CN109439058A - Coating natural minerals ionic auxiliary agent, preparation method and environmental protection coating material - Google Patents
Coating natural minerals ionic auxiliary agent, preparation method and environmental protection coating material Download PDFInfo
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- CN109439058A CN109439058A CN201710772347.1A CN201710772347A CN109439058A CN 109439058 A CN109439058 A CN 109439058A CN 201710772347 A CN201710772347 A CN 201710772347A CN 109439058 A CN109439058 A CN 109439058A
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- nanosizing
- auxiliary agent
- coating
- natural minerals
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2206—Oxides; Hydroxides of metals of calcium, strontium or barium
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/08—Metals
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
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Abstract
The invention proposes a kind of coating natural minerals ionic auxiliary agent, preparation method and environmental protection coating material, auxiliary agents: 25~35 parts of nanosizing rare earth, 8~12 parts of nanosizing medical stone, 8~12 parts of nanosizing barium monoxide, 8~12 parts of nanosizing sea-gull mountain flour and 8~12 parts of nanosizing far-infrared powder.Preparation method: 1) nanosizing rare earth, nanosizing medical stone, nanosizing barium monoxide, nanosizing sea-gull mountain flour and nanosizing far-infrared powder are according to the proportion weighed, is mixed；2) mixture of step 1) is transferred in dispersion machine and is stirred dispersion, under the revolving speed of 500r/min~2000r/min, be dispersed with stirring 15min~45min.Environment-friendly type coating: including film-forming resin and coating natural minerals ionic auxiliary agent, content of the coating natural minerals ionic auxiliary agent in environmental protection coating material is 57~83wt%.The auxiliary agent is "dead", and is added in coating and film-forming resin is made to have sustained release anion function, can reduce PM2.5 concentration to purify air especially.
Description
Technical field
The invention belongs to technical field of coatings, and in particular to a kind of coating natural minerals ionic auxiliary agent and its preparation side
Method and environmental protection coating material containing the auxiliary agent.
Background technique
In recent years, with China's expanding economy, the housing condition of the people is greatly improved, the rise of housing industry,
The huge market space is provided for the development of building coating and ornament materials industry.However, from national Coating Market sales volume
From the point of view of, what is had overwhelming superiority is the product of import or joint venture, and domestic coating can only be made in a certain territorial scope
For.Its reason is mainly that coating and decorating and renovating material do not meet environmental requirement, more than the limitation of the harmful substance of national regulation
Standard, the room after causing finishing cannot be moved in for a long time, or cause damages after moving in human health, and cause owner and exploitation
The dispute of quotient decoration company is continuous.
To solve the above-mentioned problems, it eliminates indoor pollution to endanger to health of people bring, various regions are low in development in recent years
While VOC low toxicity low contamination coating, it also developed the various coating with specific function, wherein more noticeable as anti-
Bacterium coating mildew resistant paint etc., the coating be exactly add different additives be coating generate specific function.Bear currently on the market from
The producer of sub- powder is right using radioactive element uranium, thorium, radium and kalium-40 as anion exciting agent in order to improve negative ion concentration
Human body is harmful.
Summary of the invention
The present invention proposes a kind of coating natural minerals ionic auxiliary agent, and the auxiliary agent is "dead", and is added in coating
So that film-forming resin has sustained release anion function, PM2.5 concentration can reduce to purify air especially.
The technical scheme of the present invention is realized as follows:
A kind of coating natural minerals ionic auxiliary agent includes following raw material according to the number of parts by weight:
25~35 parts of nanosizing rare earth, 8~12 parts of nanosizing medical stone, 8~12 parts of nanosizing barium monoxide, nanosizing sea-gull
8~12 parts of mountain flour and 8~12 parts of nanosizing far-infrared powder.
Preferably, the nanosizing rare earth is prepared by the following method to obtain: rare earth being ground by nanometer machine and is received
Riceization rare earth.
