CN109402782A - A kind of antistatic fibre and its manufacturing method - Google Patents
A kind of antistatic fibre and its manufacturing method Download PDFInfo
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- CN109402782A CN109402782A CN201811252127.7A CN201811252127A CN109402782A CN 109402782 A CN109402782 A CN 109402782A CN 201811252127 A CN201811252127 A CN 201811252127A CN 109402782 A CN109402782 A CN 109402782A
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- 239000000835 fiber Substances 0.000 title claims abstract description 77
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 33
- 239000000314 lubricant Substances 0.000 claims abstract description 37
- 229920006306 polyurethane fiber Polymers 0.000 claims abstract description 29
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 25
- 239000012745 toughening agent Substances 0.000 claims abstract description 25
- 239000002216 antistatic agent Substances 0.000 claims abstract description 23
- 239000012744 reinforcing agent Substances 0.000 claims abstract description 22
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 15
- 239000000203 mixture Substances 0.000 claims abstract description 8
- 239000000126 substance Substances 0.000 claims description 47
- 239000000463 material Substances 0.000 claims description 36
- 238000002156 mixing Methods 0.000 claims description 29
- 238000001125 extrusion Methods 0.000 claims description 28
- 238000006243 chemical reaction Methods 0.000 claims description 24
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 18
- 239000002245 particle Substances 0.000 claims description 16
- 235000006708 antioxidants Nutrition 0.000 claims description 14
- 238000001035 drying Methods 0.000 claims description 14
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims description 12
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 claims description 12
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 12
- 235000013339 cereals Nutrition 0.000 claims description 12
- 238000005469 granulation Methods 0.000 claims description 12
- 230000003179 granulation Effects 0.000 claims description 12
- 229920001684 low density polyethylene Polymers 0.000 claims description 12
- 239000004702 low-density polyethylene Substances 0.000 claims description 12
- SZHOJFHSIKHZHA-UHFFFAOYSA-N tridecanoic acid Chemical compound CCCCCCCCCCCCC(O)=O SZHOJFHSIKHZHA-UHFFFAOYSA-N 0.000 claims description 12
- 239000000843 powder Substances 0.000 claims description 11
- 239000002759 woven fabric Substances 0.000 claims description 8
- -1 azo Cyanogen Chemical compound 0.000 claims description 7
- OTEKOJQFKOIXMU-UHFFFAOYSA-N 1,4-bis(trichloromethyl)benzene Chemical compound ClC(Cl)(Cl)C1=CC=C(C(Cl)(Cl)Cl)C=C1 OTEKOJQFKOIXMU-UHFFFAOYSA-N 0.000 claims description 6
- QLOKJRIVRGCVIM-UHFFFAOYSA-N 1-[(4-methylsulfanylphenyl)methyl]piperazine Chemical compound C1=CC(SC)=CC=C1CN1CCNCC1 QLOKJRIVRGCVIM-UHFFFAOYSA-N 0.000 claims description 6
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 6
- 239000004698 Polyethylene Substances 0.000 claims description 6
- 239000004642 Polyimide Substances 0.000 claims description 6
- 239000004793 Polystyrene Substances 0.000 claims description 6
- 235000021355 Stearic acid Nutrition 0.000 claims description 6
- 229920002522 Wood fibre Polymers 0.000 claims description 6
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 claims description 6
- 235000013871 bee wax Nutrition 0.000 claims description 6
- 239000012166 beeswax Substances 0.000 claims description 6
- 239000006229 carbon black Substances 0.000 claims description 6
- 239000003054 catalyst Substances 0.000 claims description 6
- 239000003365 glass fiber Substances 0.000 claims description 6
- 239000003292 glue Substances 0.000 claims description 6
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 6
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims description 6
- XNLICIUVMPYHGG-UHFFFAOYSA-N pentan-2-one Chemical compound CCCC(C)=O XNLICIUVMPYHGG-UHFFFAOYSA-N 0.000 claims description 6
- 229920003229 poly(methyl methacrylate) Polymers 0.000 claims description 6
- 229920001197 polyacetylene Polymers 0.000 claims description 6
- 229920000573 polyethylene Polymers 0.000 claims description 6
- 229920001721 polyimide Polymers 0.000 claims description 6
- 239000004926 polymethyl methacrylate Substances 0.000 claims description 6
- 229920002223 polystyrene Polymers 0.000 claims description 6
- 238000009987 spinning Methods 0.000 claims description 6
- 239000008117 stearic acid Substances 0.000 claims description 6
- 229920001897 terpolymer Polymers 0.000 claims description 6
- 239000003795 chemical substances by application Substances 0.000 claims description 5
- GVJHHUAWPYXKBD-UHFFFAOYSA-N (±)-α-Tocopherol Chemical compound OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-UHFFFAOYSA-N 0.000 claims description 4
- 229930003427 Vitamin E Natural products 0.000 claims description 2
- 235000013312 flour Nutrition 0.000 claims description 2
- WIGCFUFOHFEKBI-UHFFFAOYSA-N gamma-tocopherol Natural products CC(C)CCCC(C)CCCC(C)CCCC1CCC2C(C)C(O)C(C)C(C)C2O1 WIGCFUFOHFEKBI-UHFFFAOYSA-N 0.000 claims description 2
- 235000019165 vitamin E Nutrition 0.000 claims description 2
- 229940046009 vitamin E Drugs 0.000 claims description 2
- 239000011709 vitamin E Substances 0.000 claims description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims 2
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 claims 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 1
- 229910003978 SiClx Inorganic materials 0.000 claims 1
- 229910021529 ammonia Inorganic materials 0.000 claims 1
