CN109401599A - A kind of UV coating and preparation method thereof suitable for BMC - Google Patents
A kind of UV coating and preparation method thereof suitable for BMC Download PDFInfo
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- CN109401599A CN109401599A CN201811059918.8A CN201811059918A CN109401599A CN 109401599 A CN109401599 A CN 109401599A CN 201811059918 A CN201811059918 A CN 201811059918A CN 109401599 A CN109401599 A CN 109401599A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
- C09D175/14—Polyurethanes having carbon-to-carbon unsaturated bonds
Abstract
The present invention provides a kind of UV coating suitable for BMC, belong to paint field.UV coating provided by the invention overcome traditional plastic paint wear no resistance, the disadvantage of anti ageing property difference; a kind of better coating of effect has been prepared using 20-45 part polyacrylate resin, 18-35 parts of acrylic ester monomers, 4-8 parts of photoinitiators, 10-12 parts of auxiliary agents and 50-60 parts of water by weight; wherein auxiliary agent is made of dispersing agent, levelling agent, antistatic agent and BMC protective agent, and wherein BMC protective agent is that nano-metal-oxide colloidal sol is prepared.UV paint adhesion provided by the invention suitable for BMC can reach 0 grade.
Description
Technical field
The invention belongs to paint field, especially a kind of UV coating and preparation method thereof suitable for BMC.
Background technique
UV is exactly the industrial UV wavelength of the English abbreviation of ultraviolet light (Ultra-Violet Ray) with 200nm to 450nm
For the processing procedure that its application range irradiates " UV irradiates hardenable material " with UV and hardens it, we term it " UV
Curing Process".After UV coating can be by the methods of dip-coating, showering, paint painting, spin coating or even vacuum painting coating, then through purple
Outside line photon irradiation and film-forming.As its name suggests, the solidification of UV coating is that the irradiation with UV light is inseparable.This technique functions
It is a kind of completely new green technology derived from the international coatings market of the seventies.The ultraviolet-curing paint produced using the technology,
Abbreviation UV coating.At the end of the 20th century, UV is coating material solidified comes into vogue in west, Japan and other places, is a kind of painting item for representing fashion
Kind.External coating processing applied to mobile phone, DVD, walkman shell earliest, existing the further expanding to of its later application field
The household appliance technical fields such as cosmetic, television set and computer.
UV photocureable coating, which has, is free of volatile organic compounds (VOC), and environmental pollution is small, and curing rate is fast, section
Province's energy, cured product performance is good, is suitable for the advantages that high-speed automated production.And traditional coating is volatile, curing rate is slow,
It is unfavorable for environmental protection.Therefore, UV coating is the main substitute of traditional coating.
In the prior art, UV coating to the poor adhesive force of plastic products, ask by always the long-standing of this field that wear no resistance
Topic, furthermore ultraviolet light irradiation also result in ageing of plastics.
Summary of the invention
Described above in order to overcome the shortcomings of, the present invention provides a kind of UV coating suitable for BMC, apply in traditional UV
It is improved on the basis of material, has screened photoinitiator, be added to BMC protective agent.
Specifically, the present invention is achieved through the following technical solutions:
A kind of UV coating suitable for BMC, by 20-45 part polyacrylate resin, 18-35 parts of propylene by weight
Esters of gallic acid monomer, 4-8 part photoinitiator, 10-12 parts of auxiliary agents and 50-60 parts of water are prepared；
The auxiliary agent is made of dispersing agent, levelling agent, antistatic agent and BMC protective agent；
The BMC protective agent is pickering emulsion.
Preferably, the photoinitiator is triaryl sulfonium salts.
Preferably, the triaryl sulfonium salts are 4- aminomethyl phenyl diphenyl sulphur hexafluorophosphate.
Preferably, the pickering emulsion accounts for the 60-75% of auxiliary agent gross mass.
Preferably, the auxiliary agent is by the dispersing agent of 8-15% by mass percentage, the levelling agent of 10-15%, 7-
10% antistatic agent and the pickering emulsion composition of 60-75%.
Preferably, the pickering emulsion is by nano-metal-oxide colloidal sol, acrylate, methacrylic acid, methyl-prop
Olefin(e) acid ester and ammonium persulfate and water are prepared.
Preferably, the nano-metal-oxide colloidal sol is nano titanic oxide sol, nano-zinc oxide sol, nanometer
Any one in alumina sol, nano cerium dioxide sol.
Preferably, in the nano-metal-oxide colloidal sol nano-metal-oxide content between 10%-25%.
