CN109467068A - A kind of preparation method of biological material Ba Danmu base porous carbon materials and its application in terms of anode of microbial fuel cell - Google Patents
A kind of preparation method of biological material Ba Danmu base porous carbon materials and its application in terms of anode of microbial fuel cell Download PDFInfo
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- CN109467068A CN109467068A CN201811294044.4A CN201811294044A CN109467068A CN 109467068 A CN109467068 A CN 109467068A CN 201811294044 A CN201811294044 A CN 201811294044A CN 109467068 A CN109467068 A CN 109467068A
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- H01M4/8605—Porous electrodes
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- H—ELECTRICITY
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- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
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- H—ELECTRICITY
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- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/16—Biochemical fuel cells, i.e. cells in which microorganisms function as catalysts
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- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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Abstract
The invention discloses a kind of preparation method of biological material Ba Danmu base porous carbon materials and its application in terms of anode of microbial fuel cell, includes the following steps: 1) to wash Ba Danmu shell, dries and be crushed；2) broken Ba Danmu shell is activated in activator aqueous solution, then takes out drying；3) product after drying is divided into lower high temperature cabonization in inert gas, by the product acid elution after carbonization, is washed with water and washs, it is until neutrality, the product after washing is dry, obtain Ba Danmu shell base porous carbon materials.The present invention is by " one step carbonization ", the Ba Danmu shell base porous carbon materials directly prepared, preparation method cheap and simple, provides reference for biomass and being prepared on a large scale for porous carbon materials.Biomass Ba Danmu shell base porous carbon materials are conducive to the attachment of electricity-producing microorganism in anode chamber as anode of microbial fuel cell, and stability greatly improves the electricity production power of microbiological fuel cell.
Description
Technical field
The present invention relates to the preparation technical fields of material, and in particular to a kind of biological material Ba Danmu base porous carbon materials
Preparation method and its application in terms of anode of microbial fuel cell.
Background technique
With the rapid development of global industry, a large amount of coal, the non-renewable resources such as petroleum are constantly consumed, and cause to provide
The shortage in source, therefore it is extremely urgent to explore renewable environmentally friendly new energy.Microbiological fuel cell (Microbial Fuel
Cells, MFCs) it is one and can be realized the device that energy is converted and has production capacity, it can will contain in complicated organic biomass
Chemical energy is converted into electric energy, therefore causes global extensive concern.
Carbon material is worldwide research hotspot, there are many kinds of form, including graphene, carbon nanotube, carbon fiber,
Measure porous carbon etc..Porous carbon has flourishing gap, high-specific surface area, low-density, high fever as a kind of special carbonaceous material
The advantages that conducting wire, chemical property temperature, engineering properties temperature, good conductivity, can be applied in many industries, such as medicine, change
Work, nuclear power, vacuum manufacturing industry, organic matter and absorption without metal ions and toxic gas in solution, catalyst carrier with
And the electrode material of microbiological fuel cell.
Biomass carbon material is using the renewable waste such as stalk, corncob, rice husk, sawdust as raw material, in the item of anoxic
A kind of carbon material prepared under part, and it is widely used in the industries such as catalysis, biological culture and environmental protection.Biomass is recognized
To be a kind of excellent carbon materials material precursor, there is the report that carbon material is prepared using biomass at present.Using reproducible
Biomass replaces increasingly depleted fossil fuel as carbon source, is the direction of the following whole nation or even global evolution, due to biology
Matter is cheap, from a wealth of sources, so the weight using biomass as the raw material future porous carbon materials field of porous carbon materials
Want component part.
Summary of the invention
Problem to be solved by this invention is: providing a kind of preparation method of biological material Ba Danmu base porous carbon materials
And its application in terms of anode of microbial fuel cell, it is biomass source that the present invention, which directly utilizes Ba Danmu shell, passes through one
The method of step activation carbonization, prepares porous carbon materials, and the porous carbon of preparation is used as to the electrode material of microbiological fuel cell,
The high-valued application for realizing Ba Danmu shell biological material, so that MFC produces higher electric energy.
