CN109455899A - A kind of oily sludge disposal system and its disposing technique - Google Patents

A kind of oily sludge disposal system and its disposing technique Download PDF

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Publication number
CN109455899A
CN109455899A CN201811626488.3A CN201811626488A CN109455899A CN 109455899 A CN109455899 A CN 109455899A CN 201811626488 A CN201811626488 A CN 201811626488A CN 109455899 A CN109455899 A CN 109455899A
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China
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oil
gas
thermal desorption
kiln
oily sludge
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邝焯荣
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Guangzhou Weigang Environmental Protection Technology Co ltd
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Guangzhou Green Thai Environment Technology Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00Treatment of sludge; Devices therefor
    • C02F11/12Treatment of sludge; Devices therefor by de-watering, drying or thickening
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00Treatment of sludge; Devices therefor
    • C02F11/10Treatment of sludge; Devices therefor by pyrolysis
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G1/00Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/10Nature of the water, waste water, sewage or sludge to be treated from quarries or from mining activities
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W10/00Technologies for wastewater treatment
    • Y02W10/40Valorisation of by-products of wastewater, sewage or sludge processing

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Organic Chemistry (AREA)
  • Hydrology & Water Resources (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Treatment Of Sludge (AREA)

Abstract

The invention discloses a kind of oily sludge disposal system and its disposing techniques, it include thermal desorption system, oil gas disposal system and oil recovery systems, thermal desorption system includes thermal desorption kiln, hot air chamber and the first deduster, oil gas disposal system includes subregion expansion chamber, spray column, scrubbing tower, burning chamber, heat exchanger and the second deduster, and oil recovery systems include three phase separator, spray column spray gun and scrubbing tower spray gun.The present invention can greatly improve heat transference efficiency, sufficiently recycle remaining oil product, and optimize the plantation performance of soil by the disposition by direct thermal desorption technology applied to oily sludge.In thermal desorption kiln, the high-temperature flue gas and oily sludge that generate from outside transmit heat by the direct way of contact, high-temperature flue gas by oily sludge moisture and oil be evaporated after recycling oil product and purify discharge.Oily sludge removes moisture removal and oil, becomes clean soil, after cooling is quenched, can be used for backfilling or planting.

Description

A kind of oily sludge disposal system and its disposing technique
Technical field
The present invention relates to Waste Disposal Technology fields, and in particular to a kind of oily sludge disposal system and its disposition work Skill.
Background technique
Oily sludge is the oily solid sludge of generation during oil exploitation, transport, refining and oily waste water treatment, is One of main polluting waste generated in oil and gas development and storage and transport process.In oily sludge containing a large amount of benzene homologues, phenols, The noxious material of the foul smellings such as anthracene, pyrene, but these substances are also oil component simultaneously.Oily sludge is both in oilfield process The waste of generation, while being also a kind of resource, if oily sludge is not pocessed recycling oil therein, not only pollute ring Border, and cause the waste of resource.The processing of oily sludge is always a great problem in oil field.For many years, China oil field The essentially discarded oil pit landfill of the greasy filth disposal options in area, this kind of nonstandard discarded and disposal process are brought very to environment Big pollution hidden trouble.Harmless treatment and Oil residue recuperation are carried out to oily sludge using suitable technological means, can not only be generated Certain economic benefit, and meeting pollution abatement, bring huge environmental benefit and social benefit.
Method of disposal common for oily sludge includes solvent extraction, incineration method, bioanalysis, indirect thermal phase point at present From method etc..
1, the process object of incineration method, burning is mainly greasy filth of the oil content 5~10%, and incineration temperature general control exists 800~1000 DEG C, time control is burned in 0.5~1.5h, using 50~100% excess airs.China part oil plant has Sludge incineration device, the downflow type rotary incinerator used such as Hubei Jingmen petrochemical plant, Chang Ling petrochemical plant, Yanshan Petrochemical use Fluidized bed incinerator, etc..After burning disposal, multiple harmful substances almost all removes oily sludge, works well.But It invests big, and operating cost is high, need to often be added combustion-supporting fuel, with serious air pollution in burning process, and cannot return Crude oil is received, the soil after burning is not suitable for planting.
2, solvent extraction, solvent extraction are a kind of for handling the technology of the small oily sludge of the more particles of silt. The technology utilization extractant dissolves oily sludge, and after agitated and centrifugation, most of organic matter and oil are extracted agent from mud It extracts;Then recycling extract liquor, which is distilled, is separated from the mixture solvent to be recycled, and oil is used after mutually recycling In refining again.Solvent extraction generally carries out at room temperature, and solvent is better than bigger effect of extracting, but solvent is than big extraction equipment The load becomes large, and energy consumption is relatively large.Largely fail the related request for reaching country by sludge extracted, still contains Higher oil remains a kind of hazardous waste, need to further dispose.Since cost of disposal is high and technique need to be further complete Kind, extraction is applied to refinery's disposal of oily sludge not yet.
