CN109456840A - A kind of aqueous, environmental protective residue glue cleaning agent and preparation method thereof - Google Patents
A kind of aqueous, environmental protective residue glue cleaning agent and preparation method thereof Download PDFInfo
- Publication number
- CN109456840A CN109456840A CN201811228318.XA CN201811228318A CN109456840A CN 109456840 A CN109456840 A CN 109456840A CN 201811228318 A CN201811228318 A CN 201811228318A CN 109456840 A CN109456840 A CN 109456840A
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- Prior art keywords
- parts
- cleaning agent
- aqueous
- residue glue
- environmental protective
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
- C11D1/146—Sulfuric acid esters
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/10—Carbonates ; Bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2068—Ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2093—Esters; Carbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
Abstract
The present invention relates to waterborne cleaning agent technical fields, more particularly to a kind of aqueous, environmental protective residue glue cleaning agent and preparation method thereof, formula is made of 25-40 parts of deionized water, 30-55 parts of natural plant extracts, 0.3-0.8 parts of anion emulsifier, 0.2-1.0 parts of nonionic emulsifier, biological 8-15 parts of ester environment-friendly plasticizer, 5-10 parts of sodium bicarbonate；Wherein, anion emulsifier is the alkylsurfuric acid sodium salt that HLB value is 35-40, and nonionic emulsifier is the acetylenic glycols ethoxy compound that HLB value is 3-6.Waterborne cleaning agent of the invention has extremely strong dirt-removing power to residue glue, spot, and stability is good, has the characteristics that green non-pollution.
Description
Technical field
The present invention relates to waterborne cleaning agent technical fields, and in particular to a kind of aqueous, environmental protective residue glue cleaning agent and its preparation side
Method.
Background technique
Currently, the post-press finishing of printing industry is often bonded with aqueous adhesive, it is most of in order to improve working efficiency
Mechanical or semi-machine gluing mode, including mechanical roller coating, spraying, silk screen gluing etc. are all used, some techniques are in fitting part
It needs to convey a certain distance by transmission belt after gluing and be bonded again.Due to above operation, aqueous adhesive compares appearance
The components such as board and transmission belt are easily touched, being stained with dust after dry makes board seem dirty and messy, and is possible to influence printed matter
Quality.So post-press finishing enterprise often cleans the residue glue in board and transmission belt, the cleaning agent being commonly used be gasoline,
Trichloroethanes, acetone, kerosene, Tiana and other organic solvents cleaning agent.Such cleaning agent is inflammable, it is explosive, pollute environment, endanger people
Body health, high volatility and easily causes to corrode to cleaned equipment surface.There are also the cleanings of aqueous residue glue currently on the market
Agent, but some can corrode that steel equipment, some performances are mild but cleaning force is weak, some can injure human skin.Therefore, it is protecting
Under the premise of demonstrate,proving cleaning ability, strong clear of exploitation Environmental Safety, simple process, non-combustible, non-explosive, non-volatile and dirt-removing power
Lotion receives more and more attention.
Summary of the invention
It is an object of the invention to aiming at the shortcomings in the prior art and to provide a kind of Environmental Safety, dirt-removing power strong, steady
Qualitative good and simple aqueous, environmental protective residue glue cleaning agent of preparation process and preparation method thereof.
The purpose of the present invention is achieved through the following technical solutions:
A kind of aqueous, environmental protective residue glue cleaning agent is provided, is made of raw material from the following weight: by the raw material of following parts by weight
It is made:
25-40 parts of deionized water
0.3-0.8 parts of anion emulsifier
30-55 parts of natural plant extracts
0.2-1.0 parts of nonionic emulsifier
8-15 parts of biological ester environment-friendly plasticizer
5-10 parts of sodium bicarbonate；
Wherein, the anion emulsifier is the alkylsurfuric acid sodium salt that HLB value is 35-40；
The nonionic emulsifier is the acetylenic glycols ethoxy compound that HLB value is 3-6.