Preferably, the nanosizing medical stone is prepared by the following method to obtain: medical stone being first passed through nanometer machine and is ground
It is calcined to obtain nanosizing medical stone again.
Preferably, the nano oxidized barium is prepared by the following method to obtain: barium monoxide is ground to obtain by nanometer machine
Nano oxidized barium.
Preferably, the nanometer sea-gull mountain flour is prepared by the following method to obtain: sea-gull mountain flour is ground by nanometer machine
Obtain a nanometer sea-gull mountain flour.
Preferably, the nano-far-infrared powder is prepared by the following method to obtain: far-infrared powder is ground by nanometer machine
Obtain nano-far-infrared powder.
It is a further object to provide a kind of coating preparation methods of natural minerals ionic auxiliary agent, including with
Lower step:
1) nanosizing rare earth, nanosizing medical stone, nanosizing barium monoxide, nanosizing sea-gull mountain flour are weighed according to the proportion and are received
Riceization far-infrared powder, is mixed；
2) mixture of step 1) is transferred in dispersion machine and is stirred dispersion, 500r/min~2000r/min's
Under revolving speed, it is dispersed with stirring 15min~45min.
It is also another object of the present invention to provide a kind of environment-friendly type coatings, including film-forming resin and the natural mine of above-mentioned coating
Object ionic auxiliary agent, content of the coating natural minerals ionic auxiliary agent in the environmental protection coating material are 57~83wt%.
Preferably, the film-forming resin is selected from pure-acrylic emulsion, styrene-acrylic emulsion, vinyl acetate emulsion, silicone acrylic emulsion, polyaminoester emulsion
One or more of with epoxy resin latex.
Anion can facilitate human body synthesis and vitamin storage, strengthen the physiological activity with human activin, therefore be referred to as
" air vitamin " has highly important influence to the vital movement of human body and other biological.In medical field, anion is true
Recognizing is the effective means with germ and purification air is killed；Electronegative particle increases oxygen content in blood in air, favorably
In blood oxygen conveying, absorbs and utilize.Negative oxygen ion can adjust and improve the functional status of nervous system and brain, rouse oneself essence
Mind eliminates fatigue, has the function of excited parasympathetic；Kinaesthesis and light adaptation duration can be made to shorten, adjusted
Nervous excitation；The ventilatory of lung can also be improved, increase lung capacity；Hematopoiesis function can also be stimulated, is red blood cell, blood platelet
Quantity increases, and increases globulin and pH value.
Far infrared has stronger penetration and radiant force, has significant temperature control effect and resonance effects, easily by object
The interior energy for absorbing and being converted into object, can make telangiectasis, promote blood circulation, strengthen the new old generation between each tissue
It thanks, increases the power of regeneration of tissue, improve the immunocompetence of body, the exaltation state of spirit is adjusted, to play medical treatment
The effect of health care.Magnetic field affects the growth and development and health of human body, and there is not for human body viscera internal organs, tissue, organ etc.
With the biological magnetic field of intensity, the biological magnetic field of people will rely on the supplement of external magnetic field, therefore magnetic field is as sunlight, empty gas and water
It is also the indispensable nutrient of the mankind, has expert to be called the fourth element of human life.
Coating of the invention includes film-forming resin and above-mentioned coating natural minerals ionic auxiliary agent, has good antibacterial
Net haze effect has broad application prospects especially suitable for occasions such as civil construction, commercial building, public buildings.Use this
Product is no different the conservation rate that paradoxical reaction holds 5 years to enhancement of environment to human body through dependence test.
Beneficial effects of the present invention:
1, auxiliary agent of the invention is "dead", and is added in coating and film-forming resin is made to have sustained release anion function
Can, it can reduce PM2.5 concentration to purify air especially.
2, the preparation process of auxiliary agent of the invention is simple, easy to implement, easy to operate, is conducive to industrialize extensive life
It produces, reduces industrial production cost, there is preferable economic benefit.
