CN109439259A - A kind of environmental protection household hybrid material and preparation method thereof - Google Patents
A kind of environmental protection household hybrid material and preparation method thereof Download PDFInfo
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- CN109439259A CN109439259A CN201811285599.2A CN201811285599A CN109439259A CN 109439259 A CN109439259 A CN 109439259A CN 201811285599 A CN201811285599 A CN 201811285599A CN 109439259 A CN109439259 A CN 109439259A
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- parts
- hybrid material
- environmental protection
- household hybrid
- protection household
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J171/00—Adhesives based on polyethers obtained by reactions forming an ether link in the main chain; Adhesives based on derivatives of such polymers
- C09J171/02—Polyalkylene oxides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
A kind of environmentally friendly household hybrid material provided by the invention, is made of: 30-35 parts of Silante terminated polyether polymer following parts by weight raw material；60-70 parts of filler；0.5-1 parts of deicer；0.5-1 parts of adhesive accelerant；0.1-0.5 parts of catalyst；0.1-0.5 parts of ultraviolet absorber；1-2 parts of pigment.The raw material sources of environmentally friendly household hybrid material of the invention are abundant, the product produced both had had good weatherability, durability, heat resistance, cold resistance, cementability, there is good environment friendly again, it is environment-protecting and non-poisonous, facilitate durable, the domestic blank in environmentally friendly house ornamentation hybrid material in the decoration of high-grade gap, therefore great development space and market application prospect are filled up.
Description
Technical field
The invention belongs to hybrid material fields more particularly to a kind of environmentally friendly household hybrid material and preparation method thereof.
Background technique
Currently, the environmentally friendly house ornamentation expensive goods that hybrid material is that gap is decorated, is suitable for during modern high-grade house ornamentation,
The floor ceramic tiles such as parlor, stair, toilet, kitchen, marble gap.It is environmentally protective, and VOC is intended to 0, waterproof and dampproof, no
The advantages that contraction, normal temperature cure speed is fast.Current other markets are such as: cement base joint trimming agent cohesive force is poor, and easily mouldy, cracking is received
Contracting is serious, needs the shortcomings that carrying out secondary joint filling.These materials of jointing agent, gap filler generally only have the function of filling, and hydrophobic is hated
Poor, the resistance to wiping of oiliness energy, anti-stain characteristic are poor.Extrudability difficult, poor flexibility of epoxies joint trimming agent etc. is with people's life water
Flat continuous raising, people actively find functional, harmless, environmentally friendly, green adhesive.
Environmentally friendly house ornamentation is comprehensive with hybrid material comprehensive comparison, improves appeal disadvantage, and the balance of various performances is excellent
It is good, not only there is good weatherability, durability, heat resistance, cold resistance, cementability, but also there is good environment friendly, environmental protection
It is nontoxic, facilitate durable, has filled up the domestic blank in environmentally friendly house ornamentation hybrid material in the decoration of high-grade gap, therefore great hair
Open up space and market application prospect.
Summary of the invention
Place in view of above-mentioned deficiencies of the prior art, the purpose of the present invention is to provide a kind of environmentally friendly household hybrid material and
Preparation method, it is intended to which it is poor to solve cohesive force, easily mouldy, cracking, shrinks serious, needs to carry out secondary joint filling, hydrophobic and lyophobic property
Can poor, resistance to wiping, the problem of anti-stain characteristic is poor, poor flexibility.
In order to achieve the above object, this invention takes following technical schemes:
A kind of environmental protection household hybrid material, which is characterized in that be made of following parts by weight raw material:
30-35 parts of Silante terminated polyether polymer；
60-70 parts of filler；
0.5-1 parts of deicer；
0.5-1 parts of adhesive accelerant；
0.1-0.5 parts of catalyst；
0.1-0.5 parts of ultraviolet absorber；
1-2 parts of pigment.
Preferably, the Silante terminated polyether polymer is at least one of SAX-015 and SAX-400.
Preferably, the filler is active nano-calcium carbonate, active coarse whiting, hydrophobicity aerosil, silicon powder, stone
At least one of English powder.
Preferably, the ultraviolet absorber is benzotriazole light stabilizer, low molecular weight hindered amine class light stabilizer, resists
At least one of oxidant.
Preferably, the deicer is at least one of vinyltrimethoxysilane, vinyltriethoxysilane.
Preferably, the adhesive accelerant be γ-aminopropyl triethoxysilane, 3- TSL 8330,
At least one of N- (mono- aminoethyl of β)-γ-aminopropyl front three (second) oxysilane.
Preferably, the catalyst is U-220 (dibutyl tin diacetyl acetonate), U-303H, 2 ethyl hexanoic acid, lauryl amine
At least one of.
A method of preparing the environmentally friendly household hybrid material as described in claim 1-7, which is characterized in that including following
Step:
(1), the end polyether polymer of silane envelope, filler, pigment, ultraviolet absorber are added to high viscosity mixer according to the ratio
In, it is stirred 30min, is in paste；
(2), then be evacuated to -0.09MPa, mix slowly and be warming up to 110 DEG C, until water content be down to 800ppm with
Under, continue stirring and be cooled to 40 DEG C, deicer and adhesion promoters are added, stir 30min under nitrogen protection；
(3), removing bubble is finally vacuumized, after the assay was approved packaging discharging.
