CN106752193A - A kind of preparation of UV curing chromatics nano transparent insulating coating - Google Patents
A kind of preparation of UV curing chromatics nano transparent insulating coating Download PDFInfo
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- CN106752193A CN106752193A CN201710009513.2A CN201710009513A CN106752193A CN 106752193 A CN106752193 A CN 106752193A CN 201710009513 A CN201710009513 A CN 201710009513A CN 106752193 A CN106752193 A CN 106752193A
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- nano
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- transparent insulating
- chromatics
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The present invention provides a kind of UV curing chromatics nano transparent insulating coating, and it includes base-material, coating additive, reactive diluent, light trigger, wherein described base-material is made up of UV resin oligomers, the heat-insulated powder of inorganic nano, colour developing component.The present invention combines the advantage high of low energy consumption, production efficiency in UV cured coating films function admirable, production process and rainbow member, meets market for the diversified demand of nano transparent insulating coating.The present invention also discloses a kind of transparent heat-insulated paint film.
Description
Technical field
The present invention relates to insulating moulding coating field, and in particular to a kind of UV curing chromatics transparent heat insulating dope and its preparation side
Method.
Background technology
With economic fast development, building energy consumption accounts for the ratio of social total energy consumption and has raised up to 27.8% and year by year, right
Society causes heavy energy burden and serious environmental pollution.According to statistics, the annual new building area nearly 2,000,000,000 of China is flat
Square rice, wherein more than 80% builds for high energy consumption, nearly 40,000,000,000 m of existing building2, more than 95% builds for high energy consumption, the ring of building
Protect energy-saving extremely urgent.Door and window (especially glass) is the most weak part for building energy loss, and area accounts for building outer dimension
The 30% of protection structure area, its energy dissipation accounts for building the 2/3 of total energy consumption, is building and heating and the topmost original of energy consumption for cooling
Cause, is the important research object of building energy conservation.For energy saving, scientific research personnel has carried out extensive exploration and research, successively
Develop the glass such as low radiation coated glass, sunlight controlling coated glass, adhering film to glass, antisolar glass, double glazing, vacuum glass
Glass energy-conserving product, but these products often because visible region transmitance is low, process conditions are complicated, the reason, limitation such as expensive
Its popularization and application.In recent years, it has been found that nanometer metal oxide powder has preferably selectivity to solar spectrum, can
Jian Guang areas transmitance is high, and has good shielding properties to infrared light.Added after this nano oxide powder is disperseed
To in resin solution, nano transparent insulating coating can be obtained, the coating can form transparent heat-insulating film in glass surface, can play
The transparency of the good effect of heat insulation without influence glass.
At present, it is main based on water-based system in the preparation of domestic nano transparent insulating coating, such as：
(1) patent CN200410014672.4 discloses a kind of glass, transparent resin, metal and cement surface of being applied to
The effect of heat insulation test device of nano transparent heat-insulation composite coating and its coating.The coating is by aqueous polyurethane resin, poly-
Silicone resin, polyacrylic resin, nano-indium stannum oxide (ITO) powder, nano antimony tin oxide (ATO) powder, coating additive
Constituted with diluent etc..
(2) patent CN200910189363.3 discloses a kind of aqueous nano transparent glass thermal insulation paint and its preparation side
Method, the aqueous nano transparent glass thermal insulation paint made by the method has excellent effect of heat insulation and transparency.
(3) patent CN201310128843.5 discloses a kind of water soluble hydroxy acrylic acid-heat-insulated tree of polyester type transparent
Fat, it is with hydrophily unsaturation hydroxyl telechelic polyester resin and ethene base nano metallic oxide, acrylate monomer, hydroxyl third
Olefin(e) acid ester monomer, initiator, vinylsiloxane carry out polymerisation in deionized water, are then neutralized with pH adjusting agent, obtain
To Water-soluble hydroxy acrylic acid-polyester type transparent heat insulation resin.
It is well known that generally requiring several hours to 1 day ability surface drying after water paint spraying construction, and do solid work, need
The longer time, and construction influenceed greatly by weather, this aspect causes water transparent heat insulation paint generally existing film
Hardness is low, easy scratch defect, film is allowed for over time and is easily scratched, and the film for scratching has a strong impact in turn
The landscape effect of window, is on the other hand also unfavorable for the requirement of live large-scale construction and low energy consumption.