In above-mentioned technical proposal, a kind of aqueous, environmental protective residue glue cleaning agent is made of raw material from the following weight:
25-35 parts of deionized water
0.3-0.6 parts of anion emulsifier
30-50 parts of natural plant extracts
0.4-0.8 parts of nonionic emulsifier
8-12 parts of biological ester environment-friendly plasticizer
5-8 parts of sodium bicarbonate.
In above-mentioned technical proposal, the natural plant extracts are in coconut oil, olive oil, mandarin oil and lemon
It is one or two kinds of.
In above-mentioned technical proposal, it is described biology ester environment-friendly plasticizer be tributyl citrate, tributyl 2-acetylcitrate and
One or both of acetyl tributyl citrate.
In above-mentioned technical proposal, the alkylsurfuric acid sodium salt is lauryl sodium sulfate.
In above-mentioned technical proposal, the anion emulsifier is the lauryl sodium sulfate that HLB value is 40 or HLB value is
38.1 sodium hexadecyl sulfate.
In above-mentioned technical proposal, the acetylenic glycols ethoxy compound is the marque Surfynol 420 that HLB value is 4
Or the acetylenic glycols ethoxy compound of HarcrosVenadol 20.
The present invention also provides a kind of above-mentioned preparation methods of aqueous, environmental protective residue glue cleaning agent, comprising the following steps:
Step S1, formula ratio is pressed, ionized water is removed, the anion emulsifier that HLB value is 35-40 is then added, stirring is equal
It is even to obtain water phase mixed liquor；
Step S2, formula ratio is pressed, natural plant extracts are taken, the nonionic emulsifier that HLB value is 3-6 is then added, stirs
It mixes and uniformly obtains oil and mix liquid；
Step S3, stir the water phase mixed liquor of step S1 with the shear rate of 1000-1200r/min, then by step
The oil of S2 mixes liquid and is added dropwise in the water phase mixed liquor, and control time for adding is 30-45min, after mixing evenly
To the emulsion containing natural plant extracts；
Step S4, formula ratio is pressed, biological ester environment-friendly plasticizer and sodium bicarbonate are added in Xiang Suoshu emulsion, continuation is slowly stirred
To get to the aqueous, environmental protective residue glue cleaning agent after mixing uniformly.
The present invention also provides a kind of above-mentioned preparation methods of aqueous, environmental protective residue glue cleaning agent, comprising the following steps:
Beneficial effects of the present invention:
A kind of aqueous, environmental protective residue glue cleaning agent of the invention and preparation method thereof, respectively by 25-40 part by weight
Deionized water is uniformly mixed with the anion emulsifier that HLB value is 35-40 and water phase mixed liquor is made；30-55 parts of natural plants mention
It takes object to be uniformly mixed with the nonionic emulsifier that HLB value is 3-6 and homogeneous oil phase mixed liquor is made；Then water phase mixed liquor exists
Under the shear rate stirring of 1000-1200r/min, oil is mixed into liquid and is added dropwise in the water phase mixed liquor, control drop
It is 30-45min between added-time, obtains the emulsion containing natural plant extracts after mixing evenly；Finally add into the emulsion
Enter 15 parts of biological ester environment-friendly plasticizers and 5-10 parts of sodium bicarbonate, aqueous, environmental protective residue glue cleaning agent is obtained after being slowly stirred uniformly.