3, bioanalysis, microbial degradation are degraded using original or microbe inoculation (i.e. other microorganisms of fungi, bacterium) (metabolism) pollutant in soil, and convert pollutant to the process of harmless end prod.The technology to the consumption of energy compared with It is low, can be with the biggish contaminated site of repaired area, but be affected by environmental factor, cannot degrade all dirts into environment Object is contaminated, specified microorganisms are only degraded specific pollutants.Process is slow at low temperature for biodegrade, and repair time is long, it usually needs Several years.The shadow of many factors such as the contaminated physical property matter of biological prosthetic remediation efficiency, Ecological Distribution of Soil Microorganisms structure, soil property It rings, and more demanding to the nutritional condition in soil.If soil media contaminant restraining microorganism, possibly mesh can not be removed Mark.The temperature, pH value, nutrient amount etc. for needing to control place are allowed to meet the survival environmental conditions of microorganism.Due to many The limitation of condition, bioanalysis are not applied to refinery's disposal of oily sludge yet.
4, indirect thermal phase separation method, indirect thermal phase separation method refer to that one kind by indirect heating oily sludge, is separated and simultaneously returned The method for receiving oily phase.Indirect thermal phase detachment technique passes through heat transfer using the extraneous high-temperature flue gas heating pyrolysis cavity generated Mode indirect heating oily sludge, its moisture and oil are evaporated, and are introduced condenser and are carried out spray condensation and water-oil separating, It is finally reached the purpose of oil recovery phase.The technology has many advantages, such as that technical process is simple, disposition effect is good.But indirect heat transmission Heat transfer efficiency is very low, and disposal of oily sludge amount is not high, and currently used indirect thermal device for phase saparation monomer treating capacity only has 1~2 Ton/hour, affect the large-scale application of technique.Indirect thermal phase detachment technique is very high to the material requirements of pyrolysis cavity, There should be good heat transfer efficiency to guarantee that grease sufficiently evaporates, there is good shell rigidity to guarantee the smooth operation of material again.It is right For material, the two attributes are a paradox, at present still without extraordinary solution, to affect technique Further genralrlization.
In conclusion currently used oily sludge method of disposal all has some limitations, incineration method cannot be recycled Crude oil, and the soil after burning is not suitable for planting;Solvent extraction cost of disposal is high, and soil extracted is many times It does not reach requirement;Bioanalysis is affected by environmental factor, and repair time is long;Indirect thermal phase separation method is then since heat transfer is imitated The problem of rate and material property, affects the large-scale application and popularization of the technology.
Summary of the invention
The technical problem to be solved by the present invention is in view of the deficiencies of the prior art, provide it is a kind of needed for equipment it is relatively easy, Cost is relatively low, can greatly improve heat transference efficiency, can sufficiently recycle remaining oil product, and can optimize the plantation performance of soil simultaneously Avoid pollution the oily sludge disposal system and its disposing technique of air.
In order to solve the above technical problems, the present invention adopts the following technical scheme: a kind of oily sludge disposal system, includes Thermal desorption system, oil gas disposal system and oil recovery systems, thermal desorption system are docked with oil gas disposal system, oil gas disposition system System is mutually butted with oil recovery systems;
The thermal desorption system includes thermal desorption kiln, hot air chamber and the first deduster, and the oil gas disposal system includes There are subregion expansion chamber, spray column, scrubbing tower, burning chamber, heat exchanger and the second deduster, the oil recovery systems include three Phase separator, spray column spray gun and scrubbing tower spray gun;
The kiln hood of thermal desorption kiln is docked with sewage sludge feed mechanism, and kiln tail is then docked with hot air chamber;Hot air chamber and oil gas are disposed The heat exchanger of system is docked to access hot-air, and hot air chamber also accesses natural gas;Road traffic direction in thermal desorption kiln For gentle road transport line direction on the contrary, sludge is advanced from the kiln hood of thermal desorption kiln toward kiln tail, the kiln tail of high-temperature flue gas from thermal desorption kiln is past Kiln hood is advanced;Thermal desorption kiln is additionally provided with clean soil outlet, and clean soil outlet is docked with the first deduster, the first deduster Dock smoke evacuation system;
Subregion expansion chamber is docked with the mixed gas outlet at thermal desorption kiln kiln hood to receive the mixing in thermal desorption kiln The material outlet of gas, subregion expansion chamber is docked with sewage sludge feed mechanism, receives the powder that sedimentation obtains by sewage sludge feed mechanism Dirt material;The oil gas vent of subregion expansion chamber is docked with spray column, and the lower part of spray column is connected to be formed with the lower part of scrubbing tower to be contained The structure for conveying of oil gas body;Mixed gas outlet at the top of scrubbing tower is docked with burning chamber;Burning chamber and heat exchanger form annular Connection, and burning chamber also accesses natural gas;Heat exchanger is docked with the second deduster, and the second deduster docks smoke evacuation system;
Cyclic water tank is equipped in three phase separator, cyclic water tank is connected separately with spray column spray gun and washing by circulating pump Tower spray gun, spray column spray gun access in spray column, and the top in scrubbing tower is arranged in scrubbing tower spray gun;Three phase separator it is defeated Entrance is connect with the liquid outlet of the liquid outlet of spray tower bottom and wash tower bottoms respectively, and the bottom of three phase separator is additionally provided with Spoil disposal outlet.
Further, the sewage sludge feed mechanism includes feeding hopper, conveyor belt and deflector chute, and feeding hopper is set to defeated The head end of belt is sent, deflector chute is set to below the tail end of conveyor belt for receiving oily sludge, and thermal desorption kiln connects guide Slot.
Further, the clean soil outlet of the thermal desorption kiln forms cooling to clean soil to quenched cooler is connected to Mechanism, quenched cooler dock clean soil storage cavern to chain scraper conveyor, chain scraper conveyor is connected to;First deduster and quenched cooling Device docking forms the dedusting mechanism to the dust-laden exhaust gas after cooling clean soil.