Specific embodiment
Embodiment 1
A kind of coating natural minerals ionic auxiliary agent includes following raw material according to the number of parts by weight:
30 parts of nanosizing rare earth, 10 parts of nanosizing medical stone, 10 parts of nanosizing barium monoxide, 10 parts of nanosizing sea-gull mountain flour and
10 parts of nanosizing far-infrared powder.
Nanosizing rare earth is prepared by the following method to obtain: rare earth is ground to obtain nanosizing rare earth by nanometer machine.It receives
Riceization medical stone is prepared by the following method to obtain: medical stone being first passed through a nanometer machine grinding and is calcined to obtain nanosizing wheat again
Meal stone.Nano oxidized barium is prepared by the following method to obtain: barium monoxide is ground to obtain nano oxidized barium by nanometer machine.Nanometer
Sea-gull mountain flour is prepared by the following method to obtain: sea-gull mountain flour is ground to obtain a nanometer sea-gull mountain flour by nanometer machine.Nanometer is remote
Infrared powder is prepared by the following method to obtain: far-infrared powder being ground to obtain nano-far-infrared powder by nanometer machine.
Coating natural minerals ionic auxiliary agent preparation method, comprising the following steps:
1) nanosizing rare earth, nanosizing medical stone, nanosizing barium monoxide, nanosizing sea-gull mountain flour are weighed according to the proportion and are received
Riceization far-infrared powder, is mixed；
2) mixture of step 1) is transferred in dispersion machine and is stirred dispersion, under the revolving speed of 1000r/min, stirring
Disperse 35min.
Environment-friendly type coating: including pure-acrylic emulsion and above-mentioned coating natural minerals ionic auxiliary agent, wherein coating is with naturally
Content of the mineral ion type auxiliary agent in environmental protection coating material is 70wt%.
Embodiment 2
A kind of coating natural minerals ionic auxiliary agent includes following raw material according to the number of parts by weight:
It 35 parts of nanosizing rare earth, 8 parts of nanosizing medical stone, 8 parts of nanosizing barium monoxide, 12 parts of nanosizing sea-gull mountain flour and receives
12 parts of riceization far-infrared powder.
Nanosizing rare earth is prepared by the following method to obtain: rare earth is ground to obtain nanosizing rare earth by nanometer machine.It receives
Riceization medical stone is prepared by the following method to obtain: medical stone being first passed through a nanometer machine grinding and is calcined to obtain nanosizing wheat again
Meal stone.Nano oxidized barium is prepared by the following method to obtain: barium monoxide is ground to obtain nano oxidized barium by nanometer machine.Nanometer
Sea-gull mountain flour is prepared by the following method to obtain: sea-gull mountain flour is ground to obtain a nanometer sea-gull mountain flour by nanometer machine.Nanometer is remote
Infrared powder is prepared by the following method to obtain: far-infrared powder being ground to obtain nano-far-infrared powder by nanometer machine.
Coating natural minerals ionic auxiliary agent preparation method, comprising the following steps:
1) nanosizing rare earth, nanosizing medical stone, nanosizing barium monoxide, nanosizing sea-gull mountain flour are weighed according to the proportion and are received
Riceization far-infrared powder, is mixed；
2) mixture of step 1) is transferred in dispersion machine and is stirred dispersion, under the revolving speed of 500r/min, stirring
Disperse 45min.
Environment-friendly type coating: including pure-acrylic emulsion and above-mentioned coating natural minerals ionic auxiliary agent, wherein coating is with naturally
Content of the mineral ion type auxiliary agent in environmental protection coating material is 75wt%.
Embodiment 3
A kind of coating natural minerals ionic auxiliary agent includes following raw material according to the number of parts by weight:
25 parts of nanosizing rare earth, 12 parts of nanosizing medical stone, 10 parts of nanosizing barium monoxide, 8 parts of nanosizing sea-gull mountain flour and
8 parts of nanosizing far-infrared powder.
