CN109437753A - A kind of inorganic stone and its production technology - Google Patents
A kind of inorganic stone and its production technology Download PDFInfo
- Publication number
- CN109437753A CN109437753A CN201811498622.6A CN201811498622A CN109437753A CN 109437753 A CN109437753 A CN 109437753A CN 201811498622 A CN201811498622 A CN 201811498622A CN 109437753 A CN109437753 A CN 109437753A
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- Prior art keywords
- inorganic
- stone
- powder
- particle
- cement
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
- C04B28/04—Portland cements
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B28—WORKING CEMENT, CLAY, OR STONE
- B28B—SHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
- B28B1/00—Producing shaped prefabricated articles from the material
- B28B1/08—Producing shaped prefabricated articles from the material by vibrating or jolting
- B28B1/087—Producing shaped prefabricated articles from the material by vibrating or jolting by means acting on the mould ; Fixation thereof to the mould
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B28—WORKING CEMENT, CLAY, OR STONE
- B28B—SHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
- B28B3/00—Producing shaped articles from the material by using presses; Presses specially adapted therefor
- B28B3/006—Pressing by atmospheric pressure, as a result of vacuum generation or by gas or liquid pressure acting directly upon the material, e.g. jets of compressed air
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B28—WORKING CEMENT, CLAY, OR STONE
- B28B—SHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
- B28B3/00—Producing shaped articles from the material by using presses; Presses specially adapted therefor
- B28B3/02—Producing shaped articles from the material by using presses; Presses specially adapted therefor wherein a ram exerts pressure on the material in a moulding space; Ram heads of special form
- B28B3/022—Producing shaped articles from the material by using presses; Presses specially adapted therefor wherein a ram exerts pressure on the material in a moulding space; Ram heads of special form combined with vibrating or jolting
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
- C04B28/06—Aluminous cements
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/20—Resistance against chemical, physical or biological attack
Abstract
A kind of artificial inorganic stone and its production technology, are related to the field of building materials.Inorganic stone includes following components: inorganic stoste, cement, inorganic cracking resistance powder, bamboo powder, filler, aggregate, shape material, nano powder, inorganic pigment.The production technology of inorganic stone is: above-mentioned raw materials are added sequentially in blender according to the ratio, after being quickly uniformly mixed, sealing vacuumizes, all materials are unloaded into mold, it shakes molded, then demoulding, is finally fully sealed with preservative film under vacuum conditions, it is just made in this way and exempts to conserve inorganic stone, obtain inorganic stone slab using cutting, polishing, polishing treatment.The inorganic stone production process of the present invention is directly exempted to conserve, it is high-efficient, at low cost, low energy consumption, non-environmental-pollution, low energy consumption for asepsis environment-protecting, from density is high, intensity is high, at low cost, internal structure is stable, compression strength is high, endurance quality is very good, and it is long service life, environmentally protective, it can be used for inner, external wall decorations etc..
Description
Technical field
The present invention relates to the field of building materials, and in particular to a kind of artificial inorganic stone and its production technology.
Background technique
Stone material is a kind of common building, decorative material material, can be divided into natural stone and artificial stone.Lithotome all the time
Ecology is destroyed due to largely exploiting, now slowly to be started not to exploitation.Its application range of its special decorative effect of natural stone
It is wider and welcomed by the people, but there are color difference and different degrees of radioactivity for, large area paving limited since there are resources
The problems such as exceeded, limits its comprehensive development to a certain extent.And artificial stone has that pattern is adjustable, large area paving without
Color difference, using the mined leftover pieces of lithotome and the advantages such as environmentally protective, it has also become decorative stone industry is sent out at present
The direction of exhibition.
The difference of cementitious material according to used in it, artificial stone are that organic (resin) artificial stone and inorganic (cement base) are artificial
Stone, artificial stone currently on the market are mainly organic artificial's stone.And traditional inorganic artificial stone such as Behavior of Hardened Cement Paste, because of its production technology
It wants that wet curing, decorative effect and service performance are poor, are easy that cracking, water absorption rate are high, texture is poor the later period, is difficult to meet Art Design
It is required that its market application at present is few.Therefore artificial stone is substantially the synonym of artificial resin stone.
Common are machine artificial stone currently on the market has its structural behaviour such as artificial marble, quartz, light transmitting stone, hilllock stone
It is all preferable with decorative performance, but its application range is narrower, due to major gelled material be organic material, organic material exists
It is easily deformed, holds in the various uncontrollable situations such as ultraviolet light irradiates, shines upon, infrared ray, hot and cold alternation, acid, alkali, salt environment
Easily cause the problems such as various modifications, cracking, contraction, the aquation of organic artificial's stone in use soften, prevent fires.At normal temperature
Its service life is also with regard to 1-5 under normal use.And since the cementitious material that it is used is inflammable, organic artificial's stone is not
It can be used for that building ground, external wall, the temperature difference to be big, public place temperature drift, that fire-protection rating is more demanding, it is also few to use
In home improvement industries, factors above significantly limits the application field of artificial resin stone product.