Further, the first deduster is docked by the first blower with chimney, and the second deduster is by the second blower and is somebody's turn to do Chimney docking is equipped with pollutant in the chimney and monitors mechanism on-line.
Further, the material outlet of subregion expansion chamber is docked to feed back reamer, feed back reamer is connected to conveyor belt, is led to It crosses the dust that feed back reamer collects expansion chamber and inputs thermal desorption kiln again by conveyor belt.
Further, heat exchanger is connected with air blower, by air blower towards heat exchanger input air.
Further, it is equipped in heat exchanger and carries out the heat exchanger tube of heat exchange for burning gas and air, wherein burning gas Pass through from shell side, air passes through from tube side.
Further, it is equipped with screw input feeder in the bottom of three phase separator, by screw input feeder by three phase separator Interior sedimentary clay is discharged and sends thermal desorption kiln back to.
A kind of disposing technique based on aforementioned oily sludge disposal system, it is characterised in that: oily sludge is filled by loading machine Enter feeding hopper, is delivered to deflector chute through conveyor belt, feeds thermal desorption kiln;Natural gas and the hot-air from oil gas disposal system It burns in hot air chamber, forms high-temperature flue gas and enter thermal desorption kiln;Enter the oily sludge of thermal desorption kiln in kiln varus from kiln hood Rolling is advanced, and is directly contacted with high-temperature flue gas, and the heat in flue gas is absorbed, and temperature increases, and moisture gradually evaporates;Dewatered oil-containing Sludge and the higher smoke contacts of temperature, temperature further increases after heat absorption, and oil contained in sludge gradually evaporates;Work as sludge Temperature be increased to certain phase after, oil all cracking and evaporation, be left clean soil and carbon granules;Anhydrous oil-free clean soil And thermal desorption kiln is discharged from kiln tail in carbon granules, is sent after air and water mist cooling are quenched by chain scraper conveyor into quenched cooler Enter clean soil storage cavern temporarily to store, waits outward transport;
Burn the high-temperature flue gas of formation in hot air chamber, after entering thermal desorption kiln from kiln tail, transfers heat to containing greasy dirt Mud, the temperature of itself constantly reduce;Meanwhile the aqueous vapor and oil-gas formation being evaporated from oily sludge are by flue gas, aqueous vapor With mixed gas made of air-fuel mixture;After the mixed gas of oily transfers heat to sludge, thermal desorption is discharged from kiln hood Kiln recycles oil product contained in mixed gas into oil gas disposal system;
Air and water mist quenched cooler the clean soil containing carbon granules is carried out cool down it is quenched after, form dust-laden exhaust gas;From The dust-laden exhaust gas that quenched cooler comes out enters the first deduster, is extracted out after dust separation by the first blower, is sent into chimney and is discharged into Atmosphere;Chimney is equipped with on-line computing model, monitors the concentration of emission of dust on-line;The dust collected through the first deduster is fallen into Chain scraper conveyor is sent into clean soil storage cavern and is temporarily stored with the clean soil containing carbon granules;
The mixed gas containing oil gas and dust come out from thermal desorption kiln enters subregion expansion chamber, and subregion expansion chamber is divided into Four regions, successively behind this four regions, most dust settlings gets off mixed gas;It is settled from subregion expansion chamber The dust to get off is transmitted back to thermal desorption system by feed back reamer after collecting, and is sent into heat through conveyor belt together with oily sludge and takes off Attached kiln processing;
Oil-containing gases after dedusting enter spray column, and the recirculated water from oil recovery systems is sprayed into through spray column spray gun to be sprayed Tower is drenched, oil-containing gases temperature under the cooling of shower water reduces, and the oil in gas becomes liquid by gaseous state, partially enters spray In water, and enter oil recovery systems with shower water;It is not sprayed during the dust that subregion expansion chamber settles down is in spray Water drenching collects to form mud, and enters oil recovery systems with shower water;
The tiny oil droplets for not entering shower water enter scrubbing tower with oil-containing gases, the recirculated water warp from oil recovery systems Scrubbing tower spray gun sprays into scrubbing tower;Oil-containing gases are run from bottom to top in scrubbing tower, washing water in scrubbing tower from top to bottom Wash oil-containing gases;After oil-containing gases are washed, most tiny oil droplets enter in washing water, and enter oil product with washing water Recovery system, scrubbing tower outlet are equipped with demister, the tiny oil droplets in further gas recovery;
Mixed gas after the washing of washed tower, thus cannot be straight due to still containing a small amount of tiny oil droplets and non-congealable oil gas Run in and puts and need to be for further processing;Mixed gas enters burning chamber from scrubbing tower, mixes with the hot-air from heat exchanger, in day The combustion-supporting lower burning of right gas, the tiny oil droplets contained in mixed gas and fixed gas are thoroughly destroyed by fire;Gas is burnt from burning chamber Into heat exchanger preheated air, it is equipped with heat exchanger tube in heat exchanger, gas and air is burnt by heat exchanger tube and carries out heat exchange, wherein It burns gas and walks shell side, air walks tube side;Air is blasted the tubulation in heat exchanger by air blower, and air is burnt by tube wall absorption The heat that gas passes over forms high-temperature hot air;The hot-air for exchanging heat out from heat exchanger is divided into two-way, enters combustion all the way Purification mixed gas is burned in cinder room, in addition enters the combustion-supporting natural gas of thermal desorption system all the way, provides for the thermal desorption of oily sludge Heat;