- 229910052799 carbon Inorganic materials 0.000 claims 1
- 150000002148 esters Chemical class 0.000 claims 1
- JMANVNJQNLATNU-UHFFFAOYSA-N glycolonitrile Natural products N#CC#N JMANVNJQNLATNU-UHFFFAOYSA-N 0.000 claims 1
- 229910052740 iodine Inorganic materials 0.000 claims 1
- 239000011630 iodine Substances 0.000 claims 1
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 claims 1
- 238000012986 modification Methods 0.000 claims 1
- 230000004048 modification Effects 0.000 claims 1
- 229920002635 polyurethane Polymers 0.000 claims 1
- 239000004814 polyurethane Substances 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 8
- 230000008901 benefit Effects 0.000 abstract description 4
- 239000002649 leather substitute Substances 0.000 abstract description 2
- 238000007500 overflow downdraw method Methods 0.000 abstract description 2
- 230000002688 persistence Effects 0.000 abstract description 2
- 230000003712 anti-aging effect Effects 0.000 abstract 1
- 239000004744 fabric Substances 0.000 description 18
- PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 description 5
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 5
- 238000000034 method Methods 0.000 description 4
- 230000006378 damage Effects 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 230000009286 beneficial effect Effects 0.000 description 2
- 238000004043 dyeing Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 229920000297 Rayon Polymers 0.000 description 1
- 208000027418 Wounds and injury Diseases 0.000 description 1
- 238000007259 addition reaction Methods 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 210000000085 cashmere Anatomy 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 208000014674 injury Diseases 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 239000010985 leather Substances 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
- D01F8/16—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one other macromolecular compound obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds as constituent
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/09—Addition of substances to the spinning solution or to the melt for making electroconductive or anti-static filaments
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
- D01F8/12—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyamide as constituent
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Textile Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Artificial Filaments (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The present invention relates to technical field of artificial leather, and in particular to a kind of antistatic fibre and its manufacturing method；The composition of the antistatic fibre are as follows: mass fraction is 80-100 parts of improved polyurethane fiber, 10-15 parts of Fypro, the 6-8 parts of reinforcing agents of part, 4-6 parts of toughener, 3-5 parts of lubricant, 15-20 parts of antistatic agent, 3-5 parts of antioxidant；Antistatic fibre prepared by the present invention is prepared using fusion method, preparing antistatic fibre which improve tradition is prepared by the way that a small amount of conductive fiber is added, its antistatic effect for effectively raising antistatic fibre, while guaranteeing the persistence of its antistatic effect；In addition, the antistatic fibre, intensity and flexibility with higher, while it has many advantages, such as good anti-aging property and long service life.
Description
Technical field
The invention belongs to technical field of artificial leather, and in particular to a kind of antistatic fibre and its manufacturing method.
Background technique
With the development of science and technology, the harm of electrostatic is gradually taken seriously, and especially weather is more dry in winter
Under dry environment, bedding can generate electrostatic to the clothes that people wear, and cause serious injury to human body, therefore with people
Continuous enhancing to health consciousness, fibre antistatic property has been to be concerned by more and more people, therefore develops a
Antistatic fiber product is particularly important.
Chinese patent application CN108265429A discloses that the invention discloses a kind of production works of antistatic underwear fabric
Skill.It, which solves existing Antistatic Fabric, does not have corresponding production technology, produces the technical problems such as cumbersome.This antistatic underwear face
The production technology of material, include the following steps: a, weaving: by weight, by 12-20 parts of protein fibres, 8-14 parts of cashmere fibers,
10-16 parts of viscose rayons and 4-8 parts of antistatic fibre hybrid wovens are at underwear fabric；B, it cleans: the underwear fabric that will have been weaved
Soaking and washing is carried out, impregnates in two times, first underwear fabric is put into 40-50 DEG C of water and maintains 8-12min, then takes out and is put into 5-
4-6min is maintained in 10 DEG C of water；C, it dyes: cleaned underwear fabric being dyed by dyeing installation, dyeing temperature is
50-60℃；D, it dries: the underwear fabric dyed is dried, drying temperature is 70-80 DEG C, drying time 10-
20min；E, it is formed: the underwear fabric dried being put into forming machine and is carried out shaping.The present invention has the advantages that production is easy,
But this method is to carry out intersecting the antistatic cloth worked out, antistatic effect by silk thread using woven fabric and antistatic silk thread
Its antistatic effect is uneven while fruit is poor.