Summary of the invention
The purpose of the present invention is to solve the above-mentioned shortcomings of existing artificial stone, provide a kind of high-quality, inexpensive
And it can accomplish that the inorganic stone for exempting from maintenance is widely used in various indoor and outdoors to replace natural stone, artificial resin stone in production process
Decoration, fitting-out work.
In order to achieve the above object, the invention adopts the following technical scheme:
The inorganic stone of the present invention includes each component of following mass percent:
Inorganic stoste: 0.001-3%
Cement: 10%-25%
Inorganic cracking resistance powder: 5%-15%
Bamboo powder: 0.1%-10%
Filler: 5%-35%
Aggregate: 5%-20%
Shape material: 5%-35%
Nano powder: 0.001%-0.1%
Inorganic pigment: 0%-0.001%
Inorganic stoste of the present invention after the raw material mixing of following mass percent by stirring:
Silicon nitrogen nanometer polymer 50-90%, high efficiency water reducing agent 10-20%, inorganic active agent 0.01-5%, aqueous defoamer 0.01-
5%, nano silicon complex 0.01-10%, inorganic polymer 0.01-8%.
Cement of the present invention is selected from portland cement, pozzolan cement, pulverized fuel ash cement, sulphate aluminium cement or aluminic acid
One or more of salt cement, strength grade not less than P.O42.5 or P.II42.5 or P.O52.5 or
P.II52.5。
Inorganic cracking resistance powder of the present invention is by inorganic stoste mixing slag powders, wollastonite powder, metakaolin, flyash, swollen
The powder that one or more of profit soil, titanium dioxide, agstone, zeolite powder mix.
Bamboo powder of the present invention is novel energy-saving environment-friendly raw material specification: granularity >=95%(90-400 mesh), ash≤2%, water
Part≤6%.
Filler of the present invention is -200 mesh waste material of stone of 10 mesh, lithotome particle, calcium carbonate granule, quartz sand
One or more of grain, glass particle, shell fragment, natural amber particle, potsherd mix.
Aggregate of the present invention be -40 mesh waste material of stone of 5 mesh, lithotome particle, calcium carbonate granule, quartz sand particle,
One or more of glass particle, shell fragment, natural amber particle, potsherd mix.
Shape material of the present invention be -10 mesh waste material of stone of 5 mesh, lithotome particle, calcium carbonate granule, quartz sand particle,
One or more of glass particle, shell fragment, natural amber particle, potsherd mix.
Nano powder of the present invention is also nano particle, refers generally to ultrafine particle of the size between 1-100nm, there is person
It is ultramicron.Its scale be greater than cluster and be less than general particle, the form of nano particle have spherical shape, plate,
Rodlike, horn shape, spongy etc., the ingredient that nano particle is made can be metal, can be oxide, can also be that other are various
Compound.
Inorganic pigment of the present invention is the oxide or the insoluble metal salt of some metals of non-ferrous metal, inorganic face
Material is divided into natural inorganic pigment and artificial inorganic pigment again, and natural inorganic pigment is coloring earth, to adapt to consumer to color
Different demands.
The production technology of inorganic stone of the present invention is:
Raw material described above is added sequentially in blender according to the ratio, after being quickly uniformly mixed, sealing is vacuumized, will
All materials are unloaded into mold, are shaken molded, then demoulding, are finally fully sealed with preservative film under vacuum conditions, this
Sample, which is just made, exempts to conserve inorganic stone, obtains inorganic stone slab using cutting, polishing, polishing treatment.
The inorganic stone made of the above method, has the advantage that
1, from density is high, intensity is high, at low cost, internal structure is stable, compression strength is high.
2, endurance quality it is very good (it is ageing-resistant long, non-efflorescing cementitious, a variety of chemical mediators such as salt spray resistance, saline and alkaline, seawater are invaded
Erosion), it can be used for inner, external wall decorations, and long service life.
3, the plate does not burn, and fire resistance is good, can be used for the more demanding Decorating Project of fire-protection rating.
4, decorative performance is good, and the color and decorative pattern of the plate are adjustable, can meet the different needs of design, is suitable for various public affairs
Place and home decoration industry fitting-out work altogether.
5, environmentally protective, which uses inorganic material compression moulding at normal temperature, and production process is directly exempted to conserve, efficiency
It is high, at low cost, low energy consumption, non-environmental-pollution, asepsis environment-protecting.