It burns after gas transfers heat to air, is come out from heat exchanger and enter the second deduster, dust separation;Through dedusting The gas that burns afterwards is extracted out by the second blower, is discharged into atmosphere by chimney;
The shower water and washing water come out from oil gas disposal system flows into three phase separator;Shower water and washing water disposition contain After cooking fume, the mud formed in water containing a certain number of oil and a small amount of dust needs to carry out oil, water, mud three phase separation; Grease mud three-phase mixture in three phase separator is under the collective effect of macromolecule medicament and ultrasonic wave, continuous high speed between particle Collision, tiny oil droplets increase hundreds times, and flocculation of sludge is at walk;Since the density of oil, water, mud is different, under gravity Realize three phase separation;The oil product for being suspended in three phase separator napex is pumped into oil tank storage by oil pump, is deposited on three phase separator bottom The mud in portion is discharged by the screw input feeder of separator bottom, is sent thermal desorption system back to and is disposed again;
Water after three phase separation imports the cyclic water tank set in three phase separator, cyclic water tank and circulation by guiding device Water pump is connected, and water circulating pump extracts water out from cyclic water tank, send to spray column spray gun and scrubbing tower spray gun, sprays into oil gas respectively The spray column and scrubbing tower of disposal system wash oil gas, recycle oil product;The shower water and washing water of oil-containing flow back to three phase separation again Device, three phase separation, is recycled again.
The present invention, creatively will be directly hot by using for reference the basic principle directed heat transfer in clinker production process Desorption technology is applied to the disposition of oily sludge, can greatly improve heat transference efficiency, sufficiently recycle remaining oil product, and optimize soil The plantation performance of earth.In thermal desorption kiln, the high-temperature flue gas generated from outside is transmitted with oily sludge by the direct way of contact Heat, high-temperature flue gas by oily sludge moisture and oil be evaporated, into oil gas dispose process, recycling oil product simultaneously purify Discharge, avoids pollution air.Oily sludge removes moisture removal and oil, becomes clean soil, after cooling is quenched, can be used for backfill or Plantation, to realize huge economic benefit, environmental benefit and social benefit.
Detailed description of the invention
Fig. 1 is present system structural schematic diagram.
In figure, 11 be feeding hopper, and 12 be conveyor belt, and 13 be deflector chute, and 14 be thermal desorption kiln, and 15 be quenched cooler, 16 be chain scraper conveyor, and 17 be hot air chamber, and 18 be the first deduster, and 19 be the first blower, and 21 be subregion expansion chamber, and 22 be feed back Reamer, 23 be spray column, and 24 be scrubbing tower, and 25 be burning chamber, and 26 be heat exchanger, and 27 be air blower, and 28 be the second deduster, 29 It is chimney for the second blower, 20,31 be three phase separator, and 32 be water circulating pump, and 33 be spray column spray gun, and 34 spray for scrubbing tower Rifle.
Specific embodiment
In the present embodiment, referring to Fig.1, the oily sludge disposal system includes thermal desorption system, oil gas disposal system And oil recovery systems, thermal desorption system are docked with oil gas disposal system, oil gas disposal system and oil recovery systems are mutually right It connects;
The thermal desorption system includes thermal desorption kiln 14, hot air chamber 17 and the first deduster 18, oil gas disposition system System includes subregion expansion chamber 21, spray column 23, scrubbing tower 24, burning chamber 25, heat exchanger 26 and the second deduster 28, the oil Product recovery system includes three phase separator 31, spray column spray gun 33 and scrubbing tower spray gun 34;
The kiln hood of thermal desorption kiln 14 is docked with sewage sludge feed mechanism, and kiln tail is then docked with hot air chamber 17;Hot air chamber 17 and oil The heat exchanger 26 of gas disposal system is docked to access hot-air, and hot air chamber 17 also accesses natural gas;In thermal desorption kiln 14 The gentle road transport line direction of road traffic direction is on the contrary, sludge is advanced from the kiln hood of thermal desorption kiln 14 toward kiln tail, and high-temperature flue gas is from warm The kiln tail that kiln 14 is desorbed is advanced toward kiln hood;Thermal desorption kiln 14 is additionally provided with clean soil outlet, and clean soil outlet is removed with first Dirt device 18 docks, and the first deduster 18 docks smoke evacuation system;
Subregion expansion chamber 21 is docked with the mixed gas outlet at 14 kiln hood of thermal desorption kiln to receive in thermal desorption kiln The material outlet of mixed gas, subregion expansion chamber 21 is docked with sewage sludge feed mechanism, is settled by the reception of sewage sludge feed mechanism The particulate dust arrived;The oil gas vent of subregion expansion chamber 21 is docked with spray column 23, lower part and the scrubbing tower 24 of spray column 23 Lower part is connected to the structure for conveying to form oil-containing gases, moves oil-containing gases from the bottom up;The mixed gas at 24 top of scrubbing tower It is docked with burning chamber 25 outlet;Burning chamber 25 and heat exchanger 26 form annular connection, and burning chamber 25 also accesses natural gas;It changes Hot device 26 is docked with the second deduster 28, and the second deduster 28 docks smoke evacuation system;
Cyclic water tank is equipped in three phase separator 31, cyclic water tank is connected separately with 33 He of spray column spray gun by circulating pump Scrubbing tower spray gun 34, spray column spray gun 33 access in spray column 23, and the top in scrubbing tower 24 is arranged in scrubbing tower spray gun 34; The input port of three phase separator 31 is connect with the liquid outlet of 24 bottom of the liquid outlet of 23 bottom of spray column and scrubbing tower respectively, and three The bottom of phase separator 31 is additionally provided with spoil disposal outlet.