Preferably, the pickering emulsion the preparation method comprises the following steps:
(1) 4-5 times of water of nano-metal-oxide colloidal sol is diluted, obtains dilution；
(2) the 15-30wt% metering system sour water of nano-metal-oxide colloidal sol quality 15-20% is added dropwise into dilution
Solution stirs 0.5-2 hours at room temperature after being added dropwise, and 1.5-2 times of quality of nano-metal-oxide colloidal sol of acrylic acid is added
Ester and 0.8-1.2 times of quality of nano-metal-oxide colloidal sol of methacrylate, are heated to 60-70 DEG C and keep 0.5-1 small
When after be added nano-metal-oxide colloidal sol quality 25-30% concentration be 5-8wt% ammonium persulfate aqueous solution, continue exist
It is stirred 6-12 hours at 60-70 DEG C；
(3) it was cooled to room temperature 100 μm of sieves naturally, gained liquid is pickering emulsion；
All operations carry out under inert gas protection in step (2).
The method for preparing the above-mentioned UV coating suitable for BMC, steps are as follows:
After mixing by 4-8 parts of photoinitiators and 50-60 water, 20-45 parts of polyacrylate resins, 18- are sequentially added
BMC is added after mixing evenly in 35 parts of acrylic ester monomers, dispersing agent, levelling agent and antistatic agent under inert gas protection
Protective agent, seal up for safekeeping immediately to get.
The invention has the beneficial effects that avoiding BMC material by ultraviolet light and aging, therefore develop protectant containing BMC
Coating, the BMC protective agent inherently belong to a kind of pickering emulsion, and the nano-oxide colloidal sol contained can be absorbed
Ultraviolet light, but this absorption will not influence photoinitiator and play a role in coating solidification.
Specific embodiment
The present invention is further elaborated below with reference to embodiment, but following embodiments are only used to explain that the present invention cannot
For limiting the present invention.
Specifically, the raw material used in following embodiments is as follows:
Polyacrylate resin, model U-25-20D urethane acrylate.
Acrylic ester monomer is SR285 tetrahydrofuran acrylate monomer.
Dispersing agent is full of the dispersing agent of the model 913 of chemical production for German section.
Levelling agent, for the levelling agent of the model 333 of Bi Ke company, Germany production.
Antistatic agent, for the antistatic agent of the model Basionics VS03 of BASF AG's production.
Tetrafluoro boric acid methyldiphenyl base sulfosalt, No. CAS: 10504-60-6.
4- aminomethyl phenyl diphenyl sulphur hexafluorophosphate, No. CAS: 66482-51-7.
Nano titanic oxide sol, the production of Ningbo gold thunder Nono-material Science & Technology Ltd., nano-metal-oxide content
It is 22%.
The production of nano cerium dioxide sol Ningbo gold thunder Nono-material Science & Technology Ltd., nano-metal-oxide content are
18%.
Nano-zinc oxide sol, the production of Ningbo gold thunder Nono-material Science & Technology Ltd., nano-metal-oxide content are
20%.
Methacrylic acid, No. CAS: 79-41-4.
Acrylate, be n-butyl acrylate, No. CAS: 141-32-2.
Methacrylate, be methyl methacrylate, No. CAS: 80-62-6.
Ammonium persulfate, No. CAS: 7727-54-0.
Embodiment 1
A kind of UV coating suitable for BMC, by 28 parts of polyacrylate resins, 18 parts of esters of acrylic acid by weight
Monomer, 6 parts of tetrafluoro boric acid methyldiphenyl base sulfosalts, 1.5 parts of dispersing agents, 1.5 parts of levelling agents, 1 part of antistatic agent, 7 parts of piks
Woods lotion and 55 parts of water are prepared.
The pickering emulsion the preparation method is as follows:
(1) 5 times of water of nano titanic oxide sol is diluted, obtains dilution；
(2) concentration that nano titanic oxide sol quality 18% is added dropwise into dilution is that 18wt% methacrylic acid is water-soluble
Liquid stirs 1 hour at room temperature after being added dropwise, and 1.6 times of nano titanic oxide sol quality of acrylate and nanometer two is added
The methacrylate of the quality such as titanium oxide sol quality is heated to 70 DEG C and nano-titanium dioxide is added after being kept for 0.5 hour
The concentration of quality 30% is the ammonium persulfate aqueous solution of 8wt%, and continuation is stirred 8 hours at 70 DEG C, this step whole process is in nitrogen
It is carried out under gas shielded；
(3) it was cooled to room temperature 100 μm of sieves naturally, gained liquid is up to pickering emulsion.
The method for preparing the above-mentioned UV coating suitable for BMC, steps are as follows:
After mixing by photoinitiator and water, a part polyacrylate resin, acrylic ester monomer, dispersion are sequentially added
Pickering emulsion is added after mixing evenly in agent, levelling agent and antistatic agent under nitrogen protection, seal up for safekeeping immediately to get.