Compared with prior art, the invention has the following advantages that
(1) present invention uses the nonionic emulsifier conduct that HLB value is 3-6 for the anion emulsifier of 35-40 and HLB value
Composite emulsifier can make natural plant extracts realize stable emulsion dispersion effect in water, keep the long-term of cleaning agent
Stablize；
(2) it joined biological ester environment-friendly plasticizer in inventive formulation, enhance cleaning agent to the bating effect of dry glue, by force
The cleaning effect of cleaning agent is changed and the smell pleasant with faint scent；
(3) sodium bicarbonate has been used in inventive formulation, collaboration can be played to the cleaning effect of natural plant extracts and is increased
The effect of effect makes the cleaning effect of the residue glue cleaning agent obtained that can substitute organic cleaning solvent completely, the present invention to residue glue,
Spot has extremely strong dirt-removing power, has the characteristics that non-combustible, non-explosive, non-volatile, green non-pollution, and prepare work
Skill is simple, highly-safe, and the present invention has boundless application prospect.
Specific embodiment
The invention will be further described with the following Examples.
Embodiment 1:
A kind of aqueous, environmental protective residue glue cleaning agent of the present embodiment, is prepared that (following each component is pressed using following steps
Parts by weight meter):
Step S1,30 parts of deionized waters are taken, then the lauryl sodium sulfate that HLB value is 40 is added for 0.5 part, stirs evenly
Obtain water phase mixed liquor；
Step S2,20 portions of coconut oil and 20 parts of olive oil are taken, the marque that 0.4 part of HLB value is 4 is then added
The acetylenic glycols ethoxy compound of Surfynol 420, is uniformly mixing to obtain oil and mixes liquid；
Step S3, stir the water phase mixed liquor of step S1 with the shear rate of 1100r/min, then by the oil of step S2
It mixes liquid to be added dropwise in the water phase mixed liquor, control time for adding is 40min, obtains planting containing natural after mixing evenly
The emulsion of object extract；
Step S4,10 parts of tributyl 2-acetylcitrates and 7 parts of sodium bicarbonate are added into emulsion, continue to be slowly stirred uniformly
Afterwards to get arrive aqueous, environmental protective residue glue cleaning agent.
Embodiment 2:
A kind of aqueous, environmental protective residue glue cleaning agent of the present embodiment, is prepared that (following each component is pressed using following steps
Parts by weight meter):
Step S1,25 parts of deionized waters are taken, the sodium hexadecyl sulfate that 0.3 part of HLB value is 38.1 is then added, stirring is equal
It is even to obtain water phase mixed liquor；
Step S2,35 parts of mandarin oils and 15 parts of lemons are taken, the marque that 0.6 part of HLB value is 4 is then added
The acetylenic glycols ethoxy compound of HarcrosVenadol 20, is uniformly mixing to obtain oil and mixes liquid；
Step S3, stir the water phase mixed liquor of step S1 with the shear rate of 1150r/min, then by the oil of step S2
It mixes liquid to be added dropwise in the water phase mixed liquor, control time for adding is 35min, obtains planting containing natural after mixing evenly
The emulsion of object extract；
Step S4,4 parts of tributyl citrate, 4 parts of acetyl tributyl citrate and 8 parts of sodium bicarbonate are added into emulsion,
To get to aqueous, environmental protective residue glue cleaning agent after continuing to be slowly stirred uniformly.
Embodiment 3:
A kind of aqueous, environmental protective residue glue cleaning agent of the present embodiment, is prepared that (following each component is pressed using following steps
Parts by weight meter):
Step S1,40 parts of deionized waters are taken, the lauryl sodium sulfate that 0.6 part of HLB value is 35 is then added, stirs evenly
Obtain water phase mixed liquor；
Step S2,30 portions of coconut oil are taken, the marque HarcrosVenadol 20_ that 0.8 part of HLB value is 4 is then added
Acetylenic glycols ethoxy compound, be uniformly mixing to obtain oil and mix liquid；
Step S3, stir the water phase mixed liquor of step S1 with the shear rate of 1000r/min, then by the oil of step S2
It mixes liquid to be added dropwise in the water phase mixed liquor, control time for adding is 45min, obtains planting containing natural after mixing evenly
The emulsion of object extract；
Step S4,5 parts of tributyl 2-acetylcitrates, 10 parts of acetyl tributyl citrate and 10 parts small are added into emulsion
Soda, to get to aqueous, environmental protective residue glue cleaning agent after continuing to be slowly stirred uniformly.