The present invention in order to solve the above problem provided by technical solution are as follows: a kind of biological material Ba Danmu shell base porous carbon
The preparation method of material, it is characterised in that: include the following steps,
1), Ba Danmu shell is washed, dries and is crushed；
2) broken Ba Danmu shell is activated in the aqueous solution of activator, then take out and is dried；
3), by dried product under inert gas range high temperature cabonization, by the product acid elution after carbonization, then use
Deionized water washing is dry by the product after washing until neutrality, obtains Ba Danmu shell base porous carbon materials.
Preferably, the activator in the step 2) is the ZnCl of 2m ol/L2Solution.
Preferably, the temperature of the activation processing in the step 2) is 180 DEG C, and the activation processing time is 10h.
Preferably, it is in 600 DEG C, 800 DEG C, 1000 DEG C that the condition of the high temperature cabonization in the step 3), which is carburizing temperature,
Any one temperature, the time of high temperature cabonization are 3 hours.
Preferably, the inert gas in the step 3) is N2 or Ar.
Preferably, the acid in the step 3) is the hydrochloric acid that concentration is 0.1mol/L.
A kind of application of biological material Ba Danmu base porous carbon materials in terms of anode of microbial fuel cell, feature
It is: includes the following steps,
A, any preparation method prepared Ba Danmu shell Quito hole described in claim 1 to 6 will be passed through
Carbon material and corresponding solvent cement are made by mixing into slurries and are coated in long 2cm, on the carbon cloth of wide 1cm, are fabricated to microorganism combustion
Expect galvanic anode, is assembled in together with plain carbon cloth electrode in same anode chamber；
B, use carbon brush as microorganism fuel cell cathode, two pole room of yin-yang is linked by proton exchange membrane and is built into
For H-type microbial fuel cell unit, temperature configures good corresponding microorganism growth-promoting media and is injected into anode chamber at 30 DEG C or so
In and catholyte injection cathode chamber in；
C, link voltage data collector, the external resistance voltage value of acquisition in machine every five minutes, according to external resistance voltage
The variation of value regularly replaces catholyte and anolyte；
D, by the culture of a period of time, under conditions of reducing external resistance value, filter out anti-current pass through it is micro-
Biological flora, then the stable microbial film that grows into is carried on anode microorganism, and finally production obtains microbiological fuel cell.
Preferably, the pH value of the catholyte in the step b and anolyte is neutrality.
Compared with prior art, the invention has the advantages that using castoff Ba Danmu shell, pass through pretreatment, high temperature
The easy steps such as carbonization synthesize biomass carbon material, realize waste utilization；It is applied to microbiological fuel cell simultaneously
Anode not only improves the attachment of anode electricity-producing microorganism again because it is with good biocompatibility and biggish specific surface area
Anode activation overpotential is reduced, so that the electricity production power density of microbiological fuel cell significantly improves.
Detailed description of the invention
The drawings described herein are used to provide a further understanding of the present invention, constitutes a part of the invention, this hair
Bright illustrative embodiments and their description are used to explain the present invention, and are not constituted improper limitations of the present invention.
Fig. 1 is the SEM figure of 800 DEG C of chin denier wood shell base porous carbon materials of the present invention.
Fig. 2 is the cycle efficieny figure that Ba Danmu shell base porous carbon materials of the present invention are applied to microbiological fuel cell.
Specific embodiment
Carry out the embodiment that the present invention will be described in detail below in conjunction with accompanying drawings and embodiments, how the present invention is applied whereby
Technological means solves technical problem and reaches the realization process of technical effect to fully understand and implement.
A kind of preparation method of biological material Ba Danmu shell base porous carbon materials, it is characterised in that: include the following steps,
1), Ba Danmu shell is washed, dries and is crushed；
2) broken Ba Danmu shell is activated in the aqueous solution of activator, then take out and is dried；
3), by dried product under inert gas range high temperature cabonization, by the product acid elution after carbonization, then use
Deionized water washing is dry by the product after washing until neutrality, obtains Ba Danmu shell base porous carbon materials.
The ZnCl that activator in step 2) is 2m ol/L2Solution.
The temperature of activation processing in step 2) is 180 DEG C, and the activation processing time is 10h.
The condition of high temperature cabonization in step 3) is that carburizing temperature is warm for any one in 600 DEG C, 800 DEG C, 1000 DEG C
Degree, the time of high temperature cabonization are 3 hours.
Inert gas in step 3) is N2 or Ar.