Chinese patent application CN108125481A discloses that the invention discloses a kind of antistatic quilt cover and corresponding beds
List and pillowcase belong to bedding field.A kind of antistatic quilt cover, the quilt cover include upper layer fabric and lower layer's fabric, described
Upper layer fabric and lower layer's fabric are formed along side seam system, and the quilt cover side is equipped with zipper, to be put into or take by unziping
Core out is equipped with conductive yam in the upper layer fabric and/or lower layer's fabric.By the way that antistatic yarn is added inside fabric, solve
The problem of electrostatic causes harm to the human body occurs for family of four and human contact, and is arranged inside fabric with preset interval and leads
Electric yarn can reach antistatic optimum efficiency, and save cost, but this method is by utilizing the silk thread of woven fabric and antistatic
Silk thread carries out intersecting the antistatic cloth worked out, its antistatic effect is uneven while antistatic effect is poor.
Above-mentioned patent there are aiming at the problem that, the present invention, which has developed antistatic fibre, can be good at meeting market to leather
Demand.
Summary of the invention
In order to achieve the purpose that in background technique, a kind of antistatic fibre proposed by the present invention and its manufacturing method；
What the present invention realized by the following technical solutions:
A kind of antistatic fibre and its manufacturing method, the following steps are included:
A kind of antistatic fibre and its manufacturing method, which is characterized in that the composition of the antistatic fibre are as follows: mass fraction is
80-100 parts of improved polyurethane fiber, 10-15 parts of Fypro, 6-8 part reinforcing agent of part, 4-6 parts of toughener, 3-
5 parts of lubricant, 15-20 parts of antistatic agent, 3-5 parts of antioxidant；
A kind of described antistatic fibre and its manufacturing method are as follows: by mass fraction be 80-100 parts improved polyurethane fiber,
10-15 parts of Fypro, the reinforcing agent of 6-8 parts of parts, 4-6 parts of toughener, 3-5 parts of lubricant, 15-20 parts resist it is quiet
Electric agent, 3-5 parts of antioxidant are added in batch mixer and are mixed, and after mixing, material are added in dryer and is dried
Dry, material is added in parallel single screw extrusion machine after 50-60 DEG C, drying and carries out granulation extrusion by drying temperature, obtains partial size
The identical particle of size, the substance are exactly antistatic fibre, and when use, which is added into heat fusing spinning machine, to carry out heat fusing and squeeze
It reels off raw silk from cocoons out, is prepared into filament of the diameter at 10-15 microns, which is exactly antistatic fibre silk, can be used for woven fabric, spins
Deng.
Wherein, the improved polyurethane fiber are as follows: by 60-80 parts of polyurethane fiber, 6-8 parts of wood fibre, 4-6
The flour, 1-2 parts of azo-bis-isobutyl cyanide, the organotin catalysts of 0.1-0.2,2-3 parts of lubricant of part are added in batch mixer
It is mixed, after mixing, material is added in twin-screw granulating extruder and is modified and is granulated extrusion, obtains modified materials
Grain, which is exactly improved polyurethane fiber.
Wherein, the reinforcing agent are as follows: by 15-20 parts of polystyrene, 6-10 parts of polyimide fiber, 6-8 parts
Batch mixer is added in glass fibre, 5-10 parts of nanometer silicon carbide powder, 20-30 parts of polyethylene fibre, 2-3 parts of lubricant
In mixed, after mixing, will material be added twin-screw granulating extruder in carry out granulation extrusion, obtain of uniform size
Expect grain, which is exactly reinforcing agent.
Wherein, the toughener are as follows: by 20-30 parts of acrylonitrile, butadiene, styrene according to mass ratio be 5:3:4
Terpolymer, 4-5 parts of high glue powder, 10-15 parts of the polymethyl methacrylate met are added in batch mixer
It is mixed, the substance obtained after mixing, the substance is exactly toughener.
Wherein, the lubricant are as follows: by temperature of reaction kettle control at 50-60 DEG C, revolving speed control, will in 200-300rpm
Mass fraction is 2-4 parts of beeswax, 5-10 parts of stearic acid, 1-2 parts of tridecanoic acid, the addition of 5-10 parts of low density polyethylene (LDPE)
In reaction kettle, the substance obtained after carrying out hybrid reaction 1-2 hours, which is exactly lubricant.
Wherein, the antistatic agent are as follows: the carbon black of collection is added in grinder and grinds, particle size is
300-500 nanometers, mass fraction meter is then weighed, the 20-30 parts of substances, 2-5 parts of iodine, 10-20 parts of polyacetylene are added
The substance obtained after mixing in batch mixer, the substance are exactly antistatic agent.
Wherein, the antioxidant are as follows: by mass fraction be 2-4 parts of potassium chromate, 3-5 parts of poly- hydroquinone, 3-5
The vitamin E, 3-4 parts of citric acid, 1-2 parts of 3- hydroxyl hexichol pentanone of part are added in reaction kettle, carry out in 30-50 DEG C of condition
The substance obtained after reaction, the substance are exactly antioxidant agent.