6, the wear resistance of the plate is good, luminosity is high, it is indeformable, do not crack.
7, inorganic stone slab waterproof performance that treated, anti-pollution are very good.
Specific embodiment
Embodiment 1
Inorganic stone includes each component of following mass percent:
Inorganic stoste: 0.2%
Cement: 22%
Inorganic cracking resistance powder: 10%
Bamboo powder: 0.3%
Filler: 28%
Aggregate: 13%
Shape material: 27%
Nano powder: 0.03%
Inorganic pigment: 0.001%
The inorganic stoste after the raw material mixing of following mass percent by stirring: silicon nitrogen nanometer polymer 81%, efficiently
Water-reducing agent 10%, inorganic active agent 1%, aqueous defoamer 2%, nano silicon complex 5%, inorganic polymer 1%.
The cement is selected from portland cement, pozzolan cement, pulverized fuel ash cement, sulphate aluminium cement or aluminate cement
One or more of, strength grade is not less than P.O42.5 or P.II42.5 or P.O52.5 or P.II52.5.
The inorganic cracking resistance powder is to mix slag powders, wollastonite powder, metakaolin, flyash, bentonite, titanium by inorganic stoste
The powder that one or more of white powder, agstone, zeolite powder mix.
The bamboo powder specification are as follows: granularity >=95%(90-400 mesh), ash≤2%, moisture content≤6%.
The filler is -200 mesh waste material of stone of 10 mesh, lithotome particle, calcium carbonate granule, quartz sand particle, glass
One or more of particle, shell fragment, natural amber particle, potsherd mix.
The aggregate is -40 mesh waste material of stone of 5 mesh, lithotome particle, calcium carbonate granule, quartz sand particle, glass
One or more of grain, shell fragment, natural amber particle, potsherd mix.
The shape material is -10 mesh waste material of stone of 5 mesh, lithotome particle, calcium carbonate granule, quartz sand particle, glass
One or more of grain, shell fragment, natural amber particle, potsherd mix.
The nano powder is ultrafine particle of the size between 1-100nm.
The inorganic pigment is the oxide or metal salt of non-ferrous metal.
Raw material described above is added sequentially in blender according to the ratio, after being quickly uniformly mixed, sealing is taken out true
Sky unloads all materials into mold, shakes molded, then demoulding, has finally been fully sealed with preservative film under vacuum conditions
Come, is just made exempts to conserve inorganic stone in this way, obtain inorganic stone slab using cutting, polishing, polishing treatment.The inorganic slabstone
Material belongs to true qualities series of plates, and mostly white or canescence can pass through in actual use according to different finishing requirements
It adds various inorganic pigments to match colors, pigment of the present invention has no effect to the performance of plate.
Embodiment 2
Inorganic stone includes each component of following mass percent:
Inorganic stoste: 0.015%
Cement: 20%
Inorganic cracking resistance powder: 12%
Bamboo powder: 0.2%
Filler: 30%
Aggregate: 15%
Shape material: 23%
Nano powder: 0.02%
Inorganic pigment: 0.0013%
The inorganic stoste after the raw material mixing of following mass percent by stirring: silicon nitrogen nanometer polymer 76%, efficiently
Water-reducing agent 8%, inorganic active agent 2%, aqueous defoamer 2%, nano silicon complex 5%, inorganic polymer 7%.
Raw material described above is added sequentially in blender according to the ratio, after being quickly uniformly mixed, sealing is taken out true
Sky unloads all materials into mold, shakes molded, then demoulding, has finally been fully sealed with preservative film under vacuum conditions
Come, is just made exempts to conserve inorganic stone in this way, obtain inorganic stone slab using cutting, polishing, polishing treatment.The inorganic slabstone
Material belongs to true qualities series of plates, and mostly white or canescence can pass through in actual use according to different finishing requirements
It adds various inorganic pigments to match colors, pigment of the present invention has no effect to the performance of plate.
Claims (4)
1. a kind of inorganic stone, it is characterised in that:
Each component comprising following mass percent:
Inorganic stoste: 0.2%
Cement: 22%
Inorganic cracking resistance powder: 10%
Bamboo powder: 0.3%
Filler: 28%
Aggregate: 13%
Shape material: 27%
Nano powder: 0.03%
Inorganic pigment: 0.001%
The inorganic stoste after the raw material mixing of following mass percent by stirring: silicon nitrogen nanometer polymer 81%, efficiently
Water-reducing agent 10%, inorganic active agent 1%, aqueous defoamer 2%, nano silicon complex 5%, inorganic polymer 1%.