Lifted for the rate of drying to water-based nano transparent insulating coating to improve the performance of film, there is human hair
Understand aqueous UV nano transparent insulating coatings, it is desirable to by the quick-setting advantages of UV improving water nano transparent heat insulating dope
Rate of drying so as to improve the quality of film, such as：
(1) patent CN200810243965.8 discloses a kind of preparation side of transparent heat-insulated UV-curable waterborne coatings
Method, the coating of the invention emulsifies the groups such as composite modified heat insulation nano slurry, light trigger and coating additive by aqueous UV prepolymers
Into the coating by the way of spraying or blade coating, using ultraviolet radiation-curable film forming, is capable of achieving automation with water as solvent
Streamline application, easy construction, and film have the features such as good weatherability, hardness are high, adhesive force is strong.
(2) patent CN201010121712.0 discloses a kind of nano combined painting of aqueous energy-saving heat-insulating of uV curable
Material and preparation method thereof, prepared nano composite dope curing rate is fast, mechanical property is good, can be used as automobile or building glass
The thermal insulation protection coating of glass.
(3) patent CN201210245086.5 discloses a kind of water-based ultraviolet (UV) curable full-shield nano transparent insulating coating,
The coating easily realizes automatic assembly line application, and easy construction, curing rate is fast, and production efficiency is high.
Although aqueous UV nano transparent insulating coatings have relative to water-based nano transparent insulating coating and easily realize automatically
The advantages of changing streamline application, easy construction, fast curing rate, but due to containing substantial amounts of hydrophilic radical in film, film
Water resistance is poor, and weather resistance is not good enough during long-term use.Pure UV nano transparent insulating coatings are that most have uncommon at present
Prestige can provide the excellent water resistance of film, weatherability, and easily realize that automatic assembly line application, easy construction, observable index are high
Excellent combination property nano transparent insulating coating.Such as：
(1) patent CN201010620331.7 disclose a kind of good heat-insulation effect ultraviolet and electronic beam curing nanometer thoroughly
Bright insulating moulding coating.The various aspects of performance of the UV nano transparent insulating coatings of the invention not only film is excellent and can be in process of production
Reducing energy consumption, improve production efficiency, so as to be more suitable for industrialized production.
(2) patent CN201310560344.3 discloses a kind of nano heat-insulating ultraviolet-cured paint, the coating through it is long when
Between absorb heat and will not also ftracture, with good effect of heat insulation.
At present, the research overwhelming majority of nano transparent insulating coating concentrates on achromaticity field, it has been disclosed that color nano
Transparent heat insulating dope technology based on water-based system, such as：
(1) patent CN200910039512.8 discloses a kind of colored and transparent heat-insulating energy-saving protecting function coating and its system
Method is made, which imparts the function that coloring pigment has strong reflection infrared ray and ultraviolet.
(2) patent CN201410403376.7 discloses a kind of hydrate colour transparent heat insulating dope and preparation method and uses
Method, the coating has good adhesive force on the surface such as glass and plastic sheeting, and hardness is high, resistance to ag(e)ing is excellent, heat-insulated
Effect is good.
In summary analyze, the present invention proposes a kind of new UV curing chromatic nano transparent insulating coatings, further opens up
The species of UV nano transparent insulating coatings has been opened up, the demand of market diversification has been met.
The content of the invention
A kind of UV curing chromatics nano transparent insulating coating, it includes base-material, coating additive, reactive diluent, light-initiated
Agent, wherein described base-material is made up of UV resin oligomers, the heat-insulated powder of inorganic nano, colour developing component.
Further, the inorganic nanometer powder be selected from nanometer antimony oxide tin, nano-indium stannum oxide, nano titanium oxide,
Nano silicon, nano zine oxide, nanometer alchlor, nanometer di-iron trioxide.Above goods producer：The scape of Hangzhou ten thousand is new
Materials Co., Ltd, Nanjing Tian Hang new materials Co., Ltd.