Embodiment 4:
A kind of aqueous, environmental protective residue glue cleaning agent of the present embodiment, is prepared that (following each component is pressed using following steps
Parts by weight meter):
Step S1,35 parts of deionized waters are taken, the sodium hexadecyl sulfate that 0.8 part of HLB value is 40 is then added, stirs evenly
Obtain water phase mixed liquor；
Step S2,15 parts of olive oil and 40 parts of lemons are taken, the marque that 1 part of HLB value is 6 is then added
The acetylenic glycols ethoxy compound of Surfynol 420, is uniformly mixing to obtain oil and mixes liquid；
Step S3, stir the water phase mixed liquor of step S1 with the shear rate of 1200r/min, then by the oil of step S2
It mixes liquid to be added dropwise in the water phase mixed liquor, control time for adding is 30min, obtains planting containing natural after mixing evenly
The emulsion of object extract；
Step S4,9 parts of tributyl citrate, 3 parts of tributyl 2-acetylcitrates and 5 parts of sodium bicarbonate are added into emulsion,
To get to aqueous, environmental protective residue glue cleaning agent after continuing to be slowly stirred uniformly.
The present embodiment is merely illustrative of the technical solution of the present invention, rather than limiting the scope of the invention, although ginseng
The present invention is explained in detail according to preferred embodiment, those skilled in the art should understand that, it can be to the present invention
Technical solution be modified or replaced equivalently, without departing from the spirit and scope of technical solution of the present invention.
Claims (8)
1. a kind of aqueous, environmental protective residue glue cleaning agent, it is characterised in that: be made of raw material from the following weight:
25-40 parts of deionized water
0.3-0.8 parts of anion emulsifier
30-55 parts of natural plant extracts
0.2-1.0 parts of nonionic emulsifier
8-15 parts of biological ester environment-friendly plasticizer
5-10 parts of sodium bicarbonate；
Wherein, the anion emulsifier is the alkylsurfuric acid sodium salt that HLB value is 35-40；
The nonionic emulsifier is the acetylenic glycols ethoxy compound that HLB value is 3-6.
2. a kind of aqueous, environmental protective residue glue cleaning agent according to claim 1, it is characterised in that: by the raw material of following parts by weight
It is made:
25-35 parts of deionized water
0.3-0.6 parts of anion emulsifier
30-50 parts of natural plant extracts
0.4-0.8 parts of nonionic emulsifier
8-12 parts of biological ester environment-friendly plasticizer
5-8 parts of sodium bicarbonate.
3. a kind of aqueous, environmental protective residue glue cleaning agent according to claim 1 or 2, it is characterised in that: the natural plants mention
Taking object is one or both of coconut oil, olive oil, mandarin oil and lemon.
4. a kind of aqueous, environmental protective residue glue cleaning agent according to claim 1 or 2, it is characterised in that: the biology ester environmental protection
Plasticizer is one or both of tributyl citrate, tributyl 2-acetylcitrate and acetyl tributyl citrate.
5. a kind of aqueous, environmental protective residue glue cleaning agent according to claim 1 or 2, it is characterised in that: the sodium alkyl sulfate
Salt is lauryl sodium sulfate or sodium hexadecyl sulfate.
6. a kind of aqueous, environmental protective residue glue cleaning agent according to claim 5, it is characterised in that: the anion emulsifier is
The sodium hexadecyl sulfate that the lauryl sodium sulfate or HLB value that HLB value is 40 are 38.1.
7. a kind of aqueous, environmental protective residue glue cleaning agent according to claim 1 or 2, it is characterised in that: the acetylenic glycols ethoxy
Based compound is the acetylenic glycols ethyoxyl chemical combination of marque Surfynol 420 or HarcrosVenadol 20 that HLB value is 4
Object.