The sewage sludge feed mechanism includes feeding hopper 11, conveyor belt 12 and deflector chute 13, and feeding hopper 11 is set to defeated The head end of belt 12 is sent, deflector chute 13 is set to below the tail end of conveyor belt 12 for receiving oily sludge, thermal desorption kiln 14 Connect deflector chute 13.
The clean soil outlet of the thermal desorption kiln 14 forms cooling body to clean soil to quenched cooler 15 is connected to, Quenched cooler 15 docks clean soil storage cavern to chain scraper conveyor 16, chain scraper conveyor 16 is connected to;First deduster 18 with it is quenched Cooler 15 docks, and forms the dedusting mechanism to the dust-laden exhaust gas after cooling clean soil.
First deduster 18 is docked by the first blower 19 with chimney 20, and the second deduster 28 is by the second blower 29 and is somebody's turn to do Chimney 20 docks, and pollutant is equipped in the chimney 20 and monitors mechanism on-line, to monitor the pollutants such as dust.
The material outlet of subregion expansion chamber 21 is docked to feed back reamer 22, feed back reamer 22 is connected to conveyor belt 12, is led to It crosses the dust that feed back reamer 22 collects expansion chamber and inputs thermal desorption kiln 14 again by conveyor belt.
Heat exchanger 26 is connected with air blower 27, by air blower 27 towards heat exchanger input air.
It is equipped in heat exchanger 26 and carries out the heat exchanger tube of heat exchange for burning gas and air, wherein it is logical from shell side to burn gas It crosses, air passes through from tube side.
It is equipped with screw input feeder in the bottom of three phase separator 31, it will be heavy in three phase separator 31 by screw input feeder Deposition is discharged and sends thermal desorption kiln 14 back to.
A kind of disposing technique based on aforementioned oily sludge disposal system: oily sludge is packed into feeding hopper 11 by loading machine, It is delivered to deflector chute 13 through conveyor belt 12, feeds thermal desorption kiln 14;Natural gas and the hot-air from oil gas disposal system exist It burns in hot air chamber 17, forms high-temperature flue gas and enter thermal desorption kiln 14;Enter the oily sludge of thermal desorption kiln 14 in kiln from kiln hood Interior rolling is advanced, and is directly contacted with high-temperature flue gas, and the heat in flue gas is absorbed, and temperature increases, and moisture gradually evaporates;It is dewatered Oily sludge and the higher smoke contacts of temperature, temperature further increases after heat absorption, and oil contained in sludge gradually evaporates;When After the temperature of sludge is increased to certain phase, clean soil and carbon granules are left in oil all cracking and evaporations;It is anhydrous oil-free clean The pure land and carbon granules are from kiln tail discharge thermal desorption kiln 14, into quenched cooler 15, after air and water mist cooling are quenched, by carrier bar Conveyer 16 is sent into clean soil storage cavern and is temporarily stored, and outward transport is waited;
Burn the high-temperature flue gas of formation in hot air chamber 17, after entering thermal desorption kiln 14 from kiln tail, transfers heat to and contains Greasy dirt, the temperature of itself constantly reduce;Meanwhile the aqueous vapor that is evaporated from oily sludge and oil-gas formation by flue gas, Mixed gas made of aqueous vapor and air-fuel mixture;After the mixed gas of oily transfers heat to sludge, heat is discharged from kiln hood Kiln 14 is desorbed, into oil gas disposal system, recycles oil product contained in mixed gas;
Air and water mist quenched cooler 15 clean soil containing carbon granules is carried out cool down it is quenched after, form dust-laden exhaust gas; The dust-laden exhaust gas come out from quenched cooler 15 enters the first deduster 18, is extracted out after dust separation by the first blower 19, is sent into Chimney 20 is discharged into atmosphere;Chimney 20 is equipped with on-line computing model, monitors the concentration of emission of dust on-line;It is collected through the first deduster 19 The dust to get off falls into chain scraper conveyor 16, with the clean soil containing carbon granules, is sent into clean soil storage cavern and temporarily stores;
The mixed gas containing oil gas and dust come out from thermal desorption kiln 14 enters subregion expansion chamber 21, subregion expansion chamber 21 are divided into four regions, and mixed gas is successively behind this four regions, and most dust settlings gets off, due to these powder Dirt contains oily sludge on a small quantity without thermal desorption, therefore cannot function as clean soil;The powder to settle down from subregion expansion chamber 21 Dirt is transmitted back to thermal desorption system by feed back reamer 22 after collecting, and is sent into thermal desorption kiln 14 through conveyor belt together with oily sludge Processing;
Oil-containing gases after dedusting enter spray column 23, and the recirculated water from oil recovery systems is sprayed through spray column spray gun 33 Enter spray column 23, oil-containing gases temperature under the cooling of shower water reduces, and the oil in gas becomes liquid by gaseous state, partially into Enter in shower water, and enters oil recovery systems with shower water;It was not being sprayed in the dust that subregion expansion chamber 21 settles down It is collected to form mud by shower water in journey, and enters oil recovery systems with shower water;
The tiny oil droplets for not entering shower water enter scrubbing tower 24 with oil-containing gases, the recirculated water from oil recovery systems Washed tower spray gun 34 sprays into scrubbing tower 24;Oil-containing gases are run from bottom to top in scrubbing tower 24, and washing water is in scrubbing tower Oil-containing gases are washed from top to bottom;After oil-containing gases are washed, most tiny oil droplets enter in washing water, and with washing water Into oil recovery systems, the outlet of scrubbing tower 24 is equipped with demister, the tiny oil droplets in further gas recovery;