2. a kind of inorganic stone, it is characterised in that:
Each component comprising following mass percent:
Inorganic stoste: 0.015%
Cement: 20%
Inorganic cracking resistance powder: 12%
Bamboo powder: 0.2%
Filler: 30%
Aggregate: 15%
Shape material: 23%
Nano powder: 0.02%
Inorganic pigment: 0.0013%
The inorganic stoste after the raw material mixing of following mass percent by stirring: silicon nitrogen nanometer polymer 76%, efficiently
Water-reducing agent 8%, inorganic active agent 2%, aqueous defoamer 2%, nano silicon complex 5%, inorganic polymer 7%.
3. inorganic stone according to claim 1 or 2, it is characterized in that:
The cement is in portland cement, pozzolan cement, pulverized fuel ash cement, sulphate aluminium cement or aluminate cement
One or more, strength grade are not less than P.O42.5 or P.II42.5 or P.O52.5 or P.II52.5；
The inorganic cracking resistance powder is to mix slag powders, wollastonite powder, metakaolin, flyash, bentonite, titanium white by inorganic stoste
The powder that one or more of powder, agstone, zeolite powder mix；
The bamboo powder specification are as follows: granularity >=95%(90-400 mesh), ash≤2%, moisture content≤6%；
The filler be -200 mesh waste material of stone of 10 mesh, lithotome particle, calcium carbonate granule, quartz sand particle, glass particle,
One or more of shell fragment, natural amber particle, potsherd mix；
The aggregate is -40 mesh waste material of stone of 5 mesh, lithotome particle, calcium carbonate granule, quartz sand particle, glass particle, shellfish
One or more of shell fragment, natural amber particle, potsherd mix；
The shape material is -10 mesh waste material of stone of 5 mesh, lithotome particle, calcium carbonate granule, quartz sand particle, glass particle, shellfish
One or more of shell fragment, natural amber particle, potsherd mix；
The nano powder is ultrafine particle of the size between 1-100nm；
The inorganic pigment is the oxide or metal salt of non-ferrous metal.
4. a kind of inorganic stone production technology, it is characterized in that:
Each component comprising following mass percent:
Inorganic stoste: 0.001-3%
Cement: 10%-25%
Inorganic cracking resistance powder: 5%-15%
Bamboo powder: 0.1%-10%
Filler: 5%-35%
Aggregate: 5%-20%
Shape material: 5%-35%
Nano powder: 0.001%-0.1%
Inorganic pigment: 0%-0.001%
The inorganic stoste after the raw material mixing of following mass percent by stirring:
Silicon nitrogen nanometer polymer 50-90%, high efficiency water reducing agent 10-20%, inorganic active agent 0.01-5%, aqueous defoamer 0.01-
5%, nano silicon complex 0.01-10%, inorganic polymer 0.01-8%；
Above-mentioned raw materials are added sequentially in blender according to the ratio, after being quickly uniformly mixed, sealing is vacuumized, and will be owned
Material is unloaded into mold, is shaken molded, then demoulding, is finally fully sealed with preservative film under vacuum conditions, so just
It is made and exempts to conserve inorganic stone, obtain inorganic stone slab using cutting, polishing, polishing treatment.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811498622.6A CN109437753B (en) | 2018-12-08 | 2018-12-08 | Inorganic stone and production process thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811498622.6A CN109437753B (en) | 2018-12-08 | 2018-12-08 | Inorganic stone and production process thereof |
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| Publication Number | Publication Date |
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| CN109437753A true CN109437753A (en) | 2019-03-08 |
| CN109437753B CN109437753B (en) | 2021-06-04 |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110183169A (en) * | 2019-05-08 | 2019-08-30 | 福建师范大学 | A kind of artificial inorganic stone and preparation method thereof based on processing of stone waste material |
| CN110590220A (en) * | 2019-10-25 | 2019-12-20 | 兴远辉贸易(深圳)有限公司 | Method for making inorganic quartz terrazzo |
| CN112707686A (en) * | 2020-12-30 | 2021-04-27 | 威海利东建筑科技有限公司 | Concrete stone imitation horseshoe stone and preparation method and preparation equipment thereof |
| CN113402239A (en) * | 2021-06-30 | 2021-09-17 | 广西利升石业有限公司 | Method for improving color difference of artificial marble |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN110590220A (en) * | 2019-10-25 | 2019-12-20 | 兴远辉贸易(深圳)有限公司 | Method for making inorganic quartz terrazzo |
| CN112707686A (en) * | 2020-12-30 | 2021-04-27 | 威海利东建筑科技有限公司 | Concrete stone imitation horseshoe stone and preparation method and preparation equipment thereof |
| CN113402239A (en) * | 2021-06-30 | 2021-09-17 | 广西利升石业有限公司 | Method for improving color difference of artificial marble |
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| Publication number | Publication date |
|---|---|
| CN109437753B (en) | 2021-06-04 |
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