Compared with prior art, beneficial effects of the present invention:
1. tensile strength reaches 6MPa or more, elongation can replace joint trimming agent as visitor up to 100% or more, hardness 95A
The floor ceramic tiles such as the Room, stair, toilet, kitchen, marble gap sealing, beauty requirement
2. curing rate is fast, 15 minutes surface cures, preliminary intensity, sufficiently solidification in 24 hours, than tradition are formed within 30 minutes
More than joint trimming agent solidification is fast again, decoration efficiency is greatly improved
3. the present invention has good caking property to multiple material, including to the big portion such as metal, timber, concrete, stone material
Divide construction material
4. environmentally protective, VOC is intended to 0, and one pack system is extrudability to reach 200ml/min, improves speed of application
Specific embodiment
To make the purpose of the present invention, technical solution and effect clearer, clear and definite, by the following examples to the present invention into one
Step is described in detail.It should be appreciated that described herein, specific examples are only used to explain the present invention, is not used to limit this hair
It is bright.
A kind of environmentally friendly household hybrid material provided by the invention, is made of following parts by weight raw material:
30-35 parts of Silante terminated polyether polymer；
60-70 parts of filler；
0.5-1 parts of deicer；
0.5-1 parts of adhesive accelerant；
0.1-0.5 parts of catalyst；
0.1-0.5 parts of ultraviolet absorber；
1-2 parts of pigment.
A method of preparing the environmentally friendly household hybrid material, comprising the following steps:
(1), the end polyether polymer of silane envelope, filler, pigment, ultraviolet absorber are added to high viscosity mixer according to the ratio
In, it is stirred 30min, is in paste；
(2), then be evacuated to -0.09MPa, mix slowly and be warming up to 110 DEG C, until water content be down to 800ppm with
Under, continue stirring and be cooled to 40 DEG C, deicer and adhesion promoters are added, stir 30min under nitrogen protection；
(3), removing bubble is finally vacuumized, after the assay was approved packaging discharging.
Embodiment one
The environmental protection household hybrid material includes following parts by weight raw material: 33 parts of MS Polymer SAX-015, activity
25 parts of coarse whiting, 5 parts of silicon powder, 2 parts of hydrophobic silica, 27.6 parts of active nano-calcium carbonate, 2 parts of pigment, ultraviolet absorber 3
Part, 1 part of deicer, 1 part of adhesive accelerant, 0.4 part of catalyst.
Embodiment two
The environmental protection household hybrid material includes following parts by weight raw material: 33 parts of MS Polymer SAX-400, activity
25 parts of coarse whiting, 5 parts of silicon powder, 2 parts of hydrophobic silica, 27.6 parts of active nano-calcium carbonate, 2 parts of pigment, ultraviolet absorber 3
Part, 1 part of deicer, 1 part of adhesive accelerant, 0.4 part of catalyst.
Embodiment three
The environmental protection household hybrid material includes following parts by weight raw material: 10 parts of MS Polymer SAX-015, SAX-
400 23 parts, active 25 parts of coarse whiting, 5 parts of silicon powder, 2 parts of hydrophobic silica, 27.6 parts of active nano-calcium carbonate, pigment 2
Part, 3 parts of ultraviolet absorber, 1 part of deicer, 1 part of adhesive accelerant, 0.4 part of catalyst.
Example IV
The environmental protection household hybrid material includes following parts by weight raw material: 23 parts of MS Polymer SAX-015, SAX-
400 10 parts, active 25 parts of coarse whiting, 5 parts of silicon powder, 2 parts of hydrophobic silica, 27.6 parts of active nano-calcium carbonate, pigment 2
Part, 3 parts of ultraviolet absorber, 1 part of deicer, 1 part of adhesive accelerant, 0.4 part of catalyst.
Embodiment five
The environmental protection household hybrid material includes following parts by weight raw material: 23 parts of MS Polymer SAX-015, SAX-
400 10 parts, active 5 parts of coarse whiting, 5 parts of silicon powder, 2 parts of hydrophobic silica, 12.6 parts of active nano-calcium carbonate, pigment 2
Part, 3 parts of ultraviolet absorber, 1 part of deicer, 1 part of adhesive accelerant, 0.4 part of catalyst.
The performance test results comparison of each embodiment is as follows under room temperature
It, can according to the technique and scheme of the present invention and its hair it is understood that for those of ordinary skills
Bright design is subject to equivalent substitution or change, and all these changes or replacement all should belong to the guarantor of appended claims of the invention
Protect range.
Claims (8)
1. a kind of environmental protection household hybrid material, which is characterized in that be made of following parts by weight raw material:
30-35 parts of Silante terminated polyether polymer；
60-70 parts of filler；
0.5-1 parts of deicer；
0.5-1 parts of adhesive accelerant；
0.1-0.5 parts of catalyst；
0.1-0.5 parts of ultraviolet absorber；
1-2 parts of pigment.