Acid in step 3) is the hydrochloric acid that concentration is 0.1mol/L.
A kind of application of biological material Ba Danmu base porous carbon materials in terms of anode of microbial fuel cell, feature
It is: includes the following steps,
A, by by the prepared Ba Danmu shell base porous carbon materials of any preparation method of claim 1 to 6 with
Corresponding solvent cement is made by mixing into slurries and is coated in long 2cm, on the carbon cloth of wide 1cm, is fabricated to microbiological fuel cell sun
Pole is assembled in same anode chamber together with plain carbon cloth electrode；
B, use carbon brush as microorganism fuel cell cathode, two pole room of yin-yang is linked by proton exchange membrane and is built into
For H-type microbial fuel cell unit, temperature configures good corresponding microorganism growth-promoting media and is injected into anode chamber at 30 DEG C or so
In and catholyte injection cathode chamber in；
C, link voltage data collector, the external resistance voltage value of acquisition in machine every five minutes, according to external resistance voltage
The variation of value regularly replaces catholyte and anolyte；
D, by the culture of a period of time, under conditions of reducing external resistance value, filter out anti-current pass through it is micro-
Biological flora, then the stable microbial film that grows into is carried on anode microorganism, and finally production obtains microbiological fuel cell.
The pH value of catholyte and anolyte in step b is neutrality.
Embodiment 1
The preparation of Ba Danmu base porous carbon materials: Ba Danmu shell is impregnated into supersound washing in deionized water, 60 DEG C of conditions
Lower dry 20h and ball milling；The good material of ball milling is put into the ZnCl of 2mol/L2In solution, mixed liquor capacity is no more than reaction kettle
The 70% of liner capacity carries out 10 hours of 180 DEG C of hydro-thermal reactions, filters and dries for 24 hours after reaction under the conditions of 80 DEG C；
Product after drying is calcined under atmosphere of inert gases, is warming up to 600 DEG C, 800 DEG C, 1000 DEG C from room temperature with 5 DEG C/min, and
3h is kept at a temperature of its respectively, cooled to room temperature is black cellular solid after taking-up, grinds alternative.
The removal of Ba Danmu base porous carbon materials impurity: the product ultimately generated in (1) successively used to 0.1mol/L's is dilute
Hydrochloric acid and deionized water are rinsed, and filtering and the dry 12h under 80 DEG C of vacuum conditions finally obtain Ba Danmu base porous carbon materials
's.
Application of the Ba Danmu base porous carbon materials in terms of anode of microbial fuel cell: by carbon material and corresponding solvent
And adhesive mixing is made into slurries and is uniformly applied to surplus to be fabricated to electrode on the carbon cloth of 2*1cm, with plain carbon cloth group
Loaded in same anode of microbial fuel cell room.Common carbon brush is cathode, and two pole room of yin-yang and proton exchange membrane are assembled into H-type
Microbial fuel cell unit, external circuit chain connecting resistance.Under the conditions of 30 DEG C of room temperature or so, by configured catholyte and anode
Liquid injects corresponding yin, yang pole room respectively.Pass through the voltage value of the external resistance of acquisition in voltage data collector every five minutes, root
According to the variation of external resistance voltage value, catholyte and anolyte are regularly replaced, until microorganism, which stablizes growth, can carry out correlation
The test of energy.
Only highly preferred embodiment of the present invention is described above, but is not to be construed as limiting the scope of the invention.This
Invention is not only limited to above embodiments, and specific structure is allowed to vary.All protection models in independent claims of the present invention
Interior made various change is enclosed to all fall in the scope of protection of the present invention.
Claims (8)
1. a kind of preparation method of biological material Ba Danmu shell base porous carbon materials, it is characterised in that: include the following steps,
1), Ba Danmu shell is washed, dries and is crushed；
2) broken Ba Danmu shell is activated in the aqueous solution of activator, then take out and is dried；
3), by dried product under inert gas range high temperature cabonization, by the product acid elution after carbonization, then spend from
Sub- water washing is dry by the product after washing until neutrality, obtains Ba Danmu shell base porous carbon materials.
2. the preparation method of biological material Ba Danmu shell base porous carbon materials according to claim 1, it is characterised in that:
The ZnCl that activator in the step 2) is 2mol/L2Solution.