Further, the particle size range of the inorganic nano-particle powder is 10~100 nanometers
Further, the UV resin oligomers be selected from polyacrylate, polyester acrylate, urethane acrylate,
Organic silicon modified polyurethane acrylate, organosilicon modified polyester acrylate, organosilicon-modified acrylate, epoxy acrylic
Ester, organic silicon modified epoxy acrylate.Above goods producer：Jiangsu Litian Technology Co., Ltd.
Further, the colour developing component is selected from organic dyestuff, inorganic pigment, color essence.Above goods producer：Shenzhen
Heng Hui nanosecond science and technology Co., Ltd, Xinxiang County roc is in chemical industry Co., Ltd etc..
Further, the inorganic nanometer powder accounts for the 3~55% of the base-material gross weight.
Further, the colour developing component accounts for the 1~10% of the base-material gross weight.
Further, the base-material is UV resin oligomers, colour developing component and inorganic nanometer powder by dispersion system at a high speed
Standby, it is by accounting for the UV resin oligomers of base-material gross weight 45~75%, 1~10% colour developing component, 3~55% inorganic receiving
Ground rice body is constituted.
Further, the insulating moulding coating is helped by accounting for the base-material of coating gross weight 50~85%, 1~18% coating
Agent, 10~60% reactive diluent, 1~17% light trigger composition.
Further, the coating additive is selected from levelling agent, defoamer, UV absorbers, light-initiated accelerator, plasticising
Agent.
Further, described reactive diluent is selected from hexanediyl ester, three polypropyleneglycol diacrylates, three
Hydroxymethyl-propane triacrylate, tetramethylol methane tetraacrylate.Above goods producer：Jiangsu Litian Technology Co., Ltd,
Its function is to participate in UV or electronic beam curing while dope viscosity is adjusted to adjust the crosslink density of paint film.
Further, described initiator can be any initiator for UV solidifications, such as trade name：1- hydroxyls
Phenylcyclohexyl ketone, 2- hydroxy-2-methyl -1- phenyl -1- acetone, benzophenone, benzoin dimethylether etc..Above commodity are manufactured
Business's Ciba.
Present invention also offers a kind of heat-insulated paint film of colourful transparent, it is characterised in that the paint film is above-mentioned colourful transparent
Insulating moulding coating is sprayed or brushed and obtained through UV solidifications in glass surface, in wherein UV solidification the energy range of UV 500~
1500mj/cm2, the wherein transporting velocity of glass is 20~40m/min.
Compared with prior art, the beneficial effects of the invention are as follows：By low energy in UV cured coating films function admirable, production process
Consumption, production efficiency advantage high and rainbow member combine, and meet market diversified for nano transparent insulating coating
Demand.
Specific embodiment
With reference to specific embodiment, the present invention is described in further detail, but this should not be interpreted as into of the invention
Protection domain is only limitted to the following example.
Embodiment 1
To account for coating gross weight than the organic silicon modified polyurethane acrylate for 36%, 10% nanometer antimony oxide tin,
5% nano zine oxide, 3% nano aluminium oxide, the essence mixing of 6% large red, 1000 revs/min are disperseed 30 minutes at a high speed,
Add 0.5% polysiloxane leveling agents, 0.5% polysiloxane compound defoamer, 35% hexanediyl
Ester activated diluting agent and 4% 2- hydroxy-2-methyl -1- phenyl -1- acetone light trigger are well mixed, and UV-curable is obtained
Large red transparent heat insulating dope.The coating is sprayed on glass plate to carry out UV solidifications (energy range is 880mj/cm2, conveying
Speed is 30m/min) obtain the glass that red thermal insulation layer is contained on surface.
Embodiment 2
Coating gross weight will be accounted for than the urethane acrylate for 30%, 10% nanometer antimony oxide tin, 5% nano oxygen
Change zinc, 5% yellow color essence mixing, 1000 revs/min at a high speed dispersion 30 minutes, add 0.5% polysiloxane leveling agents,
0.5% polysiloxane compound defoamer, 45% hexanediyl ester reactive diluent and 4% 2- hydroxyls -2-
Methyl isophthalic acid-phenyl -1- acetone light trigger is well mixed, and the yellow transparent insulating moulding coating of UV-curable is obtained.By coating spray
Being applied on glass plate carries out UV solidifications (energy range is 1000mj/cm2, transporting velocity is 30m/min) obtain surface and contain Huang
The glass of color thermal insulation layer.
