) 2018-12-11 2018-12-11 A kind of flame retardant of pyrotechnic composition

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201811508313.2A CN109467491A (en) 2018-12-11 2018-12-11 A kind of flame retardant of pyrotechnic composition

Publications (1)

Publication Number Publication Date
CN109467491A true CN109467491A (en) 2019-03-15

Family

ID=65676111

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201811508313.2A Pending CN109467491A (en) 2018-12-11 2018-12-11 A kind of flame retardant of pyrotechnic composition

Country Status (1)

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CN (1) CN109467491A (en)

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2232740C1 (en) * 2002-12-02 2004-07-20 Казанский государственный технологический университет Pyrotechnic igniter composition
CN101519333A (en) * 2009-01-25 2009-09-02 祁阳县顺发彩光氧化剂有限责任公司 Fireworks powder color light oxidant

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2232740C1 (en) * 2002-12-02 2004-07-20 Казанский государственный технологический университет Pyrotechnic igniter composition
CN101519333A (en) * 2009-01-25 2009-09-02 祁阳县顺发彩光氧化剂有限责任公司 Fireworks powder color light oxidant

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
国家安全生产应急救援指挥中心: "《烟花爆竹企业安全生产应急管理》", 30 June 2009, 煤炭工业出版社 *
徐强国等: "《烟花爆竹安全管理技术》", 31 December 2005, 南京大学出版社 *
潘功配: "《烟火药材料手册》", 31 May 1983, 江苏省溧水县柘塘印刷厂 *

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Application publication date: 20190315