Detailed description of the invention
Fig. 1 is antistatic fibre and its manufacturing process flow diagram proposed by the present invention.
Beneficial to benefit
(1) antistatic fibre prepared by the present invention is prepared using fusion method, which improve tradition prepare it is antistatic
Fiber is prepared by the way that a small amount of conductive fiber is added, and the antistatic effect of antistatic fibre is effectively raised,
Guarantee the persistence of its antistatic effect simultaneously；
(2) antistatic fibre prepared by the present invention, intensity and flexibility with higher, while it is with good ageing resistance
The advantages that energy and long service life.
Specific embodiment
In order to keep the purpose of the present invention, technical scheme and beneficial effects clearer, below in conjunction with experimental data, to this
The preferred embodiment of invention is described in detail, to facilitate the technical staff to understand.
Embodiment 1
A kind of antistatic fibre and its manufacturing method, the following steps are included:
A kind of antistatic fibre and its manufacturing method, which is characterized in that the composition of the antistatic fibre are as follows: mass fraction is
90 parts of improved polyurethane fiber, 12 parts of Fypro, the reinforcing agent of 8 parts of parts, 5 parts of toughener, 4 parts of lubricant,
16 parts of antistatic agent, 4 parts of antioxidant；
A kind of described antistatic fibre and its manufacturing method are as follows: by mass fraction be 90 parts improved polyurethane fiber, 12 parts
Fypro, the reinforcing agent of 8 parts of parts, 5 parts of toughener, 4 parts of lubricant, 16 parts of antistatic agent, 4 parts anti-oxidant
Agent is added in batch mixer and is mixed, and after mixing, material is added in dryer and is dried, drying temperature is in 50-60
DEG C, material is added in parallel single screw extrusion machine after drying and carries out granulation extrusion, obtains the identical particle of particle size, the object
Matter is exactly antistatic fibre, and when use, which is added into heat fusing spinning machine, to carry out heat fusing extrusion and reel off raw silk from cocoons, and is prepared into diameter and exists
10-15 microns of filament, the silk thread are exactly antistatic fibre silk, can be used for woven fabric, spin.
Wherein, the improved polyurethane fiber are as follows: by 75 parts of polyurethane fiber, 7 parts of wood fibre, 5 parts of face
Powder, 2 parts of azo-bis-isobutyl cyanide, 0.2 organotin catalysts, 3 parts of lubricant are added in batch mixer and are mixed, and mixing is equal
After even, material is added in twin-screw granulating extruder and is modified and is granulated extrusion, obtains modified materials grain, which is exactly to change
Property polyurethane fiber.
Wherein, the reinforcing agent are as follows: by 17 parts of polystyrene, 7 parts of polyimide fiber, 8 parts of glass fibre,
8 parts of nanometer silicon carbide powder, 28 parts of polyethylene fibre, 3 parts of lubricant are added in batch mixer and are mixed, and mixing is equal
After even, material is added in twin-screw granulating extruder and carries out granulation extrusion, obtains material grain of uniform size, which is exactly to increase
Strong agent.
Wherein, the toughener are as follows: by 26 parts of acrylonitrile, butadiene, styrene according to mass ratio be 5:3:4 carry out
Meet obtain terpolymer, 5 parts of high glue powder, 14 parts polymethyl methacrylate be added batch mixer in mixed,
The substance obtained after mixing, the substance are exactly toughener.
Wherein, the lubricant are as follows: by temperature of reaction kettle control at 50-60 DEG C, revolving speed control, will in 200-300rpm
Mass fraction be 2 parts of beeswax, 9 parts of stearic acid, 2 parts of tridecanoic acid, 7 parts low density polyethylene (LDPE) be added reaction kettle in,
The substance obtained after carrying out hybrid reaction 1-2 hours, which is exactly lubricant.
Wherein, the antistatic agent are as follows: the carbon black of collection is added in grinder and grinds, particle size is
300-500 nanometers, mass fraction meter is then weighed, 30 parts of substances, 4 parts of iodine, 15 parts of polyacetylene are added in batch mixer
The substance obtained after mixing, the substance are exactly antistatic agent.
Wherein, the antioxidant are as follows: potassium chromate, 4 parts of poly- hydroquinone, 5 parts of dimension by mass fraction for 3 parts
Raw element E, 3 parts of citric acid, 2 parts of 3- hydroxyl hexichol pentanone are added in reaction kettle, obtain after 30-50 DEG C of condition is reacted
Substance, which is exactly antioxidant agent.