2. environmental protection household hybrid material as described in claim 1, which is characterized in that the Silante terminated polyether polymer is
At least one of SAX-015 and SAX-400.
3. environmental protection household hybrid material as described in claim 1, which is characterized in that the filler be active nano-calcium carbonate,
At least one of active coarse whiting, hydrophobicity aerosil, silicon powder, silica flour.
4. environmental protection household hybrid material as described in claim 1, which is characterized in that the ultraviolet absorber is benzotriazole
At least one of light stabilizer, low molecular weight hindered amine class light stabilizer, antioxidant.
5. environmental protection household hybrid material as described in claim 1, which is characterized in that the deicer is vinyl trimethoxy
At least one of silane, vinyltriethoxysilane.
6. environmental protection household hybrid material as described in claim 1, which is characterized in that the adhesive accelerant is γ-aminopropyl
Triethoxysilane, 3- TSL 8330, in N- (mono- aminoethyl of β)-γ-aminopropyl front three (second) oxysilane
At least one.
7. environmental protection household hybrid material as described in claim 1, which is characterized in that the catalyst is U-220 (diacetyl third
Ketone dibutyl tin), U-303H, 2 ethyl hexanoic acid, at least one of lauryl amine.
8. a kind of method for preparing the environmentally friendly household hybrid material as described in claim 1-7, which is characterized in that including following step
It plays:
(1), the end polyether polymer of silane envelope, filler, pigment, ultraviolet absorber are added in high viscosity mixer according to the ratio,
It is stirred 30min, is in paste；
(2), then be evacuated to -0.09MPa, mix slowly and be warming up to 110 DEG C, until water content be down to 800ppm hereinafter, after
Continuous stirring is cooled to 40 DEG C, and deicer and adhesion promoters are added, stir 30min under nitrogen protection；
(3), removing bubble is finally vacuumized, after the assay was approved packaging discharging.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811285599.2A CN109439259A (en) | 2018-10-31 | 2018-10-31 | A kind of environmental protection household hybrid material and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811285599.2A CN109439259A (en) | 2018-10-31 | 2018-10-31 | A kind of environmental protection household hybrid material and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109439259A true CN109439259A (en) | 2019-03-08 |
Family
ID=65550155
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811285599.2A Pending CN109439259A (en) | 2018-10-31 | 2018-10-31 | A kind of environmental protection household hybrid material and preparation method thereof |
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Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104087238A (en) * | 2014-06-18 | 2014-10-08 | 广州新展化工新材料有限公司 | Antifouling sealing material and preparation method thereof |
| CN104479608A (en) * | 2014-12-30 | 2015-04-01 | 北京天山新材料技术有限公司 | Environment-friendly mildewproof silicone-modified polyether sealant |
| CN106634769A (en) * | 2016-12-19 | 2017-05-10 | 广州市白云化工实业有限公司 | High-intensity transparent bonding agent and preparation method thereof |
| CN106833479A (en) * | 2017-01-05 | 2017-06-13 | 河南瑞朗达新材料有限公司 | Vehicle environment protection type single-component silylated polyether fluid sealant and preparation method thereof |
| CN107189745A (en) * | 2017-06-02 | 2017-09-22 | 广州市白云化工实业有限公司 | Environment-friendly type silane modified polyether coating glue and preparation method thereof |
| CN107779170A (en) * | 2017-11-22 | 2018-03-09 | 烟台德邦科技有限公司 | Preparation method of environment-friendly adhesive sealant |
| CN108676540A (en) * | 2018-06-08 | 2018-10-19 | 杭州之江新材料有限公司 | It is a kind of it is sprayable can brush seals glue and preparation method thereof |
-
2018
- 2018-10-31 CN CN201811285599.2A patent/CN109439259A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104087238A (en) * | 2014-06-18 | 2014-10-08 | 广州新展化工新材料有限公司 | Antifouling sealing material and preparation method thereof |
| CN104479608A (en) * | 2014-12-30 | 2015-04-01 | 北京天山新材料技术有限公司 | Environment-friendly mildewproof silicone-modified polyether sealant |
| CN106634769A (en) * | 2016-12-19 | 2017-05-10 | 广州市白云化工实业有限公司 | High-intensity transparent bonding agent and preparation method thereof |
| CN106833479A (en) * | 2017-01-05 | 2017-06-13 | 河南瑞朗达新材料有限公司 | Vehicle environment protection type single-component silylated polyether fluid sealant and preparation method thereof |
| CN107189745A (en) * | 2017-06-02 | 2017-09-22 | 广州市白云化工实业有限公司 | Environment-friendly type silane modified polyether coating glue and preparation method thereof |
| CN107779170A (en) * | 2017-11-22 | 2018-03-09 | 烟台德邦科技有限公司 | Preparation method of environment-friendly adhesive sealant |
| CN108676540A (en) * | 2018-06-08 | 2018-10-19 | 杭州之江新材料有限公司 | It is a kind of it is sprayable can brush seals glue and preparation method thereof |
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Application publication date: 20190308 |
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