Washed tower 24 wash after mixed gas due to still containing a small amount of tiny oil droplets and non-congealable oil gas, thus cannot Direct emission need to be for further processing;Mixed gas enters burning chamber 25 from scrubbing tower 24, with the hot-air from heat exchanger 26 Mixing, in the combustion-supporting lower burning of natural gas, the tiny oil droplets contained in mixed gas and fixed gas are thoroughly destroyed by fire;Burn gas Enter 26 preheated air of heat exchanger from burning chamber 25, is equipped with heat exchanger tube in heat exchanger 26, burns gas and air passes through heat exchanger tube Heat exchange is carried out, wherein burning gas walks shell side, air walks tube side;Air is blasted the tubulation in heat exchanger 26 by air blower 27, Air absorbs the heat for burning gas and passing over by tube wall, forms high-temperature hot air;The heat come out from the heat exchange of heat exchanger 26 Air is divided into two-way, enters burning chamber 25 all the way and burns purification mixed gas, and it is combustion-supporting natural in addition to enter thermal desorption system all the way Gas provides heat for the thermal desorption of oily sludge;
It burns after gas transfers heat to air, is come out from heat exchanger 26 and enter the second deduster 28, dust separation;Through The gas that burns after dedusting is extracted out by the second blower 29, is discharged into atmosphere by chimney 20;
The shower water and washing water come out from oil gas disposal system flows into three phase separator 31;Shower water and washing water disposition After oil-contg. smoke, the mud formed in water containing a certain number of oil and a small amount of dust needs to carry out oil, water, mud three-phase separate From;Grease mud three-phase mixture in three phase separator 31 connects between particle under the collective effect of macromolecule medicament and ultrasonic wave Continuous high velocity impact, tiny oil droplets increase hundreds times, and flocculation of sludge is at walk;Since the density of oil, water, mud is different, in gravity Effect is lower to realize three phase separation;The oil product for being suspended in 31 napex of three phase separator is pumped into oil tank storage by oil pump, is deposited on three-phase The mud of 31 bottom of separator is discharged by the screw input feeder of separator bottom, is sent thermal desorption system back to and is disposed again;
Water after three phase separation imports the cyclic water tank set in three phase separator 31 by guiding device, cyclic water tank with follow Ring water pump 32 is connected, and water circulating pump 32 extracts water out from cyclic water tank, send to spray column spray gun 33 and scrubbing tower spray gun 34, point Not Pen Ru oil gas disposal system spray column 23 and scrubbing tower 24 wash oil gas, recycle oil product;The shower water and washing water of oil-containing Three phase separator 31 is flowed back to again, again three phase separation, be recycled.
The above has been described in detail, described above, is only a preferred embodiment of the present invention, when cannot It limit the scope of implementation of the present invention, i.e., it is all according to the made equivalent changes and modifications of the application range, it should still belong to covering scope of the present invention It is interior.

Claims (9)

1. a kind of oily sludge disposal system, it is characterised in that: include thermal desorption system, oil gas disposal system and Oil Recovery System, thermal desorption system are docked with oil gas disposal system, and oil gas disposal system is mutually butted with oil recovery systems;
The thermal desorption system includes thermal desorption kiln, hot air chamber and the first deduster, and the oil gas disposal system includes point Area's expansion chamber, spray column, scrubbing tower, burning chamber, heat exchanger and the second deduster, the oil recovery systems include three-phase separate From device, spray column spray gun and scrubbing tower spray gun;
The kiln hood of thermal desorption kiln is docked with sewage sludge feed mechanism, and kiln tail is then docked with hot air chamber;Hot air chamber and oil gas disposal system Heat exchanger dock to access hot-air, and hot air chamber also accesses natural gas;Road traffic direction in thermal desorption kiln is gentle Road transport line direction is on the contrary, sludge is advanced from the kiln hood of thermal desorption kiln toward kiln tail, and high-temperature flue gas is from the kiln tail of thermal desorption kiln toward kiln hood It advances;Thermal desorption kiln is additionally provided with clean soil outlet, and clean soil outlet is docked with the first deduster, the docking of the first deduster Smoke evacuation system;
Subregion expansion chamber is docked with the mixed gas outlet at thermal desorption kiln kiln hood to receive the mixed gas in thermal desorption kiln, The material outlet of subregion expansion chamber is docked with sewage sludge feed mechanism, receives the dust object that sedimentation obtains by sewage sludge feed mechanism Material;The oil gas vent of subregion expansion chamber is docked with spray column, and the lower part of spray column is connected to form oily with the lower part of scrubbing tower The structure for conveying of body;Mixed gas outlet at the top of scrubbing tower is docked with burning chamber;Burning chamber and heat exchanger form annular connection, And burning chamber also accesses natural gas;Heat exchanger is docked with the second deduster, and the second deduster docks smoke evacuation system;
Cyclic water tank is equipped in three phase separator, cyclic water tank is connected separately with spray column spray gun by circulating pump and scrubbing tower sprays Rifle, spray column spray gun access in spray column, and the top in scrubbing tower is arranged in scrubbing tower spray gun;The input port of three phase separator It is connect respectively with the liquid outlet of the liquid outlet of spray tower bottom and wash tower bottoms, and the bottom of three phase separator is additionally provided with spoil disposal Outlet.