Embodiment 2
A kind of antistatic fibre and its manufacturing method, the following steps are included:
A kind of antistatic fibre and its manufacturing method, which is characterized in that the composition of the antistatic fibre are as follows: mass fraction is
100 parts of improved polyurethane fiber, 12 parts of Fypro, the reinforcing agent of 7 parts of parts, 5 parts of toughener, 4 parts of lubricant,
20 parts of antistatic agent, 4 parts of antioxidant；
A kind of described antistatic fibre and its manufacturing method are as follows: by mass fraction be 100 parts improved polyurethane fiber, 12 parts
Fypro, the reinforcing agent of 7 parts of parts, 5 parts of toughener, 4 parts of lubricant, 20 parts of antistatic agent, 4 parts anti-oxidant
Agent is added in batch mixer and is mixed, and after mixing, material is added in dryer and is dried, drying temperature is in 50-60
DEG C, material is added in parallel single screw extrusion machine after drying and carries out granulation extrusion, obtains the identical particle of particle size, the object
Matter is exactly antistatic fibre, and when use, which is added into heat fusing spinning machine, to carry out heat fusing extrusion and reel off raw silk from cocoons, and is prepared into diameter and exists
10-15 microns of filament, the silk thread are exactly antistatic fibre silk, can be used for woven fabric, spin.
Wherein, the improved polyurethane fiber are as follows: by 70 parts of polyurethane fiber, 7 parts of wood fibre, 6 parts of face
Powder, 1 part of azo-bis-isobutyl cyanide, 0.2 organotin catalysts, 3 parts of lubricant are added in batch mixer and are mixed, and mixing is equal
After even, material is added in twin-screw granulating extruder and is modified and is granulated extrusion, obtains modified materials grain, which is exactly to change
Property polyurethane fiber.
Wherein, the reinforcing agent are as follows: by 16 parts of polystyrene, 8 parts of polyimide fiber, 8 parts of glass fibre,
9 parts of nanometer silicon carbide powder, 25 parts of polyethylene fibre, 3 parts of lubricant are added in batch mixer and are mixed, and mixing is equal
After even, material is added in twin-screw granulating extruder and carries out granulation extrusion, obtains material grain of uniform size, which is exactly to increase
Strong agent.
Wherein, the toughener are as follows: by 25 parts of acrylonitrile, butadiene, styrene according to mass ratio be 5:3:4 carry out
Meet obtain terpolymer, 5 parts of high glue powder, 15 parts polymethyl methacrylate be added batch mixer in mixed,
The substance obtained after mixing, the substance are exactly toughener.
Wherein, the lubricant are as follows: by temperature of reaction kettle control at 50-60 DEG C, revolving speed control, will in 200-300rpm
Mass fraction be 3 parts of beeswax, 8 parts of stearic acid, 1 part of tridecanoic acid, 6 parts low density polyethylene (LDPE) be added reaction kettle in,
The substance obtained after carrying out hybrid reaction 1-2 hours, which is exactly lubricant.
Wherein, the antistatic agent are as follows: the carbon black of collection is added in grinder and grinds, particle size is
300-500 nanometers, mass fraction meter is then weighed, 25 parts of substances, 3 parts of iodine, 15 parts of polyacetylene are added in batch mixer
The substance obtained after mixing, the substance are exactly antistatic agent.
Wherein, the antioxidant are as follows: be potassium chromate, 5 parts of the poly- hydroquinone, 4 parts of dimension of part by mass fraction
Raw element E, 4 parts of citric acid, 1 part of 3- hydroxyl hexichol pentanone are added in reaction kettle, obtain after 30-50 DEG C of condition is reacted
Substance, which is exactly antioxidant agent.
Embodiment 3
A kind of antistatic fibre and its manufacturing method, the following steps are included:
A kind of antistatic fibre and its manufacturing method, which is characterized in that the composition of the antistatic fibre are as follows: mass fraction is
80 parts of improved polyurethane fiber, 10 parts of Fypro, the reinforcing agent of 6 parts of parts, 4 parts of toughener, 3 parts of lubricant,
15 parts of antistatic agent, 3 parts of antioxidant；
A kind of described antistatic fibre and its manufacturing method are as follows: by mass fraction be 80 parts improved polyurethane fiber, 10 parts
Fypro, the reinforcing agent of 6 parts of parts, 4 parts of toughener, 3 parts of lubricant, 15 parts of antistatic agent, 3 parts anti-oxidant
Agent is added in batch mixer and is mixed, and after mixing, material is added in dryer and is dried, drying temperature is in 50-60
DEG C, material is added in parallel single screw extrusion machine after drying and carries out granulation extrusion, obtains the identical particle of particle size, the object
Matter is exactly antistatic fibre, and when use, which is added into heat fusing spinning machine, to carry out heat fusing extrusion and reel off raw silk from cocoons, and is prepared into diameter and exists
10-15 microns of filament, the silk thread are exactly antistatic fibre silk, can be used for woven fabric, spin.
Wherein, the improved polyurethane fiber are as follows: by 60 parts of polyurethane fiber, 6 parts of wood fibre, 4 parts of face
Powder, 1 part of azo-bis-isobutyl cyanide, 0.1 organotin catalysts, 2 parts of lubricant are added in batch mixer and are mixed, and mixing is equal
After even, material is added in twin-screw granulating extruder and is modified and is granulated extrusion, obtains modified materials grain, which is exactly to change
Property polyurethane fiber.