Embodiment 2
A kind of UV coating suitable for BMC, by 28 parts of polyacrylate resins, 18 parts of esters of acrylic acid by weight
Monomer, 6 parts of 4- aminomethyl phenyl diphenyl sulphur hexafluorophosphates, 1.5 parts of dispersing agents, 1.5 parts of levelling agents, 1 part of antistatic agent, 7
Part pickering emulsion and 55 parts of water are prepared.
The pickering emulsion the preparation method is as follows:
(1) 5 times of water of nano titanic oxide sol is diluted, obtains dilution；
(2) concentration that nano titanic oxide sol quality 18% is added dropwise into dilution is that 18wt% methacrylic acid is water-soluble
Liquid stirs 1 hour at room temperature after being added dropwise, and 1.6 times of nano titanic oxide sol quality of acrylate and nanometer two is added
The methacrylate of the quality such as titanium oxide sol quality is heated to 70 DEG C and nano-titanium dioxide is added after being kept for 0.5 hour
The concentration of quality 30% is the ammonium persulfate aqueous solution of 8wt%, and continuation is stirred 8 hours at 70 DEG C, this step whole process is in nitrogen
It is carried out under gas shielded；
(3) it was cooled to room temperature 100 μm of sieves naturally, gained liquid is up to pickering emulsion.
The method for preparing the above-mentioned UV coating suitable for BMC, steps are as follows:
After mixing by photoinitiator and water, a part polyacrylate resin, acrylic ester monomer, dispersion are sequentially added
Pickering emulsion is added after mixing evenly in agent, levelling agent and antistatic agent under nitrogen protection, seal up for safekeeping immediately to get.
Embodiment 3
A kind of UV coating suitable for BMC, by 28 parts of polyacrylate resins, 18 parts of esters of acrylic acid by weight
Monomer, 6 parts of 4- aminomethyl phenyl diphenyl sulphur hexafluorophosphates, 1.5 parts of dispersing agents, 1.5 parts of levelling agents, 1 part of antistatic agent, 7
Part pickering emulsion and 55 parts of water are prepared.
The pickering emulsion the preparation method is as follows:
(1) 5 times of water of nano cerium dioxide sol is diluted, obtains dilution；
(2) concentration that nano cerium dioxide sol quality 18% is added dropwise into dilution is that 18wt% methacrylic acid is water-soluble
Liquid stirs 1 hour at room temperature after being added dropwise, and 1.6 times of nano cerium dioxide sol quality of acrylate and nanometer two is added
The methacrylate of the quality such as cerium oxide sol quality is heated to 70 DEG C and nano ceric oxide is added after being kept for 0.5 hour
The concentration of quality 30% is the ammonium persulfate aqueous solution of 8wt%, and continuation is stirred 8 hours at 70 DEG C, this step whole process is in nitrogen
It is carried out under gas shielded；
(3) it was cooled to room temperature 100 μm of sieves naturally, gained liquid is up to pickering emulsion.
The method for preparing the above-mentioned UV coating suitable for BMC, steps are as follows:
After mixing by photoinitiator and water, a part polyacrylate resin, acrylic ester monomer, dispersion are sequentially added
Pickering emulsion is added after mixing evenly in agent, levelling agent and antistatic agent under nitrogen protection, seal up for safekeeping immediately to get.
Embodiment 4
A kind of UV coating suitable for BMC, by 28 parts of polyacrylate resins, 18 parts of esters of acrylic acid by weight
Monomer, 6 parts of 4- aminomethyl phenyl diphenyl sulphur hexafluorophosphates, 1.5 parts of dispersing agents, 1.5 parts of levelling agents, 1 part of antistatic agent, 7
Part pickering emulsion and 55 parts of water are prepared.
The pickering emulsion the preparation method is as follows:
(1) 5 times of water of nano-zinc oxide sol is diluted, obtains dilution；
(2) concentration that nano-zinc oxide sol quality 18% is added dropwise into dilution is that 18wt% methacrylic acid is water-soluble
Liquid stirs 1 hour at room temperature after being added dropwise, and 1.6 times of nano-zinc oxide sol quality of acrylate and nano oxidized is added
The methacrylate of the quality such as zinc colloidal sol quality is heated to 70 DEG C and nano zine oxide quality is added after being kept for 0.5 hour
30% concentration is the ammonium persulfate aqueous solution of 8wt%, and continuation is stirred 8 hours at 70 DEG C, this step whole process is protected in nitrogen
Shield is lower to be carried out；
(3) it was cooled to room temperature 100 μm of sieves naturally, gained liquid is up to pickering emulsion.