Embodiment 3
Coating gross weight will be accounted for than the urethane acrylate for 35%, 10% nanometer antimony oxide tin, 10% nanometer
Zinc oxide, 8% nanometer di-iron trioxide, the essence mixing of 7% yellow color, 1000 revs/min are disperseed 30 minutes at a high speed, are added
1.5% polysiloxane leveling agents, 0.5% polysiloxane compound defoamer, 25% hexanediyl ester activity
Diluent and 4% 2- hydroxy-2-methyl -1- phenyl -1- acetone light trigger are well mixed, and the yellow that UV-curable is obtained is saturating
Bright insulating moulding coating.The coating is sprayed on glass plate to carry out UV solidifications (energy range is 1000mj/cm2, transporting velocity is
30m/min) obtain the glass that yellow thermal insulation layer is contained on surface.
The effect of heat insulation of test example 1 is tested
The colored heat-protecting glass that embodiment is obtained is put into the Constant Temperature Detection case with identical thermal source with common white glass
It is thermally shielded measure of merit, the actual temperature difference of the glass of insulating moulding coating and common white glass is between 5~10 DEG C, it is seen that the present invention
Insulating moulding coating effect of heat insulation clearly.
The technical indicator of the paint film that test example 2 is coated with by colored insulating moulding coating of the invention is detected
According to the conventional detection method in this area, detect that every paint film of color nano insulating moulding coating coating of the invention refers to
Mark.Testing result is as shown in the table, it is seen that insulating moulding coating of the invention meets national standard, with very superior performance.
Compared with prior art, the beneficial effects of the invention are as follows：By low energy in UV cured coating films function admirable, production process
Consumption, production efficiency advantage high and rainbow member combine, and meet market diversified for nano transparent insulating coating
Demand.
Claims (10)
1. a kind of UV curing chromatics nano transparent insulating coating, it is characterised in that it includes base-material, coating additive, activity dilution
Agent, light trigger, wherein described base-material is made up of UV resin oligomers, the heat-insulated powder of inorganic nano, colour developing component.
2. UV curing chromatics nano transparent insulating coating according to claim 1, it is characterised in that the inorganic nanometer-powder
Body is selected from nanometer antimony oxide tin, nano-indium stannum oxide, nano titanium oxide, nano silicon, nano zine oxide, the oxygen of nanometer three
Change aluminium, nanometer di-iron trioxide.
3. UV curing chromatics nano transparent insulating coating according to claim 1, it is characterised in that the inorganic nano-particle
The particle size range of powder is 10~100 nanometers.
4. UV curing chromatics nano transparent insulating coating according to claim 1, it is characterised in that the UV resins are oligomeric
Thing is selected from polyacrylate, polyester acrylate, urethane acrylate, organic silicon modified polyurethane acrylate, organosilicon
Modified polyester acrylate ester, organosilicon-modified acrylate, epoxy acrylate, organic silicon modified epoxy acrylate.
5. UV curing chromatics nano transparent insulating coating according to claim 1, it is characterised in that the colour developing component choosing
From organic dyestuff, inorganic pigment, color essence.
6. UV curing chromatics nano transparent insulating coating according to claim 1, it is characterised in that the inorganic nanometer-powder
Body accounts for the 3~25% of the base-material gross weight.
7. UV curing chromatics nano transparent insulating coating according to claim 1, it is characterised in that the colour developing component is accounted for
The 1~10% of the base-material gross weight.
8. UV curing chromatics nano transparent insulating coating according to claim 1, it is characterised in that the base-material is UV trees
Fat oligomer, colour developing component and inorganic nanometer powder are prepared by dispersion at a high speed, and it is by accounting for base-material gross weight 45~75%
UV resin oligomers, 1~10% colour developing component, 3~55% inorganic nanometer powder composition.
9. UV curing chromatics nano transparent insulating coating according to claim 1, it is characterised in that the insulating moulding coating is
By accounting for the base-material of coating gross weight 50~85%, 1~18% coating additive, 10~60% reactive diluent, 1~17%
Light trigger is constituted.