Wherein, the reinforcing agent are as follows: by 15 parts of polystyrene, 6 parts of polyimide fiber, 6 parts of glass fibre,
5 parts of nanometer silicon carbide powder, 20 parts of polyethylene fibre, 2 parts of lubricant are added in batch mixer and are mixed, and mixing is equal
After even, material is added in twin-screw granulating extruder and carries out granulation extrusion, obtains material grain of uniform size, which is exactly to increase
Strong agent.
Wherein, the toughener are as follows: by 20 parts of acrylonitrile, butadiene, styrene according to mass ratio be 5:3:4 carry out
Meet obtain terpolymer, 4 parts of high glue powder, 10 parts polymethyl methacrylate be added batch mixer in mixed,
The substance obtained after mixing, the substance are exactly toughener.
Wherein, the lubricant are as follows: by temperature of reaction kettle control at 50-60 DEG C, revolving speed control, will in 200-300rpm
Mass fraction be 2 parts of beeswax, 5 parts of stearic acid, 1 part of tridecanoic acid, 5 parts low density polyethylene (LDPE) be added reaction kettle in,
The substance obtained after carrying out hybrid reaction 1-2 hours, which is exactly lubricant.
Wherein, the antistatic agent are as follows: the carbon black of collection is added in grinder and grinds, particle size is
300-500 nanometers, mass fraction meter is then weighed, 20 parts of substances, 2 parts of iodine, 10 parts of polyacetylene are added in batch mixer
The substance obtained after mixing, the substance are exactly antistatic agent.
Wherein, the antioxidant are as follows: potassium chromate, 3 parts of poly- hydroquinone, 3 parts of dimension by mass fraction for 2 parts
Raw element E, 3 parts of citric acid, 1 part of 3- hydroxyl hexichol pentanone are added in reaction kettle, obtain after 30-50 DEG C of condition is reacted
Substance, which is exactly antioxidant agent.
Embodiment 4
A kind of antistatic fibre and its manufacturing method, the following steps are included:
A kind of antistatic fibre and its manufacturing method, which is characterized in that the composition of the antistatic fibre are as follows: mass fraction is
100 parts of improved polyurethane fiber, 15 parts of Fypro, the reinforcing agent of 8 parts of parts, 6 parts of toughener, 5 parts of lubricant,
20 parts of antistatic agent, 5 parts of antioxidant；
A kind of described antistatic fibre and its manufacturing method are as follows: by mass fraction be 100 parts improved polyurethane fiber, 15 parts
Fypro, the reinforcing agent of 8 parts of parts, 6 parts of toughener, 5 parts of lubricant, 20 parts of antistatic agent, 5 parts anti-oxidant
Agent is added in batch mixer and is mixed, and after mixing, material is added in dryer and is dried, drying temperature is in 50-60
DEG C, material is added in parallel single screw extrusion machine after drying and carries out granulation extrusion, obtains the identical particle of particle size, the object
Matter is exactly antistatic fibre, and when use, which is added into heat fusing spinning machine, to carry out heat fusing extrusion and reel off raw silk from cocoons, and is prepared into diameter and exists
10-15 microns of filament, the silk thread are exactly antistatic fibre silk, can be used for woven fabric, spin.
Wherein, the improved polyurethane fiber are as follows: by 80 parts of polyurethane fiber, 8 parts of wood fibre, 6 parts of face
Powder, 2 parts of azo-bis-isobutyl cyanide, 0.2 organotin catalysts, 3 parts of lubricant are added in batch mixer and are mixed, and mixing is equal
After even, material is added in twin-screw granulating extruder and is modified and is granulated extrusion, obtains modified materials grain, which is exactly to change
Property polyurethane fiber.
Wherein, the reinforcing agent are as follows: by 20 parts of polystyrene, 10 parts of polyimide fiber, 8 parts of glass fibers
Dimension, 10 parts of nanometer silicon carbide powder, 30 parts of polyethylene fibre, 3 parts of lubricant are added in batch mixer and are mixed, and mix
After closing uniformly, material is added in twin-screw granulating extruder and carries out granulation extrusion, obtains material grain of uniform size, the substance is just
It is reinforcing agent.
Wherein, the toughener are as follows: by 30 parts of acrylonitrile, butadiene, styrene according to mass ratio be 5:3:4 carry out
Meet obtain terpolymer, 5 parts of high glue powder, 15 parts polymethyl methacrylate be added batch mixer in mixed,
The substance obtained after mixing, the substance are exactly toughener.
Wherein, the lubricant are as follows: by temperature of reaction kettle control at 50-60 DEG C, revolving speed control, will in 200-300rpm
Mass fraction is 4 parts of beeswax, 10 parts of stearic acid, 2 parts of tridecanoic acid, 10 parts of low density polyethylene (LDPE) addition reaction kettle
In, the substance obtained after carrying out hybrid reaction 1-2 hours, which is exactly lubricant.
Wherein, the antistatic agent are as follows: the carbon black of collection is added in grinder and grinds, particle size is
300-500 nanometers, mass fraction meter is then weighed, 30 parts of substances, 5 parts of iodine, 20 parts of polyacetylene are added in batch mixer
The substance obtained after mixing, the substance are exactly antistatic agent.