3. the preparation method of biological material Ba Danmu shell base porous carbon materials according to claim 1, it is characterised in that:
The temperature of activation processing in the step 2) is 180 DEG C, and the activation processing time is 10h.
4. the preparation method of biological material Ba Danmu shell base porous carbon materials according to claim 1, it is characterised in that:
The condition of high temperature cabonization in the step 3) is that carburizing temperature is any one temperature in 600 DEG C, 800 DEG C, 1000 DEG C, high
The time of temperature carbonization is 3 hours.
5. the preparation method of biological material Ba Danmu shell base porous carbon materials according to claim 1, it is characterised in that:
Inert gas in the step 3) is N2 or Ar.
6. the preparation method of biological material Ba Danmu shell base porous carbon materials according to claim 1, it is characterised in that:
Acid in the step 3) is the hydrochloric acid that concentration is 0.1mol/L.
7. a kind of application of biological material Ba Danmu base porous carbon materials in terms of anode of microbial fuel cell, feature exist
In: include the following steps,
A, any prepared Ba Danmu shell base porous carbon of preparation method described in claim 1 to 6 will be passed through
Material is made by mixing into slurries with corresponding solvent cement and is coated in long 2cm, and on the carbon cloth of wide 1cm, it is electric to be fabricated to Microbial fuel
Pond anode is assembled in same anode chamber together with plain carbon cloth electrode；
B, use carbon brush as microorganism fuel cell cathode, two pole room of yin-yang is linked by proton exchange membrane and builds as H
Type microbial fuel cell unit, temperature configure good corresponding microorganism growth-promoting media and are injected into anode chamber at 30 DEG C or so, with
And in catholyte injection cathode chamber；
C, link voltage data collector, the external resistance voltage value of acquisition in machine every five minutes, according to external resistance voltage value
Variation regularly replaces catholyte and anolyte；
D, the microorganism that anti-current passes through is filtered out under conditions of reducing external resistance value by the culture of a period of time
Flora, then the stable microbial film that grows into is carried on anode microorganism, and finally production obtains microbiological fuel cell.
8. a kind of preparation method of microbiological fuel cell according to claim 7, it is characterised in that: in the step b
Catholyte and anolyte pH value be neutrality.
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110098413A (en) * | 2019-05-09 | 2019-08-06 | 东华大学 | A kind of agricultural solid waste resource utilization method |
| CN111009648A (en) * | 2019-12-10 | 2020-04-14 | 华南农业大学 | Silicon-carbon composite material and preparation method thereof |
| CN112678821A (en) * | 2020-12-25 | 2021-04-20 | 兰州大学 | Self-supporting carbon material and preparation method and application thereof |
| CN114725462A (en) * | 2022-03-16 | 2022-07-08 | 广州市金龙峰环保设备工程股份有限公司 | Mesoporous multidimensional catalytic polar plate and preparation method thereof |
Citations (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20100279178A1 (en) * | 2009-02-23 | 2010-11-04 | Barkeloo Jason E | Microbial fuel cell |
| WO2012146897A1 (en) * | 2011-04-26 | 2012-11-01 | The University Of Nottingham | An anode and cathode for a microbial fuel cell and a microbial fuel cell incorporating the anode or cathode |
| CN104167300A (en) * | 2014-05-30 | 2014-11-26 | 燕山大学 | Active carbon and method for preparing active carbon/zinc oxide compound electrode material |
| CN105140528A (en) * | 2015-07-31 | 2015-12-09 | 华南理工大学 | Self-doped microbial fuel cell cathode material and preparation method thereof |
| CN105692611A (en) * | 2016-03-21 | 2016-06-22 | 中国科学院理化技术研究所 | Preparation method of biomass activated carbon rich in nitrogen and oxygen |