Nanosizing rare earth is prepared by the following method to obtain: rare earth is ground to obtain nanosizing rare earth by nanometer machine.It receives
Riceization medical stone is prepared by the following method to obtain: medical stone being first passed through a nanometer machine grinding and is calcined to obtain nanosizing wheat again
Meal stone.Nano oxidized barium is prepared by the following method to obtain: barium monoxide is ground to obtain nano oxidized barium by nanometer machine.Nanometer
Sea-gull mountain flour is prepared by the following method to obtain: sea-gull mountain flour is ground to obtain a nanometer sea-gull mountain flour by nanometer machine.Nanometer is remote
Infrared powder is prepared by the following method to obtain: far-infrared powder being ground to obtain nano-far-infrared powder by nanometer machine.
Coating natural minerals ionic auxiliary agent preparation method, comprising the following steps:
1) nanosizing rare earth, nanosizing medical stone, nanosizing barium monoxide, nanosizing sea-gull mountain flour are weighed according to the proportion and are received
Riceization far-infrared powder, is mixed；
2) mixture of step 1) is transferred in dispersion machine and is stirred dispersion, under the revolving speed of 2000r/min, stirring
Disperse 15min.
Environment-friendly type coating: including pure-acrylic emulsion and above-mentioned coating natural minerals ionic auxiliary agent, wherein coating is with naturally
Content of the mineral ion type auxiliary agent in environmental protection coating material is 63wt%.
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, all in essence of the invention
Within mind and principle, any modification, equivalent replacement, improvement and so on be should all be included in the protection scope of the present invention.
Claims (9)
1. a kind of coating natural minerals ionic auxiliary agent, which is characterized in that according to the number of parts by weight include following raw material:
25~35 parts of nanosizing rare earth, 8~12 parts of nanosizing medical stone, 8~12 parts of nanosizing barium monoxide, nanosizing sea-gull mountain flour
8~12 parts and 8~12 parts of nanosizing far-infrared powder.
2. coating according to claim 1 natural minerals ionic auxiliary agent, which is characterized in that the nanosizing rare earth is logical
It crosses following methods to be prepared: rare earth is ground to obtain nanosizing rare earth by nanometer machine.
3. coating according to claim 1 natural minerals ionic auxiliary agent, which is characterized in that the nanosizing medical stone
It is prepared by the following method to obtain: medical stone being first passed through into a nanometer machine grinding and is calcined to obtain nanosizing medical stone again.
4. coating according to claim 1 natural minerals ionic auxiliary agent, which is characterized in that the nano oxidized barium is logical
It crosses following methods to be prepared: barium monoxide is ground to obtain nano oxidized barium by nanometer machine.
5. coating according to claim 1 natural minerals ionic auxiliary agent, which is characterized in that the nanometer sea-gull mountain flour
It is prepared by the following method to obtain: sea-gull mountain flour is ground to obtain a nanometer sea-gull mountain flour by nanometer machine.
6. coating according to claim 1 natural minerals ionic auxiliary agent, which is characterized in that the nano-far-infrared powder
It is prepared by the following method to obtain: far-infrared powder being ground to obtain nano-far-infrared powder by nanometer machine.
7. the coating as described in claim 1 preparation method of natural minerals ionic auxiliary agent, which is characterized in that including following
Step:
1) nanosizing rare earth, nanosizing medical stone, nanosizing barium monoxide, nanosizing sea-gull mountain flour and nanosizing are weighed according to the proportion
Far-infrared powder is mixed；
2) mixture of step 1) is transferred in dispersion machine and is stirred dispersion, in the revolving speed of 500r/min~2000r/min
Under, it is dispersed with stirring 15min~45min.
8. a kind of environment-friendly type coating, which is characterized in that including film-forming resin and coating natural minerals described in claim 1 from
Subtype auxiliary agent, content of the coating natural minerals ionic auxiliary agent in the environmental protection coating material are 57~83wt%.