2. oily sludge disposal system according to claim 1, it is characterised in that: the sewage sludge feed mechanism includes to feed Hopper, conveyor belt and deflector chute, feeding hopper are set to the head end of conveyor belt, and deflector chute is set under the tail end of conveyor belt Side connects deflector chute for receiving oily sludge, thermal desorption kiln.
3. oily sludge disposal system according to claim 2, it is characterised in that: the clean soil of the thermal desorption kiln is discharged Mouthful cooling body to clean soil is formed to being connected to quenched cooler, quenched cooler is to being connected to chain scraper conveyor, carrier bar conveying Machine docks clean soil storage cavern;First deduster is docked with quenched cooler, forms removing to the dust-laden exhaust gas after cooling clean soil Dirt mechanism.
4. oily sludge disposal system according to claim 3, it is characterised in that: the first deduster by the first blower with Chimney docking, the second deduster are docked by the second blower with the chimney, and pollutant is equipped in the chimney and monitors mechanism on-line.
5. oily sludge disposal system according to claim 4, it is characterised in that: the material outlet of subregion expansion chamber docks Have feed back reamer, feed back reamer is docked with conveyor belt, the dust collected expansion chamber by feed back reamer again by Conveyor belt inputs thermal desorption kiln.
6. oily sludge disposal system according to claim 5, it is characterised in that: heat exchanger is connected with air blower.
7. oily sludge disposal system according to claim 6, it is characterised in that: be equipped in heat exchanger for burn gas and Air carries out the heat exchanger tube of heat exchange, passes through wherein burning gas from shell side, air passes through from tube side.
8. oily sludge disposal system according to claim 7, it is characterised in that: be equipped with spiral shell in the bottom of three phase separator Feeder is revolved, the sedimentary clay in three phase separator is discharged by screw input feeder and sends thermal desorption kiln back to.
9. a kind of disposing technique of oily sludge disposal system according to any one of claims 8, it is characterised in that: oily sludge is by loading Machine is packed into feeding hopper, is delivered to deflector chute through conveyor belt, feeds thermal desorption kiln;Natural gas and the heat from oil gas disposal system Air burns in hot air chamber, forms high-temperature flue gas and enters thermal desorption kiln;Enter the oily sludge of thermal desorption kiln in kiln from kiln hood Interior rolling is advanced, and is directly contacted with high-temperature flue gas, and the heat in flue gas is absorbed, and temperature increases, and moisture gradually evaporates;It is dewatered Oily sludge and the higher smoke contacts of temperature, temperature further increases after heat absorption, and oil contained in sludge gradually evaporates;When After the temperature of sludge is increased to certain phase, clean soil and carbon granules are left in oil all cracking and evaporations;It is anhydrous oil-free clean The pure land and carbon granules are conveyed after air and water mist cooling are quenched by carrier bar from kiln tail discharge thermal desorption kiln into quenched cooler Machine is sent into clean soil storage cavern and is temporarily stored, and outward transport is waited;
Burn the high-temperature flue gas of formation in hot air chamber, after entering thermal desorption kiln from kiln tail, transfers heat to oily sludge, from The temperature of body constantly reduces;Meanwhile the aqueous vapor and oil-gas formation being evaporated from oily sludge are by flue gas, aqueous vapor and oil gas The mixed gas mixed;After the mixed gas of oily transfers heat to sludge, thermal desorption kiln is discharged from kiln hood, enters Oil gas disposal system recycles oil product contained in mixed gas;
Air and water mist quenched cooler the clean soil containing carbon granules is carried out cool down it is quenched after, form dust-laden exhaust gas;From quenched The dust-laden exhaust gas that cooler comes out enters the first deduster, is extracted out after dust separation by the first blower, is sent into chimney and is discharged into atmosphere; Chimney is equipped with on-line computing model, monitors the concentration of emission of dust on-line;The dust collected through the first deduster falls into carrier bar Conveyer is sent into clean soil storage cavern and is temporarily stored with the clean soil containing carbon granules;
The mixed gas containing oil gas and dust come out from thermal desorption kiln enters subregion expansion chamber, and subregion expansion chamber is divided into four Region, successively behind this four regions, most dust settlings gets off mixed gas;It settles down from subregion expansion chamber Dust thermal desorption system is transmitted back to by feed back reamer after collecting, together with oily sludge through conveyor belt be sent into thermal desorption kiln Processing;
Oil-containing gases after dedusting enter spray column, and the recirculated water from oil recovery systems is sprayed into through spray column spray gun and sprayed Tower, oil-containing gases temperature under the cooling of shower water reduce, and the oil in gas becomes liquid by gaseous state, partially enters shower water In, and enter oil recovery systems with shower water;It is not sprayed during the dust that subregion expansion chamber settles down is in spray Water is collected to form mud, and enters oil recovery systems with shower water;