Wherein, the antioxidant are as follows: potassium chromate, 5 parts of poly- hydroquinone, 5 parts of dimension by mass fraction for 4 parts
Raw element E, 4 parts of citric acid, 2 parts of 3- hydroxyl hexichol pentanone are added in reaction kettle, obtain after 30-50 DEG C of condition is reacted
Substance, which is exactly antioxidant agent.
Finally, it is stated that preferred embodiment above is only used to illustrate the technical scheme of the present invention rather than limits, although logical
It crosses above preferred embodiment the present invention is described in detail, however, those skilled in the art should understand that, can be
Various changes are made to it in form and in details, without departing from defined by claims of the present invention.
Claims (7)
1. a kind of antistatic fibre and its manufacturing method, which is characterized in that the composition of the antistatic fibre are as follows: mass fraction
For 80-100 parts of improved polyurethane fibers, 10-15 parts of Fypro, the reinforcing agent of 6-8 parts of parts, 4-6 parts of toughener,
3-5 parts of lubricant, 15-20 parts of antistatic agent, 3-5 parts of antioxidant；
A kind of described antistatic fibre and its manufacturing method are as follows: by mass fraction be 80-100 parts improved polyurethane fiber,
10-15 parts of Fypro, the reinforcing agent of 6-8 parts of parts, 4-6 parts of toughener, 3-5 parts of lubricant, 15-20 parts resist it is quiet
Electric agent, 3-5 parts of antioxidant are added in batch mixer and are mixed, and after mixing, material are added in dryer and is dried
Dry, material is added in parallel single screw extrusion machine after 50-60 DEG C, drying and carries out granulation extrusion by drying temperature, obtains partial size
The identical particle of size, the substance are exactly antistatic fibre, and when use, which is added into heat fusing spinning machine, to carry out heat fusing and squeeze
It reels off raw silk from cocoons out, is prepared into filament of the diameter at 10-15 microns, which is exactly antistatic fibre silk, can be used for woven fabric, spins
Deng.
2. a kind of antistatic fibre according to claim 1 and its manufacturing method, which is characterized in that the poly- ammonia of the modification
Ester fiber are as follows: by 60-80 parts of polyurethane fiber, 6-8 parts of wood fibre, 4-6 parts of flour, 1-2 parts of two isobutyl of azo
Cyanogen, the organotin catalysts of 0.1-0.2,2-3 parts of lubricant are added in batch mixer and are mixed, after mixing, by material
It is added in twin-screw granulating extruder and is modified and is granulated extrusion, obtain modified materials grain, which is exactly modified polyurethane fibre
Dimension.
3. a kind of antistatic fibre according to claim 1 and its manufacturing method, which is characterized in that the reinforcing agent
Are as follows: by 15-20 parts of polystyrene, 6-10 parts of polyimide fiber, 6-8 parts of glass fibre, 5-10 parts of nano-scale carbon
SiClx powder, 20-30 parts of polyethylene fibre, 2-3 parts of lubricant are added in batch mixer and are mixed, after mixing, will
Material is added in twin-screw granulating extruder and carries out granulation extrusion, obtains material grain of uniform size, which is exactly reinforcing agent.
4. a kind of antistatic fibre according to claim 1 and its manufacturing method, which is characterized in that the toughener
Are as follows: by 20-30 parts of acrylonitrile, butadiene, styrene according to mass ratio be 5:3:4 met terpolymer,
4-5 parts of high glue powder, 10-15 parts of polymethyl methacrylate are added in batch mixer and are mixed, and obtain after mixing
Substance, the substance are exactly toughener.
5. a kind of antistatic fibre according to claim 1 and its manufacturing method, which is characterized in that the lubricant
Are as follows: by temperature of reaction kettle control at 50-60 DEG C, revolving speed controls beeswax, 5- in 200-300rpm, by mass fraction for 2-4 parts
10 parts of stearic acid, 1-2 parts of tridecanoic acid, 5-10 parts of low density polyethylene (LDPE) is added in reaction kettle, carries out hybrid reaction 1-2
The substance obtained after hour, which is exactly lubricant.
6. a kind of antistatic fibre according to claim 1 and its manufacturing method, which is characterized in that the antistatic agent
Are as follows: the carbon black of collection is added in grinder and is ground, particle size is 300-500 nanometers, then weighs mass fraction
Meter, 20-30 part substances, 2-5 parts of iodine are obtained after mixing in 10-20 parts of polyacetylene addition batch mixer
Substance, the substance are exactly antistatic agent.
7. a kind of antistatic fibre according to claim 1 and its manufacturing method, which is characterized in that the antioxidant
Are as follows: by mass fraction be 2-4 parts potassium chromate, 3-5 parts of poly- hydroquinone, 3-5 parts of vitamin E, 3-4 parts of citric acid,
1-2 parts of 3- hydroxyl hexichol pentanone is added in reaction kettle, and the substance obtained after 30-50 DEG C of condition is reacted, the substance is just
It is antioxidant agent.