The method for preparing the above-mentioned UV coating suitable for BMC, steps are as follows:
After mixing by photoinitiator and water, a part polyacrylate resin, acrylic ester monomer, dispersion are sequentially added
Pickering emulsion is added after mixing evenly in agent, levelling agent and antistatic agent under nitrogen protection, seal up for safekeeping immediately to get.
Test case 1
Adhesive force test and tear resistance test
The product made from embodiment 1-4 in the BMC material for being coated with conventional primer, using ultraviolet curing lamp to its into
Row solidification, solidification energy 500mJ/cm2, room temperature control is 20 ± 1 DEG C, curing time 1 minute, is not necessarily to preheating before solidification.To
Adhesive force test (cross-hatching) and tear resistance test (750g counterweight mill are carried out by national standard after product cooled to room temperature
100 circles, are indicated with paint film weightlessness).
Test result is as shown in table 1.
The test of 1 adhesive force of table and tear resistance test
| Adhesive force (cross-hatching) | Tear resistance/mg | |
| Embodiment 1 | 1 grade | 30 |
| Embodiment 2 | 1 grade | 24 |
| Embodiment 3 | 1 grade | 20 |
| Embodiment 4 | 0 grade | 12 |
As seen from the above table, the UV coating provided by the invention suitable for BMC is to pickering emulsion and photoinitiator progress
There is certain promotion after improvement to the adhesive force of coating and tear resistance.
Claims (8)
1. a kind of UV coating suitable for BMC, which is characterized in that by by weight 20-45 part polyacrylate resin,
18-35 parts of acrylic ester monomers, 4-8 parts of photoinitiators, 10-12 parts of auxiliary agents and 50-60 parts of water are prepared；
The auxiliary agent is made of dispersing agent, levelling agent, antistatic agent and BMC protective agent；
The BMC protective agent is pickering emulsion.
2. being suitable for the UV coating of BMC according to claim 1, which is characterized in that the photoinitiator is triaryl sulphur
Salt.
3. being suitable for the UV coating of BMC according to claim 1, which is characterized in that it is total that the pickering emulsion accounts for auxiliary agent
The 60-75% of quality.
4. being suitable for the UV coating of BMC according to claim 1, which is characterized in that the pickering emulsion is by nano metal
Oxide sol, acrylate, methacrylic acid, methacrylate and ammonium persulfate and water are prepared.
5. being suitable for the UV coating of BMC according to claim 4, which is characterized in that the nano-metal-oxide colloidal sol
It is any one in nano titanic oxide sol, nano-zinc oxide sol, nano alumina sol, nano cerium dioxide sol
Kind.
6. being suitable for the UV coating of BMC according to claim 4, which is characterized in that in the nano-metal-oxide colloidal sol
Nano-metal-oxide content is between 10%-25%.
7. being suitable for the UV coating of BMC according to claim 4, which is characterized in that the preparation method of the pickering emulsion
Are as follows:
(1) 4-5 times of water of nano-metal-oxide colloidal sol is diluted, obtains dilution；
(2) the 15-30wt% methacrylic acid that nano-metal-oxide colloidal sol quality 15-20% is added dropwise into dilution is water-soluble
Liquid stirs 0.5-2 hours at room temperature after being added dropwise, and the acrylate of 1.5-2 times of nano-metal-oxide quality is added and receives
The methacrylate of 0.8-1.2 times of quality of metal oxide of rice, is heated to 60-70 DEG C and is added after being kept for 0.5-1 hours to receive
The ammonium persulfate aqueous solution that the concentration of rice metal oxide quality 25-30% is 5-8wt%, continuation stir 6- at 60-70 DEG C
12 hours；
(3) it was cooled to room temperature 100 μm of sieves naturally, gained liquid is pickering emulsion；
All operations carry out under inert gas protection in step (2).
8. preparing the method described in claim 1-7 any one suitable for the UV coating of BMC, which is characterized in that steps are as follows:
After mixing by 4-8 parts of photoinitiators and 50-60 water, 20-45 parts of polyacrylate resins, 18-35 parts are sequentially added
BMC protection is added after mixing evenly in acrylic ester monomer, dispersing agent, levelling agent and antistatic agent under inert gas protection
Agent, seal up for safekeeping immediately to get.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811059918.8A CN109401599A (en) | 2018-09-12 | 2018-09-12 | A kind of UV coating and preparation method thereof suitable for BMC |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811059918.8A CN109401599A (en) | 2018-09-12 | 2018-09-12 | A kind of UV coating and preparation method thereof suitable for BMC |
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Application publication date: 20190301 |