10. the heat-insulated paint film of a kind of colourful transparent, it is characterised in that the paint film is the heat-insulated painting of colourful transparent as described in right 1
Material spraying brushes what is obtained through UV solidifications in glass surface.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201710009513.2A CN106752193A (en) | 2017-01-06 | 2017-01-06 | A kind of preparation of UV curing chromatics nano transparent insulating coating |
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| CN201710009513.2A CN106752193A (en) | 2017-01-06 | 2017-01-06 | A kind of preparation of UV curing chromatics nano transparent insulating coating |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107641454A (en) * | 2017-08-24 | 2018-01-30 | 张家港康得新光电材料有限公司 | Anti- precipitation PET optical thin films and its application |
| CN107936817A (en) * | 2017-11-13 | 2018-04-20 | 惠州市李唐科技发展有限公司 | A kind of nano water-proof is heat-insulated to reinforce liquid and its application method |
| CN109266206A (en) * | 2018-09-21 | 2019-01-25 | 佛山皖和新能源科技有限公司 | A kind of preparation method of nanometer heat isolation paint |
| CN109777283A (en) * | 2018-11-28 | 2019-05-21 | 湖南阳光新材料有限公司 | A kind of glass screen protective glue of ultra-violet curing |
| CN110527331A (en) * | 2019-05-28 | 2019-12-03 | 无锡海特圣大光电材料科技有限公司 | A kind of compound polyurethane material door and window UV frosted coating and preparation method |
| CN110669400A (en) * | 2019-09-22 | 2020-01-10 | 珠海东胜科技有限公司 | Ultraviolet-curing heat-insulating automobile glass coating and preparation method and application thereof |
| CN115403795A (en) * | 2022-07-19 | 2022-11-29 | 北京化工大学 | Optical film with enhanced color rendering and preparation method thereof |
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| CN101629040A (en) * | 2009-07-13 | 2010-01-20 | 黎源 | Transparent heat insulation coating with nanoparticles and preparation method thereof |
| CN102120900A (en) * | 2011-04-13 | 2011-07-13 | 高建宾 | Ultraviolet curing nano transparent heat-insulating composite coating |
| CN104789110A (en) * | 2015-05-12 | 2015-07-22 | 浙江纳美新材料股份有限公司 | Pigment-type UV curable coating for window film and preparation method of pigment-type UV curable coating |
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2017
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Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101629040A (en) * | 2009-07-13 | 2010-01-20 | 黎源 | Transparent heat insulation coating with nanoparticles and preparation method thereof |
| CN102120900A (en) * | 2011-04-13 | 2011-07-13 | 高建宾 | Ultraviolet curing nano transparent heat-insulating composite coating |
| CN104789110A (en) * | 2015-05-12 | 2015-07-22 | 浙江纳美新材料股份有限公司 | Pigment-type UV curable coating for window film and preparation method of pigment-type UV curable coating |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107641454A (en) * | 2017-08-24 | 2018-01-30 | 张家港康得新光电材料有限公司 | Anti- precipitation PET optical thin films and its application |
| CN107936817A (en) * | 2017-11-13 | 2018-04-20 | 惠州市李唐科技发展有限公司 | A kind of nano water-proof is heat-insulated to reinforce liquid and its application method |
| CN109266206A (en) * | 2018-09-21 | 2019-01-25 | 佛山皖和新能源科技有限公司 | A kind of preparation method of nanometer heat isolation paint |
| CN109777283A (en) * | 2018-11-28 | 2019-05-21 | 湖南阳光新材料有限公司 | A kind of glass screen protective glue of ultra-violet curing |
| CN110527331A (en) * | 2019-05-28 | 2019-12-03 | 无锡海特圣大光电材料科技有限公司 | A kind of compound polyurethane material door and window UV frosted coating and preparation method |
| CN110669400A (en) * | 2019-09-22 | 2020-01-10 | 珠海东胜科技有限公司 | Ultraviolet-curing heat-insulating automobile glass coating and preparation method and application thereof |
| CN115403795A (en) * | 2022-07-19 | 2022-11-29 | 北京化工大学 | Optical film with enhanced color rendering and preparation method thereof |
| CN115403795B (en) * | 2022-07-19 | 2024-02-06 | 北京化工大学 | Optical film with enhanced color development and preparation method thereof |
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Application publication date: 20170531 |