9. environment-friendly type coating according to claim 1, which is characterized in that the film-forming resin is selected from pure-acrylic emulsion, phenylpropyl alcohol
One or more of lotion, vinyl acetate emulsion, silicone acrylic emulsion, polyaminoester emulsion and epoxy resin latex.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710772347.1A CN109439058A (en) | 2017-08-31 | 2017-08-31 | Coating natural minerals ionic auxiliary agent, preparation method and environmental protection coating material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201710772347.1A CN109439058A (en) | 2017-08-31 | 2017-08-31 | Coating natural minerals ionic auxiliary agent, preparation method and environmental protection coating material |
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| Publication Number | Publication Date |
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| CN109439058A true CN109439058A (en) | 2019-03-08 |
Family
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| Application Number | Title | Priority Date | Filing Date |
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| CN201710772347.1A Pending CN109439058A (en) | 2017-08-31 | 2017-08-31 | Coating natural minerals ionic auxiliary agent, preparation method and environmental protection coating material |
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Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1421494A (en) * | 2001-11-23 | 2003-06-04 | 上海金樱环保科技有限公司 | Environment protecting building paint additive and its prepn process |
| CN1760289A (en) * | 2004-10-14 | 2006-04-19 | 大连振邦氟涂料股份有限公司 | Emulsion coating of negative ion and preparation method |
| JP2008297492A (en) * | 2007-06-01 | 2008-12-11 | Hirose Kogyo Seisakusho:Kk | Coating material generating negative ion and far-infrared ray |
| CN101343526A (en) * | 2007-07-13 | 2009-01-14 | 陈磊 | Antimicrobial, far infrared, energy-storage and smell removing multifunctional environment friendly material |
| CN101469260A (en) * | 2007-12-29 | 2009-07-01 | 张兴 | Excitated energetic particle efficient transmitting negative ion far-infrared ray material and preparation |
| CN102190959A (en) * | 2011-03-08 | 2011-09-21 | 三棵树涂料股份有限公司 | Inner wall latex paint capable of releasing far-infrared rays |
| CN106433280A (en) * | 2015-08-06 | 2017-02-22 | 上海利民环保节能科技有限公司 | Nanometer negative ion environmental-protection coating |
| CN106634063A (en) * | 2015-07-24 | 2017-05-10 | 广东骏丰频谱股份有限公司 | High-temperature-tolerance far-infrared coating as well as preparation method and application thereof |
-
2017
- 2017-08-31 CN CN201710772347.1A patent/CN109439058A/en active Pending
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1421494A (en) * | 2001-11-23 | 2003-06-04 | 上海金樱环保科技有限公司 | Environment protecting building paint additive and its prepn process |
| CN1760289A (en) * | 2004-10-14 | 2006-04-19 | 大连振邦氟涂料股份有限公司 | Emulsion coating of negative ion and preparation method |
| JP2008297492A (en) * | 2007-06-01 | 2008-12-11 | Hirose Kogyo Seisakusho:Kk | Coating material generating negative ion and far-infrared ray |
| CN101343526A (en) * | 2007-07-13 | 2009-01-14 | 陈磊 | Antimicrobial, far infrared, energy-storage and smell removing multifunctional environment friendly material |
| CN101469260A (en) * | 2007-12-29 | 2009-07-01 | 张兴 | Excitated energetic particle efficient transmitting negative ion far-infrared ray material and preparation |
| CN102190959A (en) * | 2011-03-08 | 2011-09-21 | 三棵树涂料股份有限公司 | Inner wall latex paint capable of releasing far-infrared rays |
| CN106634063A (en) * | 2015-07-24 | 2017-05-10 | 广东骏丰频谱股份有限公司 | High-temperature-tolerance far-infrared coating as well as preparation method and application thereof |
| CN106433280A (en) * | 2015-08-06 | 2017-02-22 | 上海利民环保节能科技有限公司 | Nanometer negative ion environmental-protection coating |
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Application publication date: 20190308 |