8. a kind of preparation method of aqueous, environmental protective residue glue cleaning agent as claimed in any one of claims 1 to 7, feature exist
In: the following steps are included:
Step S1, formula ratio is pressed, ionized water is removed, the anion emulsifier that HLB value is 35-40 is then added, stirs evenly
To water phase mixed liquor；
Step S2, formula ratio is pressed, natural plant extracts are taken, the nonionic emulsifier that HLB value is 3-6 is then added, stirring is equal
The even oil that obtains mixes liquid；
Step S3, stir the water phase mixed liquor of step S1 with the shear rate of 1000-1200r/min, then by step S2's
Oil mixes liquid and is added dropwise in the water phase mixed liquor, and control time for adding is 30-45min, is contained after mixing evenly
There is the emulsion of natural plant extracts；
Step S4, formula ratio is pressed, biological ester environment-friendly plasticizer and sodium bicarbonate are added in Xiang Suoshu emulsion, continues to be slowly stirred
After even to get arrive the aqueous, environmental protective residue glue cleaning agent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811228318.XA CN109456840A (en) | 2018-10-22 | 2018-10-22 | A kind of aqueous, environmental protective residue glue cleaning agent and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811228318.XA CN109456840A (en) | 2018-10-22 | 2018-10-22 | A kind of aqueous, environmental protective residue glue cleaning agent and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109456840A true CN109456840A (en) | 2019-03-12 |
Family
ID=65608041
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811228318.XA Pending CN109456840A (en) | 2018-10-22 | 2018-10-22 | A kind of aqueous, environmental protective residue glue cleaning agent and preparation method thereof |
Country Status (1)
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112452635A (en) * | 2020-11-06 | 2021-03-09 | 宝艺新材料股份有限公司 | Cleaning method of corrugated board gluing machine |
| EP4245139A1 (en) * | 2022-03-15 | 2023-09-20 | Centre national de la recherche scientifique | Compositions comprising a botanical extract as insecticidal agent |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1490390A (en) * | 2003-09-17 | 2004-04-21 | 刘凤雷 | Stain cleaning agent for pressure-sensitive adhesive and chewing gum |
| CN105316120A (en) * | 2015-11-24 | 2016-02-10 | 苏州盖德精细材料有限公司 | General type glue dissolvent composition and preparation method thereof |
| CN105861182A (en) * | 2016-04-18 | 2016-08-17 | 袁玉珍 | Adlet cleanser and preparing method thereof |
| CN106381231A (en) * | 2016-09-07 | 2017-02-08 | 芜湖德鑫汽车部件有限公司 | Automobile air-conditioner detergent and preparation method thereof |
-
2018
- 2018-10-22 CN CN201811228318.XA patent/CN109456840A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1490390A (en) * | 2003-09-17 | 2004-04-21 | 刘凤雷 | Stain cleaning agent for pressure-sensitive adhesive and chewing gum |
| CN105316120A (en) * | 2015-11-24 | 2016-02-10 | 苏州盖德精细材料有限公司 | General type glue dissolvent composition and preparation method thereof |
| CN105861182A (en) * | 2016-04-18 | 2016-08-17 | 袁玉珍 | Adlet cleanser and preparing method thereof |
| CN106381231A (en) * | 2016-09-07 | 2017-02-08 | 芜湖德鑫汽车部件有限公司 | Automobile air-conditioner detergent and preparation method thereof |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112452635A (en) * | 2020-11-06 | 2021-03-09 | 宝艺新材料股份有限公司 | Cleaning method of corrugated board gluing machine |
| EP4245139A1 (en) * | 2022-03-15 | 2023-09-20 | Centre national de la recherche scientifique | Compositions comprising a botanical extract as insecticidal agent |
| WO2023174908A1 (en) * | 2022-03-15 | 2023-09-21 | Centre National De La Recherche Scientifique | Compositions comprising a botanical extract as insecticidal agent |
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