| CN105731453A (en) * | 2016-01-25 | 2016-07-06 | 石河子大学 | Preparation method for apricot shell activated carbon and apricot activated carbon |
| CN105762372A (en) * | 2016-04-21 | 2016-07-13 | 常州大学 | Method for preparing microbial fuel cell anode electrodes from agricultural wastes |
| CN105845947A (en) * | 2016-05-31 | 2016-08-10 | 常州大学 | Method for preparing microbial fuel cell electrode material employing rape stalks |
| CN106207239A (en) * | 2016-09-26 | 2016-12-07 | 南昌航空大学 | The synthetic method of a kind of N doping porous carbon and the application in terms of anode of microbial fuel cell thereof |
| CN106744798A (en) * | 2016-12-12 | 2017-05-31 | 华中科技大学 | A kind of method and its application that hard carbon is prepared using carbon containing biological mass shell |
| CN107381776A (en) * | 2017-06-07 | 2017-11-24 | 南昌航空大学 | A kind of preparation method of microbiological fuel cell processing ion containing heavy metal copper |
-
2018
- 2018-11-01 CN CN201811294044.4A patent/CN109467068A/en active Pending
Patent Citations (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20100279178A1 (en) * | 2009-02-23 | 2010-11-04 | Barkeloo Jason E | Microbial fuel cell |
| WO2012146897A1 (en) * | 2011-04-26 | 2012-11-01 | The University Of Nottingham | An anode and cathode for a microbial fuel cell and a microbial fuel cell incorporating the anode or cathode |
| CN104167300A (en) * | 2014-05-30 | 2014-11-26 | 燕山大学 | Active carbon and method for preparing active carbon/zinc oxide compound electrode material |
| CN105140528A (en) * | 2015-07-31 | 2015-12-09 | 华南理工大学 | Self-doped microbial fuel cell cathode material and preparation method thereof |
| CN105731453A (en) * | 2016-01-25 | 2016-07-06 | 石河子大学 | Preparation method for apricot shell activated carbon and apricot activated carbon |
| CN105692611A (en) * | 2016-03-21 | 2016-06-22 | 中国科学院理化技术研究所 | Preparation method of biomass activated carbon rich in nitrogen and oxygen |
| CN105762372A (en) * | 2016-04-21 | 2016-07-13 | 常州大学 | Method for preparing microbial fuel cell anode electrodes from agricultural wastes |
| CN105845947A (en) * | 2016-05-31 | 2016-08-10 | 常州大学 | Method for preparing microbial fuel cell electrode material employing rape stalks |
| CN106207239A (en) * | 2016-09-26 | 2016-12-07 | 南昌航空大学 | The synthetic method of a kind of N doping porous carbon and the application in terms of anode of microbial fuel cell thereof |
| CN106744798A (en) * | 2016-12-12 | 2017-05-31 | 华中科技大学 | A kind of method and its application that hard carbon is prepared using carbon containing biological mass shell |
| CN107381776A (en) * | 2017-06-07 | 2017-11-24 | 南昌航空大学 | A kind of preparation method of microbiological fuel cell processing ion containing heavy metal copper |
Non-Patent Citations (5)
| Title |
|---|
| LEDESMA, B 等: "Method for promoting in-situ hydrochar porosity in hydrothermal carbonization of almond shells with air activation", 《JOURNAL OF SUPERCRITICAL FLUIDS》 * |
| SHUILIANG CHEN ET AL: ""Reticulated carbon foam derived from a sponge-like natural product as a highperformance anode in microbial fuel cells "", 《J. MATER. CHEM.》 * |
| 刘喜: "新型氮掺杂碳材料制备及其电化学性能研究", 《中国优秀博硕士学位论文全文数据库（硕士） 工程科技II辑》 * |
| 李勇 等: "几种干果核壳活性炭的表征与性能研究", 《生物质化学工程》 * |
| 林家瑾等: ""基于木薯秸秆制备三维多孔碳及其在微生物燃料电池中的应用"", 《化工进展》 * |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110098413A (en) * | 2019-05-09 | 2019-08-06 | 东华大学 | A kind of agricultural solid waste resource utilization method |
| CN111009648A (en) * | 2019-12-10 | 2020-04-14 | 华南农业大学 | Silicon-carbon composite material and preparation method thereof |
| CN112678821A (en) * | 2020-12-25 | 2021-04-20 | 兰州大学 | Self-supporting carbon material and preparation method and application thereof |
| CN112678821B (en) * | 2020-12-25 | 2024-02-02 | 兰州大学 | Self-supporting carbon material and preparation method and application thereof |
| CN114725462A (en) * | 2022-03-16 | 2022-07-08 | 广州市金龙峰环保设备工程股份有限公司 | Mesoporous multidimensional catalytic polar plate and preparation method thereof |
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Application publication date: 20190315 |