The tiny oil droplets for not entering shower water enter scrubbing tower with oil-containing gases, and the recirculated water from oil recovery systems is washed Tower spray gun sprays into scrubbing tower;Oil-containing gases are run from bottom to top in scrubbing tower, and washing water washs from top to bottom in scrubbing tower Oil-containing gases;After oil-containing gases are washed, most tiny oil droplets enter in washing water, and enter Oil Recovery with washing water System, scrubbing tower outlet are equipped with demister, the tiny oil droplets in further gas recovery;
Mixed gas after washed tower washing cannot be arranged directly due to still containing a small amount of tiny oil droplets and non-congealable oil gas Putting need to be for further processing;Mixed gas enters burning chamber from scrubbing tower, mixes with the hot-air from heat exchanger, in natural gas Combustion-supporting lower burning, the tiny oil droplets contained in mixed gas and fixed gas are thoroughly destroyed by fire;Gas is burnt to enter from burning chamber Heat exchanger preheated air, heat exchanger is interior to be equipped with heat exchanger tube, burns gas and air by heat exchanger tube and carries out heat exchange, wherein burning Gas walks shell side, and air walks tube side;Air is blasted the tubulation in heat exchanger by air blower, and air burns gas by tube wall absorption The heat passed over forms high-temperature hot air;The hot-air for exchanging heat out from heat exchanger is divided into two-way, enters burning chamber all the way Purification mixed gas is burned, in addition enters the combustion-supporting natural gas of thermal desorption system all the way, provides heat for the thermal desorption of oily sludge;
It burns after gas transfers heat to air, is come out from heat exchanger and enter the second deduster, dust separation;After dedusting It burns gas to be extracted out by the second blower, atmosphere is discharged by chimney;
The shower water and washing water come out from oil gas disposal system flows into three phase separator;Shower water and washing water disposition contain oil smoke After gas, the mud formed in water containing a certain number of oil and a small amount of dust needs to carry out oil, water, mud three phase separation;Three-phase Grease mud three-phase mixture in separator is under the collective effect of macromolecule medicament and ultrasonic wave, and continuous high speed touches between particle It hits, tiny oil droplets increase hundreds times, and flocculation of sludge is at walk;It is real under gravity since the density of oil, water, mud is different Existing three phase separation;The oil product for being suspended in three phase separator napex is pumped into oil tank storage by oil pump, is deposited on three phase separator bottom Mud by separator bottom screw input feeder be discharged, send thermal desorption system back to and dispose again;
Water after three phase separation imports the cyclic water tank set in three phase separator, cyclic water tank and water circulating pump by guiding device It is connected, water circulating pump extracts water out from cyclic water tank, send to spray column spray gun and scrubbing tower spray gun, sprays into oil gas disposition respectively The spray column and scrubbing tower of system wash oil gas, recycle oil product;The shower water and washing water of oil-containing flow back to three phase separator again, then Secondary three phase separation is recycled.
CN201811626488.3A 2018-12-28 2018-12-28 A kind of oily sludge disposal system and its disposing technique Pending CN109455899A (en)

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CN110550846A (en) * 2019-09-18 2019-12-10 纪禹操 Oily sludge harmless treatment process and equipment
CN111116006A (en) * 2019-12-26 2020-05-08 广州境薪环保服务有限公司 Circulating regenerative sludge treatment system and method
CN112871965A (en) * 2021-01-08 2021-06-01 中国石油天然气集团有限公司 Oil-containing solid waste heat treatment method and equipment
CN112960875A (en) * 2021-02-25 2021-06-15 广西博世科环保科技股份有限公司 Treatment method and treatment system for high-temperature thermochemical cleaning of heavy oil sludge
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CN115011369A (en) * 2022-06-15 2022-09-06 四川正迈时代环境科技有限公司 Thermal desorption treatment method for oil-based detritus mud
CN115531899A (en) * 2022-09-29 2022-12-30 江苏洁奥德工程技术有限公司 Oil-containing scum recycling treatment method and system
CN116947286A (en) * 2022-12-30 2023-10-27 成都启川新能源科技有限公司 Environment-friendly oil-containing sludge recycling treatment method

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Publication number Priority date Publication date Assignee Title
CN110550846A (en) * 2019-09-18 2019-12-10 纪禹操 Oily sludge harmless treatment process and equipment
CN111116006A (en) * 2019-12-26 2020-05-08 广州境薪环保服务有限公司 Circulating regenerative sludge treatment system and method
CN111116006B (en) * 2019-12-26 2022-04-01 广州境薪环保服务有限公司 Circulating regenerative sludge treatment system and method
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CN112960875A (en) * 2021-02-25 2021-06-15 广西博世科环保科技股份有限公司 Treatment method and treatment system for high-temperature thermochemical cleaning of heavy oil sludge
CN113772915A (en) * 2021-08-20 2021-12-10 新疆沃森环保科技有限责任公司 Equipment and process technology for integrally treating oily sludge through high-temperature oxidation pyrolysis thermal desorption
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CN115531899A (en) * 2022-09-29 2022-12-30 江苏洁奥德工程技术有限公司 Oil-containing scum recycling treatment method and system
CN116947286A (en) * 2022-12-30 2023-10-27 成都启川新能源科技有限公司 Environment-friendly oil-containing sludge recycling treatment method

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