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110042497A (en) * | 2019-05-09 | 2019-07-23 | 江苏恒宇纺织集团有限公司 | A kind of degradable high-elasticity fiber and preparation method thereof |
Citations (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101845163A (en) * | 2009-05-27 | 2010-09-29 | 山东天野塑化有限公司 | Application method of carbon black in master batch of conductive fiber and master batch of garment conductive fiber |
| CN102174254A (en) * | 2010-12-27 | 2011-09-07 | 东莞劲胜精密组件股份有限公司 | Highly heat-conducting insulation engineering plastic and preparation method thereof |
| CN102174189A (en) * | 2011-01-07 | 2011-09-07 | 南开大学 | Polyhydroquinone microsphere with redox activity and method for preparing same |
| CN102535308A (en) * | 2011-12-27 | 2012-07-04 | 江苏共创人造草坪有限公司 | Antistatic artificial lawn and preparation method thereof |
| CN103603085A (en) * | 2013-10-21 | 2014-02-26 | 浙江三和塑料有限公司 | Perpetual anti-static conductive fiber |
| CN103668559A (en) * | 2013-11-22 | 2014-03-26 | 南通市通州区川姜镇盛世王朝家用纺织品设计工作室 | Antistatic fiber and preparation method thereof |
| TW201445016A (en) * | 2013-05-30 | 2014-12-01 | Asiatic Fiber Corp | Antistatic elastic fiber |
| CN105273355A (en) * | 2015-04-28 | 2016-01-27 | 东莞市正和防静电材料科技有限公司 | Explosion-proof static material applied in firework and cracker protection safety, preparation and applications |
| CN105694439A (en) * | 2016-04-13 | 2016-06-22 | 苏州锦腾电子科技有限公司 | Thermoconductive and electroconductive plastic and preparation method thereof |
| CN106120013A (en) * | 2016-06-30 | 2016-11-16 | 广州大学 | A kind of static resistant polyamide fiber being applied to underwear |
| CN106605014A (en) * | 2014-05-05 | 2017-04-26 | 英威达技术有限公司 | Bio-derived polyurethane fiber |
| CN108209378A (en) * | 2017-11-21 | 2018-06-29 | 宁波东方席业有限公司 | Antistatic wave wave pad and preparation method thereof |
-
2018
- 2018-10-25 CN CN201811252127.7A patent/CN109402782A/en active Pending
Patent Citations (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101845163A (en) * | 2009-05-27 | 2010-09-29 | 山东天野塑化有限公司 | Application method of carbon black in master batch of conductive fiber and master batch of garment conductive fiber |
| CN102174254A (en) * | 2010-12-27 | 2011-09-07 | 东莞劲胜精密组件股份有限公司 | Highly heat-conducting insulation engineering plastic and preparation method thereof |
| CN102174189A (en) * | 2011-01-07 | 2011-09-07 | 南开大学 | Polyhydroquinone microsphere with redox activity and method for preparing same |
| CN102535308A (en) * | 2011-12-27 | 2012-07-04 | 江苏共创人造草坪有限公司 | Antistatic artificial lawn and preparation method thereof |
| TW201445016A (en) * | 2013-05-30 | 2014-12-01 | Asiatic Fiber Corp | Antistatic elastic fiber |
| CN103603085A (en) * | 2013-10-21 | 2014-02-26 | 浙江三和塑料有限公司 | Perpetual anti-static conductive fiber |
| CN103668559A (en) * | 2013-11-22 | 2014-03-26 | 南通市通州区川姜镇盛世王朝家用纺织品设计工作室 | Antistatic fiber and preparation method thereof |
| CN106605014A (en) * | 2014-05-05 | 2017-04-26 | 英威达技术有限公司 | Bio-derived polyurethane fiber |
| CN105273355A (en) * | 2015-04-28 | 2016-01-27 | 东莞市正和防静电材料科技有限公司 | Explosion-proof static material applied in firework and cracker protection safety, preparation and applications |
| CN105694439A (en) * | 2016-04-13 | 2016-06-22 | 苏州锦腾电子科技有限公司 | Thermoconductive and electroconductive plastic and preparation method thereof |
| CN106120013A (en) * | 2016-06-30 | 2016-11-16 | 广州大学 | A kind of static resistant polyamide fiber being applied to underwear |
| CN108209378A (en) * | 2017-11-21 | 2018-06-29 | 宁波东方席业有限公司 | Antistatic wave wave pad and preparation method thereof |
Non-Patent Citations (2)
| Title |
|---|
| 刘小波等: "《炭黑/聚氨酯共混导电纤维熔融纺丝的研究"》", 《天津工业大学学报》 * |
| 刘小波等: "《炭黑/聚氨酯共混导电纤维熔融纺丝的研究》", 《天津工业大学学报》 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110042497A (en) * | 2019-05-09 | 2019-07-23 | 江苏恒宇纺织集团有限公司 | A kind of degradable high-elasticity fiber and preparation method thereof |
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Application publication date: 20190301 |